Material Safety Data Sheet Date Prepared 3/2000 Product Number: 6000,6001,6002,6003,6004,6005,6006,6065

Transcription

1 Material Safety Data Sheet Date Prepared 3/2000 Product Number: 6000,6001,6002,6003,6004,6005,6006,6065 Section 1: Manufacturer Identification Mason Color Works, Inc. Phone: (330) East 2 nd Street/P.O. Box 76 Fax: (330) East Liverpool, OH Section 2: Identification of Product Chemical Family: Inorganic Product Names: Shell Pink 6000, Alpine Rose 6001, Rose Pink 6002, Crimson 6003, Crimson 6004, Deep Crimson 6005, Deep Crimson 6006, Pink Extender, 6067 Chemical Abstract Number (CAS): Chemical Name: Chrome Tin Pink Sphene Chemical Formula: CaO,SnO.SiO 2 : Cr 2 O 3 Section 3 & Section 4: Hazardous ingredients Identity/Information and Overexposure Symptoms ACGIH-TLVs OSHA PELs NOISHA RELs Chrome Oxide (Cr 2 O 3 ) 0.5 mg/m mg/m mg/m 3 Cas # ACGIH: Not classifiable as a human carcinogen: Inadequate data on which to classify the agent in terms of carcinogencity in humans/animals. Inhalation: Repeated prolonged exposure to trivalent compounds may cause delayed effects involving the respiratory system. Eye Contact: mechanical irritation to the eye may occur such as watering, reddening de to exposure to fines. Skin Contact: Expected to be non irritating. Ingestion: Considered to be non-irritating, non-toxic if swallowed. Silica, Crystalline (SiO 2 ) 0.1 mg/m 3 10 mg/m mg/m 3 Cas # SiO Inhalation: a) Prolonged exposure to respirable crystalline silica (quartz) can cause Silicosis, a fibrosis (scarring) of the lungs. Silicosis may be progressive; it may lead to disability and death. Silicosis increases risk of Tuberculosis. b) Inhaled from occupational sources is classified as carcinogenic to humans. (cancer) c) There is evidence that exposure to respirable crystalline silica or that the disease Silicosis is associated with increased incidence of Sceroderma, an auto-immune disorder manifested by fibrosis (scarring) of the skin and internal organs. d) There are several studies suggesting that exposure to respirable silica or that the disease Silicosis is associated with the increased incidence of kidney disorders. (Nephrotoxicity) Eye Contact: May cause abrasions of the cornea. Skin Contact: Not applicable. Ingestion: Not applicable. 1

2 Section 3 & Section 4: Hazardous ingredients Identity/Information and Overexposure Symptoms Continued ACGIH-TLVs OSHA PELs NOISHA RELs Tin Oxide (SnO) 2.0 mg/m mg/m mg/m 3 Cas # Inhalation: No information found on acute overexposure. Chronic exposure to tin oxide fumes or dust may result in Stannosis, a form of Phenumoconiosis. Eye Contact: Abrasive, mild irritant Skin Contact: Possible irritant. Ingestion: Considered non-toxic. Section 5: Emergency and First Aid Procedures: Eye: flush thoroughly with water for 15 minutes. Skin: remove contaminated clothing, wash thoroughly with soap and water. Inhalation: remove to fresh air, may give oxygen if needed. Ingestion: give large amounts of water to induce vomiting, only in conscious persons. IF THESE FIRST AID MEASURES FAIL, CONSULT PHYSICIAN!!!!!!!!!!!!!!!!!!! Principal Routes of Entry: Inhalation: Dust from this product may cause irritation of the respiratory system. Overexposure may cause lung damage. Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Skin & Eye: Nuisance dust, prolonged or repeated may cause irritation. Section 6: Special Protection Information Respiratory Protection: Use only NIOSHA/OSHA approved respiratory protection with adequate ventilation; avoid breathing dust. Do not exceed Occupational Exposure Limits. Wash thoroughly after handling. No food or beverage should be consumed in work area. Personal Protective Equip: Wear appropriate gloves and goggles to avoid skin and eye contact. Safety showers and eye stations must be present in work stations. Ventilation: Use local exhaust or mechanical such as a dust collector to maintain dust levels below Occupational Exposure Limits. Section 7: Physical and Chemical Characteristics Boiling Point: N/A Solubility in water: trace Vapor Pressure (mmhg): N/A Vapor Density (air=1): N/A Appearance: Pink Powder Odor: oderless Specific Gravity (water=1): N/A Evaporation rate: None % Volatile by volume: None Section 8: Reactivity Data Stability: Stable Hazardous Polymerization: will not occur Incompatibility: None Hazard Decomposition of product: N/A 2

3 Section 9: Fire and Explosive Data Flash point: N/A Flammable Limits: None Unusual Fire and Explosion Hazard: None expected Extinguishing Media: Carbon dioxide, dry chemical or water Special Fire Fighting Procedures: Wear self contained breathing apparatus when large quantities involved. Section 10: Spill or Leak Procedures: Contain spillage and scoop or vaccum. Avoid making dust, put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. This product is a blend of various metal oxides, salts and some compounds which are interfused by high calcination to form the finished product. Section III, Hazardous Ingredients Identity/Information, and Section IV, Symptoms of Overexposure, pertain to individual components. Section V through Section X are in reference to the finished product. **************Attention All Retailers of Mason Stains************** ALL retailers of this product are REQUIRED by law to supply their customers with a copy of this material safety data sheet with initial purchase. ***SARA 313 This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this Material Safety Data Sheet must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before using this material. PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MATERIAL SAFETY DATA SHEETS ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT OR BY REQUEST. DISCLAMER Mason Color Works, Inc. believes the information contained in this material safety data sheet is believed to be accurate and reliable as of the date of publication or revision but makes no warranty that it is. This information provided should be made available as required by the Federal OSHA Hazard Communication Standard to ANYONE who handles, uses, stores, transports or will otherwise be exposed to this product. Mason Color Works, Inc. Accepts no Responsibility for the health or safety of any individual who misuses this product by not complying with manufacturer s instructions contained herein or additional /other measures that may be required under particular conditions. Last issued: 11/97 Updated : 3/2000 3

4 Material Safety Data Sheet Date Prepared 3/2000 Product Number: 6007, 6008, 6090 Section 1: Manufacturer Identification Mason Color Works, Inc. Phone: (330) East 2 nd Street/P.O. Box 76 Fax: (330) East Liverpool, OH Section 2: Identification of Product Chemical Family: Inorganic Product Names: Peach 6007, Peach 6008, Coral 6090 Chemical Abstract Number (CAS): , Chemical Name: Chrome Tin Vanadium Coral Chemical Formula: Ca.SnO.SiO 2.Cr 2 O 3 + (Sn,V) 2 Section 3 & Section 4: Hazardous ingredients Identity/Information and Overexposure Symptoms ACGIH-TLVs OSHA PELs NOISHA RELs Chrome Oxide (Cr 2 O 3 ) 0.5 mg/m mg/m mg/m 3 Cas # ACGIH: Not classifiable as a human carcinogen: Inadequate data on which to classify the agent in terms of carcinogencity in humans/animals. Inhalation: Repeated prolonged exposure to trivalent compounds may cause delayed effects involving the respiratory system. Eye Contact: mechanical irritation to the eye may occur such as watering, reddening de to exposure to fines. Skin Contact: Expected to be non irritating. Ingestion: Considered to be non-irritating, non-toxic if swallowed. Silica, Crystalline (SiO 2 ) 0.1 mg/m 3 10 mg/m mg/m 3 Cas # SiO Inhalation: a) Prolonged exposure to respirable crystalline silica (quartz) can cause Silicosis, a fibrosis (scarring) of the lungs. Silicosis may be progressive; it may lead to disability and death. Silicosis increases risk of Tuberculosis. b) Inhaled from occupational sources is classified as carcinogenic to humans. (cancer) c) There is evidence that exposure to respirable crystalline silica or that the disease Silicosis is associated with increased incidence of Sceroderma, an auto-immune disorder manifested by fibrosis (scarring) of the skin and internal organs. d) There are several studies suggesting that exposure to respirable silica or that the disease Silicosis is associated with the increased incidence of kidney disorders. (Nephrotoxicity) Eye Contact: May cause abrasions of the cornea. Skin Contact: Not applicable. Ingestion: Not applicable. 1

5 Section 3 & Section 4: Hazardous ingredients Identity/Information and Overexposure Symptoms Continued Tin Oxide (SnO) 2.0 mg/m mg/m mg/m 3 Cas # Inhalation: No information found on acute overexposure. Chronic exposure to tin oxide fumes or dust may result in Stannosis, a form of Phenumoconiosis. Eye Contact: Abrasive, mild irritant Skin Contact: Possible irritant. Ingestion: Considered non-toxic. Vanadium Oxide (VO 3 ) 0.05 mg/m mg/m mg/m 3 Cas # Inhalation: Irritation of the respiratory tract, chest tightness, wheezing, coughing. Eye Contact: Irritation possible with corneal injury. Skin Contact: Irritation with reddening and itching. Absorption of harmful amounts possible. Ingestion: Abdominal discomfort, nausea, vomiting, cramping. Harmless greenish tongue discoloration. Section 5: Emergency and First Aid Procedures: Eye: flush thoroughly with water for 15 minutes. Skin: remove contaminated clothing, wash thoroughly with soap and water. Inhalation: remove to fresh air, may give oxygen if needed. Ingestion: give large amounts of water to induce vomiting, only in conscious persons. IF THESE FIRST AID MEASURES FAIL, CONSULT PHYSICIAN!!!!!!!!!!!!!!!!!!! Principal Routes of Entry: Inhalation: Dust from this product may cause irritation of the respiratory system. Overexposure may cause lung damage. Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Skin & Eye: Nuisance dust, prolonged or repeated may cause irritation. Section 6: Special Protection Information Respiratory Protection: Use only NIOSHA/OSHA approved respiratory protection with adequate ventilation; avoid breathing dust. Do not exceed Occupational Exposure Limits. Wash thoroughly after handling. No food or beverage should be consumed in work area. Personal Protective Equip: Wear appropriate gloves and goggles to avoid skin and eye contact. Safety showers and eye stations must be present in work stations. Ventilation: Use local exhaust or mechanical such as a dust collector to maintain dust levels below Occupational Exposure Limits. Section 7: Physical and Chemical Characteristics Boiling Point: N/A Solubility in water: trace Vapor Pressure (mmhg): N/A Vapor Density (air=1): N/A Appearance: Peach Powder Odor: oderless Specific Gravity (water=1): N/A Evaporation rate: None % Volatile by volume: None 2

6 Section 8: Reactivity Data Stability: Stable Hazardous Polymerization: will not occur Incompatibility: None Hazard Decomposition of product: N/A Section 9: Fire and Explosive Data Flash point: N/A Flammable Limits: None Unusual Fire and Explosion Hazard: None expected Extinguishing Media: Carbon dioxide, dry chemical or water Special Fire Fighting Procedures: Wear self contained breathing apparatus when large quantities involved. Section 10: Spill or Leak Procedures: Contain spillage and scoop or vaccum. Avoid making dust, put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. This product is a blend of various metal oxides, salts and some compounds which are interfused by high calcination to form the finished product. Section III, Hazardous Ingredients Identity/Information, and Section IV, Symptoms of Overexposure, pertain to individual components. Section V through Section X are in reference to the finished product. **************Attention All Retailers of Mason Stains************** ALL retailers of this product are REQUIRED by law to supply their customers with a copy of this material safety data sheet with initial purchase. ***SARA 313 This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this Material Safety Data Sheet must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before using this material. PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MATERIAL SAFETY DATA SHEETS ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT OR BY REQUEST. DISCLAMER Mason Color Works, Inc. believes the information contained in this material safety data sheet is believed to be accurate and reliable as of the date of publication or revision but makes no warranty that it is. This information provided should be made available as required by the Federal OSHA Hazard Communication Standard to ANYONE who handles, uses, stores, transports or will otherwise be exposed to this product. Mason Color Works, Inc. Accepts no Responsibility for the health or safety of any individual who misuses this product by not complying with manufacturer s instructions contained herein or additional /other measures that may be required under particular conditions. Last issued: 11/97 Updated : 3/2000 3

7 Material Safety Data Sheet Date Prepared 3/2000 Product Number: 6009,6023,6098 Section 1: Manufacturer Identification Mason Color Works, Inc. Phone: (330) East 2 nd Street/P.O. Box 76 Fax: (330) East Liverpool, OH Section 2: Identification of Product Chemical Family: Inorganic Product Names: Coral 6009, Clover Pink 6023, Flesh 6098 Chemical Abstract Number (CAS): , Chemical Name: Chrome Tin Vanadium Coral Chemical Formula: CaO.SnO.SiO 2 :Cr 2 O 3 + (Zr,V) 2 Section 3 & Section 4: Hazardous ingredients Identity/Information and Overexposure Symptoms ACGIH-TLVs OSHA PELs NOISHA RELs Chrome Oxide (Cr 2 O 3 ) 0.5 mg/m mg/m mg/m 3 Cas # ACGIH: Not classifiable as a human carcinogen: Inadequate data on which to classify the agent in terms of carcinogencity in humans/animals. Inhalation: Repeated prolonged exposure to trivalent compounds may cause delayed effects involving the respiratory system. Eye Contact: mechanical irritation to the eye may occur such as watering, reddening de to exposure to fines. Skin Contact: Expected to be non irritating. Ingestion: Considered to be non-irritating, non-toxic if swallowed. Silica, Crystalline (SiO 2 ) 0.1 mg/m 3 10 mg/m mg/m 3 Cas # SiO Inhalation: a) Prolonged exposure to respirable crystalline silica (quartz) can cause Silicosis, a fibrosis (scarring) of the lungs. Silicosis may be progressive; it may lead to disability and death. Silicosis increases risk of Tuberculosis. b) Inhaled from occupational sources is classified as carcinogenic to humans. (cancer) c) There is evidence that exposure to respirable crystalline silica or that the disease Silicosis is associated with increased incidence of Sceroderma, an auto-immune disorder manifested by fibrosis (scarring) of the skin and internal organs. d) There are several studies suggesting that exposure to respirable silica or that the disease Silicosis is associated with the increased incidence of kidney disorders. (Nephrotoxicity) Eye Contact: May cause abrasions of the cornea. Skin Contact: Not applicable. Ingestion: Not applicable. 1

8 Section 3 & Section 4: Hazardous ingredients Identity/Information and Overexposure Symptoms Continued Tin Oxide (SnO) 2.0 mg/m mg/m mg/m 3 Cas # Inhalation: No information found on acute overexposure. Chronic exposure to tin oxide fumes or dust may result in Stannosis, a form of Phenumoconiosis. Eye Contact: Abrasive, mild irritant Skin Contact: Possible irritant. Ingestion: Considered non-toxic. Vanadium Oxide (VO 3 ) 0.05 mg/m mg/m mg/m 3 Cas # Inhalation: Irritation of the respiratory tract, chest tightness, wheezing, coughing. Eye Contact: Irritation possible with corneal injury. Skin Contact: Irritation with reddening and itching. Absorption of harmful amounts possible. Ingestion: Abdominal discomfort, nausea, vomiting, cramping. Harmless greenish tongue discoloration. Zirconium Oxide (ZnO) 10 mg/m 3 (total) 15 mg/m 3 (total) 5 mg/m 3 Cas # mg/m 3 (respirable) 5 mg/m 3 (respirable) 15 min. C Inhalation: Acute inhalation to respirable dust which contains radioactive uranium, tohium and radium may cause lung cancer. Eye Contact: May cause irritation with discomfort, tearing or blurring of vision. Skin Contact: Not applicable. Section 5: Emergency and First Aid Procedures: Eye: flush thoroughly with water for 15 minutes. Skin: remove contaminated clothing, wash thoroughly with soap and water. Inhalation: remove to fresh air, may give oxygen if needed. Ingestion: give large amounts of water to induce vomiting, only in conscious persons. IF THESE FIRST AID MEASURES FAIL, CONSULT PHYSICIAN!!!!!!!!!!!!!!!!!!! Principal Routes of Entry: Inhalation: Dust from this product may cause irritation of the respiratory system. Overexposure may cause lung damage. Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Skin & Eye: Nuisance dust, prolonged or repeated may cause irritation. 2

9 Section 6: Special Protection Information Respiratory Protection: Use only NIOSHA/OSHA approved respiratory protection with adequate ventilation; avoid breathing dust. Do not exceed Occupational Exposure Limits. Wash thoroughly after handling. No food or beverage should be consumed in work area. Personal Protective Equip: Wear appropriate gloves and goggles to avoid skin and eye contact. Safety showers and eye stations must be present in work stations. Ventilation: Use local exhaust or mechanical such as a dust collector to maintain dust levels below Occupational Exposure Limits. Section 7: Physical and Chemical Characteristics Boiling Point: N/A Solubility in water: trace Vapor Pressure (mmhg): N/A Vapor Density (air=1): N/A Appearance: coral powder Odor: oderless Specific Gravity (water=1): N/A Evaporation rate: None % Volatile by volume: None Section 8: Reactivity Data Stability: Stable Hazardous Polymerization: will not occur Incompatibility: None Hazard Decomposition of product: N/A Section 9: Fire and Explosive Data Flash point: N/A Flammable Limits: None Unusual Fire and Explosion Hazard: None expected Extinguishing Media: Carbon dioxide, dry chemical or water Special Fire Fighting Procedures: Wear self contained breathing apparatus when large quantities involved. Section 10: Spill or Leak Procedures: Contain spillage and scoop or vaccum. Avoid making dust, put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. This product is a blend of various metal oxides, salts and some compounds which are interfused by high calcination to form the finished product. Section III, Hazardous Ingredients Identity/Information, and Section IV, Symptoms of Overexposure, pertain to individual components. Section V through Section X are in reference to the finished product. **************Attention All Retailers of Mason Stains************** ALL retailers of this product are REQUIRED by law to supply their customers with a copy of this material safety data sheet with initial purchase. 3

10 **SARA 313 This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this Material Safety Data Sheet must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before using this material. PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MATERIAL SAFETY DATA SHEETS ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT OR BY REQUEST. DISCLAMER Mason Color Works, Inc. believes the information contained in this material safety data sheet is believed to be accurate and reliable as of the date of publication or revision but makes no warranty that it is. This information provided should be made available as required by the Federal OSHA Hazard Communication Standard to ANYONE who handles, uses, stores, transports or will otherwise be exposed to this product. Mason Color Works, Inc. Accepts no Responsibility for the health or safety of any individual who misuses this product by not complying with manufacturer s instructions contained herein or additional /other measures that may be required under particular conditions. Last issued: 11/97 Updated : 3/2000 4

11 Material Safety Data Sheet Date Prepared 3/2000 Product Number: 6020 Section 1: Manufacturer Identification Mason Color Works, Inc. Phone: (330) East 2 nd Street/P.O. Box 76 Fax: (330) East Liverpool, OH Section 2: Identification of Product Chemical Family: Inorganic Product Names: Manganese Alumina Pink 6020 Chemical Abstract Number (CAS): Chemical Name: Manganese Alumina Pink - Corundum Chemical Formula: (Al,Mn) 2 O 3 Section 3 & Section 4: Hazardous ingredients Identity/Information and Overexposure Symptoms ACGIH-TLVs OSHA PELs NOISHA RELs Alumina Oxide (Al 2 O 3 ) 10 mg/mg 3 (total) 15 mg/m 3 (total) N/A Cas # mg/m 3 (respirable) ACGIH: The value for particulate matter containing no asbestos and 1% crystalline silica. Inhalation: Acute may cause coughing and shortness of breath. Chronic may adversely effect breathing capacity. Eye Contact: Direct contact may cause irritation. Skin Contact: May cause abrasions. Ingestion: May cause irritation. Manganese Compound (Mn) 0.2 mg/m 3 5 mg/m mg/m 3 Cas # mg/m 3 Inhalation: Elemental Manganese fume and dust, when in high concentrations, may adversely affect the central nervous system with symptoms including langour, sleepiness, weakness, emotional disturbances, spastic gait, mash-like facial expressions and paralysis. Eye Contact: May cause irritation, if persists call doctor. Skin Contact: May cause abrasions. Ingestion: In high concentrations if swallowed may cause systemic poisoning. Silica, Crystalline (SiO 2 ) 0.1 mg/m 3 10 mg/m mg/m 3 Cas # SiO

12 Silica,Crystalline cont d Inhalation: a) Prolonged exposure to respirable crystalline silica (quartz) can cause Silicosis, a fibrosis (scarring) of the lungs. Silicosis may be progressive; it may lead to disability and death. Silicosis increases risk of Tuberculosis. b) Inhaled from occupational sources is classified as carcinogenic to humans. (cancer) c) There is evidence that exposure to respirable crystalline silica or that the disease Silicosis is associated with increased incidence of Sceroderma, an auto-immune disorder manifested by fibrosis (scarring) of the skin and internal organs. d) There are several studies suggesting that exposure to respirable silica or that the disease Silicosis is associated with the increased incidence of kidney disorders. (Nephrotoxicity) Eye Contact: May cause abrasions of the cornea. Skin Contact: Not applicable. Ingestion: Not applicable. Section 5: Emergency and First Aid Procedures: Eye: flush thoroughly with water for 15 minutes. Skin: remove contaminated clothing, wash thoroughly with soap and water. Inhalation: remove to fresh air, may give oxygen if needed. Ingestion: give large amounts of water to induce vomiting, only in conscious persons. IF THESE FIRST AID MEASURES FAIL, CONSULT PHYSICIAN!!!!!!!!!!!!!!!!!!! Principal Routes of Entry: Inhalation: Dust from this product may cause irritation of the respiratory system. Overexposure may cause lung damage. Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Skin & Eye: Nuisance dust, prolonged or repeated may cause irritation. Section 6: Special Protection Information Respiratory Protection: Use only NIOSHA/OSHA approved respiratory protection with adequate ventilation; avoid breathing dust. Do not exceed Occupational Exposure Limits. Wash thoroughly after handling. No food or beverage should be consumed in work area. Personal Protective Equip: Wear appropriate gloves and goggles to avoid skin and eye contact. Safety showers and eye stations must be present in work stations. Ventilation: Use local exhaust or mechanical such as a dust collector to maintain dust levels below Occupational Exposure Limits. Section 7: Physical and Chemical Characteristics Boiling Point: N/A Solubility in water: trace Vapor Pressure (mmhg): N/A Vapor Density (air=1): N/A Appearance: pink powder Odor: oderless Specific Gravity (water=1): N/A Evaporation rate: None % Volatile by volume: None 2

13 Section 8: Reactivity Data Stability: Stable Hazardous Polymerization: will not occur Incompatibility: None Hazard Decomposition of product: N/A Section 9: Fire and Explosive Data Flash point: N/A Flammable Limits: None Unusual Fire and Explosion Hazard: None expected Extinguishing Media: Carbon dioxide, dry chemical or water Special Fire Fighting Procedures: Wear self contained breathing apparatus when large quantities involved. Section 10: Spill or Leak Procedures: Contain spillage and scoop or vaccum. Avoid making dust, put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. This product is a blend of various metal oxides, salts and some compounds which are interfused by high calcination to form the finished product. Section III, Hazardous Ingredients Identity/Information, and Section IV, Symptoms of Overexposure, pertain to individual components. Section V through Section X are in reference to the finished product. **************Attention All Retailers of Mason Stains************** ALL retailers of this product are REQUIRED by law to supply their customers with a copy of this material safety data sheet with initial purchase. ***SARA 313 This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this Material Safety Data Sheet must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before using this material. PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MATERIAL SAFETY DATA SHEETS ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT OR BY REQUEST. DISCLAMER Mason Color Works, Inc. believes the information contained in this material safety data sheet is believed to be accurate and reliable as of the date of publication or revision but makes no warranty that it is. This information provided should be made available as required by the Federal OSHA Hazard Communication Standard to ANYONE who handles, uses, stores, transports or will otherwise be exposed to this product. Mason Color Works, Inc. Accepts no Responsibility for the health or safety of any individual who misuses this product by not complying with manufacturer s instructions contained herein or additional /other measures that may be required under particular conditions. Last issued: 11/97 Updated : 3/2000 3

14 Material Safety Data Sheet Date Prepared 3/2000 Product Number: 6024,6025,6026,6027 Section 1: Manufacturer Identification Mason Color Works, Inc. Phone: (330) East 2 nd Street/P.O. Box 76 Fax: (330) East Liverpool, OH Section 2: Identification of Product Chemical Family: Inorganic Product Names: Orange 6024, Coral Red 6025, Lobster 6026, Tangerine 6027 Chemical Abstract Number (CAS): Chemical Name: Pigment & Silica mixture Section 3 & Section 4: Hazardous ingredients Identity/Information and Overexposure Symptoms ACGIH-TLVs OSHA PELs NOISHA RELs Cadmium Compound (Cd) 0.01 mg/m 3 (total).005 mg/m mg/m 3 Cas # mg/m 3 (respirable) ACGIH,OSHA,IARC,NTP consider various forms of cadmium are to be carcinogenic. Inhalation: Overexposure to Cd can result in metallic taste in mouth, headache, shortness of breath, chest pains, weakness, leg pains and fluid in the lung. These symptoms may be delayed, sometimes occurring 4 8 hrs. after exposure. Long term overexposure to cadmium fumes and dust have been associated with emphysema, bronchitis and kidney damage. Chronic overexposure to metal and cadmium compounds, such as cadmium oxide, cadmium sulfide, cadmium sulfate and cadmium chloride, may result in lung cancer, although a definite cause-effect relationship has not been fully established. Eye Contact: May cause irritation. Skin Contact: May cause irritation. Ingestion: Swallowing may result in severe nausea, vomiting, diarrhea, stomach cramps, salivation, headache, muscle cramps and dizziness. Silica, Crystalline (SiO 2 ) 0.1 mg/m 3 10 mg/m mg/m 3 Cas # SiO Inhalation: a) Prolonged exposure to respirable crystalline silica (quartz) can cause Silicosis, a fibrosis (scarring) of the lungs. Silicosis may be progressive; it may lead to disability and death. Silicosis increases risk of Tuberculosis. b) Inhaled from occupational sources is classified as carcinogenic to humans. (cancer) c) There is evidence that exposure to respirable crystalline silica or that the disease Silicosis is associated with increased incidence of Sceroderma, an auto-immune disorder manifested by fibrosis (scarring) of the skin and internal organs. d) There are several studies suggesting that exposure to respirable silica or that the disease Silicosis is associated with the increased incidence of kidney disorders. (Nephrotoxicity) Eye Contact: May cause abrasions of the cornea. Skin Contact: Not applicable. Ingestion: Not applicable. 1

15 Section 3 & Section 4: Hazardous ingredients Identity/Information and Overexposure Symptoms Continued Zirconium Oxide (ZnO) 10 mg/m 3 (total) 15 mg/m 3 (total) 5 mg/m 3 Cas # mg/m 3 (respirable) 5 mg/m 3 (respirable) 15 min. C Inhalation: Acute inhalation to respirable dust which contains radioactive uranium, tohium and radium may cause lung cancer. Eye Contact: May cause irritation with discomfort, tearing or blurring of vision. Skin Contact: Not applicable. Section 5: Emergency and First Aid Procedures: Eye: flush thoroughly with water for 15 minutes. Skin: remove contaminated clothing, wash thoroughly with soap and water. Inhalation: remove to fresh air, may give oxygen if needed. Ingestion: give large amounts of water to induce vomiting, only in conscious persons. IF THESE FIRST AID MEASURES FAIL, CONSULT PHYSICIAN!!!!!!!!!!!!!!!!!!! Principal Routes of Entry: Inhalation: Dust from this product may cause irritation of the respiratory system. Overexposure may cause lung damage. Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Skin & Eye: Nuisance dust, prolonged or repeated may cause irritation. Section 6: Special Protection Information Respiratory Protection: Use only NIOSHA/OSHA approved respiratory protection with adequate ventilation; avoid breathing dust. Do not exceed Occupational Exposure Limits. Wash thoroughly after handling. No food or beverage should be consumed in work area. Personal Protective Equip: Wear appropriate gloves and goggles to avoid skin and eye contact. Safety showers and eye stations must be present in work stations. Ventilation: Use local exhaust or mechanical such as a dust collector to maintain dust levels below Occupational Exposure Limits. Section 7: Physical and Chemical Characteristics Boiling Point: N/A Solubility in water: trace Vapor Pressure (mmhg): N/A Vapor Density (air=1): N/A Appearance: bright orange reddish powder Odor: oderless Specific Gravity (water=1): N/A Evaporation rate: None % Volatile by volume: None Section 8: Reactivity Data Stability: Stable Hazardous Polymerization: will not occur Incompatibility: None Hazard Decomposition of product: N/A 2

16 Section 9: Fire and Explosive Data Flash point: N/A Flammable Limits: None Unusual Fire and Explosion Hazard: None expected Extinguishing Media: Carbon dioxide, dry chemical or water Special Fire Fighting Procedures: Wear self contained breathing apparatus when large quantities involved. Section 10: Spill or Leak Procedures: Contain spillage and scoop or vaccum. Avoid making dust, put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. This product is a blend of various metal oxides, salts and some compounds which are interfused by high calcination to form the finished product. Section III, Hazardous Ingredients Identity/Information, and Section IV, Symptoms of Overexposure, pertain to individual components. Section V through Section X are in reference to the finished product. **************Attention All Retailers of Mason Stains************** ALL retailers of this product are REQUIRED by law to supply their customers with a copy of this material safety data sheet with initial purchase. ***SARA 313 This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this Material Safety Data Sheet must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before using this material. PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MATERIAL SAFETY DATA SHEETS ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT OR BY REQUEST. DISCLAMER Mason Color Works, Inc. believes the information contained in this material safety data sheet is believed to be accurate and reliable as of the date of publication or revision but makes no warranty that it is. This information provided should be made available as required by the Federal OSHA Hazard Communication Standard to ANYONE who handles, uses, stores, transports or will otherwise be exposed to this product. Mason Color Works, Inc. Accepts no Responsibility for the health or safety of any individual who misuses this product by not complying with manufacturer s instructions contained herein or additional /other measures that may be required under particular conditions. Last issued: 11/97 Updated : 3/2000 3

17 Material Safety Data Sheet Date Prepared 3/2000 Product Number: 6029 Section 1: Manufacturer Identification Mason Color Works, Inc. Phone: (330) East 2 nd Street/P.O. Box 76 Fax: (330) East Liverpool, OH Section 2: Identification of Product Chemical Family: Inorganic Product Names: Persimmon 6029 Chemical Abstract Number (CAS): , , Chemical Name: Chrome Alumina Zinc Pink - Spinel Chemical Formula: Zn(Al,Cr) 2 O 4 Section 3 & Section 4: Hazardous ingredients Identity/Information and Overexposure Symptoms ACGIH-TLVs OSHA PELs NOISHA RELs Alumina Oxide (Al 2 O 3 ) 10 mg/mg 3 (total) 15 mg/m 3 (total) N/A Cas # mg/m 3 (respirable) ACGIH: The value for particulate matter containing no asbestos and 1% crystalline silica. Inhalation: Acute may cause coughing and shortness of breath. Chronic may adversely effect breathing capacity. Eye Contact: Direct contact may cause irritation. Skin Contact: May cause abrasions. Ingestion: May cause irritation. Chrome Oxide (Cr 2 O 3 ) 0.5 mg/m mg/m mg/m 3 Cas # ACGIH: Not classifiable as a human carcinogen: Inadequate data on which to classify the agent in terms of carcinogencity in humans/animals. Inhalation: Repeated prolonged exposure to trivalent compounds may cause delayed effects involving the respiratory system. Eye Contact: mechanical irritation to the eye may occur such as watering, reddening de to exposure to fines. Skin Contact: Expected to be non irritating. Ingestion: Considered to be non-irritating, non-toxic if swallowed. Iron Oxide (Fe 2 O 3 ) 5 mg/m 3 10 mg/m 3 5 mg/m 3 Cas # ACGIH: Not classifiable as a human carcinogen: Inadequate data on which to classify the agent in terms of its carcinogencity in humans/animals. The value is for particulate matter containing no asbestos and 1% crystalline silica. 1

18 Iron Oxide cont d Inhalation: Repeated and prolonged exposure may cause beginnings Pneumoconiosis called Sideordsis. Eye Contact: May cause irritation. Skin Contact: May cause mechanical skin irritation. Ingestion: Expected to be non-toxic. Silica, Crystalline (SiO 2 ) 0.1 mg/m 3 10 mg/m mg/m 3 Cas # SiO Inhalation: a) Prolonged exposure to respirable crystalline silica (quartz) can cause Silicosis, a fibrosis (scarring) of the lungs. Silicosis may be progressive; it may lead to disability and death. Silicosis increases risk of Tuberculosis. b) Inhaled from occupational sources is classified as carcinogenic to humans. (cancer) c) There is evidence that exposure to respirable crystalline silica or that the disease Silicosis is associated with increased incidence of Sceroderma, an auto-immune disorder manifested by fibrosis (scarring) of the skin and internal organs. d) There are several studies suggesting that exposure to respirable silica or that the disease Silicosis is associated with the increased incidence of kidney disorders. (Nephrotoxicity) Eye Contact: May cause abrasions of the cornea. Skin Contact: Not applicable. Ingestion: Not applicable. Zinc Oxide (ZnO) 10 mg/m 3 10 mg/m 3 (Total) 5 mg/m 3 Cas # mg/m 3 (Respirable) Inhalation: High levels of dust may result in tightness of chest, metallic taste, cough, dizziness, fever, chills, headache, nausea, and dry throat. Chronic exposure may produce symptoms known as metal fume fever or zinc shakes, an acute, self-limiting condition without recognized complications. Symptoms of metal fume fever include: chills, fever, muscular pain, nausea and vomiting. May aggravate respiratory conditions. Eye Contact: May cause irritation. Skin Contact: May cause irritation. Ingestion: May cause irritation to the gastro-intestinal tract. Section 5: Emergency and First Aid Procedures: Eye: flush thoroughly with water for 15 minutes. Skin: remove contaminated clothing, wash thoroughly with soap and water. Inhalation: remove to fresh air, may give oxygen if needed. Ingestion: give large amounts of water to induce vomiting, only in conscious persons. IF THESE FIRST AID MEASURES FAIL, CONSULT PHYSICIAN!!!!!!!!!!!!!!!!!!! Principal Routes of Entry: Inhalation: Dust from this product may cause irritation of the respiratory system. Overexposure may cause lung damage. Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Skin & Eye: Nuisance dust, prolonged or repeated may cause irritation. 2

19 Section 6: Special Protection Information Respiratory Protection: Use only NIOSHA/OSHA approved respiratory protection with adequate ventilation; avoid breathing dust. Do not exceed Occupational Exposure Limits. Wash thoroughly after handling. No food or beverage should be consumed in work area. Personal Protective Equip: Wear appropriate gloves and goggles to avoid skin and eye contact. Safety showers and eye stations must be present in work stations. Ventilation: Use local exhaust or mechanical such as a dust collector to maintain dust levels below Occupational Exposure Limits. Section 7: Physical and Chemical Characteristics Boiling Point: N/A Solubility in water: trace Vapor Pressure (mmhg): N/A Vapor Density (air=1): N/A Appearance: pinkish powder Odor: oderless Specific Gravity (water=1): N/A Evaporation rate: None % Volatile by volume: None Section 8: Reactivity Data Stability: Stable Hazardous Polymerization: will not occur Incompatibility: None Hazard Decomposition of product: N/A Section 9: Fire and Explosive Data Flash point: N/A Flammable Limits: None Unusual Fire and Explosion Hazard: None expected Extinguishing Media: Carbon dioxide, dry chemical or water Special Fire Fighting Procedures: Wear self contained breathing apparatus when large quantities involved. Section 10: Spill or Leak Procedures: Contain spillage and scoop or vaccum. Avoid making dust, put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. This product is a blend of various metal oxides, salts and some compounds which are interfused by high calcination to form the finished product. Section III, Hazardous Ingredients Identity/Information, and Section IV, Symptoms of Overexposure, pertain to individual components. Section V through Section X are in reference to the finished product. **************Attention All Retailers of Mason Stains************** ALL retailers of this product are REQUIRED by law to supply their customers with a copy of this material safety data sheet with initial purchase. ***SARA 313 This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part

20 The information contained in this Material Safety Data Sheet must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before using this material. PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MATERIAL SAFETY DATA SHEETS ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT OR BY REQUEST. DISCLAMER Mason Color Works, Inc. believes the information contained in this material safety data sheet is believed to be accurate and reliable as of the date of publication or revision but makes no warranty that it is. This information provided should be made available as required by the Federal OSHA Hazard Communication Standard to ANYONE who handles, uses, stores, transports or will otherwise be exposed to this product. Mason Color Works, Inc. Accepts no Responsibility for the health or safety of any individual who misuses this product by not complying with manufacturer s instructions contained herein or additional /other measures that may be required under particular conditions. Last issued: 11/97 Updated : 3/2000 4

21 Material Safety Data Sheet Date Prepared 3/2000 Product Number: 6031 Section 1: Manufacturer Identification Mason Color Works, Inc. Phone: (330) East 2 nd Street/P.O. Box 76 Fax: (330) East Liverpool, OH Section 2: Identification of Product Chemical Family: Inorganic Product Names: Deep Salmon 6031 Chemical Abstract Number (CAS): , Chemical Name: Chrome Tin Zinc Iron Chromite Pink Chemical Formula: CaO.SnO.SiO 2 :Cr 2 O 3 + (Zn,Fe) (Fe,Cr) 2 O 4 Section 3 & Section 4: Hazardous ingredients Identity/Information and Overexposure Symptoms ACGIH-TLVs OSHA PELs NOISHA RELs Chrome Oxide (Cr 2 O 3 ) 0.5 mg/m mg/m mg/m 3 Cas # ACGIH: Not classifiable as a human carcinogen: Inadequate data on which to classify the agent in terms of carcinogencity in humans/animals. Inhalation: Repeated prolonged exposure to trivalent compounds may cause delayed effects involving the respiratory system. Eye Contact: mechanical irritation to the eye may occur such as watering, reddening de to exposure to fines. Skin Contact: Expected to be non irritating. Ingestion: Considered to be non-irritating, non-toxic if swallowed. Iron Oxide (Fe 2 O 3 ) 5 mg/m 3 10 mg/m 3 5 mg/m 3 Cas # ACGIH: Not classifiable as a human carcinogen: Inadequate data on which to classify the agent in terms of its carcinogencity in humans/animals. The value is for particulate matter containing no asbestos and 1% crystalline silica. Inhalation: Repeated and prolonged exposure may cause beginnings Pneumoconiosis called Sideordsis. Eye Contact: May cause irritation. Skin Contact: May cause mechanical skin irritation. Ingestion: Expected to be non-toxic. 1

22 Section 3 & Section 4: Hazardous ingredients Identity/Information and Overexposure Symptoms continued Silica, Crystalline (SiO 2 ) 0.1 mg/m 3 10 mg/m mg/m 3 Cas # SiO Inhalation: a) Prolonged exposure to respirable crystalline silica (quartz) can cause Silicosis, a fibrosis (scarring) of the lungs. Silicosis may be progressive; it may lead to disability and death. Silicosis increases risk of Tuberculosis. b) Inhaled from occupational sources is classified as carcinogenic to humans. (cancer) c) There is evidence that exposure to respirable crystalline silica or that the disease Silicosis is associated with increased incidence of Sceroderma, an auto-immune disorder manifested by fibrosis (scarring) of the skin and internal organs. d) There are several studies suggesting that exposure to respirable silica or that the disease Silicosis is associated with the increased incidence of kidney disorders. (Nephrotoxicity) Eye Contact: May cause abrasions of the cornea. Skin Contact: Not applicable. Ingestion: Not applicable. Tin Oxide (SnO) 2.0 mg/m mg/m mg/m 3 Cas # Inhalation: No information found on acute overexposure. Chronic exposure to tin oxide fumes or dust may result in Stannosis, a form of Phenumoconiosis. Eye Contact: Abrasive, mild irritant Skin Contact: Possible irritant. Ingestion: Considered non-toxic. Zinc Oxide (ZnO) 10 mg/m 3 10 mg/m 3 (Total) 5 mg/m 3 Cas # mg/m 3 (Respirable) Inhalation: High levels of dust may result in tightness of chest, metallic taste, cough, dizziness, fever, chills, headache, nausea, and dry throat. Chronic exposure may produce symptoms known as metal fume fever or zinc shakes, an acute, self-limiting condition without recognized complications. Symptoms of metal fume fever include: chills, fever, muscular pain, nausea and vomiting. May aggravate respiratory conditions. Eye Contact: May cause irritation. Skin Contact: May cause irritation. Ingestion: May cause irritation to the gastro-intestinal tract. Section 5: Emergency and First Aid Procedures: Eye: flush thoroughly with water for 15 minutes. Skin: remove contaminated clothing, wash thoroughly with soap and water. Inhalation: remove to fresh air, may give oxygen if needed. Ingestion: give large amounts of water to induce vomiting, only in conscious persons. IF THESE FIRST AID MEASURES FAIL, CONSULT PHYSICIAN!!!!!!!!!!!!!!!!!!! 2

23 Section 5: Continued Principal Routes of Entry: Inhalation: Dust from this product may cause irritation of the respiratory system. Overexposure may cause lung damage. Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Skin & Eye: Nuisance dust, prolonged or repeated may cause irritation. Section 6: Special Protection Information Respiratory Protection: Use only NIOSHA/OSHA approved respiratory protection with adequate ventilation; avoid breathing dust. Do not exceed Occupational Exposure Limits. Wash thoroughly after handling. No food or beverage should be consumed in work area. Personal Protective Equip: Wear appropriate gloves and goggles to avoid skin and eye contact. Safety showers and eye stations must be present in work stations. Ventilation: Use local exhaust or mechanical such as a dust collector to maintain dust levels below Occupational Exposure Limits. Section 7: Physical and Chemical Characteristics Boiling Point: N/A Solubility in water: trace Vapor Pressure (mmhg): N/A Vapor Density (air=1): N/A Appearance: pinkish powder Odor: oderless Specific Gravity (water=1): N/A Evaporation rate: None % Volatile by volume: None Section 8: Reactivity Data Stability: Stable Hazardous Polymerization: will not occur Incompatibility: None Hazard Decomposition of product: N/A Section 9: Fire and Explosive Data Flash point: N/A Flammable Limits: None Unusual Fire and Explosion Hazard: None expected Extinguishing Media: Carbon dioxide, dry chemical or water Special Fire Fighting Procedures: Wear self contained breathing apparatus when large quantities involved. Section 10: Spill or Leak Procedures: Contain spillage and scoop or vaccum. Avoid making dust, put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. This product is a blend of various metal oxides, salts and some compounds which are interfused by high calcination to form the finished product. Section III, Hazardous Ingredients Identity/Information, and Section IV, Symptoms of Overexposure, pertain to individual components. Section V through Section X are in reference to the finished product. 3

24 **************Attention All Retailers of Mason Stains************** ALL retailers of this product are REQUIRED by law to supply their customers with a copy of this material safety data sheet with initial purchase. ***SARA 313 This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this Material Safety Data Sheet must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before using this material. PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MATERIAL SAFETY DATA SHEETS ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT OR BY REQUEST. DISCLAMER Mason Color Works, Inc. believes the information contained in this material safety data sheet is believed to be accurate and reliable as of the date of publication or revision but makes no warranty that it is. This information provided should be made available as required by the Federal OSHA Hazard Communication Standard to ANYONE who handles, uses, stores, transports or will otherwise be exposed to this product. Mason Color Works, Inc. Accepts no Responsibility for the health or safety of any individual who misuses this product by not complying with manufacturer s instructions contained herein or additional /other measures that may be required under particular conditions. Last issued: 11/97 Updated : 3/2000 4