Sound 22.0%SC. AL-Burj Agrivet. Suspension concentrate (SC) Introduction. Composition. Formulation

Transcription

1 Sound 22.0%S Suspension concentrate (S) Introduction Sound 22.0%S is a mixture of Thiamethoxam & Lambda-yhalothrin Thiamethoxam is a Insecticide with contact, stomach and systemic activity. Rapidly taken up into the plant and transported acropetally in the xylem. It is used to controls aphids, whitefly, thrips, ricehoppers, ricebugs, mealybugs, white grubs, olorado potato beetle, flea beetles, wireworms, ground beetles, leaf miners and some lepidopterous species, at application rates from 10 to 200 g/ha.major crops for foliar and soil treatments are cole crops, leafy and fruity vegetables, potatoes, rice, cotton, deciduous fruit, citrus, tobacco and soyabeans; for seed treatment use, maize, sorghum, cereals, sugar beet, oilseed rape, cotton, peas, beans, sunflowers, rice and potatoes. And Lambda-yhalothrin is a non-systemic insecticide with contact & stomach action, and repellent properties. Gives rapid knockdown and long residual activity. omposition Each liter contains: Thiamethoxam gm /Lt. Lambda-yhalothrin gm/lt. Formulation Suspension oncentrate (S). Physical & chemical properties of active ingredients: ommon name accepted by IS and synonyms: 1. Lambda-cyhalothrin. 2. Thiamethoxam. AS no.: 1. Lambda-cyhalothrin: Thiamethoxam: Al-Burj Agrivet Pesticide Manufacturing o. 1

2 hemical name (IUPA): 1. Lambda-cyhalothrin: A reaction product comprising equal quantities of (S)- μ -cyano-3-phenoxybenzyl (Z)-(1R,3R)-3-(2-chloro- 3,3,3-trifluoroprop-1-enyl)-2,2-dimethylcyclopropanecarboxylate and (R)-μ-cyano-3-phenoxybenzyl (Z)-(1S,3S)-3-(2-chloro-3,3,3- trifluoroprop-1-enyl)-2,2-dimethylcyclopropanecarboxylate Roth: (S)- μ -cyano-3-phenoxybenzyl (Z)-(1R)-cis-3-(2-chloro-3,3,3-trifluoropropenyl)-2,2- dimethylcyclopropanecarboxylate and (R)- μ -cyano-3-phenoxybenzyl (Z)-(1S)- cis-3-(2-chloro-3,3,3-trifluoropropenyl)-2,2-dimethylcyclopropanecarboxylate (1:1). 2. Thiamethoxam: (E,Z) 3-(2-chloro-1,3-thiazol-5-ylmethyl)-5- methyl-1,3,5- oxadiazinan-4-ylidene(nitro)amine. Emprical formula: 1. Lambda-cyhalothrin LF 3 N Thiamethoxam 8 10 ln 5 3 S. Structural formula: 1. Lambda-cyhalothrin: (S) (Z)-(1R)-cis- F 3 l N 3 3 N l F (R) (Z)-(1S)-cis- Al-Burj Agrivet Pesticide Manufacturing o. 2

3 2. Thiamethoxam 8 10 ln 5 3 S. N 2 N S l 3 N N 2 N hemical class: 1. Lambda-cyhalothrin: Pyrethroid. 2. Thiamethoxam: Neonicotinoid. Mol. Weight: 1. Lambda-cyhalothrin Thiamethoxam Purity (%w/w) of technical active (%) minimum %: 1. Lambda-cyhalothrin: > 95% w/w min. 2. Thiamethoxam: > 980 g/kg. olour: 1. Lambda-cyhalothrin: olourless. 2. Thiamethoxam: Slightly cream. Physical state: 1. Lambda-cyhalothrin: solid. 2. Thiamethoxam: Fine crystalline powder. dour: 1. Lambda-cyhalothrin: mild odour. 2. Thiamethoxam: dorless. Melting point: 1. Lambda-cyhalothrin: 49.2 º; (tech., º). 2. Thiamethoxam: (= K). Vapour pressure: 1. Lambda-cyhalothrin: 2 X10-4 mpa (20 º, est.); 2 X10-1 mpa (60 º, interpolated) Thiamethoxam: Pa at 20, Pa at 25. Density: 1. Lambda-cyhalothrin: º Thiamethoxam: at 20 : 1.57 g/cm 3. Al-Burj Agrivet Pesticide Manufacturing o. 3

4 Solubility in water and organic solvents (at stated temperature): 1. In water mg/l (20 ). In acetone, methanol, toluene, hexane, ethyl acetate >500 g/l. 2. Thiamethoxam: In water 4.1 g/l (25 ). In organic solvents: (Purity: 98.2%), acetone: 48 g / l, ethyl acetate 7.0 g / l, dichloromethane 110 g / l, hexane < 1 mg / l,toluene 680 mg / l, methanol 13 g / l, n-octanol 620 mg / l. Physical & chemical properties for Finished Product: olour: White to beige liquid. Physical state: Liquid. dour: aromatic odour. p: P (1%): Density: 1.1 Gm/Ltl. Explosivity: Not explosive. Acute toxicity: 1. Lambda-yhalothrin 2. Thiamethoxam RUTE F APPLIATIN ANIMAL ATIVE INGREDIENT FRMULATED PRDUT ral LD50 Rat 1. Male: 79mg/kg/ Female: 56 mg/kg mg/kg mg/kg > 6252 mg/kg. Dermal (LD50) Rabbits mg/kg 2. > 2000 mg/kg b.w >8000 mg/kg. Inhalation (L50) Rat 1. >0.06mg/l mg/l (4 hr) mg/l. Skin irritation Rabbit 1. Non irritation 2. Non-irritant Non irritation. Eye irritation Rabbit 1. Mild irritation 2. Non-irritant Non irritation. Skin sensitisation Guinea pig 1. Not a sensitizer 2. Not a sensitizer Not a sensitizer. Al-Burj Agrivet Pesticide Manufacturing o. 4

5 W lassification: active ingredient and formulated product are classified in the W as: Lambda-yhalothrin: active ingredient: II (Moderately armful) and formulated product: III (Slightly harmful). Thiamethoxam: active ingredient and formulated product are classified in the W class as slightly toxic lass III. Finish Product: III slightly toxic. Acceptable daily intake: 1. Lambda-yhalothirn: mg/kg b.w. ADI is calculated on the basis of the NAEL in the most susceptible species, the dog in this case, in the long-term studies and an appropriate safety factor (usually 100). ADI = NAEL/100 = mg/kg body weight per day. 2. Thiamethoxam: Australian Government: 0.02 mg/kg (2000) ADI (European ommission): mg/kg bw/day (2002). ADI is calculated on the basis of the NAEL in the most susceptible species, the dog in this case, in the long-term studies and an appropriate safety factor (usually 100). ADI = NAEL/100 = mg/kg body weight per day. Finish Prodcut: ADI: mg/kg bw. Ecotoxicology: Effect on Bees: 1. Lambda-yhalothrin: highly toxic to bees 2. Thiamethoxam: ighly toxic to honey bees & ighly Toxic for bee. 3. Finish Product: ighly toxic to honey bees & bee. Effect on Fish: 1. Lambda-yhalothrin: very highly toxic to many fish & aquatic invertebrate species. 2. Thiamethoxam: Slightly Toxic to fish. 3. Finish Product: Moderately Toxic to fish. Effect on Birds: 1. Lambda-yhalothrin: Low Toxic for birds 2. Thiamethoxam: Slightly Toxic for birds. 3. Finish Product: Slightly Toxic for birds. Al-Burj Agrivet Pesticide Manufacturing o. 5

6 Usage & recommendation: MAIN RPS Broccoli, abbagem auliflower ucumber, squash, pumpkin, watermelon, muskmelon Eggplant, tomato, pepper, cherry Lettuce ( head & leaf) Apricot, nectarine, peach, plum, cherry Almond, walnut, chesnut, beech nut, cashew, pistachio, Ginger, artichoke, potato, sweet potato, turmeric TYPIAL PESTS Looper, webworm, cutworm, aphid, corn earnworm, diamond back moth, armyworm, flea beetles, grasshopper, leafhopper, plant bug, spider mites, vegetables weevils, thrips, whitefly Armyworm, beetles, looper, corn earworm, cutworm, flea beetles, grasshopper, leafhopper, melonworm, plant bug, thrips, budworms, webworms, aphid, leafminer, whitefly, spider mites. Aphid, beetle, looper, coloradom potato beetle, cutworm, cucumber beetles, European corn borer, armyworm, flea beetles, grasshopper, leafhopper, hornworm, plant bug, tomato fruit worm, vegetable weevils, leafminer, pepper weevils, apidermite, thrips, budworm, pinworm, tomato psyllid, whitefly. Aphid, armyworm, corn earworm, European corn borer, beetle, grahopper, plant bug, Leafhopper, vegetables weevils, diamond back moth, apider mite, budworm, whitefly Aphid, American plum borer, codling moth, green fruitworm, bettles, leafhopper, leafroller, fruit moth, peach twig borerplant bug, thrips, Ant species, plant bug, codling moth, leafroller, peach twigs borer, walnut aphid. olorado potato beetle, cutworms, beetle, leaf hoppers, sweet potato hornworm, armyworm, corn earnworm, European corn borer, grasshopper, looper, plant bug, potato psyllid, potato tuberworm, sweet potato leaf beetle, & vine borer, thrips, webworm, weevils, aphid, leafminer, spidermite, whitefly. DSAGE L/A ML/100L PI* DAYS days days days days days days days rop tolerance: Non phytotoxic when used as recommended. ompatibility: compatible with commonly pesticides. Al-Burj Agrivet Pesticide Manufacturing o. 6

7 Safety handling: Keep locked up out of reach of children and other, unauthorized persons. AZARDS AND SAFETY PREAUTINS Keep out of reach of children. Avoid contact with skin and inhalation of spray mist. Keep away from food, drink and animal feeding stuffs. Store in original containers, tightly closed. Avoid contamination of any water supply with chemical or empty container. andling precautions: Prevent eating, drinking, tobacco used, ans cosmetic application in areas where there is a potential for exposure to the material. Ash thoroughly with soap and water after handling. Symptoms: Lambda-yhalothrin: tingling, burning or numbness sensations (particularly at the point of skin contact); tremors, incoordination of movement, paralysis or other disrupted motor function; and confusion or loss consciousness. Thiamethoxam is harmful if inhaled or absorbed through skin. auses moderate eye irritation. Avoid contact with eyes, skin, or clothing. Avoid breathing vapor or spray mist. Wash thoroughly with soap and water after handling, and before eating, drinking, chewing gum, or using tobacco. Remove and wash contaminated clothing before reuse. First aid: Eye ontact: Rinse eyes with clean water for several minutes. Ingestion: Repeatedly administer medicinal charcoal in a large quantity of water. NTE: Never give anything by mouth to an unconscious person. Do not induce vomiting. Skin ontact: Remove contaminated clothing and thoroughly wash the affected parts of the body with soap and water. Inhalation: Immediately remove to fresh air. Antidote if available: Antidote: No specific antidote is known. Apply symptomatic therapy. Storage & disposal: Keep away the reach of children, food and drinks. Keep in its original packages and in a dry and fresh place. Keep away from fire and sparks. Store in a cool, dry, well-ventilated area. Do not allow to become wet of overheated in storage. ontainer disposal: Triple rinse container and add rinsate to the spray tank. Burn if circumstances, especially wind direction permit, otherwise bury in landfill. Al-Burj Agrivet Pesticide Manufacturing o. 7

8 Shelf-life is: For temperate climates: 2 years form Mfg. Date For hot climates: 2 years form Mfg. Date. rop tolerance: Non phytotoxic when used as recommended. ompatibility: compatible with commonly pesticides. Al-Burj Agrivet Pesticide Manufacturing o. 8