TEST REPORT. LAB NO. : (9313) DATE : Apr 22, 2013 PAGE : 1 OF 14 APPLICANT :
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1 TEST REPORT LAB NO. : (9313) PAGE : 1 OF 14 APPLICANT : CONTACT PERSON : / DATE OF SUBMISSION : Apr 16, 2013 TEST PERIOD : Apr 16, 2013 to Apr 22, 2013 NO. OF WORKING DAYS : 5 SAMPLE DESCRIPTION : CAPS Color: Style No.: P.O. No.: / Country of Origin: / Country of Destination: / MANUFACTURER : / White/Royal, French Navy, Red, Sky Blue, Sky Blue, Orange, Black, Royal Blue BULL, SUNNY, BUZZ RW Bureau Veritas Consumer Products Services (Guangzhou) Co.,Ltd No. 183, Shinan Road, Meilin Plaza Block B, Dongchong, Panyu, Guangzhou, Guangdong Province, China Tel: (86) Fax:(86) BVCPS_pyinfo@cn.bureauveritas.com Website:cps.bureauveritas.com This report is governed by, and incorporates by reference, the Conditions of Testing as posted at the date of issuance of this report at and is intended for your exclusive use. Any copying or replication of this report to or for any other person or entity, or use of our name or trademark, is permitted only with our prior written permission. This report sets forth our findings solely with respect to the test samples identified herein. The results set forth in this report are not indicative or representative of the quality or characteristics of the lot from which a test sample was taken or any similar or identical product unless specifically and expressly noted. Our report includes all of the tests requested by you and the results thereof based upon the information that you provided to us. You have 60 days from date of issuance of this report to notify us of any material error or omission caused by our negligence, provided, however, that such notice shall be in writing and shall specifically address the issue you wish to raise. A failure to raise such issue within the prescribed time shall constitute your unqualified acceptance of the completeness of this report, the tests conducted and the correctness of the report contents.
2 PAGE : 2 OF 14 SUMMARY OF TEST RESULTS TEST REQUESTED CONCLUSION REMARK Aromatic Amines Content in Azo Colorants European Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) with Amendments PASS up to EU No. 412/2012, Annex XVII, Entry 43, Points 1 and 2 Total Cadmium Content in Plastic Material European Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction PASS of Chemicals (REACH) with Amendments up to EU No. 412/2012, Annex XVII, Entry 23 Phthalates Content in Toys and Childcare Articles European Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation and PASS Restriction of Chemicals (REACH) with Amendments up to EC No. 552/2009, Annex XVII, Entry 51 Phthalates Content in Toys and Childcare Articles which can be placed in the Mouth by Children European Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation and PASS Restriction of Chemicals (REACH) with Amendments up to EC No. 552/2009, Annex XVII, Entry 52 Free and Hydrolyzed Formaldehyde in Textiles PASS Determination Of Fabric Weight See result on page 14 BUREAU VERITAS CONSUMER PRODUCTS SERVICES (GUANGZHOU) CO., LTD REMARK CHARLES WONG ANALYTICAL LAB MANAGER If there are questions or concerns on this report, please contact the following persons: a) GENERAL TEL: (86) FAX: (86) b) BUSINESS SZ TEL: (86) FAX: (86) BUSINESS GZ TEL: (86) FAX: (86) WEBSITE eechemical.sc@cn.bureauveritas.com cps.bureauveritas.cn
3 Photo of the Submitted Sample LAB NO. : (9313) PAGE : 3 OF 14
4 PAGE : 4 OF 14 TEST RESULT Aromatic Amines Content in Azo Colorants European Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) with Amendments up to EU No. 412/2012, Annex XVII, Entry 43, Points 1 and 2 Test Method I : European Standard EN : Test Method II: International Standard ISO : Test Item(s) 3 Item / Component Description(s) Royal blue fabric Location(s) Style(s) 4 Black fabric 5 6 Orange fabric Navy fabric 7 Red fabric 8 Sky blue fabric Maximum Allowable Limit : Each 30 mg/kg Result Test Item(s) Test Method Detected Analyte(s) Conc. Unit Conclusion I ND ND mg/kg PASS I ND ND mg/kg PASS Note / Key : Remark : ND = Not detected > = Greater than Conc. = Concentration mg/kg = milligram(s) per kilogram = ppm = part(s) per million mg/kg = 1 % % = percent EU No. = European Commission Regulation number Detection Limit (mg/kg) : Each 10 The list of aromatic amines in azo colorants is summarized in table of Appendix. Quantitative and qualitative determinations of aromatic amines are carried out by gas chromatography with mass spectrometer (GCMS) while qualitative confirmation is carried out by high performance liquid chromatography with diode array detector (HPLCDAD). The colorant(s) of Test Item(s), that are able to form 4aminoazobenzene, is (are) able to generate aniline and 1,4phenylenediamine under the condition of Test Method I or II.
5 PAGE : 5 OF 14 APPENDIX List of Aromatic Amines in Azo Colorants [ European Regulation EC No. 1907/2006, Annex XVII, Entry 43, Points 1 and 2 ] : CASNo. CASNo. No. Name of Analytes No. Name of Analytes [ EC No. ] [ EC No. ] 4Aminodiphenyl ,3`Dimethylbenzidine (Biphenyl4ylamine or 12 [ ] (4,4`Biotolidine) [ ] Xenylamine) ,4`Methylenediotoluidine Benzidine 13 (3,3`Dimethyl [ ] 4,4`diaminodiphenylmethane) [ ] pcresidine Chlorootoluidine 14 [ ] (6Methoxymtoluidine) [ ] 4,4`Methylenebis( Naphthylamine 15 chloraniline) [ ] (2,2`Dichloro4,4`methylene [ ] dianiline) oaminoazotoluene (4Amino2`, ,4`Oxydianiline dimethylazobenzne or 4o [ ] [ ] tolyazootoluidine) 5nitrootoluidine ,4`Thiodianiline (2Amino4nitrotoluene) [ ] [ ] 4Chloroaniline otoluidine (pchloroaniline) [ ] (2Aminotoluene) [ ] 4Methoxymphenylenediamine Methylmphenylenediamine (2,4Diaminoanisole) [ ] (2,4Toluenediamine) [ ] 4,4`Diaminodiphenylmethane ,4,5Trimethylaniline (4,4`Methylenedianiline) [ ] [ ] 3,3`Dichlorobenzidine oanisidine (3,3`Dichlorobiphenyl4,4` 21 [ ] (2Methoxyaniline) [ ] ylenediamine) 11 3,3`Dimethoxybenzidine Aminoazobenzene (odianisidine) [ ] (paminoazobenzene) [ ] CASNo. = Chemical Abstracts Service registry number EC No. = European Commission number
6 PAGE : 6 OF 14 TEST RESULT Total Cadmium Content in Plastic Material European Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) with Amendments up to EU No. 412/2012, Annex XVII, Entry 23 Test Method : British Standard BS EN 1122: 2001, Method B. Test Item(s) Item / Component Description(s) Location(s) Style(s) 1 Blue plastic buckle Maximum Allowable Limit : 100 mg/kg Unit Result Test Item(s) 1 Parameter Test Sample(s) / Trial(s) Trial 1 mg/kg ND Trial 2 mg/kg ND Average Total Cadmium mg/kg ND (Cd) Conclusion PASS Note / Key : Remark : ND = Not detected > = Greater than mg/kg = milligram(s) per kilogram = ppm = part(s) per million mg/kg = 1 % % = percent Detection Limit (mg/kg) : 10 Plastic material(s) produced from recovered polyvinyl chloride (PVC) is (are) not allowed to comply with this requirement and has (have) to comply with another total cadmium requirement with maximum allowable limit of mg/kg.
7 PAGE : 7 OF 14 TEST RESULT Phthalates Content in Toys and Childcare Articles European Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) with Amendments up to EC No. 552/2009, Annex XVII, Entry 51 Test Item(s) Item / Component Description(s) Location(s) Style(s) 2 Beige plastic eyeshade Maximum Allowable Limit : 0.1 % ( Sum of all listed phthalates ) Test Item(s) Result Detected Analyte(s) Conc. Unit Conclusion 2 ND ND % PASS Note / Key : Remark : ND = Not detected > = Greater than Conc. = Concentration % = percent 1 % = mg/kg mg/kg = milligram(s) per kilogram Detection Limit (%) : Each The list of phthalates is summarized in table of Appendix.
8 PAGE : 8 OF 14 APPENDIX List of Phthalates [ European EC No. 1907/2006, Annex XVII, Entry 51 ] : CASNo. CASNo. No. Name of Analytes No. Name of Analytes [ EC No. ] [ EC No. ] Butyl benzyl phthalate (BBP) 3 Di2ethylhexyl phthalate (DEHP) [ ] [ ] Dibutyl phthalate (DBP) [ ]
9 PAGE : 9 OF 14 APPENDIX TEST PROCESS Sample weight measurement Extraction with organic solvent Filtration through syringe filter GCMS / LCMS analysis
10 PAGE : 10 OF 14 TEST RESULT Phthalates Content in Toys and Childcare Articles which can be placed in the Mouth by Children European Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) with Amendments up to EC No. 552/2009, Annex XVII, Entry 52 Test Item(s) Item / Component Description(s) Location(s) Style(s) 2 Beige plastic eyeshade Maximum Allowable Limit : 0.1 % ( Sum of all listed phthalates ) Test Item(s) Result Detected Analyte(s) Conc. Unit Conclusion 2 ND ND % PASS Note / Key : Remark : ND = Not detected > = Greater than Conc. = Concentration % = percent 1 % = mg/kg mg/kg = milligram(s) per kilogram Detection Limit (%) : Each The list of phthalates is summarized in table of Appendix. Test Item(s) has (have) to comply together with the phthalates requirement of European Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) with Amendments up to EC No. 552/2009, Annex XVII, Entry 51.
11 PAGE : 11 OF 14 List of Phthalates [ European EC No. 1907/2006, Annex XVII, Entry 52 ] : CASNo. CASNo. No. Name of Analytes No. Name of Analytes [ EC No. ] [ EC No. ] & & Diisononyl phthalate (DINP) 3 Diisodecyl phthalate (DIDP) [ & [ & ] ] Dinoctyl phthalate (DNOP) [ ]
12 PAGE : 12 OF 14 APPENDIX TEST PROCESS Sample weight measurement Extraction with organic solvent Filtration through syringe filter GCMS / LCMS analysis
13 PAGE : 13 OF 14 Free and Hydrolyzed Formaldehyde in Textiles TEST RESULT Unit Result Client s Limt Test item(s) Parameter 3 Formaldehyde mg/kg < Conclusion PASS Test Item 3: Note: Royal blue fabric mg/kg = milligram per kilogram < = less than Method: ISO : 1998
14 PAGE : 14 OF 14 DETERMINATION OF FABRIC WEIGHT(ISO 3801) TEST RESULT G. / SQ. M 172 / OZ / SQ. YD 5.08 / Color: sky blue fabric (BUZZ) END
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