S-20 BETADET LAURYL HYDROXYSULTAINE: A HIGH-END AMPHOTERIC SURFACTANT

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1 BETADET S-2 ULTRA MILD SURFACTANT GREAT FORMULATION STABILITY ENHANCED FOAM VOLUME IMPROVED THICKENING EFFECT LAURYL HYDROXYSULTAINE: A HIGH-END AMPHOTERIC SURFACTANT KAO SURFACTANTS TECHNOLOGY AT YOUR SERVICE

2 BETADET S-2, a gentle touch with impressive results BETADET S-2 (INCI name: Lauryl Hydroxysultaine) is an ultra mild co-surfactant for personal care formulations. Hydroxysultaines are highly effective amphoteric surfactants that improve the performance of final cosmetic products. Lauryl Hydroxysultaine is an extremely mild co-surfactant that increases the performance of personal care formulations compared to alkylbetaines and amidopropyl betaines. MAIN FEATURES Vegetable origin Preservative-free Biodegradable Compatible with anionic, non-ionic and cationic surfactants Provides excellent thickening Foam booster and foam stabilizer Extremely mild for the eyes and skin Stable at a wide range of ph and temperatures Good ecotoxicological profile Biocidal activity BETADET S-2 Lauryl Hydroxysultaine TECHNICAL DATA CH 3 Appearance (25ºC) Colorless to light yellow transparent liquid R N + CH 2 CH CH 2 SO 3 Dry Matter % Viscosity (2ºC) < 5 cps CH 3 OH R= C 12 ph (1% in water) BETADET S-2 Kao Chemicals Europe

3 CHARACTERISTICS BETADET S-2 is recommended as a secondary surfactant for very mild and high foaming products, achieving higher foam volumes than alkyl betaines or alkyl amidopropyl betaines. This product is easier to thicken when combined with SLES, thus reducing the amount of electrolytes needed to obtain a desired viscosity compared to other amphoteric surfactants. One of the main features of BETADET S-2 is the ability to reduce the cloud point of final formulations making them more stable at low temperatures, which helps to obtain clear final stable products. It also shows excellent stability to hard water, improving the behavior of some sensitive anionic surfactants under extreme conditions. Furthermore, BETADET S-2 is stable at extreme ph s thus allowing its use in cosmetics formulations where an alkali (i.e. depilatories) or acid media is necessary. VERY MILD VISCOSITY BUILDER BABY SHAMPOO COLD STABILIZER FACIAL CLEANSER BETADET S-2 LIQUID HAND SOAP EMULSIFIER BETADET S-2 is a transparent concentrated betaine, very easy to handle thanks to its low viscosity at room temperature. RELAXING CREAM SHOWER/BATH FEMININE HYGIENE FOAM BOOSTER ph AND Tº STABLE SLES: Sodium Laureth Sulfate Kao Chemicals Europe BETADET S-2 3

4 MAIN PROPERTIES In order to compare the properties of BETADET S-2 with other betaines, a Model Formula has been studied with standard levels of anionic surfactant (SLES), non-ionic thickener (CDEA) and the Amphoteric Surfactant as the variable. ph has been adjusted to 6.5 in all cases. MODEL FORMULA % in active matter (a.m.) Sodium Laureth Sulfate 1. Cocamide DEA 1.5 AMPHOTERIC SURFACTANT 3. ZEIN VALUE (mg N/1 ml) SKIN IRRITATION POTENTIAL TEST ZEIN TEST EYE IRRITATION POTENTIAL TEST RBC: MIOI NON IRRITANT CAPB CADA CAHS BETADET S-2 MILDNESS There s an ever-growing awareness over consu mers of rinse-off products to buy the correct one for their skin. Babies, elders, people with sensitive epidermis, all of them need very mild formulations to avoid dryness, itchiness or even rashes on their skin. The mildness of amphoteric surfactants is well known but hydroxysultaines are especially mild to the eyes and skin. Therefore, BETADET S-2 is a good option to formulate a wide variety of very mild end products such as intimate hygiene cleansers or no-tears baby shampoos. Moreover, thanks to its detoxifying properties, it reduces the irritation produced by anionic surfactants. As seen in the graphics, the conclusion of the skin and eye irritation potential tests is that Lauryl Hydroxysultaine is completely non irritant. RBC: MIOI Ref. C-1 BABY SHAMPOO % EMAL 27D Sodium Laureth Sulfate 12. BETADET S-2 Lauryl Hydroxysultaine 7. LEVENOL H&B Glycereth-2 Cocoate 2. AKYPO FOAM RL 4 Sodium Laureth-5 Carboxylate 1.5 AMIDET N PEG-4 Rapeseedamide 1.5 EDTA.Na 2.5 NON IRRITANT CAPB CADA CAHS BETADET S-2 CAPB: Cocamidopropyl Betaine. CAHS Cocamidopropyl Hydroxysultaine. CADA: Disodium Cocoamphodiacetate. CDEA: Cocamide DEA. SLES: Sodium Laureth Sulfate *Additives: Perfume, dyes, preservatives, etc. 4 BETADET S-2 Kao Chemicals Europe

5 THICKENING ABILITY BETADET S-2 has a great thickening ability in SLES-based rinse-off products and even in other anionic-based formulations. It achieves higher viscosity levels when compared with alkyl betaines, alkyl amidopropyl betaines and alkyl amphodiacetates so less amount of product (or electrolytes) can be used. As seen in the graphic, the enhanced thickening ability of the product in comparison with the other betaines is noticeable in all range of salt evaluated. VISCOSITY (cps) THICKENING ABILITY MODEL FORMULA % NaCl CAPB CADA CAHS BETADET S-2 Ref. C-32 HAND LIQUID SOAP % EMAL 27D Sodium Laureth Sulfate 9.5 BETADET S-2 Lauryl Hydroxysultaine 3. LEVENOL H&B Glycereth-2 Cocoate 2. DANOX P-15 Pearlizing agent 3. The combination of BETADET S-2 with LEVENOL H&B, a thickening emollient surfactant, makes this hand soap a mild highly foaming product with very good after-feeling. Ref. C-227 NON-IRRITANT SHOWER GEL % ALFANOX 46 Sodium α-olefine Sulfonate 27. BETADET S-2 Lauryl Hydroxysultaine 1.5 AMIDET N PEG-4 Rapeseedamide 2.1 EXCEPARL LM-LC Lauryl Lactate.3 BETADET S-2 can also be used in formulations with alternative anionic surfactants like Sodium α-olefine Sulfonate giving a viscous, transparent and non-irritant product. CAPB: Cocamidopropyl Betaine. CAHS Cocamidopropyl Hydroxysultaine. CADA: Disodium Cocoamphodiacetate. CDEA: Cocamide DEA. SLES: Sodium Laureth Sulfate *Additives: Perfume, dyes, preservatives, etc. Kao Chemicals Europe BETADET S-2 5

6 MAIN PROPERTIES STABILITY BETADET S-2 stabilizes formulations at low temperatures thus helping the formulator to get clear products in rough environments with complex formulations. The cold cloud point test performed over the Model Formula shows a much better turbidity point by cold with BETADET S-2 than the ones containing other types of betaines. EMULSIFYING ABILITY Lauryl hydroxysultaine is capable of emulsifying oils and sebum more thoroughly than other betaines so the washing process becomes more effective. BETADET S-2 avoids the redeposition of hydrophobic substances to the skin so it is also advised for facial cleansing formulations. COLD CLOUD POINT (ºC) STABILITY AT LOW TEMPERATURES Cold Cloud Point % NaCl ABS (5nm) EMULSIFICATION TEST WITH COLORED SEBUM SLES / Betaine: ratio 17/3 in weight Sebum (ml) Lanolin/Triolein=25/75 wt% SLES SLES / CAPB SLES / BETADET S-2 Ref. C-161 CAPB CADA CAHS BETADET S-2 FORTIFYING SHAMPOO % EMAL 27D Sodium Laureth Sulfate 14.3 AKYPO SOFT 1 BVC Sodium Laureth-11 Carboxylate 5.7 BETADET S-2 Lauryl Hydroxysultaine 5. LEVENOL H&B Glycereth-2 Cocoate 2. Hair Loss Prevention Complex 2. Promois WJ Hydrolyzed Pea Protein 2. Ref. C-222 SENSITIVE SKIN FACE CLEANSER EMAL 27D Sodium Laureth Sulfate 9.7 AKYPO FOAM RL 4 Sodium Laureth-5 Carboxylate 3.3 BETADET S-2 Lauryl Hydroxysultaine 5.3 Glycerine 2. Propylene Glycol 1.5 Carbopol Ultrez Carbomer 1.3 % CAPB: Cocamidopropyl Betaine. CAHS Cocamidopropyl Hydroxysultaine. CADA: Disodium Cocoamphodiacetate. CDEA: Cocamide DEA. SLES: Sodium Laureth Sulfate *Additives: Perfume, dyes, preservatives, etc. 6 BETADET S-2 Kao Chemicals Europe

7 FOAMING ABILITY BETADET S-2 is an excellent foaming surfactant at different ph s and even at high concentration of cationic ions (Ca 2+ and Mg 2+ ). When it is combined with anionic surfactants, all foam characteristics are improved: foam volume, speed and quality. As seen in the graphic where the results of a Ross Miles test are shown, the Model Formula with BETADET S-2 produces higher foam volume with better foam stability. Foam volume (mm) Ref. C-72 FOAM BEHAVIOUR Ross Miles:.1% a.m. ; 25ºC; 2ºf CONDITIONING SHAMPOO % EMAL 27D Sodium Laureth Sulfate 12.3 BETADET S-2 Lauryl Hydroxysultaine 8. LEVENOL H&B Glycereth-2 Cocoate 2. AMIDET APA-22 Behenamidopropyl Dimethylamine.5 5 sec 5 min Time CAPB CADA CAHS BETADET S-2 Alsind test mimics the natural washing process of the hair by using a device where foam is produced directly on hair. Foam ability has been determined for the Model Formula containing CAPB/ CDEA or BETADET S-2 and AMIDET N (PEG-4 Rapeseedamide), a Cocamide DEA replacement. As seen in the graphic, the foaming ability of the formulation containing BETADET S-2 and AMIDET N is better than the regular one; foam is produced faster and higher volume is achieved in all time range evaluated. Foam volume (mm) FOAM BEHAVIOUR Alsind test Time (sec) SLES/CAPB/CDEA SLES/BETADET S-2/ AMIDET N The relatively low foaming ability of cosmetic products in presence of sebum or oil is substantially improved after the addition of BETADET S-2 due to its emulsifying properties. CAPB: Cocamidopropyl Betaine. CAHS Cocamidopropyl Hydroxysultaine. CADA: Disodium Cocoamphodiacetate. CDEA: Cocamide DEA. SLES: Sodium Laureth Sulfate *Additives: Perfume, dyes, preservatives, etc. Kao Chemicals Europe BETADET S-2 7

8 KAO CHEMICALS EUROPE Enriching lives, in harmony with nature. Kao Corporation, S.A. Puig dels Tudons, 1 E-821 Barberà del Vallès (Barcelona) Spain Tel.: Fax: sales@kao.es Kao Chemicals GmbH Kupferstrasse 1 D Emmerich, Germany Tel.: +49 () Fax: +49 () sales@kaochemicals.de (Edited December 213. EU version) OUR CHEMICALS, YOUR BUSINESS

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