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3 Esterifying is our attitude Emollients: Real smoothness Pag 6 Application guide Pag 7 Customized answer Pag 8 Typical product characteristics Pag 9 Consistency Agents/Thickeners Pag 10 Our Polybutenes Pag 11 Emulsifiers: Make easier your formulations Pag 12 Our surfactants Pag 14 3

4 Enhancing your Natural portfolio Temix Oleo starts its own activity on October the 1st 2014, after the merger of Oleochimica Italia Srl (former Undesa Italia) with Temix International srl. As a result, the new company brings along not only strong historical traditions and values, but also a great experience in their respective business activities: detergents and cosmetics of Temix International; lubricants, rubber and other industrial application products of Oleochimica Italia. Honouring Temix International s slogan Enhancing your natural portfolio, Temix Oleo combines its experience in the distribution of raw materials, selected mainly from renewable sources, together with the technology and the long-standing experience of Oleochimica Italia in the esters and fatty acids production. Combining experience and innovation, Temix Oleo pays particular attention to a sustainable chemistry, promoting the use of selected renewable and biodegradable raw materials. Real sustainability Following the idea of a tailor made chemistry, Temix Oleo aims to create a mutual trust relationship with all the Customers. By doing so, Temix Oleo daily pursues the creation of a sustainable business management and an eco-compatible internal process, which leads to re-thinking of suitable, sustainable and qualitative solutions. Research and Development The market is constantly changing, the ability to innovate is likely to be increasingly important, in fact, the research and development (R & D) is the only engine for the growth of the company. For Temix Oleo, technological innovation is an investment which is a part of the business strategy. Green Chemistry Temix Oleo always embraces the principle of green chemistry, a concept that aims to follow the sustainability as the approch in chemical industry through technological progress. Customized products Temix Oleo is also able to supply tailor made products managing to deal with the unique and detailed Customer s requirements. For any further technical details, get in contact with our Sales Offices. 4

5 Our product range is based on different raw materials: Ethylhexyl Alcohol Isopropyl Alcohol Glycerol Oleic acid Isononyl alcohol Stearic acid Cetyl/Cetearyl alcohol Tridecyl-Isotridecyl alcohol 5

6 Emollients Real smoothness Emollients are products, which have softening and smoothing properties. They may also impart general smoothing by flattening the skin s profile, diminishing facial lines, through the pumping of individual corneocyte. These effects may be simply due to the hydration caused by the occlusive effect of the emollients. They can also serve to lubricate skin s surface and diminish the rough feeling associated with the saw tooth dead cells of the outmost skin layer. The list of emollients is almost endless, covering: Water-soluble and Oilsoluble, Refatting agents, which should replace lipids of the horney layer lost by cleansing with soap, detergent and so on. Present-day consumers prefer cosmetic products which they perceive as natural, i.e. products with harmless ingredients because of health and safety is of high importance and those with lighter, non-greasy textures and with additional conveniences such as two-in-one function, quick drying, longlasting and good performance, etc. 6

7 Emollients Application guide Commercial name INCI Sun Care Body Care Face Care Hair Care Make Up AP Deo TEMEST 2 EHS Ethylhexyl Stearate *** * TEMEST 2 EHP Ethylhexyl Palmitate *** * TEMEST 2 EHC Ethylhexyl Cocoate *** ** TEMEST 2 EHI Ethylhexyl Isononanoate ** *** *** *** TEMEST 2EHL Ethylhexyl Laurate *** * * * TEMEST J30 Di Ethylhexyl Sebacate *** ** ** ** TEMEST J05 Di Ethylhexyl Adipate *** ** * ** ** TEMEST J65 Ethyhexyl Oleate ** * ** TEMEST 99 Isononyl Isononanoate * *** * *** * TEMEST 810 Caprylic/Capric Triglyceride *** ** * ** TEMEST GMO Glyceryl Oleate *** ** *** TEMEST GMS Glyceryl Stearate ** ** TEMEST GTO Triolein ** ** TEMEST E05 Di Butyl Adipate *** * *** TEMEST E30 Di Butyl Sebacate *** * *** TEMEST ALB C12-15 Alkyl Benzoate *** *** ** TEMEST TEC Triethyl Citrate *** TEMEST CTE Cetearyl Ethylhexanoate *** ** ** ** ** TEMEST CTN Cetearyl Isononanoate ** * ** ** ** ** TEMEST COT Cetyl Caprylate * ** ** * TEMEST CTP Cetyl Palmitate * ** ** * TEMEST IPP Isopropyl Palmitate * ** ** ** ** TEMEST IPM Isopropyl Myristate ** ** ** ** TEMEST IPMP Isopropyl Myristate Isopropyl Palmitate ** ** ** ** TEMEST DO Decyl Oleate ** ** TEMEST TMO Triethylhexyl Trimellitate *** ** * *** ** TEMEST TMID Triisodecyl Trimellitate *** ** ** *** 7

8 Emollients Customized answer The choice of an emollient or a blend of emollients depends on various characteristics: Chemical structure Polarity Spreading value Molecular weight Hydrolytic stability Rheological properties Solubilizing properties Polarity The polar emollients, mostly triglycerides, esters, liquid waxes possess the characteristic of not clogging the skin pores and allowing the skin to breathe. Non-polar emollients are characterized by good retention of skin moisture and providing a good protective barrier. Polarity is also an important factor for stabilisation of W/O formulation. Spreading The spreading values of emollients depend on their chemical structure, consistency and molecular weight. The spreading value provide information about the fatty characteristics of an emollient, which play a dominant role in assessment an emollient. Spreading value inform about how regularly an oil spreads on the irregular skin surface and how it penetrates and disappears from the skin surface. Branched chain Esters Due to the good spreading characteristic and independence of viscosity from temperature, the saturated branched chain esters have gained an attention. Human sebum contain high proportions of branched chain fatty acids. Sebum, however, is highly unstable material prone to discoloration and forming malodourous decomposition product through autoxidation. Synthetic, stable, saturated branched chain esters are therefore good substitution products for natural skin lipids. Not only human but also the preen gland of duck produces a lot of branched chain fatty acid to improve the water-flow. 8

9 Emollients Typical product characteristics Commercial Name INCI Polarity Spreading vallue Feeling on the skin Molecular weight Cloud point Refractive index TEMEST 2 EHS Ethylhexyl Stearate medium medium medium light feeling ,465 TEMEST 2 EHP Ethylhexyl Palmitate medium medium medium light feeling ,445 TEMEST 2 EHC Ethylhexyl Cocoate medium medium medium light feeling ,455 TEMEST 2 EHI Ethylhexyl Isononanoate medium medium non-oily silky touch ,44 TEMEST 2EHL Ethylhexyl Laurate medium medium medium light feeling ,445 TEMEST J30 Di Ethylhexyl Sebacate high medium velvet sensation excellent uv solubilisation ,442 TEMEST J05 Di Ethylhexyl Adipate high high non-oily silky touch ,442 TEMEST J65 Ethyhexyl Oleate medium medium dry emollient ,458 TEMEST 99 Isononyl Isononanoate medium high non-oily silky touch ,435 TEMEST 810 Caprylic/Capric Triglyceride medium medium rich skin feeling excellent uv solubilisation ,445 TEMEST GMO Glyceryl Oleate medium low refatting agent ,4833 TEMEST GMS Glyceryl Stearate medium low refatting agent ,465 TEMEST GTO Triolein medium low conditiong agent ,477 TEMEST E05 Di Butyl Adipate high high non oily silky touch ,445 TEMEST E30 Di Butyl Sebacate high high non oily silky touch ,442 TEMEST ALB C12-15 Alkyl Benzoate high high TEMEST TEC Triethyl Citrate high high dry emollient excellent uv solubilisation dry emollient excellent for deo formulation , ,442 TEMEST CTE Cetearyl Ethylhexanoate medium medium non greasy ligh skin feeling ,445 TEMEST CTN Cetearyl Isononanoate medium medium dry skin feeling. no tacky ,449 TEMEST COT Cetyl Caprylate medium medium moisturizing properties ,45 TEMEST CTP Cetyl Palmitate medium medium moisturizing properties ,457 TEMEST IPP Isopropyl Palmitate medium high high spreading and lubrification ,436 TEMEST IPM Isopropyl Myristate medium high high spreading and lubrication ,433 TEMEST IPMP Isopropyl Myristate and Isopropyl Palmitate medium high high spreading and lubrication ,433 TEMEST DO Decyl Oleate medium medium dry emollient ,46 TEMEST TMO Triethylhexyl Trimellitate n.a n.a excellent for make up formulation ,488 TEMEST TMID Triisodecyl Trimellitate n.a n.a ,486 9

10 Consistency agents and thickeners Consistency agents are substances that provide creams with density, increase stability and improve suspension of added ingredients. Thickeners enhance the consistency and viscosity of cosmetic products and also improve stability and change the skin conditions, therefore selection of the correct thickener provide better performance. Ester based thickeners may have emulsifying or gelling properties as well; due to their biocompatibility can also provide a moisturizing effect. Commercial Name Inci Melting Point Hlb Main Properties ALCOLTEX1498 Myristyl Alcohol C ALCOLTEX 1698 F&B Cetyl Alcohol C ALCOLTEX 1618 F&B (30:70) Cetearyl Alcohol C ALCOLTEX 1618 F&B (50:50) Cetearyl Alcohol C Used in emulsion to increase viscosity and impart a dry non-greasy feeling Fatty Alcohol. Acts as consistency factor O/W co-emulsifier Fatty Alcohol. Acts as consistency factor O/W co-emulsifier Fatty Alcohol. Acts as consistency factor O/W co-emulsifier ALCOLTEX 1618 F&B (70:30) Cetearyl Alcohol C ALCOLTEX 1898 F&B Stearyl Alcohol C Fatty Alcohol. Acts as consistency factor O/W co-emulsifier Fatty Alcohol. Acts as consistency factor O/W co-emulsifier TEMEST CTP Cetyl Palmitate 54 C Increase viscosity, impart a dry feeling and results in dense white emulsion Used to bulid structure in cosmetic stick TEMEST GMS Glyceryl Stearate 57 C 3,4 TEMEST GMS SE Glyceryl Stearate and Sodium Stearate Used in cosmetic O/W emulsion for the viscosity adjustment. Acts as a consistency giving agents 57 C 3,4 Acts as an emulsifier TEMEST EGMS Glycol Distearate 62 C 1,5 Acts as perling agent 10

11 Our Polybutenes Polybuten is a versatile cosmetic emollient ideal for a wide range of personal care products. It is available in a low and high viscosity grades that are easily blended (graph1). Polybuten is ideal for use in colour cosmetic and lip products due to their characteristics providing skin with a soft feeling, waterproofing capability and moisturizing effects. Polybuten is an effective water-proofing agent for sunscreen formulations. Skin texture improves significantly within minutes after application of Polybuten containing formulations, showing a clear contrast and fine texture. Therefore, it is effective in production, has long lasting effects, retaining skin moisture content and thus improving skin tone and texture. Polybuten is an affordable alternative to high priced esters yet it provides the soft feeling that cosmetic formulations demand. Classification Molecular weight Viscosity 100 C Color (APHA) Water Acid value PB max ppm 0,01 PB max ppm 0,01 PB max ppm 0,01 PB max ppm 0,01 PB max ppm 0,01 PB max ppm 0,01 PB max ppm 0,01 PB max ppm 0,01 PB max ppm 0,01 PB max ppm 0,01 PB max ppm 0,01 11

12 Emulsifiers Make easier your formulations Emulsifiers are the most common type of delivery system used in cosmetics. They enable a wide variety of ingredients to be delivered quickly to skin and hair. Water plays two main roles in cosmetic formulation: Solvent and vehicle for hydro-soluble active ingredients; Fresh feeling due to evaporation. The best-known cosmetic products are based on emulsion. In these emulsions, small droplets of oil are disperse in water (W/O) or small droplets of water are dispersed in oil (W/O). Since oil and water are incompatible, emulsifiers were added to produce the small droplets and to prevent the oil and water phase from separating. Depend on the nature of the alcohol used in esterification process, they may be predominantly hydrophobic or hydrophilic, and thus suitable as W/O or O/W respectively. Non ionic emulsifiers are not affected by water hardness or ph levels. 12

13 Hair care Commercial Name Inci Applications ETOMIX HCS ETOWAX PO Cetearyl alcohol, PEG-40 hydrogenated castor oil, Behentrymonium chloride, Stearalkonium chloride Laureth-3 phosphate, Cetearyl Alcohol, laureth-3, lauryl mirystyl alcohol Conditioning base for hair care; ideal for balm and hair mask formulations Effective emulsifier for peroxide emulsions. Stable in a wide range of ph ETOWAX NBL35 Cetearyl Alcohol, Ceteareth-25, Laureth-3 Phosphate Co-emulsifier and stabilizer for hair and body care ETOWAX AB ETOWAX AB/F Cetearyl Alcohol, Sodium Cetearyl Sulfate, Sodium lauryl Sulfate Cetearyl Alcohol, PEG-40 Castor Oil, Sodium Cetearyl Sulfate Emulsifier for hair balms and creams Emulsifier for hair balms and creams ETOWAX AB/W Cetearyl Alcohol, Sodium Lauryl Sulfate Emulsifier for hair balms and creams ETOWAX AB/N Cetearyl Alcohol, Sodium Cetearyl Sulfate Emulsifier for hair balms and creams ETOWAX NB Cetearyl alcohol, Ceteareth-20 Emulsifier for skin care and hair care ETOWAX NB10 Cetearyl alcohol, Ceteareth-25 Emulsifier for skin care and hair care ETOWAX NB30 Cetearyl alcohol, Ceteareth-30 Emulsifier for skin care and hair care Skin care Commercial Name Inci Applications ETOWAX LC Steareth-21, Steareth-2, PPG/PEG-4/14 Dimethicone Emulsifier for Liquid Cristals emulsions ETOWAX DC Cetearyl alcohol, lanolin, peg-8 stearate, ceteareth-25, glyceryl stearate Emulsifier for acids and basics emulsions; suitable in a wide range of ph and at high level of salts. Suitable for depilatory system Our Specialties Commercial Name Inci Applications ETOWAX SP ETOWAX EB Glyceryl Stearate, Ceteareth-20, Ceteareth-12, Cetearyl Alcohol, Cetyl Palmitate Cetearyl Alcohol, Ceteareth-25, Polysorbate 60, PEG-100 Stearate Self emulsifier for O/W emulsions; stable in a wide range of ph Self emulsifier for O/W emulsions; stable in a wide range of ph ETOWAX LP15 C12-20 Acid, PEG-8 Ester Non ionic emulsifier for O/W emulsions ETOWAX GMPG ETOWAX CGP60 ETOWAX EB2 Glyceryl Stearate, PEG-100 Stearate Cetearyl Alcohol, Glyceryl Stearate, PEG-100 Stearate Cetearyl Alcohol, PEG-20 Stearate Emulsifier for skin care; it gives more consistency to the emulsions Self emulsifier for O/W emulsions; stable in a wide range of ph Self emulsifier for O/W emulsions; stable in a wide range of ph TEMEST GMS Glyceryl Stearate Co-emulsifier and emollient TEMEST GMS ST Glyceryl Stearate, Sodium stearate Self emulsifier for skin and hair care 13

14 Our Surfactants According to the company s philosophy, Temix Oleo offers surfactants from renewable sources and a wide range of traditional surfactants, which completes the portfolio and allows us to satisfy each customer s request. Commercial Name Inci Applications Non Ionic Surfactant ETOMIX HC20 Ceteareth-20 Non-ionic surfactant with HLB 15,2 ETOMIX HC25 Ceteareth-25 Non-ionic surfactant with HLB 16,4 Anionic Surfactant TEMIXAN SERIE Sodium Laureth Sulphate Primary surfactant for persoanl care applications TEMIXAL SERIE Sodium Alkyl Sulphate Primary surfactant for persoanl care applications TEMIXAN A SERIE Ammonium Laureth Sulphate Primary surfactant for persoanl care applications Amphoteric Surfactant BETAMIX C Cocamidopropyl Betaine Co-surfactant for personal care applications AMITEX MEA Cocamide MEA Co-surfactant for personal care applications AMITEX DEA Cocamide DEA Co-surfactant for personal care applications 14

15 We care 15

16 Temix Oleo Srl Head office Via Piero Portaluppi, Milano - Italy ph fax Production site Via Giuseppe Garibaldi, Calderara di Reno (BO) - Italy ph fax