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1 Safety Data Sheet LOCTITE EA 1C-LV A RESIN known as Kit Hysol 1CLV Resin Page 1 of 9 SDS No. : V001.5 Revision: printing date: Section 1. Identification of the substance/preparation and of the company/undertaking Product name: LOCTITE EA 1C-LV A RESIN known as Kit Other means of identification: LOCTITE EA 1C-LV A RESIN 50ML Product code: IDH Recommended use of the chemical and restrictions on use Intended use: Part A of 2-K-Epoxy Adhesive Identification of manufacturer, importer or distributor Importer: Henkel Malaysia Sdn Bhd 46th Floor, Menara TM, Jalan Pantai Baharu, Kuala Lumpur, Malaysia. Phone : Fax : address of person responsible for Safety Data Sheet: Emergency information: ap-ua-psra.sea@henkel.com FOR EMERGENCIES ONLY (Spill, major leak, Fire, Exposure, or Accident). Call CHEMTREC: Section 2. Hazards identification GHS Classification: Hazard Class Hazard Category Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Skin sensitizer Category 1 Chronic hazards to the aquatic Category 2 environment GHS label elements: Hazard pictogram: Signal word: Warning
2 Page 2 of 9 Hazard statement: H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H411 Toxic to aquatic life with long lasting effects. Precaution: Prevention: Response: Disposal: P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash hands thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty of water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P391 Collect spillage. P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Section 3. Composition / information on ingredients Substance or Mixture: Mixture Declaration of hazardous chemical: Hazard component CAS-No. Content GHS Classification (epichlorhydrin); epoxy % Skin corrosion/irritation 2 resin H315 Serious eye damage/eye irritation 2 H319 Skin sensitizer 1 H317 Chronic hazards to the aquatic environment 2 H % 4,4'-Methylenediphenol, polymer with 1-chloro-2,3- epoxypropane % Skin corrosion/irritation 2 H315 Serious eye damage/eye irritation 2 H319 Skin sensitizer 1 H317 Chronic hazards to the aquatic environment 2 H411 Section 4. First aid measures
3 Page 3 of 9 Inhalation: Skin contact: Eye contact: Ingestion: Move to fresh air. If symptoms persist, seek medical advice. Immediately wash skin thoroughly with soap and water. Obtain medical attention if irritation persists. Wash with plenty of water immediately and continue for several minutes, holding eyelid open. Consult a doctor. Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor. Indication of immediate medical attention and special treatment needed: See section: Description of first aid measures Section 5. Fire fighting measures Suitable extinguishing media: Improper extinguishing media: Specific hazards arising from the chemical: Special protection equipment and precautions for firefighters: Foam, extinguishing powder, carbon dioxide. Water spray jet High pressure waterjet Danger of decomposition if exposed to heat. In case of fire, keep containers cool with water spray. Closed containers may rupture (due to build up of pressure) when exposed to extreme heat. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Hazardous combustion products: See section 10. Section 6. Accidental release measures Personal precautions: Environmental precautions: Clean-up methods: Avoid contact with skin and e. Wear protective equipment. Ensure adequate ventilation. Do not empty into drains / surface water / ground water. Ensure adequate ventilation. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Dispose of contaminated material as waste according to Section 13. Section 7. Handling and storage Handling: Storage: Use only in well-ventilated areas. Extract when the product is heated. Avoid skin and eye contact. See advice in section 8 Store in sealed original container. Protect against contamination.ensure that storage and workrooms are adequately ventilated. Store in a cool, dry place. Keep away from heat and direct sunlight.
4 Page 4 of 9 Components with specific control parameters for workplace: Section 8. Exposure controls / personal protection TALC, CONTAINING NO ASBESTOS FIBERS, RESPIRABLE FRACTION TALC (CONTAINING NO ASBESTOS FIBRES), RESPIRABLE FRACTION Time Weighted Average (TWA): mg/m 3 2 Remarks ACGIH The value is for particulate matter containing no asbestos and <1% crystalline silica. Time Weighted Average (TWA): mg/m 3 2 Remarks MY OEL Respiratory protection: Hand protection: Eye protection: Body protection: Engineering controls: Hygienic measures: Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A (EN 14387) Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): Isobutylene-isoprene rubber (IIR; >= 0.7 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): Isobutylene-isoprene rubber (IIR; >= 0.7 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk of splashing. Protective eye equipment should conform to EN166. Suitable protective clothing Protective clothing should conform to EN for liquid splashes or to EN for dusts. Ensure good ventilation/extraction. Good industrial hygiene practices should be observed. Appearance: Off white Viscous, Liquid Odor: mild Odor threshold (CA): ph: Not applicable Melting point / freezing point: Specific gravity: 1.57 Boiling point: > 200 C (> 392 F) Flash point: > 93 C (> F) (Tagliabue closed cup) Evaporation rate: Flammability (solid, gas): Section 9. Physical and chemical properties
5 Page 5 of 9 Lower explosive limit: Upper explosive limit: Vapor pressure: Vapor density: Density: Solubility: Partition coefficient: n- octanol/water: Auto ignition: Decomposition temperature: Viscosity: VOC content: (2010/75/EC) 1.57 g/cm3 < 3 % Reactivity/Incompatible materials: Section 10. Stability and reactivity Reacts with alcohols and amines. Reacts with oxidants, acids and l Reaction with some curing agents may produce an exothermic reaction which in large masses could cause runaway polymerization. Stable under recommended storage conditions. Chemical stability: Possibility of hazardous reactions: Rapid polymerization may generate excessive heat and pressure. Conditions to avoid: Stable under normal conditions of storage and use. Excessive heat. Danger of decomposition if exposed to heat. Hazardous decomposition products: Hydrocarbons carbon oxides. Polymerization may occur at elevated temperature or in the presence of incompatible materials. May produce fumes when heated to decomposition. Fumes may contain carbon monoxide and other toxic fumes. See section 5. Section 11. Toxicological information Symptoms of Overexposure: EYE: Irritation, conjunctivitis. SKIN: Redness, inflammation. SKIN: Rash, Urticaria. Acute oral toxicity: LD50 > 2,000 mg/kg rat OECD Guideline 420 (Acute Oral Toxicity) LD50 > 2,000 mg/kg rat EU B.1 (Acute Toxicity (Oral))
6 Page 6 of 9 Acute dermal toxicity: LD50 > 2,000 mg/kg rat not specified Skin corrosion/irritation: (number average molecular weight Serious eye damage/irritation: (number average molecular weight Respiratory or skin sensitization: moderately irritating 24 h Draize Test slightly irritating 4 h OECD Guideline 404 (Acute Dermal Irritation / Corrosion) not irritating OECD Guideline 405 (Acute Eye Irritation / Corrosion) moderately irritating 24 h OECD Guideline 405 (Acute Eye Irritation / Corrosion) slightly irritating EU B.5 (Acute Toxicity: Eye Irritation / Corrosion) Test type sensitising Mouse local lymphnode assay (LLNA) mouse OECD Guideline 429 (Skin Sensitisation: Local Lymph Node Assay) Germ cell mutagenicity: (number average molecular weight (number average molecular weight Repeated dose toxicity: (number average molecular weight Type of study / Route of administration Metabolic activation / Type of study / Route of administration Metabolic activation / Route of application / Frequency of treatment negative bacterial reverse mutation assay (e.g Ames test) with and without OECD Guideline 472 (Genetic Toxicology: Escherichia coli, Reverse Mutation Assay) negative oral: gavage mouse NOAEL=50 mg/kg oral: gavage 14 wdaily rat OECD Guideline 408 (Repeated Dose 90-Day Oral Toxicity in Rodents) Section 12. Ecological information
7 Page 7 of 9 Ecotoxicity: Toxic to aquatic life with long lasting effects., Do not empty into drains / surface water / ground water. Toxicity: Acute Toxicity Study Acute Toxicity Study Acute Toxicity Study Acute Toxicity Study LC mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Acute Toxicity Test) EC mg/l Algae 72 h Scenedesmus capricornutum OECD Guideline 201 (Alga, Growth Inhibition Test) NOEC 2.4 mg/l Algae 72 h Scenedesmus capricornutum OECD Guideline 201 (Alga, Growth Inhibition Test) LC50 > 100 g/l Fish 24 h Brachydanio rerio (new name: Danio rerio) OECD Guideline 203 (Fish, Acute Toxicity Test) Persistence and degradability: (number average molecular weight Route of application aerobic Degradability 5 % OECD Guideline 301 F (Ready Biodegradability: Manometric Respirometry Test) Section 13. Disposal considerations Product of disposal: Dispose of in accordance with local and national regulations. Packaging Disposal of uncleaned packages: Use packages for recycling only when totally empty. Packaging that cannot be cleaned are to be disposed of in the same manner as the product. Section 14. Transport information
8 Page 8 of 9 Road transport ADR: Classification code: M6 Hazard ident. number: 90 Technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy resin) Railroad transport RID: Classification code: M6 Hazard ident. number: 90 Technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy resin) Inland water transport ADN: Classification code: M6 Hazard ident. number: Technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy resin) Marine transport IMDG: EmS: F-A,S-F Seawater pollutant: Marine pollutant Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy resin) Air transport IATA: Packaging instructions (passenger): 964 Packaging instructions (cargo): 964 Proper shipping name: Environmentally hazardous substance, liquid, n.o.s. (Epoxy resin)
9 Page 9 of 9 Section 15. Regulatory information Regulatory Information: Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations 2013 [P.U.(A) 310/213] Industry Code of Practice on Chemicals Classification and Hazard Communication Global inventory status: Regulatory list EINECS TSCA DSL ENCS (JP) KECI (KR) PICCS (PH) IECSC NZIOC Notification Section 16. Other information Disclaimer: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.
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