Bio-based Building Blocks - Priplast. Taipei, 24 th May 2017
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1 Bio-based Building Blocks - Priplast Taipei, 24 th May 2017
2 Bio-based Building Blocks Company introduction Raw materials Technology Features & benefits Conclusion
3 Our History
4 Where We Operate
5 Our Technologies Speciality alkoxylates Esters Bio-based dimer acids Proteins & biopolymers Fatty amides Polymeric surfactants High purity lipid concentrates Plant cell culture Plant extraction technology Peptides Metal oxides Lanolin & derivatives
6 Pripol Dimerised Fatty Acid Unsaturated, natural oils and fats C=C C=O C=C-C-C=C C=O heat, pressure, catalyst C=O separation O=C HO C=O trimerised fatty acid O=C HO C=O dimerised fatty acid C=O isostearic fatty acid
7 General Features Pripol Dimer Acids Bio-based from natural fatty acids Large hydrocarbon part (C 36 ) hydrophobic hydrolytic resistance of derivatives affinity for non-polar matrices and surfaces O=C HO Irregular non-crystalline structure flexibility low Tg flow, wetting low modulus, no strain hardening no shrinkage C=O Di-functional constituent for: polyamides polyesters polyurethanes epoxies polyimides
8 Different Forms Dimer Technology Dimer acid Pripol Dimer diol Pripol HOOC HO CO Polyester polyols Priplast HO---- E--E n Dimer diamine Priamine H 2 N NH 2
9 Priplast Technology Hydrocarbon nature Bio-based No ether linkage Stability against heat, oxygen and UV Hydrophobicity Hydrolytic stability Low moisture absorption Affinity for low polarity matrices and surfaces Non-crystalline structure Flexibility, low Tg No strain hardening Good flow and wetting Good adhesion to a wide range of substrates Hydroxyl functionality Reactivity in: polyurethanes, co-polyamides, co-polyesters etc. E--E n
10 Low Moisture Absorption of PU Priplast brings water resistance vs. conventional polyols Moisture uptake at 23 o C (%) To limit performance difference in wet or dry conditions Recipe : 1 Polyol 2 Butanediol 3.1 MDI Conditions : 1 week in H 2 O dist. Priplast 3196 Priplast 1838 Poly BD Priplast 3190 HDO carbonate Priplast 3192 HDO-adipate Polycaprolactone BDO-adipate PTMEG PPG
11 Hydrolytic Stability of PU in Boiling Water Priplast brings good hydrolysis resistance Retention of tensile strength [%] Priplast: hydrolytic and oxidative stability To resist moisture for enhanced durability ester: hydrolysis ether: oxidation PTMEG HDO-adipate Priplast Days Recipe : 1 Polyol 2 Butanediol 3.1 MDI Conditions : Boiling water
12 Durability: Thermo-oxidative Stability Priplast improves stability vs. other polyols Retention of tensile strength / elongation [%] ester Strength Elongation To resist thermal oxidation for enhanced durability ether; fell apart unsaturated diol; no ether / ester BDO-adipate Priplast 1838 PTMEG PPG Poly BD PU elastomer Recipe : 1 Polyol 2 Butanediol 3.1 MDI Conditions: 4 weeks at 140 o C
13 Mechanical Properties Flexible and no strain-hardening, ca. 600% elongation Recipe: 1 polyol 2 BDO 3.1 MDI crystalline adipate PTMEG Priplast 3192 (semi-crystalline) Priplast 1838 (amorphous) Poly BD/rubber Strain
14 10 0 Flexibility: Low T g of Polyurethanes Priplast brings flexibility also at low temperatures Glass transition temperature [ o C] To be flexible even at low temperatures HDO-adipate Polycaprolactone Priplast 3192 Priplast 3196 Priplast 1838 PPG Priplast 1838 (*) PTMEG Priplast 3190 Recipe : 1 Polyol 2 Butanediol 3.1 MDI P1838 (*) =
15 Summary Bio-based Priplast Durability Hydrolysis and thermo-oxidative resistance Chemical resistance Excellent moisture repellency Flexibility Rubber-like behaviour (best comparison PTMEG), no strain hardening Low temperature flexibility Excellent flow properties Up to 100% renewable carbon content
16 Keep Up to-date With Croda C&P Visit our website for our latest product and event news Sign up for Croda Direct, our customer extranet, to download our latest literature, view webinar recordings and simple sample ordering and more Follow us on: LinkedIn Croda Coatings and Polymers
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