Issue Date 20-May-2015 Revision Date 20-May-2015 Version 1 1. PRODUCT AND COMPANY IDENTIFICATION 2. HAZARDS IDENTIFICATION

Transcription

1 SAFETY DATA SHEET Issue Date 20-May-2015 Revision Date 20-May-2015 Version 1 1. PRODUCT AND COMPANY IDENTIFICATION Product Name Product Code Recommended Use 4x Laundry Detergent MSDS-AC Consumer use Detergent Supplier Address Method Products Inc. 637 Commercial St Suite 300 San Francisco, CA ATTENTION 2. HAZARDS IDENTIFICATION Emergency Overview May produce an allergic reaction May cause skin irritation and/or dermatitis Appearance translucent, amber Physical state Liquid. Odor Pleasant Potential health effects Principle Routes of Exposure Acute toxicity Eyes Skin Inhalation Ingestion CHRONIC EFFECTS Aggravated Medical Conditions Skin Contact Avoid contact with eyes. Direct contact with eyes poses risk of serious damage Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. May cause inflammation t an expected route of exposure. Intentional ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea Avoid repeated exposure. Repeated contact may cause allergic reactions in very susceptible persons Allergies Skin disorders Interactions with Other Chemicals Irritants Sensitizers Epoxies Page 1 / 7

2 Environmental hazard See Section 12: Ecological Information 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS Weight-% Sulfuric acid, mono-c10-16-alkyl esters, sodium salts Genapol LA Sodium Lauryl Sulfate Solid (95%) PEG 600 Decyl Ether PEG 300 Monoctyl Ether Soya methyl ester ethoxylate Potassium Cocoate subtisilin C11-15 Pareth <0.1 Benzisothiazolinone <0.1 Alpha Amylase Concentrate (Bacterial) <0.1 Methylisothiazolinone < FIRST AID MEASURES General advice Eye Contact Skin Contact Inhalation Ingestion te to physicians Self-protection of the first aider If symptoms persist, call a physician. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice Wash off immediately with plenty of water. Remove to fresh air. Do NOT induce vomiting. Clean mouth with water and drink plenty of water. Get medical attention Treat symptomatically Use personal protective equipment as required 5. FIRE-FIGHTING MEASURES Flammable properties Flash Point Method Suitable Extinguishing Media Explosion data Sensitivity to Mechanical Impact Sensitivity to Static Discharge Specific hazards arising from the product t flammable t determined Use extinguishing measures that are appropriate to local circumstances and the surrounding environment ne ne In the event of fire and/or explosion do not breathe fumes. May cause sensitization by inhalation and skin contact. Thermal decomposition can lead to release of irritating and toxic gases and vapors Page 2 / 7

3 Protective equipment and Wear self contained breathing apparatus for fire fighting if necessary precautions for firefighters NFPA Health hazards 1 Flammability 0 Stability 0 Physical and Chemical Properties - HMIS Health hazards 1 Flammability 0 Physical hazards 0 Personal protection - 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for containment Methods for cleaning up Avoid contact with eyes. Avoid release to the environment Prevent further leakage or spillage if safe to do so Take up mechanically, placing in appropriate containers for disposal. 7. HANDLING AND STORAGE Advice on safe handling Storage Conditions Avoid contact with eyes. Keep container closed when not in use. Keep out of the reach of children. Keep container tightly closed in a dry and well-ventilated place 8. EXPOSURE CONTROLS/PERSONAL PROTECTION For Household Settings For Occupational Settings This product is safe for consumers and other users under normal and reasonably foreseen use. Use safety goggles if splash hazards exist. Avoid prolonged contact with skin and clothing. Always follow good hygienic work practices. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state Liquid Odor Pleasant Color translucent and Colored Property Values Remarks Method ph Melting point / freezing point < 0 C Boiling point / boiling range > 100 C Flash Point t established Evaporation rate > 1.00 (water = 1) Flammability (solid, gas) Flammability Limit in Air Upper Flammability Limit t flammable Lower flammability limit t flammable Vapor pressure C Vapor density t established Specific Gravity 1.06 Water solubility completely soluble Autoignition temperature t established Decomposition temperature t established Kinematic viscosity t Determined Dynamic viscosity C Explosive properties t an explosive Page 3 / 7

4 Oxidizing properties ne VOC Content (%) 0 Bulk density information available 10. STABILITY AND REACTIVITY Stability Incompatible materials Conditions to Avoid Stable under recommended storage conditions ne known based on information supplied ne known based on information supplied Hazardous Decomposition Products ne known based on information supplied Hazardous polymerization Hazardous polymerization does not occur 11. TOXICOLOGICAL INFORMATION Acute toxicity Product Information Eye Contact Skin Contact Ingestion Product does not present an acute toxicity hazard based on known or supplied information Direct contact with eyes poses risk of serious damage Prolonged or repeated contact may dry skin and cause irritation Intentional ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Sodium Lauryl Sulfate Solid (95%) = 977 mg/kg ( Rat ) = 580 mg/kg ( Rat ) Chronic toxicity Chronic toxicity Avoid repeated exposure. Repeated contact may cause allergic reactions in very susceptible persons Target Organ Effects t expected 12. ECOLOGICAL INFORMATION Ecotoxicity Considering the limited amount applied during normal use and the size of the container, the risk of adverse environmental effects is considered small. Chemical Name Algae/aquatic plants Fish Crustacea Sodium Lauryl Sulfate Solid (95%) 117: 96 h Pseudokirchneriella subcapitata mg/l Lactic Acid Isopropanolamine 3.5: 70 h Pseudokirchneriella subcapitata mg/l 23: 72 h Desmodesmus subspicatus mg/l : 96 h Pimephales promelas mg/l LC50 semi-static : 96 h Oncorhynchus mykiss mg/l LC50 static Page 4 / : 96 h Lepomis macrochirus mg/l LC50 static : 96 h Oncorhynchus mykiss mg/l LC50 static 320: 96 h Brachydanio rerio mg/l LC50 semi-static 1.8: 48 h Daphnia magna mg/l : 48 h Daphnia magna mg/l Static 240: 48 h Daphnia magna mg/l : 48 h Daphnia magna Straus mg/l

5 Phenoxyethanol 500: 72 h Desmodesmus : 96 h Leuciscus idus mg/l 500: 48 h Daphnia magna mg/l subspicatus mg/l LC50 static : 96 h Pimephales promelas mg/l LC50 flow-through Calcium Chloride 10650: 96 h Lepomis macrochirus 2400: 48 h Daphnia magna mg/l mg/l LC50 static LC50 Propylene Glycol 41-47: 96 h Oncorhynchus mykiss ml/l LC50 static 710: 96 h Pimephales promelas mg/l LC50 Disodium Distyrylbiphenyl Disulfonate Persistence and degradability : 96 h Desmodesmus subspicatus mg/l 10: 72 h Desmodesmus subspicatus mg/l 76: 96 h Brachydanio rerio mg/l LC50 static 1000: 48 h Daphnia magna mg/l The surface active components used in this product are readily biodegradable. Chemical Name Partition coefficient Sodium Lauryl Sulfate Solid (95%) 1.6 Benzisothiazolinone DISPOSAL CONSIDERATIONS Contaminated packaging Dispose of in accordance with federal, state and local regulations. Recover or recycle if possible. 14. TRANSPORT INFORMATION DOT TDG MEX ICAO (air) IATA IMDG RID ADR ADN 15. REGULATORY INFORMATION International Inventories Chemical Name TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS Sulfuric acid, Present X Present Present X Present X X mono-c10-16-alkyl esters, sodium salts Genapol LA060 Present X Present X Present X X Sodium Lauryl Sulfate Solid Present X Present Present X Present X X (95%) PEG 300 Monoctyl Ether Present X Present X Present X Soya methyl ester ethoxylate Present X Potassium Cocoate Present X Present Present X Present X X Page 5 / 7

6 subtisilin Present X Present X Present X X C11-15 Pareth 90 Present X Present X Present X X Benzisothiazolinone Present X Present Present X Present X X Alpha Amylase Concentrate Present X Present X Present X X (Bacterial) Methylisothiazolinone Present X Present Present X Present X X DSL/NDSL - Canadian Domestic Substances List/n-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of tified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Chronic Health Hazard Fire hazard Sudden release of pressure hazard Reactive Hazard Yes CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 Complies U.S. State Right-to-Know Regulations Chemical Name Massachusetts New Jersey Pennsylvania Glycerin X X X International Regulations Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR Page 6 / 7

7 WHMIS Hazard Class n-controlled WHMIS te Class D2B - Skin/Eye Irritation reversible damage 16. OTHER INFORMATION Issue Date Revision Date Revision te 20-May May-2015 information available End of Safety Data Sheet Page 7 / 7