Shin-Etsu Unique Materials

Transcription

1 Silicone Products for Personal Care Shin-Etsu Unique Materials Volatile Silicone TMF-1.5 Emulsifiers Silicone Gels KSG Series Silicone Acrylates KP Series Hybrid Silicone Powders KSP Series Inorganic Powder Dispersions SPD Series 2.28

2 Shin-Etsu materials enable the personal care industry to develop products with greater functionality and diversity than ever before. ur silicone materials have the basic properties required for personal care products in general, and also provide the functionality and diversity required for special applications including skin care, make up, and sun care products. Shin-Etsu develops a range of original, innovative materials including silicone-based emulsifiers essential to basic processing and silicone gels, silicone acrylates and silicone powders, products that impart unique features to end-products. ur materials make it possible for manufacturers to develop unique, high-quality personal care products with greater functionality. Contents Formulation Design 2 Volatile Silicone TMF Emulsifiers 4 Silicone Gels for Personal Care KSG Series 8 Silicone Acrylates for Personal Care KP Series 12 Hybrid Silicone Powders for Personal Care KSP Series 14 Inorganic Powder Dispersions for Personal Care SPD Series 16 Handling precautions 17 Applications Formulation Design Basic Formula KP Series Silicone Fluids Make-up KSP Series KSG Series Emulsifiers Skin Care SPD Series Water Sun Screen 2

3 TMF-1.5 Volatile Silicone The volatile silicone TMF-1.5 is volatile better than KF-995, and has low freezing point. Me 6 Volatility Structure of TMF-1.5 Me Me Si Me Me Volatile rate (%) TMF-1.5 KF-995 Me Si Si Si Me Me Me Me Properties of TMF-1.5 Product name INCI Appearance Time (min) Measurement method 1. Sample 1 g onto filter paper (9 mm Ø) in Petri dish. 2. Keep under the condition of 25 C/65%RH. 3. Measure the residue of sample by each time. Viscosity Specific Refractive Freezing Point Boiling Point mm 2 /s Gravity Index C C TMF-1.5 METHYL TRIMETHICNE transparent fluid Applications (Not specific values) We offer various products made using TMF-1.5 as base oil. Trimethylsiloxysilicate Product name INCI Appearance Viscosity Specific Refractive Film mm 2 /s Gravity Index Hardness KF-7312T TRIMETHYLSILXYSILICATE (and) METHYL TRIMETHICNE transparent fluid Hard Silicone Cross-linked polymer Product name INCI Appearance Penetration (worked) 25 C Refractive Index KSG-161 METHYL TRIMETHICNE (and) DIMETHICNE/VINYL DIMETHICNE CRSSPLYMER translucent Silicone Acrylate Product name INCI Appearance Viscosity mm 2 /s Specific Gravity KP-549 METHYL TRIMETHICNE (and) ACRYLATES DIMETHICNE CPLYMER transparentlight hazy fluid 5-5,.9 Silicone Dispersion Product name INCI Appearance Viscosity Specific Powder Content mpa s Gravity wt % SPD-T3 METHYL TRIMETHICNE (and) TITANIUM DIXIDE (and) PLYGLYCERYL-3 PLYDIMETHYLSILXYETHYL DIMETHICNE (and) SILICA (and) HYDRGEN DIMETHICNE/CTYL SILSESQUIXANE CPLYMER (and) ALUMINUM HYDRXIDE Whitelight gray < 4, SPD-Z3 ZINC XIDE (and) METHYL TRIMETHICNE (and) PLYGLYCERYL-3 PLYDIMETHYLSILXYETHYL DIMETHICNE (and) HYDRGEN DIMETHICNE/CTYL SILSESQUIXANE CPLYMER Whitelight < 4, These documents are not a certification of quality. For documentation of quality assurance and standards, please contact our Sales Department. INCI names are subject to change without notice. 3

4 Emulsifiers The two main classes of emulsifiers are polyether modified silicones and polyglycerin modified silicones. Polyether modified silicones include linear types, branched types and cross-linked polymer types, while polyglycerin modified silicones include branched types and cross-linked polymer types. We also offer distinctive alkyl co-modified emulsifiers. Applying these products enables the development of diverse cosmetic formulations. Product Classification Type Product Model Linear Type Polyether modified KF-611 KF-612 KF-613 KF-615 KF-616 KF-617 KF-643 Polyether chain Silicone chain Polyether modified KF-628 Silicone chain Polyglycerin modified KF-61 KF-614 Polyether chain (Polyglycerin chain) Branched Type Polyether / alkyl co-modified KF-638 Silicone chain Alkyl chain Polyglycerin / alkyl co-modified KF-615 Polyether chain (Polyglycerin chain) Polyether modified KSG-21 KSG-24 Silicone chain Polyglycerin modified KSG-71 Polyether chain (Polyglycerin chain) Cross-linked polymer Type Polyether / alkyl co-modified KSG-31 KSG-32 KSG-33 KSG-34 Silicone chain Alkyl chain Polyglycerin / alkyl co-modified Cross-linked polymer Type: Please refer to KSG Series (page 8-11). KSG-81 KSG-82 KSG-83 KSG-84 Polyether chain (Polyglycerin chain) 4

5 Emulsifiers Polyether modified silicones [Linear Type] We offer numerous polyether modified silicone emulsifiers with varying HLB values, meaning these products can be used as either Si/W or W/Si emulsifiers. Product name INCI Viscosity Specific Gravity Refractive Index Calculated HLB Cloud Point 25 C mm 2 /s 25 C 25 C wt % E/5 C KF-611 PEG-11 METHYL ETHER DIMETHICNE KF-612 PEG/PPG-2/22 BUTYL ETHER DIMETHICNE 1, KF-613 PEG-9 DIMETHICNE KF-615 PEG-3 DIMETHICNE KF-616 PEG-9 METHYL ETHER DIMETHICNE KF-617 PEG-1 DIMETHICNE KF-643 PEG-1 DIMETHICNE This document is not a certification of quality. For documentation of quality assurance and standards, please contact our Sales Department. INCI names are subject to change without notice. 5

6 Polyether modified silicones [Branched Type] The silicone component has a branched structure, providing unique solubility, superior to that of linear structures. These emulsifiers enable creation of distinctive products in terms of the viscosity and stability of the emulsions. KF-638 has good solubility in both silicone fluid and organic oils. Product name INCI Viscosity Specific Gravity Refractive Index Calculated HLB 25 C mm 2 /s 25 C 25 C wt % E/5 KF-628 PEG-9 PLYDIMETHYLSILXYETHYL DIMETHICNE Alkyl co-modified type KF-638 LAURYL PEG-9 PLYDIMETHYLSILXYETHYL DIMETHICNE This document is not a certification of quality. For documentation of quality assurance and standards, please contact our Sales Department. INCI names are subject to change without notice. Polyglycerin modified silicones [Branched Type] These silicone emulsifiers feature polyglycerin as the hydrophilic component. These emulsifiers hold moisture well, so emulsions agree with skin and impart a distinctly soft and moist feel. KF-615 is a W/ emulsifier that is co-modified with alkyl chains. Product name INCI Viscosity Specific Gravity Refractive Index Estimated HLB 25 C mpa s 25 C 25 C KF-61 PLYGLYCERYL-3 DISILXANE DIMETHICNE 4, Medium KF-614 PLYGLYCERYL-3 PLYDIMETHYLSILXYETHYL DIMETHICNE 4, Low Alkyl co-modified type KF-615 LAURYL PLYGLYCERYL-3 PLYDIMETHYLSILXYETHYL DIMETHICNE 4, Low This document is not a certification of quality. For documentation of quality assurance and standards, please contact our Sales Department. INCI names are subject to change without notice. 6

7 Emulsifiers Compatibility (concentration 2%) KF-611 KF-612 KF-613 KF-615 KF-616 KF-617 KF-628 KF-638 KF-643 KF-61 KF-614 KF-615 DM-FLUID A-6cs (Dimethicone) TMF-1.5 (Methyl Trimethicone) KF-995 (Cyclopentasiloxane) KF-56A (Diphenylsiloxy Phenyl Trimethicone) I I PS I S S S S I PS S S I I I S S S S S I PS S S I I I S S S S S I PS S S S S PS S S S S S I I S S Mineral il I PS I I PS PS PS S I I I S Isotridecyl Isononanoate I S S S S S S S I PS S S Triethylhexanoin S S S S S S S S S PS PS S Ethyl Alcohol S S S S S S S PS S S PS PS Isopropyl Alcohol S S S S S S S S S S S S Propylene Glycol S I S I I S I PS S S I I 1,3-Butylene Glycol S I S I I S I PS S S PS PS Glycerin I I I I I I I PS I S PS PS Water S S I I I I I I S G I I S: Soluble PS: Partially Soluble I: Insoluble G: Gel Surface tension Surface Tension (mn/m) KF-617 KF-628 KSG-21 KF Measured using a "fully automated interfacial tensiometer (model PD-W, KYWA INTERFACE SCIENCE C., LTD.)" Concentration (%) (Base Fluid: DM-FLUID A-6cs) 7

8 KSG Series Silicone Gels for Personal Care Commonly known thickening agents have never been compatible with silicone systems and have left a heavy, draggy feel on the skin. The KSG series was developed to solve these problems. Silicone Cross-linked polymers Because of their 3-dimensional network structure, the KSG series products silicone systems, improve formulation stability, and provide a smooth, silky and luxurious feel to products. Product name INCI Component A Penetration Refractive- Appearance Component B (worked) 25 C Index 25 C Heavy Metal Arsenic KSG-15 DIMETHICNE/VINYL DIMETHICNE CRSSPLYMER 4-1% CYCLPENTASILXANE 9-96% transparent < 2ppm < 2ppm USG-13 DIMETHICNE/VINYL DIMETHICNE CRSSPLYMER 8-12% CYCLPENTASILXANE 88-92% transparent < 2ppm < 2ppm KSG-16 DIMETHICNE/VINYL DIMETHICNE CRSSPLYMER 2-3% DIMETHICNE 7-8% translucent < 2ppm < 2ppm KSG-161 DIMETHICNE/VINYL DIMETHICNE CRSSPLYMER 15-2% METHYL TRIMETHICNE 8-85% translucent < 2ppm < 2ppm USG-16 DIMETHICNE/VINYL DIMETHICNE CRSSPLYMER 8-12% ISDDECANE 88-92% transparent < 2ppm < 2ppm KSG-18A DIMETHICNE/PHENYL VINYL DIMETHICNE CRSSPLYMER 1-2% DIPHENYLSILXY PHENYL TRIMETHICNE 8-9% translucent < 2ppm < 2ppm KSG-41 VINYL DIMETHICNE/LAURYL DIMETHICNE CRSSPLYMER 25-35% MINERAL IL 65-75% translucent < 2ppm < 2ppm KSG-42 VINYL DIMETHICNE/LAURYL DIMETHICNE CRSSPLYMER 2-3% ISDDECANE 7-8% translucent < 2ppm < 2ppm KSG-43 VINYL DIMETHICNE/LAURYL DIMETHICNE CRSSPLYMER 25-35% TRIETHYLHEXANIN 65-75% translucent < 2ppm < 2ppm KSG-44 VINYL DIMETHICNE/LAURYL DIMETHICNE CRSSPLYMER 25-35% SQUALANE 65-75% translucent < 2ppm < 2ppm This document is not a certification of quality. For documentation of quality assurance and standards, please contact our Sales Department. INCI names are subject to change without notice. 8

9 KSG Series Silicone Gels for Personal Care Polyether modified Silicone Cross-linked polymers KSG-21, 24, 31, 32, 33, 34 are polyether modified self-emulsifying systems allowing for easy formulation of unique W/Si and W/ products, and provide a smooth and silky feel to them. Product name INCI Component A Penetration Refractive- Appearance Component B (worked) 25 C Index 25 C Heavy Metal Arsenic KSG-21 DIMETHICNE/PEG-1/15 CRSSPLYMER 2-3% DIMETHICNE 7-8% < 2ppm < 2ppm KSG-24 DIMETHICNE/PEG-1/15 CRSSPLYMER 15-25% CYCLPENTASILXANE 75-85% < 2ppm < 2ppm Alkyl co-modified type KSG-31 PEG-15/LAURYL DIMETHICNE CRSSPLYMER 25-35% MINERAL IL 65-75% < 2ppm < 2ppm KSG-32 PEG-15/LAURYL DIMETHICNE CRSSPLYMER 2-3% ISDDECANE 7-8% < 2ppm < 2ppm KSG-33 PEG-15/LAURYL DIMETHICNE CRSSPLYMER 15-25% TRIETHYLHEXANIN 75-85% < 2ppm < 2ppm KSG-34 PEG-1/LAURYL DIMETHICNE CRSSPLYMER PEG-15/LAURYL DIMETHICNE CRSSPLYMER 25-35% SQUALANE 65-75% < 2ppm < 2ppm This document is not a certification of quality. For documentation of quality assurance and standards, please contact our Sales Department. INCI names are subject to change without notice. Polyglycerin modified Silicone Cross-linked polymers KSG-71, 81, 82, 83, 84 contain a hydrophilic polyglycerin group, which acts as a moisturizer. These products allow for easy formulation of unique W/Si and W/ products. Product name INCI Component A Penetration Refractive- Appearance Component B (worked) 25 C Index 25 C Heavy Metal Arsenic KSG-71 DIMETHICNE/PLYGLYCERIN-3 CRSSPLYMER 2-3% DIMETHICNE 7-8% < 2ppm < 2ppm 9

10 Product name INCI Component A Penetration Refractive- Appearance Component B (worked) 25 C Index 25 C Heavy Metal Arsenic Alkyl co-modified type KSG-81 LAURYL DIMETHICNE/PLYGLYCERIN-3 CRSSPLYMER 25-35% MINERAL IL 65-75% < 2ppm < 2ppm KSG-82 LAURYL DIMETHICNE/PLYGLYCERIN-3 CRSSPLYMER 2-3% ISDDECANE 7-8% < 2ppm < 2ppm KSG-83 LAURYL DIMETHICNE/PLYGLYCERIN-3 CRSSPLYMER 15-25% TRIETHYLHEXANIN 75-85% < 2ppm < 2ppm KSG-84 LAURYL DIMETHICNE/PLYGLYCERIN-3 CRSSPLYMER 25-35% SQUALANE 65-75% < 2ppm < 2ppm This document is not a certification of quality. For documentation of quality assurance and standards, please contact our Sales Department. INCI names are subject to change without notice. Swelling ability of KSG series with cosmetic oils KSG-15 USG-13 KSG-16 KSG-161 USG-16 KSG-18A KSG-41 KSG-42 KSG-43 KSG-44 KSG-21 KSG-24 KSG-31 KSG-32 KSG-33 KSG-34 KSG-71 KSG-81 KSG-82 KSG-83 KSG-84 TMF-1.5 (Methyl Trimethicone) KF-995 (Cyclopentasiloxane) DM-FLUID A-6cs (Dimethicone) DM-FLUID A-2cs (Dimethicone) DM-FLUID A-1cs (Dimethicone) KF-56A (Diphenylsiloxy Phenyl Trimethicone) Isododecane Mineral il Squalane Isotridecyl Isononanoate Cetyl Caprylate Jojoba (Buxus Chinensis) il Triethylhexanoin Triisostearin Macadamia Ternifolia Nut il B: Base il : ptional Amount R: Restrictive Use B R R R R R R B B R R R R B R R B R R R R B R R R R R R R R R R R R R R R R R R R R R R B R R R R R R B R B B R R R R R B R R B R R R R R R R R B R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R B R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R B R R R R R R R R R R R R R R R R R R R R R R R B R B R B R R R R B R R R R R R R R R B B R R R R R R R R 1

11 KSG Series Silicone Gels for Personal Care Viscosity vs. Cross-linked polymer content KSG-1 series enables us to make gel-like products from low viscosity silicone fluids. This is accomplished by combining a silicone cross-linked polymer with a silicone fluid. The viscosity of the final product depends upon the concentration of cross-linked polymer as illustrated in this graph. The viscosity curve is different for each KSG-1 series due to the type of silicone fluid and the ability of the cross-linked polymer to thicken that particular silicone fluid. Note that KSG-15 requires much less cross-linked polymer to reach a particular viscosity than does KSG-16. As a result, the cross-linked polymer film formed by KSG-15 is thinner than that of KSG-16. Viscosity vs. Shear rate The viscosity of KSG products remains constant over time when the products are in a still, unagitated condition. However, the materials are shear sensitive and the viscosity will decrease upon the application of shear. This is illustrated for each KSG product in the accompanying graph. When formulating, this can be advantageous to facilitate the dispersion of cosmetic ingredients, such as pigments. nce formulated, the dispersions demonstrate excellent stability. (mpa s) (mpa s) 8, 6, 4, KSG-15 KSG-18A KSG-16 5, 4, 3, KSG-16 KSG-18A KSG-15 KSG-21 KF-96A-5cs 2, 2, 1, Cross-linked polymer content (%) 5 1 Shear rate (per min.) Formulating W/ creams with KSG-21, KSG-31, KSG-71 or KSG-81 KSG-21 and KSG-71 are self-emulsifying which can be used to formulate stable W/Si creams without the addition of an emulsifying agent. This graph illustrates formulation ratios of 1 KSG-21 or KSG-71, DM-FLUID A-6cs and water (and also ratios of KSG-31 or KSG-81, Mineral il and water). W/ emulsions can be produced in the area marked W/ area illustrating the formulation latitude of KSG-21, KSG-31, KSG-71 or KSG-81. Stable W/ emulsions can be obtained using the formulation area indicated in green. Water 5 W/ area DM-FLUID A-6cs or Mineral il 5 W/ emulsion with KSG-31 ( x2 A point) 1 A 5 1 KSG-21, KSG-31, KSG-71, KSG-81 1µm A Component of Emulsion KSG-31 5wt % Mineral il 5wt % Water 9wt % The A point This diagram illustrates a formulation containing 9 % water, 5 % DM-FLUID A-6cs and 5 % KSG-21 or KSG-71 (9 % water, 5 % mineral oil and 5 % KSG-31 or KSG-81). This example illustrates the ability of KSG-21, KSG-31, KSG-71 or KSG-81 to form stable W/ creams with extremely high water content. 11

12 KP Series Silicone Acrylates for Personal Care KP products combine the benefits of acrylic resins with silicones. They are graft copolymers with an acrylic polymer backbone and dimethylpolysiloxane side chains. Silicone acrylates dissolved in volatile silicone or hydrocarbon carriers to form soft flexible films with excellent water and oil repellency. Powder treatment Product name INCI Component A Component B Appearance Viscosity 25 C mpa s ph Heavy Metal Arsenic KP-541 ACRYLATES/DIMETHICNE CPLYMER 6% ISPRPYL ALCHL 4% transparentlight hazy fluid 5-1, Neutral < 2ppm < 2ppm Dispersant Product name INCI Component A Viscosity Appearance Component B 25 C mm 2 /s ph Heavy Metal Arsenic KP-575 ACRYLATES/ETHYLHEXYL ACRYLATE/DIMETHICNE METHACRYLATE CPLYMER 3% CYCLPENTASILXANE 7% transparentlight hazy fluid 1-5 Neutral < 2ppm < 2ppm Film former Product name INCI Component A Viscosity Appearance Component B 25 C mm 2 /s ph Heavy Metal Arsenic KP-543 ACRYLATES/DIMETHICNE CPLYMER 5% BUTYL ACETATE 5% transparentlight hazy fluid 1-1, Neutral < 2ppm < 2ppm KP-545 ACRYLATES/DIMETHICNE CPLYMER 3% CYCLPENTASILXANE 7% transparentlight hazy fluid 1-5 Neutral < 2ppm < 2ppm KP-549 ACRYLATES/DIMETHICNE CPLYMER 4% METHYL TRIMETHICNE 6% transparentlight hazy fluid 5-5, Neutral < 2ppm < 2ppm KP-55 ACRYLATES/DIMETHICNE CPLYMER 4% ISDDECANE 6% transparentlight hazy fluid 1-3, Neutral < 2ppm < 2ppm Silicone wax Product name INCI Appearance Melting Point C ph Heavy Metal Arsenic KP-561P ACRYLATES/STEARYL ACRYLATE/DIMETHICNE METHACRYLATE CPLYMER light Neutral < 2ppm < 2ppm KP-562P ACRYLATES/BEHENYL ACRYLATE/DIMETHICNE METHACRYLATE CPLYMER hazy solid light hazy solid Neutral < 2ppm < 2ppm This document is not a certification of quality. For documentation of quality assurance and standards, please contact our Sales Department. INCI names are subject to change without notice. 12

13 KP Series Silicone Acrylates for Personal Care The physical properties of silicone acrylate film KP-541 KP-543 KP-545 Contact Angle degree Glass Transition Point C Softening Point C Performance of nail enamel containing KP-543 Testing sample: KP-543 and other raw materials are combined at 1 %, 3 %, 5 % of KP-543. Each enamel is painted on a glass plate by wire bar (#2). Main component is Nitrocellulose. Tack free time KP-543 wt % Tack free time (min) Dispersibility of titanium dioxide Powder: Fine grain titanium dioxide Solvent: Cyclopentasiloxane (KF-995) Dispersing agent: KP-545 Test method: Mix KF-995 with KP-545, add 2 g of titanium dioxide, then put in a 3 p sedimentary tube, disperse by ultrasound, observe without disturbing. Test results Sedimentary capacity (p) The resin portion of KP-545 After 4 hours After 68 hours powder weight: KP-545 resin weight Tack free time of each sample is measured by touching with cotton every one minute. Water repellency KP-543 wt % Contact angle degree ( ) Tix Tix Silicone Acrylic polymer Measure the contact angle of water on each sample. Lubricity KP-543 wt % CF (µk) Measure the CF (Coefficient of friction) of each sample. (PET, 15 mm/min, 2 g pressure) Gloss degree of lipstick containing KP-561P Sample A Sample B Sample C Candelilla Wax 8. wt % 8. wt % 8. wt % Polyethylene 8. wt % 8. wt % 8. wt % KP-561P 15. wt % Polyol Ester 15. wt % Testing Rosin Ester 15. wt % sample KF wt % 3. wt % 3. wt % formulations Isotridecyl Isononanoate 2. wt % 2. wt % 2. wt % Glyceryl Isostearate 16. wt % 16. wt % 16. wt % Polyglyceryl-2 Triisostearate 3. wt % 3. wt % 3. wt % Pigment q.s. q.s. q.s. Test results Gloss degree Testing method Measure the gloss degree of each sample above painted on test paper by Gloss Meter VG-2. (Gloss Meter VG-2, Nippon Denshoku Co., Ltd.) Tix Cosmetic Ingredients Tix Compatibility in cosmetic ingredients KP-541 KP-543 KP-545 KP-561P KP-562P Water I I I I I Ethanol S P S I I Isopropyl Alcohol S S S I I Glycerin I P I I I C13-16 Isoparaffin S I S S S Liquid Isoparaffin I I I S S Squalane I I I S S Cetyl Isooctanate S I S S S Triethylhexanoin S I S S S Jojoba il I I I P P leic Acid I I I S S KF-995 S I S S S DM-FLUID A-6cs S I S S S DM-FLUID A-1cs I I I S S KF-54 P I P I I S: soluble P: partially soluble I: insoluble (at room temperature) KP series/cosmetic ingredients = 1/1 (weight ratio) 13

14 KSP Series Hybrid Silicone Powders for Personal Care The KSP series is a new generation of "hybrid" silicone powders. The structure consists of silicone rubber coated with silicone resin. The KSP series provides a uniquely soft, silky feel and good dispersibility with reduced agglomeration. Hybrid silicone powders combine the features of rubber and resin powders Molecular structure of KSP Series Silicone Resin Si Si Si Si Si Si Si c Si Si Si Si Si Si c Si c c Si c Si Si Si c Silicone Rubber KSP series powders consist of a spherical silicone rubber core chemically bonded to an outer shell of silicone resin. KSP-1 powders will swell in silicone fluids such as cyclomethicone and dimethicone. Therefore, KSP-3 was developed for applications where swelling is undesirable. KSP-3 is a hybrid silicone powder functionalized with phenyl groups. The phenyl groups prevent swelling in low viscosity dimethicone fluids. The physical properties Product name INCI Appearance Volatile Content True Specific Average Particle- Hardness Heavy Metal Arsenic 15 C/3h % Gravity Size µ Durometer A KSP-1 VINYL DIMETHICNE/METHICNE SILSESQUIXANE CRSSPLYMER White spherical powder.1 < 2ppm < 2ppm KSP-11 VINYL DIMETHICNE/METHICNE SILSESQUIXANE CRSSPLYMER White spherical powder.1 < 2ppm < 2ppm KSP-12 VINYL DIMETHICNE/METHICNE SILSESQUIXANE CRSSPLYMER White spherical powder.1 < 2ppm < 2ppm KSP-15 VINYL DIMETHICNE/METHICNE SILSESQUIXANE CRSSPLYMER White spherical powder.1 < 2ppm < 2ppm KSP-3 DIPHENYL DIMETHICNE/VINYL DIPHENYL DIMETHICNE/SILSESQUIXANE CRSSPLYMER White spherical powder.1 < 2ppm < 2ppm This document is not a certification of quality. For documentation of quality assurance and standards, please contact our Sales Department. INCI names are subject to change without notice. 14

15 KSP Series Hybrid Silicone Powders for Personal Care Scanning electron micrographs and particle size distributions KSP-1 KSP-11 KSP-15 Volume (%) Volume (%) Volume (%) Particle Size (µm) Particle Size (µm) Particle Size (µm) KSP-3 Swelling properties of silicone powder 3 25 Cyclopentasiloxane (KF-995) Dimethicone (DM-FLUID A-6cs) Volume (%) Particle Size (µm) Swelling Weight ( g ) KSP-3 KSP-1 Rubber powder Swelling weight = A - riginal weight (5. g) 'A' value is the filtered cake weight (g) of powder after shaking for 3 days in silicone fluid (5 g). 15

16 SPD Series Inorganic Powder Dispersions for Personal Care The SPD series is a dispersion of fine Ti2/Zn in Volatile silicone designed for use in sunscreens as well as other skincare and make-up products. The SPD products offer performance enhancements due to the use of high performance dispersant. Features High Solids Dispersions that are Stable and have Very Low Viscosity Excellent Stability High Transparency that facilitates transparent formulations without the use of organic UV absorbers High SPF Enhanced Water Resistance Smooth, Non-Tacky Skin Feel The physical properties Product name Composition Appearance Viscosity Specific Gravity Powder Content Transmissivity 25 C mpa s 25 C wt % % METHYL TRIMETHICNE TITANIUM DIXIDE SPD-T3 PLYGLYCERYL-3 PLYDIMETHYLSILXYETHYL DIMETHICNE White- SILICA light gray < 4, > 65 SPD-T5 HYDRGEN DIMETHICNE/CTYL SILSESQUIXANE CPLYMER ALUMINUM HYDRXIDE CYCLPENTASILXANE TITANIUM DIXIDE White- PLYGLYCERYL-3 PLYDIMETHYLSILXYETHYL DIMETHICNE light gray ALUMINUM HYDRXIDE < 4, > 65 STEARIC ACID CYCLPENTASILXANE TITANIUM DIXIDE SPD-T6 PLYGLYCERYL-3 PLYDIMETHYLSILXYETHYL DIMETHICNE White- SILICA light gray < 4, > 65 HYDRGEN DIMETHICNE/CTYL SILSESQUIXANE CPLYMER ALUMINUM HYDRXIDE SPD-Z3 ZINC XIDE METHYL TRIMETHICNE PLYGLYCERYL-3 PLYDIMETHYLSILXYETHYL DIMETHICNE HYDRGEN DIMETHICNE/CTYL SILSESQUIXANE CPLYMER Whitelight < 4, > 6 SPD-Z5 ZINC XIDE CYCLPENTASILXANE PLYGLYCERYL-3 PLYDIMETHYLSILXYETHYL DIMETHICNE TRIETHXYSILYLETHYL PLYDIMETHYLSILXYETHYL HEXYL DIMETHICNE Whitelight < 4, > 65 SPD-Z6 ZINC XIDE CYCLPENTASILXANE PLYGLYCERYL-3 PLYDIMETHYLSILXYETHYL DIMETHICNE HYDRGEN DIMETHICNE/CTYL SILSESQUIXANE CPLYMER Whitelight < 4, > 6 Percent transmission at 4nm by using spectrophotometer. This document is not a certification of quality. For documentation of quality assurance and standards, please contact our Sales Department. INCI names are subject to change without notice. 16

17 SPD Series Inorganic Powder Dispersions for Personal Care SPD-T5 Composition SPD-Z5 Composition Fine Titanium Dioxide (coated) 4 wt % Fine Zinc Dioxide (coated) 6 wt % Cyclopentasiloxane 5 wt % Cyclopentasiloxane 35 wt % Silicone Dispersant 1 wt % Silicone Dispersant 5 wt % Photographs taken through a glass plate coated with SPD-T5/Z5 (Thickness ; 6 µm). UV attenuation of SPD-T6, SPD-Z6 1 Transmittance Spectrum Transmissivity (%) SPD-T6 SPD-Z Wave Length (nm) Test method A sample was coated on a quartz plate with thickness of 6 µm by wire bar. Percent transmission was measured by a spectrophotometer after the plate was dried. Handling precautions Quality, Storage and Handling Since changes in quality may occur due to exposure to heat, humidity, light or acidic or alkaline environments, be sure to close tightly and store in a cool, dark location. Do not leave products in an open state while working. Please read the Material Safety Data Sheet (MSDS) before use. MSDS can be obtained from our Sales Department. 17

18 Applications Si/W Cream 1. KSG wt % 2. KSG wt % 3. KF wt % 4. 1,3-Butylene Glycol 3. wt % 5. KF wt % 6. KF wt % 7. SIMULGEL wt % /W Cream 1. KSG wt % 2. Isotridecyl Isononanoate 2. wt % 3. Glycerin 5. wt % 4. 1,3-Butylene Glycol 7. wt % 5. KF wt % 6. PEG-6 Hydrogenated Caster il.5 wt % 7. SIMULGEL EG 2.8 wt % Ammonium Acryloyldimethyltaurae/ 8. vp copolymer (5% aq) 13. wt % Ammonium Acryloyldimethyltaurae/ 8. vp copolymer (5% aq) 1. wt % 9. Sodium Chloride (1% aq) 8. wt % 1. Water 26.5 wt % 9. Sodium Chloride.1 wt % 1. Water 3.9 wt % A. Combine 1, 2 and 3 with stirring. B. Combine 4-9 and 1 with stirring. C. Add A to B with stirring. 1: Shin-Etsu 2: SEPPIC A. Combine 1 and 2 with stirring. B. Combine 3-9 and 1 with stirring. C. Add A to B with stirring. 1: Shin-Etsu 2: SEPPIC W/Si Cream 1. KSG wt % 2. KF wt % 3. KSG wt % 4. DM-FLUID A-6cs wt % 5. 1,3-Butylene Glycol 8. wt % 6. Sodium Citrate.2 wt % 7. Sodium Chloride.5 wt % 8. Ethyl Alcohol 5. wt % 9. Water 68.3 wt % A. Combine 1-3 and 4 with stirring. B. Combine 5-8 and 9 with stirring. C. Add B to A with stirring. 1: Shin-Etsu W/ Cream 1. KSG wt % 2. KSG wt % 3. KF wt % 4. Mineral il 12. wt % 5. Neopentyl Glycol Diethylhexanoate 5. wt % 6. KSP wt % 7. Glycerin 3. wt % 8. 1,3-Butylene Glycol 7. wt % 9. Sodium Citrate.2 wt % 1. Sodium Chloride.5 wt % 11. Water 6.3 wt % A. Combine 1-5 and 6 with stirring. B. Combine 7-1 and 11 with stirring. C. Add B to A with stirring. 1: Shin-Etsu 18

19 W/ Liquid foundation 1. KSG wt % 2. KSG wt % 3. KF wt % 4. Quaternium-18 Hectorite 1.2 wt % 5. Triethylhexanoin 5. wt % 6. DM-FLUID A-6cs wt % 7. KF wt % 8. KP (KP ) 1.5 wt % 9. Pigment (Treated with KF-999) 1. wt % 1. Dipropylene Glycol 5. wt % 11. Sodium Citrate.2 wt % 12. Water 38.5 wt % A. Combine 1-5, a part of 6 and a part of 7 until uniformly dispersed. B. Add 9 to the rest of 6, the rest of 7 and 8, and mix with roller. C. Combine 1, 11 and 12 mix until dissolved D. Add C to A with Stirring. E. Add B to D with Stirring. 1: Shin-Etsu W/ Cream foundation 1. KSG wt % 2. KSG wt % 3. KF wt % 4. Mineral il 2. wt % 5. Triethylhexanoin 5. wt % 6. Isotridecyl isononanoate 9. wt % 7. Lecithin.2 wt % 8. Polysorbate 8.5 wt % 9. 1,3-Butylene Glycol 5. wt % 1. KSP wt % 11. Pigment (Treated Pigment) 1. wt % 12. Sodium Citrate.2 wt % 13. Sodium Chloride.5 wt % 14. Water 6.6 wt % A. Combine 1-5 and 6 until uniformly dispersed. B. Combine 7-1 and 11mix with roller. C. Combine 12, 13 and a part of 14 mix until dissolved. D. Add B to the rest of 14, and until uniformly dispersed. E. Add C to A with Stirring. F. Add D to E with Stirring. 1: Shin-Etsu Sunscreen lotion (SPF: 5+, PA++ 2 ) 1. KSG wt % 2. KSG wt % 3. DM-FLUID A-6cs 1 5. wt % 4. KF wt % 5. KF wt % 6. Isotridecyl Isononanoate 4. wt % 7. SPD-T wt % 8. SPD-Z wt % 9. Dipropylene Glycol 2. wt % 1. Sodium Citrate.2 wt % 11. Sodium Chloride 1. wt % 12. Water 16.8 wt % Lip Stick 1. Candelilla Wax 4. wt % 2. Polyethylene 2. wt % 3. Microcrystalline Wax 3. wt % 4. Ceresin 7. wt % 5. KP-561P wt % 6. KF wt % 7. Macadamia Ternifolia Nut il 28. wt % 8. Diisostearyl Malate 1. wt % 9. Hydrogenated Polyisobutene 1. wt % 1. Isotridecyl Isononanoate 18. wt % 11. Pigment Base 2 q.s 12. Mica q.s A. Combine 1-5 and 6 with stirring. B. Combine 9-11 and 12 with stirring. C. Add B to A. with stirring. D. Add 7, 8 to C with stirring. 1: Shin-Etsu 2: By Consumer Product Testing Co. A. Combine 1-9 and 1 with stirring (9 C). B. Add 11, 12 to A with stirring. 1: Shin-Etsu 2: Polyglyceryl-2 Triisostearate 6 % Base 19

20 Silicone Division Sales and Marketing Department1 6-1, htemachi 2-chome, Chiyoda-ku, Tokyo, Japan Phone : +81-() Fax : +81-() Shin-Etsu Silicones of America, Inc. 115 Damar Drive, Akron, H 4435, U.S.A. Phone : Fax : Shin-Etsu Silicones Europe B. V. Bolderweg 32, 1332 AV, Almere, The Netherlands Phone : +31-() Fax : +31-() Shin-Etsu Silicone Taiwan Co., Ltd. Hung Kuo Bldg. 11F-D, No. 167, Tun Hua N. Rd., Taipei, 1549 Taiwan, R..C. Phone : +886-() Fax : +886-() Shin-Etsu Silicone Korea Co., Ltd. Danam Bldg., 9F, 12, Namdaemunno5(o)-ga, Jung-gu, Seoul 1-74, Korea Phone : +82-() Fax : +82-() Shin-Etsu Singapore Pte. Ltd. 4 Shenton Way, #1-3/6, SGX Centre2, Singapore 6887 Phone : Fax : Shin-Etsu Silicones (Thailand) Ltd. 7th Floor, Harindhorn Tower, 54 North Sathorn Road, Bangkok 15, Thailand Phone : +66-() Fax : +66-() Shin-Etsu Silicone International Trading (Shanghai) Co., Ltd. 29F Junyao International Plaza, No.789, Zhao Jia Bang Road, Shanghai Phone : +86-() Fax : +86-() The data and information presented in this catalog may not be relied upon to represent standard values. Shin-Etsu reserves the right to change such data and information, in whole or in part, in this catalog, including product performance standards and specifications without notice. Users are solely responsible for making preliminary tests to determine the suitability of products for their intended use. Statements concerning possible or suggested uses made herein may not be relied upon, or be construed, as a guaranty of no patent infringement. The silicone products described herein have been designed, manufactured and developed solely for general industrial use only; such silicone products are not designed for, intended for use as, or suitable for, medical, surgical or other particular purposes. Users have the sole responsibility and obligation to determine the suitability of the silicone products described herein for any application, to make preliminary tests, and to confirm the safety of such products for their use. Users must never use the silicone products described herein for the purpose of implantation into the human body and/or injection into humans. Users are solely responsible for exporting or importing the silicone products described herein, and complying with all applicable laws, regulations, and rules relating to the use of such products. Shin-Etsu recommends checking each pertinent country's laws, regulations, and rules in advance, when exporting or importing, and before using, the products. Please contact Shin-Etsu before reproducing any part of this catalog. Copyright belongs to Shin-Etsu Chemical Co., Ltd. The Development and Manufacture of Shin-Etsu Silicones are based on the following registered international quality and environmental management standards. Gunma Complex IS 91 IS 141 (JCQA-4 JCQA-E-2) Naoetsu Plant IS 91 IS 141 (JCQA-18 JCQA-E-64) Takefu Plant IS 91 IS 141 (JQA-479 JQA-EM298) C Shin-Etsu 25.2/ B.P. Printed in Japan.