Recent Developments in Processing of Fats and Oils

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1 Ken Carlson Technologies Inc., USA.

2 Topics General Trends Fractionation Degumming/Neutralization Bleaching Hydrogenation Interesterification Deodorization Fish Oil Biodiesel Controls

3 General Trends New Processing Technology: BioChem (enzymes) Environmental: Effluents, water, odors Sustainability: Consumption vs supply, energy Oil uality: Flavor, shelf life, nutrition, toxins, etc. Recovery of by-products: Fatty acids, tocos, etc. Automated lab: FFA, OSI, ICP, moisture, etc. On-line uality monitoring: Color, FFA Controls: Ethernet

4 Fractionation

5 Degumming/Neutralization Cavitation technology Combined PLC/PLA enzymes for degumming Integrated direct drive separators

6 Cavitation Technology

7 Cavitation Technology Arisdyne Systems Controlled Flow Cavitation Degumming and Neutralization with Higher Yield and Less Chemicals Small footprint Easy to install Robust and durable Adjustable capacity Resists clogging

8 Combined PLC/PLA Enzymes

9 Integrated Direct Drive Separators

10 Bleaching In-line color monitoring New clays & gum/soap adsorbents Increased use of activated carbon for removal of toxins (PAH s, dioxins, etc.) and non-carotene red/brown colors Bleaching clay with activated carbon Enzymatic bleaching trials Increased use of pulse tube filters

11 In-line Color Monitoring

12 New Clays and Gum Adsorbents

13 New Clays and Gum Adsorbents

14 New Clays and Gum Adsorbents

15 Bleaching Clay with Activated Carbon

16 Enzymatic Bleaching

17 Increased use of Pulse Tube Filters

18 Hydrogenation Partial hydrogenation replaced by fully hydrogenated fats blended and interesterified with liuid oils New more efficient/selective catalysts Improved reactor agitator designs

19 New Catalysts

20 Interesterification Soap removal by adsorbents rather than washing in chemical process Safer handling of catalyst Enzymatic replacing chemical process

21 Batch Chemical Interesterification Sodium Methoxide To Dosing vacuum System Silica Earth Adsorbent Filter N2 N2 Dosing System Safety Filter Reactor Spent Adsorbent Filter Aid Blended bleached oils Heater Citric Acid Dosing System Drop Tank Precoat Tank Interesterified oil

22 Continuous Enzymatic Interesterification As per DeSmet/Novozymes Vacuum Dryer To vacuum To vacuum Buffer Tank Enzyme To vacuum Enzyme Preparation Tank Heater Cooler Blended oils 4-6 Interesterification Reactors To vacuum Product Tank Safety Filters Cooler Interesterified oils

23 Deodorization Two-stage scrubbers for separation of FFA s and micro nutrients (tocos etc.) (various designs by Alfa-Laval, Crown, DeSmet, Lipico etc.) Increasing use of clean vacuum systems Increasing use of ice condensation vacuum systems

24 Two Stage Scrubbers To vacuum system Generic Design (no proprietary details) Low Temp Section High Temp Section Vapor from Deodorizer High Toco Fraction High FFA Fraction Circ Pump Cooler Circ Pump Cooler

25 Dirty vs Clean Vacuum Systems Vapor from Deodorization Dirty System Vapor from Deodorization Clean System Greasy water to Cooling Tower Clean water to Cooling Effluent Tower Hot Well Caustic Greasy water Cooler Water Chiller Cooling Water

26 Ice Condensation Systems In use Hot ammonia Melting Ice Condensers Vapor from Deodorizer Ammonia to Chiller Ammonia from Chiller Melted fat Hot Well Effluent

27 Enzyme for Fish Oil Concentrates

28 Enzyme for Biodiesel

29 Recent Developments in Controls Fieldbus allowing multiple units per wire set as well as two-way communication with digital HART type instruments with EDDL Wireless instruments for remote locations Handheld communicators for linking with SCADA system Some common terms: RTU Remote Terminal Unit (converts sensor to digital data) PLC Programmable Logic Controller SCADA Supervisory Control Automation Data Acuisition HMI Human Machine Interface (PC) LAN Local Area Network WLAN Wireless Local Area Network Fieldbus Digital two-way data transfer (6 8 devices/cable) Ethernet Standard communications protocol for building LANs HART Highway Addressable Remote Transducer (communication protocol for smart hosts and devices) EDDL Electronic Device Description Language (for accessing instrument manuals in SCADA system)

30 Thanks for Your Attention! XV Latin AOCS Congress, Santiago 2013 Thanks for Your Attention!

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