GC/MS BATCH NUMBER: O10106

Transcription

1 GC/MS BATCH NUMBER: O10106 ESSENTIAL OIL: ORANGE BLOOD BOTANICAL NAME: CITRUS SINENSIS ORIGIN: ITALY KEY CONSTITUENTS PRESENT IN THIS BATCH OF ORANGE BLOOD OIL % LIMONENE 93.2 MYRCENE 1.8 Comments from Robert Tisserand: Full-bodied, sweet citrus odor quality. All thirteen key ISO constituents are within range nd St S. Twin Falls, ID * * planttherapy.com facebook.com/planttherapy * planttherapy.com/blog

2 Date : May 25, 2018 CERTIFICATE OF ANALYSIS GC PROFILING SAMPLE IDENTIFICATION Internal code : 18E18-PTH3-1-CC Customer identification : Orange Blood - Italy - O R Type : Essential oil Source : Citrus sinensis Customer : Plant Therapy ANALYSIS Method: PC-PA J19 - Analysis of the composition of an essential oil, or other volatile liquid, by FAST GC-FID (in French); identifications validated by GC-MS. Analyst : Sylvain Mercier, M. Sc., Chimiste Analysis date : May 24, 2018 Checked and approved by : Alexis St-Gelais, M. Sc., chimiste Note: This report may not be published, including online, without the written consent from Laboratoire PhytoChemia. This report is digitally signed, it is only considered valid if the digital signature is intact. Page 1/9

3 PHYSICOCHEMICAL DATA Physical aspect: Bright yellow/orange liquid Refractive index: ± (20 C) CONCLUSION No adulterant, contaminant or diluent has been detected using this method. Page 2/9

4 ANALYSIS SUMMARY Identification DB-5 (%) DB-WAX (%) Classe Hexanal tr tr Aliphatic aldehyde Heptanal tr tr Aliphatic aldehyde α-thujene tr tr Monoterpene α-pinene Monoterpene Camphene tr tr Monoterpene Sabinene 0.44* 0.38 Monoterpene β-pinene [0.44]* 0.06 Monoterpene Myrcene Monoterpene α-phellandrene 0.31* 0.03 Monoterpene Octanal [0.31]* 0.29 Aliphatic aldehyde Δ3-Carene Monoterpene para-cymene 93.14* 0.02 Monoterpene Limonene [93.14]* Monoterpene 1,8-Cineole [93.14]* 0.21 Monoterpenic ether (Z)-β-Ocimene tr tr Monoterpene (E)-β-Ocimene Monoterpene γ-terpinene tr 0.01 Monoterpene cis-sabinene hydrate Monoterpenic alcohol Octanol Aliphatic alcohol Isoterpinolene tr tr Monoterpene Terpinolene Monoterpene Linalool Monoterpenic alcohol Nonanal Aliphatic aldehyde trans-para-mentha-2,8-dien-1-ol Monoterpenic alcohol cis-limonene oxide Monoterpenic ether cis-para-mentha-2,8-dien-1-ol * Monoterpenic alcohol trans-limonene oxide Monoterpenic ether Citronellal Monoterpenic aldehyde Terpinen-4-ol Monoterpenic alcohol α-terpineol * Monoterpenic alcohol cis-piperitol tr tr Monoterpenic alcohol Decanal Aliphatic aldehyde Octyl acetate Aliphatic ester trans-carveol Monoterpenic alcohol Nerol Monoterpenic alcohol cis-carveol Monoterpenic alcohol Neral 0.09 [0.09]* Monoterpenic aldehyde (E)-Isogeraniol? Monoterpenic alcohol Geraniol Monoterpenic alcohol Perillaldehyde Monoterpenic aldehyde Geranial Monoterpenic aldehyde Limonen-10-ol Monoterpenic alcohol Undecanal Aliphatic aldehyde Neryl acetate tr 0.01 Monoterpenic ester α-copaene Sesquiterpene Geranyl acetate Monoterpenic ester β-elemene Sesquiterpene Dodecanal Aliphatic aldehyde Page 3/9

5 β-caryophyllene Sesquiterpene β-copaene Sesquiterpene α-humulene Sesquiterpene (E)-β-Farnesene Sesquiterpene γ-muurolene tr 0.01 Sesquiterpene Germacrene D 0.02 [0.12]* Sesquiterpene Valencene Sesquiterpene α-muurolene 0.01 tr Sesquiterpene γ-cadinene Sesquiterpene δ-cadinene 0.03 [0.04] Sesquiterpene Caryophyllene oxide Sesquiterpenic ether β-sinensal Sesquiterpenic aldehyde α-sinensal Sesquiterpenic aldehyde Myristic acid Aliphatic acid Palmitic acid Aliphatic acid Linoleic acid Aliphatic acid Oleic acid * Aliphatic acid cis-vaccenic acid? 0.02 [0.08]* Aliphatic acid Stearic acid Aliphatic acid Tetramethoxyflavone isomer 0.02 Flavonoid Tangeretin 0.02 Flavonoid 3,3',4',5,6,7,8-Heptamethoxyflavone tr Flavonoid Nobiletin 0.01 Flavonoid Total identified 98.76% 99.03% *: Two or more compounds are coeluting on this column [xx]: Duplicate percentage due to coelutions, not taken account in the identified total tr: The compound has been detected below 0.005% of total signal. Note: no correction factor was applied Page 4/9

6 This page was intentionally left blank. The following pages present the complete data of the analysis. Page 5/9

7 Page 6/9

8 Page 7/9

9 FULL ANALYSIS DATA Identification Column DB-5 Column DB-WAX R.T R.I % R.T R.I % Hexanal tr tr Heptanal tr tr α-thujene tr tr α-pinene Camphene tr tr Sabinene 3.58* β-pinene 3.58* 970 [0.44] Myrcene α-phellandrene 4.08* Octanal 4.08* 1003 [0.31] Δ3-Carene para-cymene 4.65* Limonene 4.65* 1039 [93.14] ,8-Cineole 4.65* 1039 [93.14] (Z)-β-Ocimene tr tr (E)-β-Ocimene γ-terpinene tr cis-sabinene hydrate Octanol Isoterpinolene tr tr Terpinolene Linalool Nonanal trans-para-mentha- 2,8-dien-1-ol cis-limonene oxide cis-para-mentha-2,8- dien-1-ol * trans-limonene oxide Citronellal Terpinen-4-ol α-terpineol * cis-piperitol tr tr Decanal Octyl acetate trans-carveol Nerol cis-carveol Neral * 1630 [0.09] (E)-Isogeraniol? Geraniol Perillaldehyde Geranial Limonen-10-ol Undecanal Neryl acetate tr α-copaene Geranyl acetate Page 8/9

10 β-elemene Dodecanal β-caryophyllene β-copaene α-humulene (E)-β-Farnesene γ-muurolene tr Germacrene D * 1654 [0.12] Valencene α-muurolene tr γ-cadinene δ-cadinene [0.04] Caryophyllene oxide β-sinensal α-sinensal Myristic acid Palmitic acid Linoleic acid Oleic acid * cis-vaccenic acid? * 3160 [0.08] Stearic acid Tetramethoxyflavone isomer Tangeretin ,3',4',5,6,7,8- Heptamethoxyflavone tr Nobiletin Total identified 98.76% 99.03% Total reported 98.76% 99.03% *: Two or more compounds are coeluting on this column [xx]: Duplicate percentage due to coelutions, not taken account in the identified total : Peaks apexes were resolved, but peaks overlapped and were summed for analysis tr: The compound has been detected below 0.005% of total signal. Note: no correction factor was applied R.T.: Retention time (minutes) R.I.: Retention index Page 9/9