Safety Data Sheet Page 1 of 17

Transcription

1 Safety Data Sheet Page 1 of 17 SDS No. : Revision: printing date: Section 1. Identification of the substance/prepaion and of the company/undertaking Product name: Other means of identification: LOCTITE AA MLEN. Product code: IDH Recommended use of the chemical and restrictions on use Intended use: Acrylics Identification of manufacturer, importer or distributor Importer: Henkel Malaysia Sdn Bhd 46th Floor, Menara TM, Jalan Pantai Baharu, Kuala Lumpur, Malaysia. Phone : Fax : address of person responsible for Safety Data Sheet: Emergency information: ap-ua-psra.sea@henkel.com FOR EMERGENCIES ONLY (Spill, major leak, Fire, Exposure, or Accident). Call CHEMTREC: Section 2. Hazards identification GHS Classification: Hazard Class Hazard Category Target organ Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Skin sensitizer Category 1 Toxic to reproduction Category 1B Specific target organ toxicity - Category 3 respiory tract irritation single exposure Chronic hazards to the aquatic environment Category 3 GHS label elements: Hazard pictogram: Signal word: Danger

2 Page 2 of 17 Precaution: Hazard statement: H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H335 May cause respiory irritation. H360 May damage fertility or the unborn child. H412 Harmful to aquatic life with long lasting effects. Prevention: Response: Storage: Disposal: P201 Obtain special instructions before use. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash hands thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty of water. P304+P340+P310 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or physician. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P363 Wash contaminated clothing before reuse. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

3 Page 3 of 17 Substance or Mixture: Mixture Section 3. Composition / information on ingredients Declaion of hazardous chemical: Hazard component CAS-No. Content GHS Classification Tetrahydrofurfuryl methacrylate % Skin corrosion/irritation 2; Dermal H315 Serious eye damage/eye irritation 2 H319 Toxic to reproduction 1B H360 Specific target organ toxicity - single exposure 3; Inhalation H335 Chronic hazards to the aquatic environment 3 H412 (epichlorhydrin); epoxy resin (number average molecular weight <= 700) 1-Methyltrimethylene dimethacrylate % Acute toxicity 4; Oral H302 Acute toxicity 4; Inhalation H332 Acute toxicity 3; Dermal H311 Skin corrosion/irritation 1A H314 Serious eye damage/eye irritation 1 H318 Specific target organ toxicity - single exposure 3 H % Skin corrosion/irritation 2 H315 Serious eye damage/eye irritation 2 H319 Specific target organ toxicity - single exposure 3 H335 Chronic hazards to the aquatic environment 3 H % Skin corrosion/irritation 2 H315 Serious eye damage/eye irritation 2 H319 Skin sensitizer 1 H317 Chronic hazards to the aquatic environment 2 H % Skin sensitizer 1 H % Acute hazards to the aquatic environment 1 H400 Chronic hazards to the aquatic environment 1 H % Organic peroxides E H242 Acute toxicity 4; Oral H302 Acute toxicity 3; Inhalation H331 Acute toxicity 4; Dermal H312 Skin corrosion/irritation 1B H314 Specific target organ toxicity - repeated exposure 2 H373 Chronic hazards to the aquatic environment 2 H411 < 0.1 % Acute toxicity 4; Oral H302 Serious eye damage/eye irritation 1 H318 Skin sensitizer 1

4 Page 4 of 17 H317 Germ cell mutagenicity 2 H341 Carcinogenicity 2 H351 Acute hazards to the aquatic environment 1 H400 Section 4. First aid measures Inhalation: Skin contact: Eye contact: Ingestion: Should not be a problem as product is of low volatility. However, if feeling unwell remove patient to fresh air. Seek medical advice. Rinse with running water and soap. Rinse immediately with plenty of running water (for 10 minutes). Seek medical attention if necessary. Seek medical advice. Rinse out mouth, drink 1-2 glasses of water, do not induce vomiting. Indication of immediate medical attention and special treatment needed: See section: Description of first aid measures Section 5. Fire fighting measures Suitable extinguishing media: Special protection equipment and precautions for firefighters: Hazardous combustion products: Additional fire fighting advice: Carbon dioxide, foam, powder Wear self-contained breathing appaus and full protective clothing, such as turn-out gear. Oxides of carbon, oxides of nitrogen, irritating organic vapors. In case of fire, keep containers cool with water spray. Section 6. Accidental release measures Personal precautions: Environmental precautions: Clean-up methods: Ensure adequate ventilation. See advice in section 8 Do not let product enter drains. For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal. Wash spillage site thoroughly with soap and water or detergent solution. Dispose of contaminated material as waste according to Section 13. Section 7. Handling and storage

5 Page 5 of 17 Handling: Storage: Use only in well-ventilated areas. Avoid skin and eye contact. Prolonged or repeated skin contact should be avoided to minimise any risk of sensitisation. Store in original containers at 8-21 C ( F) and do not return residual materials to containers as contamination may reduce the shelf life of the bulk product.

6 Page 6 of 17 Section 8. Exposure controls / personal protection Components with specific control parameters for workplace: METHACRYLIC ACID METHACRYLIC ACID BUTYLATED HYDROXYTOLUENE (BHT), INHALABLE FRACTION AND VAPOR 2,6-DI-TERT-BUTYL-P-CRESOL [BUTYLATED HYDROXYTOLUENE (BHT)] HYDROQUINONE HYDROQUINONE Time Weighted Average (TWA): ppm 20 Remarks ACGIH Time Weighted Average (TWA): ppm 20 mg/m 3 70 Remarks MY OEL Time Weighted Average (TWA): mg/m 3 2 Remarks ACGIH Time Weighted Average (TWA): mg/m 3 10 Remarks MY OEL Time Weighted Average (TWA): mg/m 3 1 Remarks ACGIH Time Weighted Average (TWA): mg/m 3 2 Remarks MY OEL Respiory protection: Ensure adequate ventilation. Do not inhale vapors and fumes. Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on liteure references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. tempeure). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Body protection: Engineering controls: Hygienic measures: Tightly fitting safety goggles Avoid eye contact. Wear suitable protective clothing. Ensure good ventilation/extraction. Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. Good industrial hygiene practices should be observed.

7 Page 7 of 17 Section 9. Physical and chemical properties Appearance: yellow liquid Odor: Acrylic Odor threshold (CA): ph: 10 Melting point / freezing point: Specific gravity: 1.16 Boiling point: Flash point: > 100 C (> 212 F) Evapoion e: Flammability (solid, gas): Lower explosive limit: Upper explosive limit: Vapor pressure: < 4 mbar Vapor density: Density: Solubility: Partition coefficient: n- octanol/water: Auto ignition: Decomposition tempeure: Viscosity: VOC content: (2010/75/EC) < 9 % Section 10. Stability and reactivity Reactivity/Incompatible materials: Chemical stability: Conditions to avoid: Hazardous decomposition products: Reaction with strong oxidants. Stable under recommended storage conditions. Stable under normal conditions of storage and use. carbon oxides. Section 11. Toxicological information Oral toxicity: Inhalative toxicity: Dermal toxicity: Acute toxicity estimate (ATE) : > 2,000 mg/kg : Calculation method Acute toxicity estimate (ATE) : > 5 mg/l : 4 h Test atmosphere: dust/mist : Calculation method Acute toxicity estimate (ATE) : > 2,000 mg/kg : Calculation method

8 Page 8 of 17 Symptoms of Overexposure: SKIN: Rash, Urticaria. RESPIRATORY: Irritation, coughing, shortness of breath, chest tightness. SKIN: Redness, inflammation. EYE: Irritation, conjunctivitis. Acute oral toxicity: Tetrahydrofurfuryl methacrylate (number average molecular weight <= 700) 1-Methyltrimethylene dimethacrylate ,000 mg/kg OECD Guideline 401 (Acute Oral Toxicity) 1,320 mg/kg OECD Guideline 401 (Acute Oral Toxicity) > 2,000 mg/kg OECD Guideline 401 (Acute Oral Toxicity) > 2,000 mg/kg OECD Guideline 420 (Acute Oral Toxicity) > 5,000 mg/kg > 6,000 mg/kg OECD Guideline 401 (Acute Oral Toxicity) 550 mg/kg 367 mg/kg OECD Guideline 401 (Acute Oral Toxicity)

9 Page 9 of 17 Acute inhalative toxicity: Acute dermal toxicity: (number average molecular weight <= 700) 1-Methyltrimethylene dimethacrylate Skin corrosion/irritation: LC50 > 3.6 mg/l 4 h OECD Guideline 403 (Acute Inhalation Toxicity) 500-1,000 mg/kg Dermal Toxicity Screening > 2,000 mg/kg > 3,000 mg/kg > 2,000 mg/kg OECD Guideline 402 (Acute Dermal Toxicity) 1,200-1,520 mg/kg (number average molecular weight <= 700) Serious eye damage/irritation: (number average molecular weight <= 700) corrosive 3 min OECD Guideline 404 (Acute Dermal Irritation / Corrosion) modeely irritating 24 h Draize Test not irritating 4 h OECD Guideline 404 (Acute Dermal Irritation / Corrosion) corrosive Draize Test corrosive Draize Test not irritating OECD Guideline 405 (Acute Eye Irritation / Corrosion) slightly irritating OECD Guideline 405 (Acute Eye Irritation / Corrosion)

10 Page 10 of 17 Respiory or skin sensitization: (number average molecular weight <= 700) 1-Methyltrimethylene dimethacrylate Test type Test type Test type Test type Test type not sensitising Buehler test guinea pig OECD Guideline 406 (Skin Sensitisation) sensitising Mouse local lymphnode assay (LLNA) mouse OECD Guideline 429 (Skin Sensitisation: Local Lymph Node Assay) sensitising Mouse local lymphnode assay (LLNA) mouse OECD Guideline 429 (Skin Sensitisation: Local Lymph Node Assay) not sensitising Draize Test guinea pig Draize Test sensitising Guinea pig maximisation test guinea pig

11 Page 11 of 17 Germ cell mutagenicity: (number average molecular weight <= 700) (number average molecular weight <= 700) Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / bacterial reverse mutation assay (e.g Ames test) with and without OECD Guideline 471 (Bacterial Reverse Mutation Assay) inhalation mouse OECD Guideline 478 (Genetic Toxicology: Rodent Dominant Lethal Test) bacterial reverse mutation assay (e.g Ames test) with and without OECD Guideline 471 (Bacterial Reverse Mutation Assay) bacterial reverse mutation assay (e.g Ames test) with and without OECD Guideline 472 (Genetic Toxicology: Escherichia coli, Reverse Mutation Assay) oral: gavage mouse bacterial reverse mutation assay (e.g Ames test) with and without in vitro mammalian chromosome aberion test with and without mammalian cell gene mutation assay with oral: feed positive bacterial reverse mutation assay (e.g Ames test) without OECD Guideline 471 (Bacterial Reverse Mutation Assay) dermal mouse bacterial reverse mutation assay (e.g Ames test) with and without EU B.13/14 (Mutagenicity)

12 Page 12 of 17 Repeated dose toxicity: Tetrahydrofurfuryl methacrylate (number average molecular weight <= 700) / Frequency of treatment / Frequency of treatment / Frequency of treatment / Frequency of treatment / Frequency of treatment / Frequency of treatment NOAEL=300 mg/kg oral: unspecified 28 days OECD Guideline 422 (Combined Repeated Dose Toxicity Study with the Reproduction / Developmental Toxicity Screening Test) NOAEL=50 mg/kg oral: gavage 14 wdaily OECD Guideline 408 (Repeated Dose 90-Day Oral Toxicity in Rodents) NOAEL=25 mg/kg oral: feed daily inhalation: aerosol 6 h/d5 d/w NOAEL=>= 250 mg/kg oral: gavage 14 days5 days/week. 12 doses OECD Guideline 407 (Repeated Dose 28-Day Oral Toxicity in Rodents) LOAEL=<= 500 mg/kg oral: gavage 14 days5 days/week. 12 doses OECD Guideline 407 (Repeated Dose 28-Day Oral Toxicity in Rodents) Section 12. Ecological information General ecological information: Ecotoxicity: Do not empty into drains / surface water / ground water. Harmful to aquatic organisms. Toxicity: Tetrahydrofurfuryl methacrylate Tetrahydrofurfuryl methacrylate LC mg/l Fish 96 h Pimephales promelas OECD Guideline 203 (Fish, Acute Toxicity Test) > 100 mg/l Desmodesmus subspicatus NOEC > 100 mg/l Desmodesmus subspicatus LC50 85 mg/l Fish

13 Page 13 of 17 (number average molecular weight <= 700) (number average molecular weight <= 700) (number average molecular weight <= 700) 96 h Salmo gairdneri (new name: Oncorhynchus mykiss) EPA OTS (Fish Acute Toxicity Test) > 130 mg/l Daphnia 48 h Daphnia magna EPA OTS (Aquatic Invertebe Acute Toxicity Test, Freshwater Daphnids) NOEC 8.2 mg/l Selenastrum capricornutum (new name: Pseudokirchneriella subcapitata) 45 mg/l Selenastrum capricornutum (new name: Pseudokirchneriella subcapitata) EC mg/l Bacteria 17 h LC mg/l Fish 96 h Oryzias latipes OECD Guideline 203 (Fish, Acute Toxicity Test) 4.56 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) 7.68 mg/l Pseudokirchneriella subcapitata NOEC 0.28 mg/l Pseudokirchneriella subcapitata LC mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Acute Toxicity Test) 1.7 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) > 11 mg/l Scenedesmus capricornutum

14 Page 14 of 17 (number average molecular weight <= 700) 1-Methyltrimethylene dimethacrylate Methyltrimethylene dimethacrylate Methyltrimethylene dimethacrylate NOEC 4.2 mg/l Scenedesmus capricornutum IC50 > 100 mg/l Bacteria 3 h activated sludge, industrial other guideline: LC mg/l Fish 48 h DIN mg/l Desmodesmus subspicatus NOEC 2.11 mg/l Desmodesmus subspicatus NOEC 20 mg/l Bacteria 28 d activated sludge, domestic NOEC mg/l Fish 30 d Oryzias latipes OECD Guideline 210 (fish early lite stage toxicity test) 0.48 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC mg/l Desmodesmus subspicatus (reported as Scenedesmus subspicatus) EU C.3 (Algal Inhibition test) LC mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Acute Toxicity Test) EC 50 7 mg/l Daphnia 24 h Water flea (Daphnia magna) 18 mg/l Daphnia 48 h

15 Page 15 of 17 Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) ErC mg/l Pseudokirchneriella subcapitata EC10 70 mg/l Bacteria 30 min LC mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Acute Toxicity Test) mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) mg/l Selenastrum capricornutum (new name: Pseudokirchneriella subcapitata) EC mg/l Bacteria 30 min Persistence and degradability: Tetrahydrofurfuryl methacrylate (number average molecular weight <= 700) 1-Methyltrimethylene dimethacrylate not readily biodegradable. Degradability 75 % OECD Guideline 301 F (Ready Biodegradability: Manometric Respirometry Test) inherently biodegradable Degradability 100 % OECD Guideline 302 B (Inherent biodegradability: Zahn-Wellens/EMPA Test) readily biodegradable Degradability 86 % OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Test) readily biodegradable Degradability 88 % OECD Guideline 301 C (Ready Biodegradability: Modified MITI Test (I)) not readily biodegradable. Degradability 5 % OECD Guideline 301 F (Ready Biodegradability: Manometric Respirometry Test) readily biodegradable Degradability 84 % OECD Guideline 310 (Ready BiodegradabilityCO2 in Sealed Vessels (Headspace Test)

16 Page 16 of 17 not readily biodegradable. Degradability 4.5 % OECD Guideline 301 C (Ready Biodegradability: Modified MITI Test (I)) not inherently biodegradable Degradability % OECD Guideline 302 C (Inherent Biodegradability: Modified MITI Test (II)) no data Degradability 0 % OECD Guideline 301 B (Ready Biodegradability: CO2 Evolution Test) readily biodegradable Degradability % EU C.4-E (Determination of the "Ready" BiodegradabilityClosed Bottle Test) Bioaccumulative potential / Mobility in soil: Tetrahydrofurfuryl methacrylate (number average molecular weight <= 700) LogPow 1.76 Tempeure EU A.8 (Partition Coefficient) LogPow 0.93 Tempeure 22 C OECD Guideline 107 (Partition Coefficient (n-octanol / water), Shake Flask ) Bioconcention factor (BCF) h Danio rerio Tempeure 24 C OECD Guideline 305 (Bioconcention: Flow-through Fish Test) LogPow 4.95 Tempeure 20 C OECD Guideline 107 (Partition Coefficient (n-octanol / water), Shake Flask ) LogPow Tempeure 25 C EU A.8 (Partition Coefficient) Bioconcention factor (BCF) 330-1, d Cyprinus carpio Tempeure OECD Guideline 305 C (Bioaccumulation: Test for the Degree of Bioconcention in Fish) LogPow 5.1 Tempeure OECD Guideline 107 (Partition Coefficient (n-octanol / water), Shake Flask ) Bioconcention factor (BCF) 9.1 calculation Tempeure OECD Guideline 305 (Bioconcention: Flow-through Fish Test) LogPow 2.16 Tempeure LogPow 0.59 Tempeure EU A.8 (Partition Coefficient)

17 Page 17 of 17 Product Packaging of disposal: Section 13. Disposal consideions Dispose of in accordance with local and national regulations. Disposal of uncleaned packages: After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incineed. Section 14. Transport information Road transport ADR: Not dangerous goods Railroad transport RID: Not dangerous goods Inland water transport ADN: Not dangerous goods Marine transport IMDG: Not dangerous goods Air transport IATA: Not dangerous goods Section 15. Regulatory information Regulatory Information: Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations 2013 [P.U.(A) 310/213] Industry Code of Practice on Chemicals Classification and Hazard Communication Global inventory status: Regulatory list EINECS TSCA AICS DSL ENCS (JP) KECI (KR) PICCS (PH) IECSC ISHL (JP) NZIOC Notification Section 16. Other information Disclaimer: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.