SAFETY DATA SHEET. SECTION 1: Identification of the substance/mixture and of the company/undertaking

Transcription

1 SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Name of the substance Identification number Registration number Synonyms SDS Number Issue date Version number 02 Revision date Supersedes date Phosphoric acid, diammonium salt * Diammonium hydrogenorthophosphate * Diammonium hydrophosphate * DAP KFT_DAP_EU_EN 17January October January Relevant identified uses of the substance or mixture and uses advised against Identified uses Fertiliser. Uses advised against None known Details of the supplier of the safety data sheet Manufacturer/Supplier Emergency SECTION 2: Hazards identification Koch Fertilizer Trading Sarl 20, route de PreBois Case Postale 1843 Geneva, Switzerland or For Chemical Emergency Call CHEMTREC day or night Outside USA/Canada (collect calls accepted) 2.1. Classification of the substance or mixture The product has been assessed and/or tested for its physical, health and environmental hazards and the following classification applies. Classification according to Directive 67/548/EEC or 1999/45/EC as amended This substance does not meet the criteria for classification according to Directive 67/548/EEC as amended. Classification according to Regulation (EC) No 1272/2008 as amended This substance does not meet the criteria for classification according to Regulation (EC) 1272/2008 as amended. Hazard summary Physical hazards Health hazards Environmental hazards Specific hazards Main symptoms 2.2. Label elements Not classified for physical hazards. Not classified for health hazards. Not classified for hazards to the environment. Label according to Regulation (EC) No. 1272/2008 as amended Contains: Identification number Hazard pictograms Signal word Hazard statements Precautionary statements Prevention Response Dusts or powder may irritate the respiratory tract, skin and eyes. Dusts may irritate the respiratory tract, skin and eyes. Symptoms can include irritation, redness, scratching of the cornea, and tearing. None. None. The substance does not meet the criteria for classification. P280 Wear eye/face protection. Wash hands after handling Version No.: 02 Revision date: 24October2013 Issue date: 17January / 7

2 Storage Store away from incompatible materials. Disposal Dispose of waste and residues in accordance with local authority requirements. Supplemental label information Not applicable Other hazards Not a PBT or vpvb substance or mixture. SECTION 3: Composition/information on ingredients 3.1. Substances General information Chemical name % CASNo. / EC No. REACH Registration No. INDEX No. Notes 100 Classification: DSD: CLP: DSD: Directive 67/548/EEC. CLP: Regulation No. 1272/2008. Composition comments SECTION 4: First aid measures General information The full text for all Rphrases is displayed in section 16 of the SDS. All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. This Safety Data Sheet is not a guarantee of product specification or NPK value(s). NPK content is on specified sales orders, customer invoices, or product specification sheets obtained from supplier. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Description of first aid measures Inhalation Move to fresh air. Get medical attention if any discomfort continues. Skin contact Eye contact Ingestion 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures General fire hazards 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters Special protective equipment for firefighters Special fire fighting procedures Flush skin thoroughly with water. Get medical attention if irritation develops or persists. Dust in the eyes: Do not rub eyes. Flush eyes immediately with large amounts of water. Get medical attention if irritation develops and persists. If ingestion of a large amount does occur, call a poison control centre immediately. Dusts may irritate the respiratory tract, skin and eyes. Symptoms can include irritation, redness, scratching of the cornea, and tearing. Treat symptomatically. The product is noncombustible. During fire, gases hazardous to health may be formed. Water. Foam. Dry chemical powder. Carbon dioxide (CO2). None known. None known. SECTION 6: Accidental release measures Selfcontained breathing apparatus and full protective clothing should be worn when fighting chemical fires. Selection of respiratory protection for firefighting: follow the general fire precautions indicated in the workplace. In the event of fire, cool tanks with water spray. Move containers from fire area if you can do it without risk Personal precautions, protective equipment and emergency procedures For nonemergency Avoid inhalation of dust and contact with skin and eyes. Ensure adequate ventilation. Do not touch personnel damaged containers or spilled material unless wearing appropriate protective clothing. Use personal protection as recommended in section 8 of the SDS. For emergency responders Wear protective clothing as described in Section 8 of this safety data sheet Version No.: 02 Revision date: 24October2013 Issue date: 17January / 7

3 6.2. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not allow material to enter storm or sanitary sewers, groundwater or soil Methods and material for containment and cleaning up Stop the flow of material, if this is without risk. If sweeping of a contaminated area is necessary use a dust suppressant agent which does not react with the product. Collect dust using a vacuum cleaner. If not possible, gently moisten dust with water fog before it is collected with shovel, broom or the like. After removal flush contaminated area thoroughly with water Reference to other sections Never return spills to original containers for reuse. Avoid dust formation. For personal protection, see section 8 of the SDS. SECTION 7: Handling and storage 7.1. Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities 7.3. Specific end use(s) Fertiliser SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits UK. EH40 Workplace Exposure Limits (WELs) Avoid inhalation of dust and contact with skin and eyes. Use only with adequate ventilation. Use work methods which minimise dust production. Keep the workplace clean. Store in a wellventilated place. Keep container tightly closed. Store away from incompatible materials. Components Dust (CAS ) Biological limit values Recommended monitoring procedures Derived noeffect level (DNEL) Predicted no effect concentrations (PNECs) Type Value Form TWA 4 mg/m3 Respirable dust. 10 mg/m3 Inhalable dust. No biological exposure limits noted for the ingredient(s). Follow standard monitoring procedures Exposure controls Appropriate engineering controls Provide sufficient ventilation for operations causing dust formation. Individual protection measures, such as personal protective equipment General information Personal protective equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment. Eye/face protection Skin protection Use tight fitting goggles if dust is generated. Hand protection Risk of contact: Wear protective gloves. Suitable gloves can be recommended by the glove supplier. Other Wear suitable protective clothing. Respiratory protection Thermal hazards Hygiene measures Environmental exposure controls SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Odour Physical state Form Colour If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Wear appropriate thermal protective clothing, when necessary. Do not breathe dust. Avoid contact with eyes. Handle in accordance with good industrial hygiene and safety practices. Environmental manager must be informed of all major releases. Granules. Granular. Solid. Solid. Colorless, Offwhite, White, Brown Version No.: 02 Revision date: 24October2013 Issue date: 17January / 7

4 Odour threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate (25 C) 155 C (311 F) Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit lower (%) Flammability limit upper (%) Vapour pressure Vapour density Relative density Solubility(ies) C Partition coefficient (noctanol/water) Autoignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties 9.2. Other information Density Flammability Molecular formula Molecular weight 1.62 g/cm3 H9N2O4P g/mol SECTION 10: Stability and reactivity Reactivity Chemical stability Material is stable under normal conditions Possibility of hazardous reactions Conditions to avoid None known. Hazardous polymerisation does not occur Incompatible materials Bases. Metals. Oxidising material Hazardous decomposition products SECTION 11: Toxicological information Nitrogen oxides (NOx). Phosphorus oxides. Ammonia. General information Occupational exposure to the substance or mixture may cause adverse effects. Information on likely routes of exposure Ingestion May irritate and cause stomach pain, vomiting and diarrhoea. Inhalation Dust may irritate respiratory system. Skin contact Dust may irritate skin. Eye contact Dust may irritate the eyes. Symptoms Symptoms can include irritation, redness, scratching of the cornea, and tearing Information on toxicological effects Acute toxicity Dusts may irritate the respiratory tract, skin and eyes. Dust irritates the respiratory system, and may cause coughing and difficulties in breathing. Exposure to sufficient concentrations of decomposition products may result in pulmonary oedema. May irritate and cause stomach pain, vomiting, diarrhoea and nausea Version No.: 02 Revision date: 24October2013 Issue date: 17January / 7

5 Components Species (CAS ) Acute Dermal LD50 SpragueDawley rat Test results > 5000 mg/kg Inhalation LC50 Oral LD50 Rat SpragueDawley rat > 5000 mg/m³, 4 hours > 2000 mg/kg Skin corrosion/irritation Serious eye damage/eye irritation Respiratory sensitisation Skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity single exposure Specific target organ toxicity repeated exposure Aspiration hazard Mixture versus substance information Other information Dust may irritate skin. Dust may irritate the eyes. No data available. Not a skin sensitiser. No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. IARC not listed. Contains no ingredient listed as toxic to reproduction Not classified. Not classified. No data available. No other specific acute or chronic health impact noted. SECTION 12: Ecological information Toxicity Not classified. Components (CAS ) Aquatic Crustacea LC50 Species Daphnia Test results 1790 mg/l, 96 hours Fish LC50 Carp, hawk fish (Cirrhinus mrigala) 1700 mg/l, 96 hours Persistence and degradability There are no data on the degradability of this product Bioaccumulative potential Partition coefficient noctanol/water (log Kow) Bioconcentration factor (BCF) Mobility in soil Results of PBT and vpvb assessment Not a PBT or vpvb substance or mixture Other adverse effects No data available. SECTION 13: Disposal considerations Waste treatment methods Residual waste Contaminated packaging EU waste code Disposal methods/information SECTION 14: Transport information ADR Dispose of in accordance with local regulations. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Dispose in accordance with all applicable regulations Version No.: 02 Revision date: 24October2013 Issue date: 17January / 7

6 RID ADN IATA IMDG Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information This substance/mixture is not intended to be transported in bulk Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulations Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex II Regulation (EC) No. 850/2004 On persistent organic pollutants, Annex I as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 1 as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 2 as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 3 as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex V as amended Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry Regulation (EC) No. 1907/2006, REACH Article 59(1) Candidate List as currently published by ECHA Authorisations Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorisation, as amended Restrictions on use Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended (CAS ) Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at work Not regulated. Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently given birth or are breastfeeding Not regulated. Other EU regulations Directive 96/82/EC (Seveso II) on the control of majoraccident hazards involving dangerous substances Not regulated. Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work Directive 94/33/EC on the protection of young people at work Other regulations National regulations Chemical safety assessment The product is classified and labelled in accordance with Regulation (EC) 1272/2008 (CLP Regulation) as amended and respective national laws implementing EC directives. This Safety Data Sheet complies with the requirements of Regulation (EC) No 1907/2006. Follow national regulation for work with chemical agents Version No.: 02 Revision date: 24October2013 Issue date: 17January / 7

7 SECTION 16: Other information List of abbreviations References Information on evaluation method leading to the classification of mixture Full text of any statements or Rphrases and Hstatements under Sections 2 to 15 This SDS contains revisions in the following section(s): Training information Disclaimer DNEL: Derived NoEffect Level. PNEC: Predicted NoEffect Concentration. PBT: Persistent, bioaccumulative and toxic. vpvb: Very Persistent and very Bioaccumulative. The classification for health and environmental hazards is derived by a combination of calculation methods and test data, if available. None. 5, 6, 7, 8. NOTICE: The information presented herein is based on data considered to be accurate as of the date of preparation of this Safety Data Sheet (SDS) and was prepared pursuant to Government regulation(s) that identify specific types of information to be provided. This SDS may not be used as a commercial specification sheet of manufacturer or seller, and no warranty or representation, expressed or implied, is made as to the accuracy or comprehensiveness of the foregoing data and safety information, nor is any authorization given or implied to practice any patented invention without a license. Additional information may be needed to evaluate other uses of the product, including use of the product in combination with any materials or in any processes other than those specifically referenced. Information provided herein with respect to any hazards that may be associated with the product is not meant to suggest that use of the product in a given application will necessarily result in any exposure or risk to workers or the general public. No responsibility can be assumed by vendor for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices, or from any hazards inherent in the nature of the product. Purchasers and users assume all risk of use, storage and handling of the product in compliance with applicable federal, state and local laws and regulations. Purchasers and users of the product specifically should advise all of their employees, agents, contractors and customers who will use the product of this (M)SDS Version No.: 02 Revision date: 24October2013 Issue date: 17January / 7