Safety Data Sheet Page 1 of 12

Transcription

1 Safety Data Sheet Page 1 of 12 Loctite 3430B Kit component SDS No. : V002.3 Revision: printing date: Section 1. Identification of the substance/prepaion and of the company/undertaking Product name: Loctite 3430B Kit component Other means of identification: Loctite 3430B Kit component Product code: IDH Recommended use of the chemical and restrictions on use Intended use: Epoxy Hardener Identification of manufacturer, importer or distributor Manufacturer: Henkel S.p.A., Milano, Via C. Amoretti No. 78, Milano, Italy. Phone: Fax: Importer: Henkel Thailand Ltd The Offices at Centralworld, 35th Floor, 999/9 Rama 1 Rd, Kwang Patumwan, Khet Patumwan, Bangkok 10330, Thailand. Phone : Fax : address of person responsible for Safety Data Sheet: ap-ua-psra.sea@henkel.com Emergency information: FOR EMERGENCIES ONLY (Spill, major leak, Fire, Exposure, or Accident). Call CHEMTREC: GHS Classification: Hazard Class Hazard Category Skin corrosion/irritation Category 1A Serious eye damage/eye irritation Category 1 Skin sensitizer Category 1 Chronic hazards to the aquatic Category 3 environment GHS label elements: Hazard pictogram: Section 2. Hazards identification Signal word: Danger

2 Page 2 of 12 Precaution: Hazard statement: H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects. Prevention: P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash hands thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. Response: P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304+P340+P310 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or physician. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P363 Wash contaminated clothing before reuse. Disposal: P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

3 Page 3 of 12 Section 3. Composition / information on ingredients Substance or Mixture: Mixture Declaion of hazardous chemical: Hazard component CAS-No. Content GHS Classification 2,2'-[1,2-ethanediylbis(oxy)]bis(ethanethiol) % Acute toxicity 4; Oral H302 Acute toxicity 4; Inhalation H332 Acute hazards to the aquatic environment 2 H401 Chronic hazards to the aquatic environment 2 H411 N'-(3-Aminopropyl)-N,N-dimethylpropane-1,3- diamine (epichlorhydrin); epoxy resin (number average molecular weight 1-10 % Acute toxicity 5; Oral H303 Acute toxicity 5; Dermal H313 Skin corrosion/irritation 1 H314 Skin sensitizer 1 H % Acute toxicity 4; Oral H302 Skin corrosion/irritation 1 H314 Skin sensitizer 1B H317 Acute hazards to the aquatic environment 2 H % Skin corrosion/irritation 2 H315 Serious eye damage/eye irritation 2A H319 Skin sensitizer 1 H317 Acute hazards to the aquatic environment 2 H401 Chronic hazards to the aquatic environment 2 H411 Inhalation: Move to fresh air. In case of adverse health effects seek medical advice. Skin contact: Rinse with running water and soap. Obtain medical attention if irritation persists. Section 4. First aid measures Eye contact: Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor. Indication of immediate medical attention and special treatment needed: See section: Description of first aid measures

4 Page 4 of 12 Section 5. Fire fighting measures Suitable extinguishing media: Carbon dioxide, foam, powder Improper extinguishing media: None known Specific hazards arising from the chemical: Do not expose to direct heat. In the event of a fire, carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx) can be released. Special protection equipment and precautions for firefighters: Wear self-contained breathing appaus. Wear protective equipment. Additional fire fighting advice: In case of fire, keep containers cool with water spray. Personal precautions: Ensure adequate ventilation. Avoid skin and eye contact. Wear protective equipment. Environmental precautions: Do not let product enter drains. Section 6. Accidental release measures Clean-up methods: For large spills absorb onto inert absorbent material and place in sealed container for disposal. For small spills wipe up with paper towel and place in container for disposal. Dispose of contaminated material as waste according to Section 13. Handling: Avoid skin and eye contact. Use only in well-ventilated areas. Gloves and safety glasses should be worn Do not inhale vapors and fumes. Storage: Store in sealed original container. Store in a cool, well-ventilated place. Section 7. Handling and storage

5 Page 5 of 12 Components with specific control parameters for workplace: Section 8. Exposure controls / personal protection Respiory protection: Ensure adequate ventilation. An approved mask or respior fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A (EN 14387) Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on liteure references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. tempeure). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk of splashing. Protective eye equipment should conform to EN166. Body protection: Wear suitable protective clothing. Protective clothing should conform to EN for liquid splashes or to EN for dusts. Engineering controls: Ensure good ventilation/extraction. Hygienic measures: Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. Good industrial hygiene practices should be observed. Section 9. Physical and chemical properties Appearance: Odor: Odor threshold (CA): ph: Melting point / freezing point: Specific gravity: Boiling point: Flash point: (no method) Evapoion e: Flammability (solid, gas): Lower explosive limit: Upper explosive limit: Vapor pressure: (no method; 50 C (122 F)) Clear liquid characteristic > 230 C (> 446 F) > C (> 212 F) < 700 mbar

6 Page 6 of 12 Vapor density: Density: Solubility: Partition coefficient: n- octanol/water: Auto ignition: Decomposition tempeure: Viscosity: (Cone and plate; 25 C (77 F); Shear gradient: 10 s-1; : ;; LCT STM 740; cone & plate viscosity) VOC content: (2010/75/EC) 1.1 g/cm3 19,000-26,000 mpa.s < 3 % Reactivity/Incompatible materials: Reaction with strong acids. Chemical stability: Stable under recommended storage conditions. Conditions to avoid: No decomposition if used according to specifications. Avoid contact with acids and oxidizing agents. Avoid contact with water. Hazardous decomposition products: None if used for intended purpose. Section 10. Stability and reactivity Section 11. Toxicological information Oral toxicity: Inhalative toxicity: Symptoms of Overexposure: Acute toxicity estimate (ATE) : > 2,000 mg/kg : Calculation method Acute toxicity estimate (ATE) : > 20 mg/l : 4 h Test atmosphere: Vapor. : Calculation method Causes burns. SKIN: Rash, Urticaria. Acute oral toxicity: 2,2'-[1,2- ethanediylbis(oxy)]bis(ethanethiol) N'-(3-Aminopropyl)-N,Ndimethylpropane-1,3-diamine (number average molecular weight type type type type LD mg/kg not specified LD50 3,160 mg/kg OECD Guideline 401 (Acute Oral Toxicity) LD50 1,669 mg/kg OECD Guideline 401 (Acute Oral Toxicity) LD50 > 2,000 mg/kg OECD Guideline 420 (Acute Oral Toxicity)

7 Page 7 of 12 Acute dermal toxicity: (number average molecular weight Skin corrosion/irritation: type type type Acute toxicity estimate (ATE) 2,500 mg/kg Expert judgement LD50 > 2,150 mg/kg OECD Guideline 402 (Acute Dermal Toxicity) LD50 > 2,000 mg/kg not specified (number average molecular weight Serious eye damage/irritation: (number average molecular weight Respiory or skin sensitization: corrosive rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) modeely irritating 24 h rabbit Draize Test not irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) (number average molecular weight Test type sensitising Mouse local lymphnode assay (LLNA) mouse OECD Guideline 429 (Skin Sensitisation: Local Lymph Node Assay) Germ cell mutagenicity: Oxybis(ethyleneoxy)bis(propyla mi Oxybis(ethyleneoxy)bis(propyla mi Oxybis(ethyleneoxy)bis(propyla mi (number average molecular weight (number average molecular weight Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / negative in vitro mammalian cell micronucleus test with and without OECD Guideline 487 (In vitro Mammalian Cell Micronucleus Test) negative mammalian cell gene mutation assay with and without OECD Guideline 476 (In vitro Mammalian Cell Gene Mutation Test) negative bacterial reverse mutation assay (e.g Ames test) with and without OECD Guideline 471 (Bacterial Reverse Mutation Assay) negative bacterial reverse mutation assay (e.g Ames test) with and without OECD Guideline 472 (Genetic Toxicology: Escherichia coli, Reverse Mutation Assay) negative oral: gavage mouse not specified

8 Page 8 of 12 Repeated dose toxicity: Oxybis(ethyleneoxy)bis(propyla mi (number average molecular weight / Frequency of treatment / Frequency of treatment NOAEL=< 100 mg/kg oral: gavage 59 daysdaily OECD Guideline 422 (Combined Repeated Dose Toxicity Study with the Reproduction / Developmental Toxicity Screening Test) NOAEL=50 mg/kg oral: gavage 14 wdaily OECD Guideline 408 (Repeated Dose 90-Day Oral Toxicity in Rodents) Section 12. Ecological information Ecotoxicity: Do not empty into drains / surface water / ground water., Harmful to aquatic life with long lasting effects. Toxicity: 2,2'-[1,2- ethanediylbis(oxy)]bis(ethanethiol) N'-(3-Aminopropyl)-N,Ndimethylpropane-1,3-diamine (number average molecular weight type EC mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) type LC50 > mg/l Fish 96 h Leuciscus idus DIN type EC mg/l Daphnia 48 h Daphnia magna EU C.2 (Acute Toxicity for Daphnia) type EC mg/l Algae 72 h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) DIN type NOEC 15.6 mg/l Algae 72 h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) DIN type EC mg/l Bacteria 17 h Pseudomonas putida DIN 38412, part 8 (Pseudomonas Zellvermehrungshemm-Test) type EC mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) type LC mg/l Fish 96 h

9 Page 9 of 12 Oncorhynchus mykiss OECD Guideline 203 (Fish, Acute Toxicity Test) type EC mg/l (number average molecular weight Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) type EC50 > 11 mg/l (number average molecular weight Algae 72 h Scenedesmus capricornutum OECD Guideline 201 (Alga, Growth Inhibition Test) type NOEC 4.2 mg/l Algae 72 h Scenedesmus capricornutum OECD Guideline 201 (Alga, Growth Inhibition Test) type IC50 > 100 mg/l (number average molecular weight Bacteria 3 h activated sludge, industrial other guideline: Persistence and degradability: 2,2'-[1,2- ethanediylbis(oxy)]bis(ethanethi ol) Oxybis(ethyleneoxy)bis(propyla mi N'-(3-Aminopropyl)-N,Ndimethylpropane-1,3-diamine Degradability < 10 % OECD Guideline 301 A (new version) (Ready Biodegradability: DOC Die Away Test) not inherently biodegradable aerobic Degradability < 20 % OECD Guideline 302 B (Inherent biodegradability: Zahn-Wellens/EMPA Test) not readily biodegradable. aerobic Degradability 0 % OECD Guideline 301 B (Ready Biodegradability: CO2 Evolution Test) readily biodegradable Degradability 100 % OECD Guideline 301 A (new version) (Ready Biodegradability: DOC Die Away Test)

10 Page 10 of 12 (number average molecular weight aerobic Degradability 5 % OECD Guideline 301 F (Ready Biodegradability: Manometric Respirometry Test) Bioaccumulative potential / Mobility in soil: 2,2'-[1,2- ethanediylbis(oxy)]bis(ethanethi ol) Oxybis(ethyleneoxy)bis(propyla mi N'-(3-Aminopropyl)-N,Ndimethylpropane-1,3-diamine (number average molecular weight LogPow 0.66 Tempeure not specified LogPow Tempeure 25 C OECD Guideline 107 (Partition Coefficient (n-octanol / water), Shake Flask ) LogPow Tempeure 25 C other (calculated) LogPow Tempeure 25 C EU A.8 (Partition Coefficient) Section 13. Disposal consideions Product Packaging of disposal: Dispose of in accordance with local and national regulations. Collection and delivery to recycling enterprise or other registered elimination institution. Disposal of uncleaned packages: After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incineed. Section 14. Transport information Road transport ADR: Class: 8 Packing group: II Classification code: C7 Hazard ident. number: 80 UN no.: 2735 Label: 8 Technical name: AMINES, LIQUID, CORROSIVE, N.O.S. (N,N'- Dimethyldipropyltriamine,oxybis(ethyleneoxy)bis(propylami)

11 Page 11 of 12 Railroad transport RID: Class: 8 Packing group: II Classification code: C7 Hazard ident. number: 80 UN no.: 2735 Label: 8 Technical name: AMINES, LIQUID, CORROSIVE, N.O.S. (N,N'- Dimethyldipropyltriamine,oxybis(ethyleneoxy)bis(propylami) Inland water transport ADN: Class: 8 Packing group: II Classification code: C7 Hazard ident. number: UN no.: 2735 Label: 8 Technical name: AMINES, LIQUID, CORROSIVE, N.O.S. (N,N'- Dimethyldipropyltriamine,oxybis(ethyleneoxy)bis(propylami) Marine transport IMDG: Class: 8 Packing group: II UN no.: 2735 Label: 8 EmS: F-A,S-B Seawater pollutant: Marine pollutant Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (N,N'- Dimethyldipropyltriamine, oxybis(ethyleneoxy)bis(propylami,epoxy resin) Air transport IATA: Class: 8 Packing group: II Packaging instructions (passenger): 851 Packaging instructions (cargo): 855 UN no.: 2735 Label: 8 Proper shipping name: Amines, liquid, corrosive, n.o.s. (N,N'-Dimethyldipropyltriamine, oxybis(ethyleneoxy)bis(propylami) Section 15. Regulatory information Regulatory Information: Ministry of Industry Notice. The system to classify and communicate the hazard of hazardous material, BE Global inventory status: Regulatory list TSCA Notification yes

12 Page 12 of 12 Section 16. Other information Disclaimer: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.