recovery of humic substances from ion exchange brine

Size: px
Start display at page:

Download "recovery of humic substances from ion exchange brine"

Transcription

1 recovery of humic substances from ion exchange brine Elisabeth Vaudevire

2 recovery of humic substances from ion exchange brine overview origin of the brine specific adsorption of humic substances by IEX characterization of the humic substances technological aspects for compounds separation and recovery contamination with micropollutants applications opportunity for humic substances, business case and legal framework

3 origin and quality figures IEX process

4 NOM adsorption to IEX resin LC OCD profile OCD signal retention time (minute) raw water ion exchange treated

5 NOM desorbed in the brine LC-OCD profile Humic s Building blocks Biopolymers LMW Acids and HS

6 characterization of the humic substances humic fraction as part of NOM Why characterization Prior step of purification Results from Fourier transform infra red characterization

7 characterization of the humic substances isolation protocol recommended by IHSS acidification to ph 1 to 2 precipitate neutralized, centrifuged and reacidified until inorganic ashes <1% = humic fraction supernatant passed through XAD-8 column = fluvic fraction

8 characterization of the humic substances isolation protocol recommended by IHSS SAMPLE Corg mg/l Humic C fractions IEX brine PWN total NOM 2112 non humic C % humic acid 51% humic C 1093 fluvic acid 49% IEX brine DEWG total NOM non humic C % humic acid 37% humic C 4978 fluvic acid 63% Waste Water treated total NOM 1328 non humic C % humic acid 57% humic C 323 fluvic acid 43%

9 characterization of the humic substances FTIR spectra Fourier transform infra red spectrometry: qualitative molecular analysis method use infra red source as baseline of energy when a sample is expose to IR, absorbance of that sample is used to measure the bonds of the carbon atoms

10 characterization of the humic substances FTIR spectra FT-IR Spectra_CF FA1_CF HA1_CF %T wavenumber (cm -1 ) wavenumber (cm-1)

11 characterization of the humic substances FTIR spectra FT-IR Spectra_CF FA1_CF HA1_CF PWN %T 40 FT-IR Spectra_IEX BRINE FA2_IEX BRINE HA2_IEX BRINE wavenumber (cm -1 ) %T de Watergoep wavenumber (cm -1 ) SIMILAR CARBON BONDS

12 characterization of the humic substances FTIR spectra FT-IR Spectra_CF FA1_CF HA1_CF PWN %T FT-IR Spectra_TILBURG FA3_TILBURG HA3_TILBURG wavenumber (cm -1 ) %T waste water evides wavenumber (cm -1 )

13 characterization of the humic substances FTIR spectra FT-IR Spectra_CF FA1_CF HA1_CF C=O %T wavenumber (cm -1 ) wavenumber (cm-1)

14 characterization of the humic substances FTIR spectra FT-IR Spectra_CF FA1_CF HA1_CF %T wavenumber (cm -1 ) wavenumber (cm-1)

15 characterization of the humic substances FTIR spectra -CH2- -CH3 FT-IR Spectra_CF FA1_CF HA1_CF %T wavenumber (cm -1 ) wavenumber (cm-1)

16 characterization of the humic substances FTIR conclusions stretch of C=0 bond, indicates high polarity higher than in most commercially available samples stretch of C=0 in carbonyl linked to benzene ring higher proportion of aromatic rings in fulvic acids presence of CH3 and CH2 in aliphatic parts of the structure, indicates hydrophobicity HS from brine are more soluble and presumably have better chelating properties compared to other sources of commercial humic substances

17 separation of humic substances on industrial scale

18 mono-selective electrodialysis c SO 4 NO M a c a c a SO 4 NO M SO 4 NO M brine water brine water brine

19 mono-selective electrodialysis c SO 4 NO M a c a c a SO 4 NO M SO 4 NO M brine water brine water brine

20 mono-selective electrodialysis c SO 4 NO M a c a c a SO 4 NO M SO 4 NO M brine brine brine

21 electrodialysis standard c NO M a c a c a SO 4 SO 4 SO 4 NO M NO M brine water brine water brine

22 electrodialysis standard c NO M a c a c a SO 4 NO M SO 4 NO M SO 4 brine 2 SO 4 brine 2 SO 4 brine

23 separation of humic substances on industrial scale

24 contamination with organic micropollutants definition organic substances whose toxic, persistent and bioaccumulative properties may have a negative effect on the environment and/or organisms. They are present in many products that we consume daily (drugs, cosmetics, phytosanitary products, insecticides, etc.), at the home or in industry.

25 contamination with micropollutants micropollutants from IJssel lake concentrating in the brine 40% 35% 30% 25% 20% 15% 10% 5% 0% negative neutral zwitter positive

26 contamination with micropollutants passage from brine through mono selective electrodialysis 0,90 0,70 0,50 0,30 0,10-0,10 percentage remaining in the brine percentage adsorbed/ degrading percentage transferred to concentrate

27 contamination with micropollutants passage from ED effluent through electrodialysis standard 0,90 0,70 0,50 0,30 0,10-0,10 percentage remaining in the brine percentage adsorbed/ degrading Percentage transferred to concentrate

28 contamination with micropollutants conclusions confirms the retention onto ion exchange resin of negatively charged organic micro-pollutants specifically explains the passage through selective and standard ion exchange membranes by van der waals radius: smaller molecules only through selective membranes most organic micropollutants species passing standard membranes no standards available for organic micro-pollutants limits in NOM applications

29 recovery of humic substances from ion exchange brine overview origin of the brine specific adsorption of humic substances by IEX characterization of the humic substances technological aspects for compounds separation and recovery contamination with micropollutants applications opportunity for humic substances, business case and legal framework

30 Thank you!

Junias Adusei-Gyamfi. Supervisors: University of Lille: Justine Criquet, Baghdad Ouddane TU Delft: Bas Heijman, Luuk Rietveld. Second DOC2C's workshop

Junias Adusei-Gyamfi. Supervisors: University of Lille: Justine Criquet, Baghdad Ouddane TU Delft: Bas Heijman, Luuk Rietveld. Second DOC2C's workshop Characterization of Natural Organic Matter and processes during drinking water treatments Junias Adusei-Gyamfi 1 Supervisors: University of Lille: Justine Criquet, Baghdad Ouddane TU Delft: Bas Heijman,

More information

CEE 697z Organic Compounds in Water and Wastewater

CEE 697z Organic Compounds in Water and Wastewater Print version CEE 697z Organic Compounds in Water and Wastewater Isolation of NOM Lecture #3 A USGS Preparative-based method Leenheer, J.A. and Noyes, T.I. (1984) A Filtration and Column- Adsorption System

More information

anna.ida3@gmail.com/2013 Have you ever heard HUMUS?? A brown to black complex variable of carbon containing compounds as possessing cellular organization in the form of plant and animal bodies Derived

More information

CEE 697z Organic Compounds in Water and Wastewater

CEE 697z Organic Compounds in Water and Wastewater Print version CEE 697z Organic Compounds in Water and Wastewater NOM and MS Methods Lecture #10 NOM Characterization Analytical Tests elemental analysis spectral properties functional group chemistry Separation/Fractionation

More information

CEE 697z Organic Compounds in Water and Wastewater

CEE 697z Organic Compounds in Water and Wastewater Print version CEE 697z Organic Compounds in Water and Wastewater NOM and MS Methods Lecture #10 NOM Characterization Analytical Tests elemental analysis spectral properties functional group chemistry Separation/Fractionation

More information

Introduction to humic substances

Introduction to humic substances Hymato Products Ltd. The harmony of the elements Introduction to humic substances Writen by: Dr János Csicsor member of the International Humic Substance Society 1 THE PROBLEM Researchers often face insolvable

More information

Identification of Aromatic Fatty Acid Ethyl Esters

Identification of Aromatic Fatty Acid Ethyl Esters Chapter 3.2 Identification of Aromatic Fatty Acid Ethyl Esters The only use of gas chromatography is not sufficient to determine which compounds are eluting from the catalytic bed. At the beginning of

More information

Guixue.Song 1, Julieta.Ferreira 1, Corinna.Byrne 1, Deirdre.Fay 2, Michael.H.B.Hayes 1

Guixue.Song 1, Julieta.Ferreira 1, Corinna.Byrne 1, Deirdre.Fay 2, Michael.H.B.Hayes 1 Guixue.Song 1, Julieta.Ferreira 1, Corinna.Byrne 1, Deirdre.Fay 2, Michael.H.B.Hayes 1 1 Chemical & Environmental Sciences Department, University of Limerick 2 Johnstown Castle Research Centre, Teagasc

More information

Chapter 12: Mass Spectrometry: molecular weight of the sample

Chapter 12: Mass Spectrometry: molecular weight of the sample Structure Determination: hapter 12: Mass Spectrometry- molecular weight of the sample; formula hapter 12: Infrared Spectroscopy- indicated which functional groups are present hapter 13: Nuclear Magnetic

More information

Bacterial adhesion is important for understanding biofilm formation, pathogen and contaminant transport, and bioremediation of soil and water. Bacterial adhesion represents the attachment of the bacteria

More information

Organic Chemistry Diversity of Carbon Compounds

Organic Chemistry Diversity of Carbon Compounds Organic Chemistry Diversity of Carbon Compounds Hydrocarbons The Alkanes The Alkenes The Alkynes Naming Hydrocarbons Cyclic Hydrocarbons Alkyl Groups Aromatic Hydrocarbons Naming Complex Hydrocarbons Chemical

More information

ENVE 424 Anaerobic Treatment

ENVE 424 Anaerobic Treatment ENVE 424 Anaerobic Treatment Lecture 6 Toxic substances in anaerobic treatment 2012 2013 Fall 01 Nov 2012 Assist. Prof. A. Evren Tugtas Basic Fundamentals Inhibition Competitive Inhibition Uncompetitive

More information

Kinetic model of the biomass hydrolysis by polysulfone. membrane with chemically linked acidic ionic liquids via.

Kinetic model of the biomass hydrolysis by polysulfone. membrane with chemically linked acidic ionic liquids via. Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2018 Kinetic model of the biomass hydrolysis by polysulfone membrane with chemically linked acidic

More information

Thesis Summary THE CHEMICAL AND ANALYTICAL CONTROL OF HUMIC ACIDS IN NATURAL PRODUCTS

Thesis Summary THE CHEMICAL AND ANALYTICAL CONTROL OF HUMIC ACIDS IN NATURAL PRODUCTS Thesis Summary THE CHEMICAL AND ANALYTICAL CONTROL OF HUMIC ACIDS IN NATURAL PRODUCTS Scientific Coordinator, Prof. PhD Alexandru Popescu PhD student, Irina Daniela Nicolaescu The PhD thesis entitled The

More information

Using DGT to Measure Bioavailable Metals in a Constructed Wetland Treatment System

Using DGT to Measure Bioavailable Metals in a Constructed Wetland Treatment System Using DGT to Measure Bioavailable Metals in a Constructed Wetland Treatment System Michael H. Paller (Savannah River National Laboratory) Anna Sophia Knox (Savannah River National Laboratory) Coral Springs,

More information

APPLICATIONS OF FTIR SPECTROSCOPY IN ENVIRONMENTAL STUDIES SUPPORTED BY TWO DIMENSIONAL CORRELATION ANALYSIS

APPLICATIONS OF FTIR SPECTROSCOPY IN ENVIRONMENTAL STUDIES SUPPORTED BY TWO DIMENSIONAL CORRELATION ANALYSIS Global NEST Journal, Vol 11, No 4, pp 593-6, 29 Copyright 29 Global NEST Printed in Greece. All rights reserved APPLICATIONS OF FTIR SPECTROSCOPY IN ENVIRONMENTAL STUDIES SUPPORTED BY TWO DIMENSIONAL CORRELATION

More information

Effect of NOM Characteristics on the Removal of Pharmaceutically Active and Endocrine Disrupting Compounds by Coagulation

Effect of NOM Characteristics on the Removal of Pharmaceutically Active and Endocrine Disrupting Compounds by Coagulation Effect of NOM Characteristics on the Removal of Pharmaceutically Active and Endocrine Disrupting Compounds by Coagulation Sabrina Diemert (M.A.Sc. Candidate) sabrina.diemert@utoronto.ca Robert C. Andrews

More information

Biochemical Techniques 06 Salt Fractionation of Proteins. Biochemistry

Biochemical Techniques 06 Salt Fractionation of Proteins. Biochemistry . 1 Description of Module Subject Name Paper Name 12 Module Name/Title 2 1. Objectives Understanding the concept of protein fractionation Understanding protein fractionation with salt 2. Concept Map 3.

More information

Isolation, Separation, and Characterization of Organic Acids*

Isolation, Separation, and Characterization of Organic Acids* In Dashek, William V., ed. Methods in plant biochemistry and molecular biology. Boca Raton, FL: CRC Press: pp. 107-113. Chapter 9.1997. Isolation, Separation, and Characterization of Organic Acids* William

More information

This place covers: Reducing the size of material from which sugars are to be extracted; Presses and knives therefor,

This place covers: Reducing the size of material from which sugars are to be extracted; Presses and knives therefor, CPC - C13B - 2017.08 C13B PRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR (chemically synthesised sugars or sugar derivatives C07H; fermentation or enzyme-using processes for preparing compounds

More information

BCH302 [Practical] 1

BCH302 [Practical] 1 BCH302 [Practical] 1 Amino acids play a central role: i. As building blocks of proteins. ii. As intermediates in metabolism, converted to specialized products. There are 20 natural amino acids that are

More information

Application Note # FTMS-46 solarix XR: Analysis of Complex Mixtures

Application Note # FTMS-46 solarix XR: Analysis of Complex Mixtures Application Note # FTMS-46 solarix XR: Analysis of Complex Mixtures Introduction Natural organic matter (NOM) as well as crude oil and crude oil fractions are very complex mixtures of organic compounds

More information

The potential utilization of coconut oil and palm oil as raw material of alkanolamide under alkaline conditions

The potential utilization of coconut oil and palm oil as raw material of alkanolamide under alkaline conditions IOP Conference Series: Earth and Environmental Science PAPER OPEN ACCESS The potential utilization of coconut oil and palm oil as raw material of alkanolamide under alkaline conditions To cite this article:

More information

The effect of humic acid and fulvic acid on adsorption-desorption behavior of copper and zinc in the yellow soil

The effect of humic acid and fulvic acid on adsorption-desorption behavior of copper and zinc in the yellow soil The effect of humic acid and fulvic acid on adsorption-desorption behavior of copper and zinc in the yellow soil Zhantai Wang, Minxia Cao, Wenchang Cai, and Heping Zeng Citation: AIP Conference Proceedings

More information

Time (min) Supplementary Figure 1: Gas decomposition products of irradiated DMC.

Time (min) Supplementary Figure 1: Gas decomposition products of irradiated DMC. 200000 C 2 CH 3 CH 3 DMC 180000 160000 140000 Intensity 120000 100000 80000 60000 40000 C 2 H 6 CH 3 CH 2 CH 3 CH 3 CCH 3 EMC DEC 20000 C 3 H 8 HCCH 3 5 10 15 20 25 Time (min) Supplementary Figure 1: Gas

More information

The four levels of protein structure are: primary structure, secondary structure, tertiary structure, and quaternary structure.

The four levels of protein structure are: primary structure, secondary structure, tertiary structure, and quaternary structure. Proteins Proteins are organic complex nitrogenous compounds of high molecular weight, formed of C, H, O and N. They are formed of a number of amino acids linked together by peptide linkage [-CO-NH-]. Proteins

More information

3.1 Background. Preformulation Studies

3.1 Background. Preformulation Studies Preformulation Studies 3.1 Background Delivery of any drug requires a suitable dosage form to get optimum therapeutic effects. The development of such dosage forms fundamental properties of the drug molecule

More information

Differentiation Between Nutritional and Carcinogenic Selenium via Speciation Analyses

Differentiation Between Nutritional and Carcinogenic Selenium via Speciation Analyses Presented at the AOAC Conference, September 29, 2015 Differentiation Between Nutritional and Carcinogenic Selenium via Speciation Analyses Russell Gerads Business Development Director Brooks Applied Labs

More information

Topic 6 Structure Determination Revision Notes

Topic 6 Structure Determination Revision Notes 1) Introduction Topic 6 Structure Determination Revision Notes Mass spectrometry, infrared spectroscopy and NMR spectroscopy can be used to determine the structure of unknown compounds 2) Mass spectrometry

More information

Qualitative chemical reaction of functional group in protein

Qualitative chemical reaction of functional group in protein Qualitative chemical reaction of functional group in protein Certain functional groups in proteins can react to produce characteristically colored products. The color intensity of the product formed by

More information

Fundamentals of Organic Chemistry CHEM 109 For Students of Health Colleges Credit hrs.: (2+1)

Fundamentals of Organic Chemistry CHEM 109 For Students of Health Colleges Credit hrs.: (2+1) Fundamentals of Organic Chemistry CHEM 109 For Students of Health Colleges Credit hrs.: (2+1) King Saud University College of Science, Chemistry Department CHEM 109 CHAPTER 7. CARBOXYLIC ACIDS AND THEIR

More information

AMINO ACIDS. Qualitative Tests

AMINO ACIDS. Qualitative Tests AMINO ACIDS Qualitative Tests AMINO ACIDS Amino acid play A central role as building block of proteins. Amino acids also converted to specialized products. More than 300 different amino acids have been

More information

Chemical Nature of the Amino Acids. Table of a-amino Acids Found in Proteins

Chemical Nature of the Amino Acids. Table of a-amino Acids Found in Proteins Chemical Nature of the Amino Acids All peptides and polypeptides are polymers of alpha-amino acids. There are 20 a- amino acids that are relevant to the make-up of mammalian proteins (see below). Several

More information

FOULING RESISTANT REVERSE OSMOSIS MEMBRANES. Ja-young Koo, Sung Pyo Hong, Hoon Hyung, Young Hun Kim, Sungro Yoon, Soon Sik Kim

FOULING RESISTANT REVERSE OSMOSIS MEMBRANES. Ja-young Koo, Sung Pyo Hong, Hoon Hyung, Young Hun Kim, Sungro Yoon, Soon Sik Kim FOULING RESISTANT REVERSE OSMOSIS MEMBRANES Ja-young Koo, Sung Pyo Hong, Hoon Hyung, Young Hun Kim, Sungro Yoon, Soon Sik Kim Filter Business Division Saehan Industries, Inc, 1 Jungsandong, Kyungsan city,

More information

GC/MS and GC/FTIR as Powerful Tools for Identifying Bioactive Compounds

GC/MS and GC/FTIR as Powerful Tools for Identifying Bioactive Compounds ACTA CHEMICA IASI, 19, 1-19 (2011) GC/MS and GC/FTIR as Powerful Tools for Identifying Bioactive Compounds Steluţa Gosav a,b* and Rodica Dinică c a Chemistry Departament, Al.I. Cuza University Iasi, 11

More information

Foliar Feeding DOES Work! The Science and Philosophy of Foliar Nutri7on Roch Gaussoin. PhD University of Nebraska Lincoln

Foliar Feeding DOES Work! The Science and Philosophy of Foliar Nutri7on Roch Gaussoin. PhD University of Nebraska Lincoln Foliar Feeding DOES Work! The Science and Philosophy of Foliar Nutri7on Roch Gaussoin. PhD University of Nebraska Lincoln rgaussoin1@unl.edu 2013 Winter Seminar What the heck is a turf specialist doing

More information

Preparation and Application of Chitosan - Polyethersulfone Composite Ultrafiltration Membrane for Humic Acid Removal

Preparation and Application of Chitosan - Polyethersulfone Composite Ultrafiltration Membrane for Humic Acid Removal Preparation and Application of Chitosan - Polyethersulfone Composite Ultrafiltration Membrane for Humic Acid Removal Yong Sun 1, Tianshi Wang 1, Jiasen Wang 1, Huiling Yang 1, Fuqiao Guo 1, Xinyu Wang

More information

Wastewater Treatment: Reducing Salts Generated During Treatment to Promote Water Re-Use. By: David Calnan Cherokee Chemical Inc, (CCI)

Wastewater Treatment: Reducing Salts Generated During Treatment to Promote Water Re-Use. By: David Calnan Cherokee Chemical Inc, (CCI) Wastewater Treatment: Reducing Salts Generated During Treatment to Promote Water Re-Use By: David Calnan Cherokee Chemical Inc, (CCI) Objective Cost-effective effluent recovery utilizing chemical pre-treatment

More information

The complexing capacities of humic substances isolated from Baltic sediments and their molecular weight fractions towards copper(ii) and iron (III)*

The complexing capacities of humic substances isolated from Baltic sediments and their molecular weight fractions towards copper(ii) and iron (III)* The complexing capacities of humic substances isolated from Baltic sediments and their molecular weight fractions towards copper(ii) and iron (III)* OCEANOLOGIA, No. 34 pp. 39-47, 1993. PL ISSN 0078-3234

More information

Chapter 20: Carboxylic Acids and Nitriles شیمی آلی 2

Chapter 20: Carboxylic Acids and Nitriles شیمی آلی 2 Chapter 20: Carboxylic Acids and Nitriles شیمی آلی 2 Dr M. Mehrdad University of Guilan, Department of Chemistry, Rasht, Iran m-mehrdad@guilan.ac.ir Based on McMurry s Organic Chemistry, 7 th edition The

More information

Preliminary Study of Zinc Removal from Cyanide-free Alkaline Electroplating Effluent by Precipitation using Oxalis Plants

Preliminary Study of Zinc Removal from Cyanide-free Alkaline Electroplating Effluent by Precipitation using Oxalis Plants ORIENTAL JOURNAL OF CHEMISTRY An International Open Free Access, Peer Reviewed Research Journal www.orientjchem.org ISSN: 0970-020 X CODEN: OJCHEG 2014, Vol. 30, No. (2): Pg. 515-519 Preliminary Study

More information

Ion exchange for NOM removal

Ion exchange for NOM removal Ion exchange for NOM removal from a sulfaterich surface water incorporating full reuse of the brine Feasibility study at WTW the Blankaart L. Verdickt, V. D Haeseleer, W. Closset, J. Cromphout VMW (Flemish

More information

Humic Substan. Humic Substances. The Real Dirt On. by Ryan Zadow. and require that only humic acid be used on labels. This creates

Humic Substan. Humic Substances. The Real Dirt On. by Ryan Zadow. and require that only humic acid be used on labels. This creates by Ryan Zadow The Real Dirt n Humic Substances Humic substances (HS) are the least understood component acid, which is no surprise to people who have experience using of soil, yet one of the most important

More information

The Removal of Metal Ions (Cu 2+ and Zn 2+ ) using Waste-reclaimed Adsorbent for Plating Wastewater Treatment Process

The Removal of Metal Ions (Cu 2+ and Zn 2+ ) using Waste-reclaimed Adsorbent for Plating Wastewater Treatment Process , October 20-22, 2010, San Francisco, USA The Removal of Metal Ions (Cu 2+ and Zn 2+ ) using Waste-reclaimed Adsorbent for Plating Wastewater Treatment Process Young-Hoon Jo, Si-Hyun Do, Yoon-Seok Jang,

More information

Calcium Complexing Abilities of Fulvic Acids Extracted from Lacustrine Sediments Masae HASEGAWA,KeijiUSUI and Haruo SHINDO

Calcium Complexing Abilities of Fulvic Acids Extracted from Lacustrine Sediments Masae HASEGAWA,KeijiUSUI and Haruo SHINDO Chikyukagaku Geochemistry Calcium Complexing Abilities of Fulvic Acids Extracted from Lacustrine Sediments Masae HASEGAWA,KeijiUSUI and Haruo SHINDO Faculty of Agriculture, Yamaguchi University Yoshida

More information

Life Sciences 1a. Practice Problems 4

Life Sciences 1a. Practice Problems 4 Life Sciences 1a Practice Problems 4 1. KcsA, a channel that allows K + ions to pass through the membrane, is a protein with four identical subunits that form a channel through the center of the tetramer.

More information

Great Lakes Generation

Great Lakes Generation Great Lakes Generation Jack Boilerman 20338 Progress Dr. Strongsville, OH 44149 216-251-2510 Machine No: 19-1-3007 Fluid Type: Phosphate Ester Machine Type: EHC Hydraulic System Sample Source: Unit 1 EHC

More information

1/3/2011. Chapter 17 Carboxylic Acids and Their Derivatives. Nucleophilic Addition- Elimination at the Acyl Carbon

1/3/2011. Chapter 17 Carboxylic Acids and Their Derivatives. Nucleophilic Addition- Elimination at the Acyl Carbon Introduction The carboxyl group (-CO 2 H) is the parent group of a family of compounds called acyl compounds or carboxylic acid derivatives Chapter 17 Carboxylic Acids and Their Derivatives. Nucleophilic

More information

Downloaded from

Downloaded from Question 16.1: Why do we need to classify drugs in different ways? The classification of drugs and the reasons for classification are as follows: (i) On the basis of pharmacological effect: This classification

More information

Eszopiclone (Lunesta ): An Analytical Profile

Eszopiclone (Lunesta ): An Analytical Profile Eszopiclone (Lunesta ): An Analytical Profile Roxanne E. Franckowski, M.S.* and Robert A. Thompson, Ph.D. U.S. Department of Justice Drug Enforcement Administration Special Testing and Research Laboratory

More information

Copyright 2016 Dan Dill 1

Copyright 2016 Dan Dill 1 carbonate These solutions are mixed and a precipitate forms. After the precipitation, the solution 1. will be positively charged 2. will be electrically neutral 3. will be negatively charged 4. More information

More information

Reactions and amino acids structure & properties

Reactions and amino acids structure & properties Lecture 2: Reactions and amino acids structure & properties Dr. Sameh Sarray Hlaoui Common Functional Groups Common Biochemical Reactions AH + B A + BH Oxidation-Reduction A-H + B-OH + energy ª A-B + H

More information

Journal of Chemical and Pharmaceutical Research, 2015, 7(8): Research Article

Journal of Chemical and Pharmaceutical Research, 2015, 7(8): Research Article Available online www.jocpr.com Journal of Chemical and Pharmaceutical Research, 215, 7(8):257-261 Research Article ISSN : 975-7384 CODEN(USA) : JCPRC5 Pulping process for rice straw in basic ionic liquid

More information

Patrick, An Introduction to Medicinal Chemistry 5e Chapter 1 Drugs and drug targets: an overview

Patrick, An Introduction to Medicinal Chemistry 5e Chapter 1 Drugs and drug targets: an overview Patrick, An Introduction to dicinal hemistry 5e Answers to end-of-chapter questions 1) The ability of a molecule to cross the fatty cell membrane has little to do with its size, but more with its hydrophobic

More information

Lignin-phenol-formaldehyde adhesives with residual. lignin from hardwood bioethanol production

Lignin-phenol-formaldehyde adhesives with residual. lignin from hardwood bioethanol production Lignin-phenol-formaldehyde adhesives with residual lignin from hardwood bioethanol production Soo Jung Lee Bioenergy research center at chonnam national university Contents 1. Background 2. Isolation of

More information

Ex17. Analgesics, TLC Analysis. Analgesics. The Experiment. Part A. Carboxylic Acids. Part B. Willow Bark Esters & Esterification

Ex17. Analgesics, TLC Analysis. Analgesics. The Experiment. Part A. Carboxylic Acids. Part B. Willow Bark Esters & Esterification Ex17 Analgesics, TLC Analysis Analgesics Carboxylic Acids Structure Properties Willow Bark Esters & Esterification The Experiment Part A Use TLC to Separate Compounds Part B Determine Elution Solvents

More information

Separation of Macrocyclic Lactones (Avermectins) on FLARE C18 MM & FLARE C18+ Columns

Separation of Macrocyclic Lactones (Avermectins) on FLARE C18 MM & FLARE C18+ Columns Separation of Macrocyclic Lactones (Avermectins) on FLARE C8 MM & FLARE C8+ Columns Introduction Diamond Analytics Technical Note: T05- Avermectins are a series of 6-membered macrocyclic lactone derivatives

More information

A New Method for Free Fatty Acid Reduction in Frying Oil Using Silicate Films Produced from Rice Hull Ash

A New Method for Free Fatty Acid Reduction in Frying Oil Using Silicate Films Produced from Rice Hull Ash A New Method for Free Fatty Acid Reduction in Frying Oil Using Silicate Films Produced from Rice Hull Ash U. Kalapathy* and A. Proctor Department of Food Science, University of Arkansas, Fayetteville,

More information

DETECTION OF BEESWAX ADULTERATION WITH HYDROCARBONS USING GAS CHROMATOGRAPHY WITH MASS DETECTOR (GC-MS)

DETECTION OF BEESWAX ADULTERATION WITH HYDROCARBONS USING GAS CHROMATOGRAPHY WITH MASS DETECTOR (GC-MS) DETECTION OF BEESWAX ADULTERATION WITH HYDROCARBONS USING GAS CHROMATOGRAPHY WITH MASS DETECTOR (GC-MS) Ewa Waś,, Helena Rybak-Chmielewska, Teresa Szczęsna e-mail: ewa.was@man.pulawy.pl Research Institute

More information

HUMIC SUBSTANCES AND THE POTENTIAL TO COUNTER FIGHT DESERTIFICATION

HUMIC SUBSTANCES AND THE POTENTIAL TO COUNTER FIGHT DESERTIFICATION HUMIC SUBSTANCES AND THE PTENTIAL T CUNTER FIGHT DESERTIFICATIN Dr. Raimonds Kasparinskis Faculty of Geography and Earth Sciences, University of Latvia WHAT DES IT MEAN HUMIC SUBSTANCES (HS)? 1.rganic

More information

IR Spectroscopy Part II

IR Spectroscopy Part II IR Spectroscopy Part II Carbonyl - compounds For simple aldehydes and ketones, the stretching vibration of the carbonyl group is a strong infrared absorption beetwen 1710 and 1740 cm -1. Alkyl substituents

More information

Chapter 2 pt 2. Atoms, Molecules, and Life. Gregory Ahearn. John Crocker. Including the lecture Materials of

Chapter 2 pt 2. Atoms, Molecules, and Life. Gregory Ahearn. John Crocker. Including the lecture Materials of Chapter 2 pt 2 Atoms, Molecules, and Life Including the lecture Materials of Gregory Ahearn University of North Florida with amendments and additions by John Crocker Copyright 2009 Pearson Education, Inc..

More information

Lecture 10: MS Interpretation Part 4 Postulation of Molecular Structures

Lecture 10: MS Interpretation Part 4 Postulation of Molecular Structures Lecture 10: MS Interpretation Part 4 Postulation of Molecular Structures CU- Boulder CHEM 5181 Mass Spectrometry & Chromatography Prof. Jose-Luis Jimenez Postulation of Molecular Structures There are several

More information

DEPARTMENT OF CHEMISTRY AND CHEMICAL ORGANIC CHEMISTRY II 202-BZG-05 03

DEPARTMENT OF CHEMISTRY AND CHEMICAL ORGANIC CHEMISTRY II 202-BZG-05 03 DEPARTMENT OF CHEMISTRY AND CHEMICAL TECHNOLOGY ORGANIC CHEMISTRY II 202-BZG-05 03 TEST 1 11 MARCH 2010 INSTRUCTOR: I. DIONNE PRINT YOUR NAME: Answers INSTRUCTIONS: Answer all questions in the space provided.

More information

SPECIATION OF NATURAL ORGANIC CARBON

SPECIATION OF NATURAL ORGANIC CARBON SPECIATION OF NATURAL ORGANIC CARBON IN TERRESTRIAL SYSTEMS Radosław ZBYTNIEWSKI and Bogusław BUSZEWSKI Department of Environmental Chemistry and Ecoanalytics Faculty of Chemistry, Nicholas Copernicus

More information

Humic acid - ability to use as natural surfactants Jelena Avdalović 1, Srđan Miletić 2, Vladimir Beškoski 2, Mila Ilić 2, Gordana-Gojgić Cvijović 2, Miroslav Vrvić 3 1 Institute for Technology of Nuclear

More information

Extraction News Notes Blog

Extraction News Notes Blog Extraction News Notes Blog www.infinitysupercritical.com BY: Infinity Supercritical Staff EG TAGS: Supercritical CO2 Oil Extraction, Cannabis, Oil Concentrates Sustainable Production of Cannabinoids with

More information

130327SCH4U_biochem April 09, 2013

130327SCH4U_biochem April 09, 2013 Option B: B1.1 ENERGY Human Biochemistry If more energy is taken in from food than is used up, weight gain will follow. Similarly if more energy is used than we supply our body with, weight loss will occur.

More information

MBB 694:407, 115:511. Please use BLOCK CAPITAL letters like this --- A, B, C, D, E. Not lowercase!

MBB 694:407, 115:511. Please use BLOCK CAPITAL letters like this --- A, B, C, D, E. Not lowercase! MBB 694:407, 115:511 First Test Severinov/Deis Tue. Sep. 30, 2003 Name Index number (not SSN) Row Letter Seat Number This exam consists of two parts. Part I is multiple choice. Each of these 25 questions

More information

Proteins. Amino acids, structure and function. The Nobel Prize in Chemistry 2012 Robert J. Lefkowitz Brian K. Kobilka

Proteins. Amino acids, structure and function. The Nobel Prize in Chemistry 2012 Robert J. Lefkowitz Brian K. Kobilka Proteins Amino acids, structure and function The Nobel Prize in Chemistry 2012 Robert J. Lefkowitz Brian K. Kobilka O O HO N N HN OH Ser65-Tyr66-Gly67 The Nobel prize in chemistry 2008 Osamu Shimomura,

More information

Genetic and Environmental Info in goat milk FTIR spectra

Genetic and Environmental Info in goat milk FTIR spectra Genetic and Environmental Info in goat milk FTIR spectra B. Dagnachew and T. Ådnøy Department of Animal and Aquacultural Sciences, Norwegian University of Life Sciences EAAP 2011 29 th August, Stavanger,

More information

I) Choose the best answer: 1- All of the following amino acids are neutral except: a) glycine. b) threonine. c) lysine. d) proline. e) leucine.

I) Choose the best answer: 1- All of the following amino acids are neutral except: a) glycine. b) threonine. c) lysine. d) proline. e) leucine. 1- All of the following amino acids are neutral except: a) glycine. b) threonine. c) lysine. d) proline. e) leucine. 2- The egg white protein, ovalbumin, is denatured in a hard-boiled egg. Which of the

More information

9/6/2011. Amino Acids. C α. Nonpolar, aliphatic R groups

9/6/2011. Amino Acids. C α. Nonpolar, aliphatic R groups Amino Acids Side chains (R groups) vary in: size shape charge hydrogen-bonding capacity hydrophobic character chemical reactivity C α Nonpolar, aliphatic R groups Glycine (Gly, G) Alanine (Ala, A) Valine

More information

PROTEINS. Building blocks, structure and function. Aim: You will have a clear picture of protein construction and their general properties

PROTEINS. Building blocks, structure and function. Aim: You will have a clear picture of protein construction and their general properties PROTEINS Building blocks, structure and function Aim: You will have a clear picture of protein construction and their general properties Reading materials: Compendium in Biochemistry, page 13-49. Microbiology,

More information

Long-term acid generation containing heavy metals from the tailings of a closed mine and its countermeasures

Long-term acid generation containing heavy metals from the tailings of a closed mine and its countermeasures Long-term acid generation containing heavy metals from the tailings of a closed mine and its countermeasures Kimleang KHOEURN Candidate for the Degree of Doctorate in Engineering Supervisor : Professor

More information

Title: Column Chromatography of Green Fluorescent Protein

Title: Column Chromatography of Green Fluorescent Protein Title: Column Chromatography of Green Fluorescent Protein Approvals: Preparer Date_07Oct06 Reviewer: Mary Jane Kurtz Date 09Jul13 Part I Crude Isolation of GFP from Lysed Cells q Page 1 of 6 1. Purpose:

More information

SYNTHESIS AND CHARACTERIZATION OF SEVERAL AMPHIPHILIC CHITOSAN DERIVATIVES NADHRATUN NAIIM MOBARAK & MD. PAUZI ABDULLAH

SYNTHESIS AND CHARACTERIZATION OF SEVERAL AMPHIPHILIC CHITOSAN DERIVATIVES NADHRATUN NAIIM MOBARAK & MD. PAUZI ABDULLAH SYNTHESIS AND CHARACTERIZATION OF SEVERAL AMPHIPHILIC CHITOSAN DERIVATIVES NADHRATUN NAIIM MOBARAK & MD. PAUZI ABDULLAH School of Chemistry Science and Food Technology, Faculty of Science and Technology,

More information

Metabolite: substance produced or used during metabolism such as lipids, sugars and amino acids

Metabolite: substance produced or used during metabolism such as lipids, sugars and amino acids Metabolomica Analisi di biofluidi mediante spettroscopia NMR Michael Assfalg Università di Verona Terminology Metabolite: substance produced or used during metabolism such as lipids, sugars and amino acids

More information

CHEM 242 UV-VIS SPECTROSCOPY, IR SPECTROSCOPY, CHAP 13A ASSIGN AND MASS SPECTROMETRY C 8 H 17 A B C

CHEM 242 UV-VIS SPECTROSCOPY, IR SPECTROSCOPY, CHAP 13A ASSIGN AND MASS SPECTROMETRY C 8 H 17 A B C CEM 242 UV-VIS SPECTRSCPY, IR SPECTRSCPY, CAP 13A ASSIGN AND MASS SPECTRMETRY 1. Which choice matches the max of each steroid in the order given? C 8 17 C 8 17 C 8 17 A B C A. 209 nm 241 nm 284 nm B. 241

More information

CHAPTER 3 Amino Acids, Peptides, Proteins

CHAPTER 3 Amino Acids, Peptides, Proteins CHAPTER 3 Amino Acids, Peptides, Proteins Learning goals: Structure and naming of amino acids Structure and properties of peptides Ionization behavior of amino acids and peptides Methods to characterize

More information

Chapter 18 Carboxylic Acids and Their Derivatives. Nucleophilic Addition- Elimination at the Acyl Carbon

Chapter 18 Carboxylic Acids and Their Derivatives. Nucleophilic Addition- Elimination at the Acyl Carbon Chapter 18 Carboxylic Acids and Their Derivatives. Nucleophilic Addition- Elimination at the Acyl Carbon Introduction The carboxyl group (-CO 2 H) is the parent group of a family of compounds called acyl

More information

109 IWA Publishing 2002 Journal of Water Supply: Research and Technology AQUA

109 IWA Publishing 2002 Journal of Water Supply: Research and Technology AQUA 109 IWA Publishing 2002 Journal of Water Supply: Research and Technology AQUA 51.2 2002 Effects of molecular weight cutoff, f/k ratio (a hydrodynamic condition), and hydrophobic interactions on natural

More information

Toxicant Disposition and Metabolism. Jan Chambers Center for Environmental Health Sciences College of Veterinary Medicine

Toxicant Disposition and Metabolism. Jan Chambers Center for Environmental Health Sciences College of Veterinary Medicine Toxicant Disposition and Metabolism Jan Chambers Center for Environmental Health Sciences College of Veterinary Medicine chambers@cvm.msstate.edu Definitions Disposition Absorption passage across membrane.

More information

EFFECT OF DIFFERENT TREATMENTS ON CELLULOSE TOWARD CARBOXYLATION AND ITS APPLICATION FOR METAL ION ABSORPTION

EFFECT OF DIFFERENT TREATMENTS ON CELLULOSE TOWARD CARBOXYLATION AND ITS APPLICATION FOR METAL ION ABSORPTION EFFECT OF DIFFERENT TREATMENTS ON CELLULOSE TOWARD CARBOXYLATION AND ITS APPLICATION FOR METAL ION ABSORPTION A. M. A. Nada*, S. Abd El-Mongy**, and E. S. Abd El-Sayed* Carboxylation of was investigated

More information

Introduction to Membrane

Introduction to Membrane Heinrich Strathmann Introduction to Membrane Science and Technology WILEY- VCH WILEY-VCH Verlag GmbH & Co. KG aa V Preface Symbols XIII XV 1 Introduction 2 1.1 Overview of Membrane Science and Technology

More information

Biotic and abiotic degradation studies of organic contaminants

Biotic and abiotic degradation studies of organic contaminants Biotic and abiotic degradation studies of organic contaminants Manuela Peschka Ankara, 8th ctober 2007 utline rganic pollutants Selected compounds Simulation of abiotic/biotic degradation ixed bed bioreactor

More information

Amino Acids and Proteins Hamad Ali Yaseen, PhD MLS Department, FAHS, HSC, KU Biochemistry 210 Chapter 22

Amino Acids and Proteins Hamad Ali Yaseen, PhD MLS Department, FAHS, HSC, KU Biochemistry 210 Chapter 22 Amino Acids and Proteins Hamad Ali Yaseen, PhD MLS Department, FAHS, HSC, KU Hamad.ali@hsc.edu.kw Biochemistry 210 Chapter 22 Importance of Proteins Main catalysts in biochemistry: enzymes (involved in

More information

Ultrafiltration as a method of separation of natural organic matter from water

Ultrafiltration as a method of separation of natural organic matter from water Materials Science-Poland, Vol. 26, No. 2, 2008 Ultrafiltration as a method of separation of natural organic matter from water M. KABSCH-KORBUTOWICZ * Wrocław University of Technology, Institute of Environment

More information

Spectroscopic and conductometric study of complexes formed by humic and fulvic acid with metal ions

Spectroscopic and conductometric study of complexes formed by humic and fulvic acid with metal ions 2017; 5(5): 766-770 P-ISSN: 2349 8528 E-ISSN: 2321 4902 IJCS 2017; 5(5): 766-770 2017 IJCS Received: 13-07-2017 Accepted: 14-08-2017 M Eshwar M Srilatha K Bhanu Rekha Department of Agronomy, Agriculture

More information

HICHROM. Chromatography Columns and Supplies NEW PRODUCTS. Catalogue 9. Hichrom Limited

HICHROM. Chromatography Columns and Supplies NEW PRODUCTS. Catalogue 9. Hichrom Limited HICHROM Chromatography Columns and Supplies NEW PRODUCTS Catalogue 9 1 The Markham Centre, Station Road Theale, Reading, Berks, RG7 4PE, UK Tel: +44 (0)118 930 3660 Fax: +44 (0)118 932 3484 Email: sales@hichrom.co.uk

More information

Chapter 13: Alcohols, Phenols, and Ethers

Chapter 13: Alcohols, Phenols, and Ethers Chapter 13: Alcohols, Phenols, and Ethers ALCOHOLS, PHENOLS, AND ETHERS Hydroxy group the OH functional group An alcohol has an OH group attached to an aliphatic carbon. General formula: R-OH A phenol

More information

Improve Protein Analysis with the New, Mass Spectrometry- Compatible ProteasMAX Surfactant

Improve Protein Analysis with the New, Mass Spectrometry- Compatible ProteasMAX Surfactant Improve Protein Analysis with the New, Mass Spectrometry- Compatible Surfactant ABSTRACT Incomplete solubilization and digestion and poor peptide recovery are frequent limitations in protein sample preparation

More information

A 3D Porous Metal-Organic Framework Exhibiting Selective. Adsorption of Water over Organic Solvents

A 3D Porous Metal-Organic Framework Exhibiting Selective. Adsorption of Water over Organic Solvents Supporting Information for A 3D Porous Metal-Organic Framework Exhibiting Selective Adsorption of Water over Organic Solvents Jin-Zhong Gu, Long Jiang, Wen-Guan Lu, Hong-Cai Zhou, and Tong-Bu Lu* Table

More information

Savesta Herbals is engaged in manufacturing

Savesta Herbals is engaged in manufacturing Savesta Herbals is engaged in manufacturing standardized herbal extracts that synergistically combine the ancient wisdom of Ayurveda with the modern production and QC methods. Our state-of- the- art production

More information

PB1617-Irrigation Water Quality for Greenhouse Production

PB1617-Irrigation Water Quality for Greenhouse Production University of Tennessee, Knoxville Trace: Tennessee Research and Creative Exchange Commercial Horticulture UT Extension Publications 2-1999 PB1617-Irrigation Water Quality for Greenhouse Production The

More information

Proteins consist in whole or large part of amino acids. Simple proteins consist only of amino acids.

Proteins consist in whole or large part of amino acids. Simple proteins consist only of amino acids. Today we begin our discussion of the structure and properties of proteins. Proteins consist in whole or large part of amino acids. Simple proteins consist only of amino acids. Conjugated proteins contain

More information

Chem 60 Takehome Test 2 Student Section

Chem 60 Takehome Test 2 Student Section Multiple choice: 1 point each. Mark only one answer for each question. 1. are composed primarily of carbon and hydrogen, but may also include oxygen, nitrogen, sulfur, phosphorus, and a few other elements.

More information

Percentage yield of Polysaccharides

Percentage yield of Polysaccharides Asian J. Biol. Life Sci. Sep-Dec 2016 Vol-5 Issue-3 a. Sargassumwightii b. Padina tetrastromatica C. Dictyota sp Figure 1 : Macroscopic appearance of the seaweeds collected from Madapam, Rameshwaram, India.

More information

Modern Aspects of Colloid Science MICELLES

Modern Aspects of Colloid Science MICELLES Modern Aspects of Colloid Science MICELLES critical micelle concentration (CMC) micellar shape determination of critical micelle concentration purity of surfactants Krafft temperature micellar equilibria

More information

REMOVAL OF HUMIC SUBSTANCES IN WATER BY COAGULATION

REMOVAL OF HUMIC SUBSTANCES IN WATER BY COAGULATION REMOVAL OF HUMIC SUBSTANCES IN WATER BY COAGULATION *Danka BARLOKOVÁ 1, Ján ILAVSKÝ 1 1 Department of Sanitary and Environmental Engineering, Faculty of Civil Engineering of the Slovak University of Technology,

More information