Safety Data Sheet according to (EC) No 1907/2006

Transcription

1 Safety Data Sheet according to (EC) No 1907/2006 Pattex Contact Kraftkleber Liquid Classic Page 1 of 14 sds no. : Revision: printing date: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Pattex Contact Kraftkleber Liquid Classic 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Contact adhesive 1.3. Details of the supplier of the safety data sheet Henkel AG & Co. KGaA Henkelstr Düsseldorf Germany ua-productsafety.de@henkel.com 1.4. Emergency telephone number The Henkel information service also provides an around-the-clock telephone service on phone no.+49-(0) for exceptional cases. The product is notified at the 'Information Centers for Cases of Poisoning in Germany'. These centers provide information by telephone day and night in poisoning cases. Central emergency phone number: ++49 (0) Classification of the substance or mixture SECTION 2: Hazards identification Classification (DPD): F - Highly flammable R11 Highly flammable. Xi - Irritant R36/38 Irritating to eyes and skin. N - Dangerous for the environment R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness Label elements

2 Pattex Contact Kraftkleber Liquid Classic Page 2 of 14 Label elements (DPD): F - Highly flammable Xi - Irritant N - Dangerous for the environment Risk phrases: R11 Highly flammable. R36/38 Irritating to eyes and skin. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. Safety phrases: S2 Keep out of the reach of children. S9 Keep container in a well-ventilated place. S16 Keep away from sources of ignition - No smoking. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S29 Do not empty into drains. S46 If swallowed, seek medical advice immediately and show this container or label. S51 Use only in well-ventilated areas. Contains Rosin. May produce an allergic reaction Other hazards Solvents contained in the product evaporate during processing and their vapors can form explosive/highly inflammable air/vapor mixtures. Pregnant women should absolutely avoid inhalation and skin contact. General chemical description: Adhesive Base substances of preparation: aliphatic hydrocarbons SECTION 3: Composition/information on ingredients

3 Pattex Contact Kraftkleber Liquid Classic Page 3 of 14 Declaration of the ingredients according to CLP (EC) No 1272/2008: Hydrocarbon aliphatic C4-11 < 0,1% benzene Rosin EC Number REACH-Reg No content Classification >= 25- <= 50 % Flammable liquids 2 H225 Specific target organ toxicity - single exposure 3 H336 Serious eye irritation 2 H319 >= 25- <= 50 % Skin irritation 2 H315 Aspiration hazard 1 H304 Specific target organ toxicity - single exposure 3 H336 Flammable liquids 2 H225 Chronic hazards to the aquatic environment 2 H >= 10- <= 20 % Aspiration hazard 1 H304 Skin irritation 2 H315 Specific target organ toxicity - single exposure 3 H336 Flammable liquids 2 H225 Chronic hazards to the aquatic environment 2 H >= 0,1- < 1 % Skin sensitizer 1 H >= 0,1- < 1 % Acute hazards to the aquatic environment 1 H400 Chronic hazards to the aquatic environment 1 H >= 0,1- < 0,5 % Flammable liquids 2 H225 Toxic to reproduction 2 H361f Aspiration hazard 1 H304 Specific target organ toxicity - repeated exposure 2 H373 Skin irritation 2 H315 Specific target organ toxicity - single exposure 3 H336 Chronic hazards to the aquatic environment 2 H411 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available.

4 Pattex Contact Kraftkleber Liquid Classic Page 4 of 14 Declaration of ingredients according to DPD (EC) No 1999/45: Hydrocarbon aliphatic C4-11 < 0,1% benzene Rosin EC Number REACH-Reg No content Classification >= 25 - <= 50 % F - Highly flammable; R11 R66 Xi - Irritant; R36 R67 >= 25 - <= 50 % F - Highly flammable; R11 Xn - Harmful; R65 R67 Xi - Irritant; R38 N - Dangerous for the environment; R51/ >= 10 - <= 20 % F - Highly flammable; R11 Xi - Irritant; R38 Xn - Harmful; R65 R67 N - Dangerous for the environment; R51/ >= 0,1 - < 1 % R >= 0,1 - < 1 % N - Dangerous for the environment; R50/ >= 0,1 - < 0,5 % F - Highly flammable; R11 Toxic for reproduction - category 3.; R62 Xi - Irritant; R38 R67 Xn - Harmful; R65, R48/20 N - Dangerous for the environment; R51/53 For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available Description of first aid measures General information: In case of adverse health effects seek medical advice. Inhalation: Move to fresh air, consult doctor if complaint persists. SECTION 4: First aid measures Skin contact: Rinse with running water and soap. Skin care. Remove contaminated clothes immediately. Eye contact: Immediately flush eyes with soft jet of water or eye rinse solution for at least 5 minutes. If pains remains (intensive smarting, sensivity to light, visual disturbance) continue flushing and contact/seek doctor or hospital. Ingestion: Rinse mouth and throat. Drink 1-2 glasses of water. Seek medical advice Most important symptoms and effects, both acute and delayed SKIN: Redness, inflammation. EYE: Irritation, conjunctivitis. Vapors may cause drowsiness and dizziness Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures SECTION 5: Firefighting measures

5 Pattex Contact Kraftkleber Liquid Classic Page 5 of Extinguishing media Suitable extinguishing media: carbon dioxide, foam, powder, water spray jet, fine water spray Extinguishing media which must not be used for safety reasons: High pressure waterjet 5.2. Special hazards arising from the substance or mixture In the event of a fire, carbon monoxide (CO) and carbon dioxide (CO2) can be released Advice for firefighters Wear self-contained breathing apparatus. Wear protective equipment. Additional information: Cool endangered containers with water spray jet. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Keep away from sources of ignition. Ensure adequate ventilation. Danger of slipping on spilled product Environmental precautions Do not empty into drains / surface water / ground water Methods and material for containment and cleaning up Remove with liquid-absorbing material (sand, peat, sawdust). Dispose of contaminated material as waste according to Chapter Reference to other sections See advice in chapter 8 SECTION 7: Handling and storage 7.1. Precautions for safe handling Ventilate working rooms thoroughly. Avoid naked flames, sparking and sources of ignition. Switch off electrical devices. Do not smoke, do not weld. Do not empty waste into waste water drains. Also to be noted when processing larger amounts (> 1 kg): during processing and drying after adhesion, ventilate well. Avoid all sources of fire such as stoves and ovens. Switch off all electrical devices such as parabolic heaters, hot plates, storage heaters etc. in good time for them to have cooled down before commencing work. Avoid all sparks, including those occurring at electrical switches and devices. Hygiene measures: Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working Conditions for safe storage, including any incompatibilities Keep only in the original container. Close the container carefully after use and store it at a good ventilated place. Avoid strictly temperatures below + 5 C and above + 50 C. Do not store together with food or other consumables (coffee, tea, tobacco, etc.) Specific end use(s) Contact adhesive

6 Pattex Contact Kraftkleber Liquid Classic Page 6 of 14 SECTION 8: controls/personal protection 8.1. Control parameters Valid for Germany Ingredient ppm mg/m 3 Type Category Remarks Short Term Classification: Category I: substances for which the localized effect has an assigned OEL or for substances with a sensitizing effect in respiratory passages. TRGS 900 N-HEXANE AGW: 2 If the AGW and BGW values are complied with, there should be no risk of reproductive damage (see Number 2.7). TRGS AGW: 2 TRGS 900 Short Term Classification: Category II: substances with a resorptive effect. Short Term Category II: substances with a Classification: resorptive effect AGW: 8 If the AGW and BGW values are complied with, there should be no risk of reproductive damage (see Number 2.7) Time Weighted Average Indicative (TWA): TRGS 900 TRGS 900 TRGS 900 ECTLV Predicted No-Effect Concentration (PNEC): Name on list Environmental Compartment STP aqua (freshwater) aqua (marine water) sediment (freshwater) soil sediment (marine water) period Value mg/l ppm mg/kg others 650 mg/l 1,25 mg/kg 0,24 mg/kg 0,125 mg/kg 0,26 mg/l 0,026 mg/l Remarks

7 Pattex Contact Kraftkleber Liquid Classic Page 7 of 14 Derived No-Effect Level (DNEL): Name on list Application Area Route of Health Effect worker inhalation Long term worker inhalation Long term local effects worker dermal Long term general inhalation Acute/short term population local effects general population inhalation Acute/short term worker dermal Long term worker inhalation Long term general population general population general population dermal inhalation oral Long term Long term Long term Time Value 730 mg/m3 730 mg/m3 63 mg/kg bw/day 730 mg/m3 730 mg/m3 773 mg/kg bw/day 2035 mg/m3 699 mg/kg bw/day 608 mg/m3 699 mg/kg bw/day Remarks 8.2. controls: Respiratory protection: Suitable breathing mask when there is inadequate ventilation. Combination filter: ABEKP This recommendation should be matched to local conditions. Hand protection: Recommended are gloves made from Nitril rubber ( Material thickness >0,1 mm, Perforation time < 30s).Gloves should be replaced after each short time contact or contamination. Available at laboratory specialized trade or at pharmacies / chemist's shops. In the case of longer and repeated contact please note that in practice the penetration times may be considerably shorter than those determined according to EN 374. The protective gloves must always be checked for their suitability for use at the specific workplace (e.g. mechanical and thermal stress, product compatibility, antistatic effects, etc.). The gloves must be replaced immediately at the first signs of wear and tear. The information provided by the manufacturers and given in the relevant trade association regulations for industrial safety must always be observed. We recommend that a hand care plan is drawn up in cooperation with a glove manufacturer and the trade association in accordance with the local operating conditions. Perforation time > 10 minutes material thickness > 0.4 mm In the case of longer contact protective gloves made from nitrile rubber are recommended according to EN 374. Eye protection: Goggles which can be tightly sealed. Skin protection: Suitable protective clothing

8 Pattex Contact Kraftkleber Liquid Classic Page 8 of 14 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance liquid highly viscous beige Odor Solvent ph Initial boiling point Flash point Decomposition temperature Vapour pressure Density () Bulk density Viscosity (Brookfield; speed of rotation: 50 min-1; Spindle No: 4) Viscosity (kinematic) Explosive properties Solubility (qualitative) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties -21 C (-5.8 F); DIN Closed cup flash point 0,84-0,88 g/ml mpa.s 9.2. Other information Reactivity None if used for intended purpose Chemical stability Stable under recommended storage conditions Possibility of hazardous reactions See section reactivity Conditions to avoid None if used for intended purpose Incompatible materials None if used properly Hazardous decomposition products None known SECTION 10: Stability and reactivity Information on toxicological effects SECTION 11: Toxicological information General toxicological information: The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following.

9 Pattex Contact Kraftkleber Liquid Classic Page 9 of 14 Inhalative toxicity: The toxicity of the product is due to its narcotic effect after inhalation. In the event of protracted or repeated exposure, damage to health cannot be excluded. Vapors may cause drowsiness and dizziness. Skin irritation: Primary skin irritation: irritating Eye irritation: Primary eye irritation: irritating Sensitizing: An allergic reaction cannot be excluded after repeated skin contact. Acute toxicity: Value type Value Route of application time Species LD mg/kg oral rat LC mg/l inhalation 1 h rat LD50 > mg/kg dermal rabbit LD50 > mg/kg oral rat Method Skin corrosion/irritation: Result time Species not irritating 24 h rabbit not irritating rabbit Method Serious eye damage/irritation: Result time Species Method slightly irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) slightly irritating rabbit Respiratory or skin sensitization: not sensitising not sensitising Result Test type Species Method Guinea pig maximisat ion test Guinea pig maximisat ion test guinea pig guinea pig OECD Guideline 406 (Skin Sensitisation) OECD Guideline 406 (Skin Sensitisation) Germ cell mutagenicity: Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g Ames test) negative bacterial reverse mutation assay (e.g Ames test) Metabolic activation / time with and without with and without negative inhalation rat Species Method

10 Pattex Contact Kraftkleber Liquid Classic Page 10 of 14 Repeated dose toxicity Result NOAEL=900 mg/kg NOAEL=0,002 mg/l Route of application time / Frequency of treatment oral: gavage 90 d daily rat inhalation 90 d continuous rat Species Method SECTION 12: Ecological information General ecological information: The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Do not empty into drains / surface water / ground water. Toxic to aquatic organisms May cause long-term adverse effects in the aquatic environment.

11 Pattex Contact Kraftkleber Liquid Classic Page 11 of Toxicity Hydrocarbon aliphatic C4-11 < 0,1% benzene Hydrocarbon aliphatic C4-11 < 0,1% benzene Hydrocarbon aliphatic C4-11 < 0,1% benzene Rosin Rosin Rosin Value type Value Acute Toxicity Study time Species LC mg/l Fish 48 h Leuciscus idus melanotus Method EC mg/l Daphnia 48 h Daphnia cucullata OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 > mg/l Algae 96 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) OECD Guideline 201 (Alga, Growth Inhibition Test) EC mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) LC mg/l Fish OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 3 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC mg/l Algae OECD Guideline 201 (Alga, Growth Inhibition Test) LC50 > mg/l Fish 96 h Pimephales promelas OECD Guideline 203 (Fish, Acute Toxicity Test) EC mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 > 100 mg/l Algae 72 h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) LC50 > mg/l Fish Leuciscus idus OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 0,17 mg/l Algae 72 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) OECD Guideline 201 (Alga, Growth Inhibition Test) LC mg/l Fish OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 2,1 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC mg/l Algae OECD Guideline 201 (Alga, Growth Inhibition Test) Persistence and degradability Result Route of application Degradability Method

12 Rosin Pattex Contact Kraftkleber Liquid Classic Page 12 of 14 readily biodegradable aerobic 100 % OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Test) aerobic % OECD Guideline 301 F (Ready Biodegradability: Manometric Respirometry Test) readily biodegradable aerobic > 60 % Bioaccumulative potential / Mobility in soil LogKow Bioconcentration factor (BCF) time Species Temperature Method 0,6 OECD Guideline 107 (Partition Coefficient (noctanol / water), Shake Flask Method) 3,61 4 SECTION 13: Disposal considerations Waste treatment methods Product disposal: Dispose of waste and residues in accordance with local authority requirements. Disposal of uncleaned packages: Use packages for recycling only when totally empty. Waste code waste adhesives and sealants containing organic solvents and other dangerous substances Road transport ADR: SECTION 14: Transport information Class: 3 Packaging group: II Classification code: F1 Hazard ident. number: 33 UN no.: 1133 Label: 3 Technical name: ADHESIVES Tunnelcode: (D/E) Additional information: Special provision 640D Additional substance property: Environmentally Hazardous Railroad transport RID: Class: 3 Packaging group: II Classification code: F1 Hazard ident. number: 33 UN no.: 1133 Label: 3 Technical name: ADHESIVES Tunnelcode: Additional information: Special provision 640D Additional substance property: Environmentally Hazardous

13 Pattex Contact Kraftkleber Liquid Classic Page 13 of 14 Inland water transport ADN: Class: 3 Packaging group: II Classification code: F1 Hazard ident. number: UN no.: 1133 Label: 3 Technical name: ADHESIVES Additional information: Special provision 640D Additional substance property: Environmentally Hazardous Marine transport IMDG: Class: 3 Packaging group: II UN no.: 1133 Label: 3 EmS: F-E,S-D Seawater pollutant: Marine pollutant Proper shipping name: ADHESIVES () Air transport IATA: Class: 3 Packaging group: II Packaging instructions (passenger) 353 Packaging instructions (cargo) 364 UN no.: 1133 Label: 3 Proper shipping name: Adhesives SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content 62,43 % (VOCV VOC regulation CH) National regulations/information (Germany): WGK: 2, water-endangering product. (German VwVwS of May 17, 1999 ) Classification in conformity with the calculation method Storage class VCI: 3

14 Pattex Contact Kraftkleber Liquid Classic Page 14 of 14 SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: R11 Highly flammable. R36 Irritating to eyes. R38 Irritating to skin. R43 May cause sensitisation by skin contact. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R62 Possible risk of impaired fertility. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. H225 Highly flammable liquid and vapor. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. H361f Suspected of damaging fertility. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.