w WOER RSFR-H TUBE 125 VW-1 H)

Transcription

1 Test Report No.: CANEC Date: 22 Aug 2013 Page 1 of 18 SHENZHEN WOER HEAT-SHRINKABLE MATERIAL CO.,LTD. WOER MANSION,LANJING NORTH ROAD,PINGSHAN INDUSTRIAL ZONE,LONGGANG DISTRICT,SHENZHEN CHINA The following sample(s) was/were submitted and identified on behalf of the applicant as w WOER RSFR-H TUBE 125 VW-1 H) RSFR-H HEAT SHRINKABLE TUBINGS(E SGS Job No. : CP SZ Date of sample received : 12 Aug 2013 Testing Period : 12 Aug Aug 2013 Test Requested : Selected test (s) as requested by client. Test Method : Please refer to next page(s). Test Results : Please refer to next page(s). Signed for and on behalf of SGS-CSTC Ltd. Almay Gao Approved Signatory

2 Test Report No.: CANEC Date: 22 Aug 2013 Page 2 of 18 Test Results : Test Part Description : Specimen No. SGS Sample ID Description 1 CAN Black plastic tube w/ white printing Remarks : (1) 1 mg/kg = % (2) MDL = Method Detection Limit (3) ND = Not Detected ( < MDL ) (4) "-" = Not Regulated 4-(1,1,3,3-tetramethylbutyl)phenol, Bis(2-methoxyethyl) ether, N,N-dimethylacetamide;, 1,2- dimethoxyethane; ethylene glycol dimethyl ether (EGDME) Test Method : SGS In-House method- GZTC CHEM-TOP , Analyzed by GC-MS. Test Item(s) CAS_N Unit MDL % (w/w) ND (1,1,3,3-tetramethylbutyl)phen ol Bis(2-methoxyethyl) ether % (w/w) ND N,N-dimethylacetamide % (w/w) ND EGDME % % (w/w) ND olychlorinated Biphenyls (PCBs) Test Method: With reference to US EPA Method 8082A:2007, analysis was performed by GC-MS. Test Item(s): CAS No. Unit MDL Trichlorobiphenyl (PCB 28) mg/kg 0.5 ND Tetrachloro-biphenyl (PCB 52) mg/kg 0.5 ND Pentachloro-biphenyl (PCB 101) mg/kg 0.5 ND Pentachlorobiphenyl (PCB 118) mg/kg 0.5 ND Hexachloro-biphenyl (PCB 138) mg/kg 0.5 ND Hexachloro-biphenyl (PCB 153) mg/kg 0.5 ND Heptachlorobiphenyl (PCB 180) mg/kg 0.5 ND

3 Test Report No.: CANEC Date: 22 Aug 2013 Page 3 of 18 Polychlorinated Naphthalenes (PCNs) Test Method: With reference to US EPA Method 8081B:2007, analysis was performed by GC-MS. Test Item(s): Unit MDL Chlorinated Naphthalene mg/kg 5 ND 2-Chlorinated Naphthalene mg/kg 5 ND 1,4-Dichlorinated Naphthalene mg/kg 5 ND 1,5-Dichlorinated Naphthalene mg/kg 5 ND 1,2-Dichlorinated Naphthalene mg/kg 5 ND 1,8-Dichlorinated Naphthalene mg/kg 5 ND 1,2,3-Trichlorinated Naphthalene mg/kg 5 ND 1,2,3,4-Tetrachlorinated Naphthalene mg/kg 5 ND 1,2,3,4,6-Pentachlorinated Naphthalene mg/kg 5 ND Octa-chlorinaed Naphthalene mg/kg 5 ND Polychlorinated Terphenyls (PCTs) Test Method: With reference to US EPA Method 8082A:2007, analysis was performed by GC-ECD/MS. Test Item(s): Unit MDL 001 Aroclor5432 mg/kg 5 ND Aroclor5442 mg/kg 5 ND Aroclor5460 mg/kg 5 ND Note: by (1) PCTs Reference Information: Entry 1 of Regulation (EC) No 552/2009 amending Annex XVII of REACH Regulation (EC) No 1907/2006 (previously restricted under Directive 89/677/EC) Shall not be placed on the market, or used: as substances, In mixtures, including waste oils, or in equipment, in concentrations greater than 50 mg/kg (0,005 % weight). Please refer to Regulation (EC) No 552/2009 to get more detail information. SCCP (Short chained chlorinated paraffins) Test Method: With reference to US EPA 3550C:2007, analysis was performed by GC-ECD. Test Item(s) Unit MDL 001 Short Chained Chlorinated Paraffins (C10-C13) mg/kg 50 ND

4 Test Report No.: CANEC Date: 22 Aug 2013 Page 4 of 18 Organic-Tin compounds Test Method: With reference to ISO 17353:2004, analysis was performed by GC-MS. Test Item(s): Unit MDL 001 Dibutyltin (DBT) mg/kg 0.02 ND Tributyltin (TBT) mg/kg 0.02 ND Triphenyltin (TPhT) mg/kg 0.02 ND Dioctyltin (DOT) mg/kg 0.02 ND Benzotriazole UV Absorbant Test Method : With reference to US EPA 3550C: 2007, analysis was performed by GC-MS. Test Item(s) Unit MDL (3,5-Di-tert-butyl-2-hydroxyphenyl) benzotriazole mg/kg 5 ND (UV-320) (CAS No: ) 2-(3,5 -Di-tert-butyl-2 -hydroxyphenyl)-5-chloro mg/kg 5 ND benzotriazole (UV-327) (CAS No: ) 2-(2 -hydroxy-3,5 -di-tert- amylphenyl) mg/kg 5 ND benzotriazole (UV-328) (CAS No: ) TinUVin 350 (UV-350) (CAS No: ) mg/kg 5 ND Dimethyl fumarate(dmf) Test Method: SGS Inhouse method (GZTC CHEM-TOP-095), analysis was performed by GC-MS. Test Item(s): Recommended Max. Limit Unit MDL 001 Dimethyl fumarate(dmf) 0.1 mg/kg 0.1 ND Conclusion PASS Note: (1) The maximum permissible limit is quoted from the document EU Directive 2011/135/EU (previously restricted under 2010/153/EU and 2009/251/EC)

5 Test Report No.: CANEC Date: 22 Aug 2013 Page 5 of 18 Polyvinyl chloride (PVC) Test Method: SGS in house method (GZTC CHEM-TOP-066), analysis was performed by FTIR. Test Item(s): CAS No. 001 Polyvinyl chloride (PVC) Negative Note: (1) Negative = Undetectable, Positive = Detectable. ODS Test Method : With reference to US EPA 5021A-2003, analysis was performed by HS-GC-MS. Test Item(s) Unit MDL 001 CFC CAS No CFC mg/kg 0.1 ND CFC mg/kg 0.1 ND CFC mg/kg 0.1 ND CFC mg/kg 0.1 ND CFC mg/kg 0.1 ND CFC mg/kg 0.1 ND CFC mg/kg 0.1 ND CFC mg/kg 0.1 ND CFC mg/kg 0.1 ND CFC mg/kg 0.1 ND CFC mg/kg 0.1 ND CFC mg/kg 0.1 ND CFC mg/kg 0.1 ND CFC mg/kg 0.1 ND CFC mg/kg 0.1 ND CFC mg/kg 0.1 ND CFC mg/kg 0.1 ND CFC mg/kg 0.1 ND CFC mg/kg 0.1 ND CFC mg/kg 0.1 ND HCFC CAS No HCFC mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC-123a mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC-124a mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC-131a mg/kg 0.1 ND

6 Test Report No.: CANEC Date: 22 Aug 2013 Page 6 of 18 HCFC-132a mg/kg 0.1 ND HCFC-132b mg/kg 0.1 ND HCFC-133a mg/kg 0.1 ND HCFC-141b mg/kg 0.1 ND HCFC-142b mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC-225ca mg/kg 0.1 ND HCFC-225cb mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC mg/kg 0.1 ND HCFC mg/kg 0.1 ND HBFC CAS No CHF 2 Br mg/kg 0.1 ND CH 2 FBr mg/kg 0.1 ND C 2 HFBr 4 - mg/kg 0.1 ND C 2 HF 2 Br 3 - mg/kg 0.1 ND C 2 HF 3 Br mg/kg 0.1 ND C 2 HF 4 Br - mg/kg 0.1 ND C 2 H 2 FBr 3 - mg/kg 0.1 ND C 2 H 2 F 2 Br mg/kg 0.1 ND C 2 H 2 F 3 Br mg/kg 0.1 ND C 2 H 3 FBr 2 - mg/kg 0.1 ND C 2 H 3 F 2 Br mg/kg 0.1 ND C 2 H 4 FBr mg/kg 0.1 ND C 3 HFBr 6 - mg/kg 0.1 ND C 3 HF 2 Br 5 - mg/kg 0.1 ND C 3 HF 3 Br 4 - mg/kg 0.1 ND C 3 HF 4 Br 3 - mg/kg 0.1 ND C 3 HF 5 Br 2 - mg/kg 0.1 ND C 3 HF 6 Br - mg/kg 0.1 ND C 3 H 2 FBr 5 - mg/kg 0.1 ND C 3 H 2 F 2 Br 4 - mg/kg 0.1 ND C 3 H 2 F 3 Br 3 - mg/kg 0.1 ND

7 Test Report No.: CANEC Date: 22 Aug 2013 Page 7 of 18 C 3 H 2 F 4 Br 2 - mg/kg 0.1 ND C 3 H 2 F 5 Br - mg/kg 0.1 ND C 3 H 3 FBr 4 - mg/kg 0.1 ND C 3 H 3 F 2 Br 3 - mg/kg 0.1 ND C 3 H 3 F 3 Br 2 - mg/kg 0.1 ND C 3 H 3 F 4 Br - mg/kg 0.1 ND C 3 H 4 FBr 3 - mg/kg 0.1 ND C 3 H 4 F 2 Br 2 - mg/kg 0.1 ND C 3 H 4 F 3 Br - mg/kg 0.1 ND C 3 H 5 FBr 2 - mg/kg 0.1 ND C 3 H 5 F 2 Br - mg/kg 0.1 ND C 3 H 6 FBr - mg/kg 0.1 ND HALON CAS No Halon mg/kg 0.1 ND Halon mg/kg 0.1 ND Halon mg/kg 0.1 ND OTHERS CAS No Dibromofluoromethane mg/kg 0.1 ND Methyl bromide mg/kg 0.1 ND Bromochloromethane mg/kg 0.1 ND SF mg/kg 0.1 ND HFC CAS No ND HFC mg/kg 0.1 ND HFC mg/kg 0.1 ND HFC mg/kg 0.1 ND HFC-43-10mee - mg/kg 0.1 ND HFC mg/kg 0.1 ND HFC mg/kg 0.1 ND HFC-134a mg/kg 0.1 ND HFC-152a mg/kg 0.1 ND HFC mg/kg 0.1 ND HFC-143a mg/kg 0.1 ND HFC-227ea - mg/kg 0.1 ND HFC-236 cb - mg/kg 0.1 ND HFC-236ea mg/kg 0.1 ND HFC-236fa mg/kg 0.1 ND HFC-245ca mg/kg 0.1 ND HFC-245fa - mg/kg 0.1 ND HFC-365mfc - mg/kg 0.1 ND PFC CAS No Perfluoromethane mg/kg 0.1 ND Perfluoroethane mg/kg 0.1 ND Perfluoropropane mg/kg 0.1 ND Perfluorobutane mg/kg 0.1 ND Perfluoropentane mg/kg 0.1 ND Perfluorohexane mg/kg 0.1 ND Perfluorocyclobutane mg/kg 0.1 ND CHC CAS No

8 Test Report No.: CANEC Date: 22 Aug 2013 Page 8 of 18 1,3-dichloropropane mg/kg 0.1 ND 2,2-dichloropropane mg/kg 0.1 ND Carbon tetrachloride mg/kg 0.1 ND Chloroethane mg/kg 0.1 ND Chloroform mg/kg 0.1 ND Chloromethane mg/kg 0.1 ND Cis-1,2-dichloroethene mg/kg 0.1 ND Cis-1,3-dichloropropene mg/kg 0.1 ND Hexachlorobutadiene mg/kg 0.1 ND Methylene chloride mg/kg 0.1 ND Tetrachloroethylene mg/kg 0.1 ND Trans-1,2-dichloroethene mg/kg 0.1 ND Trans-1,3-dichloropropene mg/kg 0.1 ND Trichloroethylene mg/kg 0.1 ND 1,1,1,2-tetrachloroethane mg/kg 0.1 ND 1,1,1-trichloroethane mg/kg 0.1 ND 1,1,2,2-tetrachloroethane mg/kg 0.1 ND 1,1,2-trichloroethane mg/kg 0.1 ND 1,1-dichloroethane mg/kg 0.1 ND 1,1-dichloroethene mg/kg 0.1 ND 1,1-dichloropropene mg/kg 0.1 ND 1,2,3-trichloropropane mg/kg 0.1 ND 1,2-dichloroethane mg/kg 0.1 ND 1,2-dichloropropane mg/kg 0.1 ND Formaldehyde Test Method: With reference to ISO :2008, analysis was preformed by HPLC-DAD. Test Item(s): Unit MDL 001 Formaldehyde mg/kg 20 ND Halogen Test Method: With reference to EN 14582:2007, analysis was performed by IC. Test Item(s): Unit MDL 001 Chlorine (Cl) mg/kg 50 ND

9 Test Report No.: CANEC Date: 22 Aug 2013 Page 9 of 18 Bromine (Br) mg/kg 50 ND Asbestos Test Method: With reference to NIOSH 9000:1994&ISO :2012, analysis was performed by XRD&PLM. Test Item (s) CAS NO Unit MDL 001 Chrysotile %(w/w) 0.1 Negative Amosite %(w/w) 0.1 Negative Crocidolite %(w/w) 0.1 Negative Anthophyllite %(w/w) 0.1 Negative Tremolite %(w/w) 0.1 Negative Actinolite %(w/w) 0.1 Negative Note: (1) Negative < 0.1%(w/w), Positive 0.1%(w/w) Azo Dyes Test Method : Textile: According to EN : Analysis was conducted with GC-MS/HPLC-DAD. Determination of 4-aminoazobenzene (CAS No.: ) EN :2012; with the use of Gas Chromatography Mass Spectrometry (GC-MS/HPLC-DAD) Test Item(s) CAS No. Unit MDL Aminobiphenyl mg/kg 5 ND Benzidine mg/kg 5 ND 4-Chlor-o-toluidine mg/kg 5 ND 2-Naphthylamine mg/kg 5 ND o-aminoazotoluene mg/kg 5 ND 5-nitro-o-toluidine / 2-Amino-4-nitrotoluene mg/kg 5 ND 4-Chloroaniline mg/kg 5 ND 4-methoxy-m-phenylenediamine mg/kg 5 ND /2,4-Diaminoanisole 4,4'-Diaminodiphenylmethane mg/kg 5 ND 3,3'-Dichlorobenzidine mg/kg 5 ND 3,3'-Dimethoxybenzidine mg/kg 5 ND 3,3'-Dimethybenzidine mg/kg 5 ND 4,4'-methylenedi-o-toluidine / 3,3'-Dimethyl-4,4'-diaminodiphenyl methane mg/kg 5 ND p-cresidine mg/kg 5 ND 4,4'-Methylene-bis-(2-chloroaniline) mg/kg 5 ND 4,4'-Oxydianiline mg/kg 5 ND 4,4'-Thiodianiline mg/kg 5 ND o-toluidine mg/kg 5 ND 4-methyl-m-phenylenediamine / mg/kg 5 ND

10 Test Report No.: CANEC Date: 22 Aug 2013 Page 10 of 18 2,4-Toluylendiamine 2,4,5-Trimethylaniline mg/kg 5 ND 4-aminoazobenzene mg/kg 5 ND O-Anisidine mg/kg 5 ND 2,4-Xylidine mg/kg 5 ND 2,6-Xylidine mg/kg 5 ND Notes : Remark: The EN methods will enable further cleavage of 4-aminoazobenzene to non-forbidden amines: aniline and 1,4-phenylenediamine, therefore, the test method of EN :2012 was employed to verify the presence of 4-aminoazobenzene. Whenever 4-aminodiphenyl (CAS number ), 2-naphylamine (CAS number ) and 4-methoxy-m-phenylene-diamine (CAS number ) is found, the use of banned azo colorants cannot be reliably ascertained without additional information, e.g. the chemical structure of the colorants used. In case polyurethane materials are used, e.g. PU foams and coatings and in prints, it cannot be ruled out that certain amines, e.g. 4,4 -methylene-dianiline (MDA, CAS number ) and 2,4-toluylen-diamine (TDA, CAS number ) are released from the PU component and not from a banned azo colorant.in case of pigment prints care has to be taken that 4,4 -methylene-dianiline (MDA, CAS number ) is not released from a source of banned azo colorants but from e.g. a chemical fixing agent. Tris(2-chloroethyl) phosphate Test Method: With reference to EN71-11, analysis was performed by LC-MS. Test Item(s) Unit MDL 001 Tris(2-chloroethyl) phosphate mg/kg 5.0 ND Element(s) Test Method: With reference to US EPA Method 3052:1996, analysis was performed by ICP-OES. Test Item(s): Unit MDL 001 Beryllium (Be) mg/kg 5 ND Beryllium oxide (BeO) Test Method: With reference to US EPA Method 3052:1996, analysis was performed by ICP-OES.

11 Test Report No.: CANEC Date: 22 Aug 2013 Page 11 of 18 Test Item(s): Unit MDL 001 Beryllium oxide (BeO) mg/kg 15 ND Note: (1) BeO: Calculate from Beryllium content Perchlorate Test Method: With reference to SGS In-house method (GZTC-R&D-TOP-287), analysis was performed by LC- MSMS. Test Item(s) Unit MDL 001 Perchlorate µg/kg 5 ND

12 Test Report No.: CANEC Date: 22 Aug 2013 Page 12 of 18 ATTACHMENTS SVHC Testing Flow Chart 1) Name of the person who made testing: Martin He / Alison Zhang 2) Name of the person in charge of testing: Cutey Yu Sample cutting/preparation Sample measurement Sample Pretreatment Instrumental Analysis DATA

13 Test Report No.: CANEC Date: 22 Aug 2013 Page 13 of 18 ATTACHMENTS SCCP/MCCP Testing Flow Chart 1) Name of the person who made testing: Alison Zhang 2) Name of the person in charge of testing: Cutey Yu Sample cutting / preparation Sample Measurement Solvent extraction Concentration Clean-Up Filtration GC-ECD DATA

14 Test Report No.: CANEC Date: 22 Aug 2013 Page 14 of 18 ATTACHMENTS Dimethyl Fumarate Testing Flow Chart 1) Name of the person who made testing: Liu Qiong 2) Name of the person in charge of testing: Yolanda Wei Sample cutting / preparation Sample Measurement Solvent extraction Concentration/Dilution Filtration GC-MS DATA

15 Test Report No.: CANEC Date: 22 Aug 2013 Page 15 of 18 ATTACHMENTS PVC Testing Flow Chart 1) Name of the person who made testing: Alison Zhang 2) Name of the person in charge of testing: Cutey Yu Sample cutting/preparation FTIR Check wave-number of C-Cl bonding DATA

16 Test Report No.: CANEC Date: 22 Aug 2013 Page 16 of 18 ATTACHMENTS Halogen Testing Flow Chart 1) Name of the person who made testing: Bella Wang 2) Name of the person in charge of testing: Adams Yu Sample cutting / preparation Sample Measurement Combustion in oxygen bomb Dissolved in an absorption solution Filtration Analyzed by ion chromatography. Double confirm by other instruments, if necessary DATA

17 Test Report No.: CANEC Date: 22 Aug 2013 Page 17 of 18 ATTACHMENTS Elementary Testing Flow Chart 1) Name of the person who made testing: Bella Wang 2) Name of the person in charge of testing: Adams Yu Sample cutting / preparation Sample Measurement Acid digestion Filtration Solution ICP-OES/AAS DATA

18 Test Report No.: CANEC Date: 22 Aug 2013 Page 18 of 18 Sample photo : CANEC CAN SGS authenticate the photo on original report only *** End of Report ***