Material Safety Data Sheet according to Regulation (EC) 1907/2006

Transcription

1 01. Identification of the substance/preparation and of the company/undertaking Product name : Manufacturer/Supplier : Rostosan Plus Rust primer gray 3 x 750 ml Chemische Werke Kluthe Werk Oberhausen Street/P.O.Box : Feldstraße 55 Country code/postal code/town/city : D Oberhausen Telephone : / Telefax : / Contact : sds.ob@kluthe.com Emergency information : / Hazards identification Hazard designation Directive 67/548/EEC or 1999/45/EC Flammable. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Vapours may cause drowsiness and dizziness. : R 10 N ; R 51/53 R 67 Regulation (EC) No 1272/2008 (GHS) Flammable liquid and vapour. Causes skin irritation. May cause drowsiness or dizziness. Toxic to aquatic life with long lasting effects. : Flam. Liq. 3 ; H226 Skin Irrit. 2 ; H315 STOT SE 3 ; H335 STOT SE 3 ; H336 Aquatic Chronic 2 ; H Composition/information on ingredients Hazardous components HYDROCARBONS, C9, AROMATES ; Registration number (EC) : ; EC-No. : ; CAS-No. : Percentage : 10 - < 20 % 67/548/EEC : R10 N ; R51/53 Xn ; R65 Xi ; R37 R67 R /2006 (GHS) : Flam. Liq. 3 ; H226 Asp. Tox. 1 ; H304 STOT SE 3 ; H335 STOT SE 3 ; H336 Aquatic Chronic 2 ; H411 XYLENE ; Registration number (EC) : ; EC-No. : ; CAS-No. : Percentage : 5 - < 10 % 67/548/EEC : R10 Xn ; R20/21 Xi ; R /2006 (GHS) : Flam. Liq. 3 ; H226 Acute Tox. 4 ; H312/332 Skin Irrit. 2 ; H315 HYDROCARBONS, C9, AROMATES (ex CAS-no.: ) ; Registration number (EC) : ; EC-No. : Percentage : 5 - < 10 % 67/548/EEC : R10 N ; R51/53 Xn ; R65 Xi ; R37 R67 R /2006 (GHS) : Flam. Liq. 3 ; H226 Asp. Tox. 1 ; H304 STOT SE 3 ; H335 STOT SE 3 ; H336 Aquatic Chronic 2 ; H411 ZINC OXIDE ; Registration number (EC) : ; EC-No. : ; CAS-No. : Percentage : 2,5 - < 5 % 67/548/EEC : N ; R50/ /2006 (GHS) : Aquatic Chronic 1 ; H410 1-METHOXY-2-PROPANOL ; Registration number (EC) : ; EC-No. : ; CAS-No. : Percentage : 1 - < 5 % 67/548/EEC : R10 R /2006 (GHS) : Flam. Liq. 3 ; H226 STOT SE 3 ; H336 ALUMINIUMTRIHYDROGENDIPHOSPHATE ; EC-No. : ; CAS-No. : Page : 1 / 6

2 Percentage : 1 - < 5 % 1907/2006 (GHS) : Skin Irrit. 2 ; H315 Eye Irrit. 2 ; H319 STOT SE 3 ; H335 TRIZINKBIS (ORTHOPHOSPHAT) ; EC-No. : ; CAS-No. : Percentage : 1 - < 2,5 % 67/548/EEC : N ; R50/ /2006 (GHS) : Aquatic Acute 1 ; H400 Aquatic Chronic 1 ; H410 2-BUTANONE OXIME ; Registration number (EC) : ; EC-No. : ; CAS-No. : Percentage : 0,1 - < 0,5 % 67/548/EEC : Carc. Cat.3 ; R40 R43 Xi ; R41 Xn ; R /2006 (GHS) : Carc. 2 ; H351 Eye Dam. 1 ; H318 Acute Tox. 4 ; H312 Skin Sens. 1 ; H317 hazardous components above-mentioned substances/ substance mixtures ETHYLBENZENE ; Registration number (EC) : ; EC-No. : ; CAS-No. : Percentage : 1 - < 5 % 67/548/EEC : F ; R11 Xn ; R /2006 (GHS) : Flam. Liq. 2 ; H225 Acute Tox. 4 ; H332 For the wording of the listed risk phrases refer to section First aid measures 05. Firefighting measures 06. Accidental release measures 07. Handling and storage Further information about storage conditions Storage class (VCI): 3 Storage class (TRGS 510) : Exposure controls/personal protection Components with critical values that require monitoring at the workplace (exposure limits) XYLENE ; CAS-No. : Specification : TRGS 900 ( D ) Value : 100 ppm / 440 mg/m 3 Category : 2(II) Remarks : H Version date : Specification : TRGS 903 ( D ) Parameter : Xylene / Whole blood (B) / End of exposure or end of shift Value : 1,5 mg/l Version date : Specification : TRGS 903 ( D ) Parameter : Methylhippuric acid / Urine (U) / End of exposure or end of shift Value : 2 g/l Version date : Specification : STEL ( EC ) Value : 100 ppm / 442 mg/m 3 Remarks : H Version date : Page : 2 / 6

3 Specification : TWA ( EC ) Value : 50 ppm / 221 mg/m 3 Remarks : H Version date : Physical and chemical properties Relevant safety data Physical state : liquid Appearance : liquid Colour : red brown Odour : characteristic Boiling temperature/boiling range : ( 1013 hpa ) > 100,0 C Flash point : > 23,0 C DIN part 1 Vapour pressure : ( 50 C ) < 1100,0 hpa Density : ( 20 C ) ca. 1,420 g/cm 3 Solvent separation test : ( 20 C ) < 3,0 % Flow time : ( 20 C ) > 200 s DIN-cup 4 mm VOC-value : ca. 430,0 g/l 10. Stability and reactivity 11. Toxicological information 12. Ecological information 13. Disposal considerations Contaminated packaging Waste key Waste code (91/689/EEC) : Transport information Land transport ADR/RID Class : 3 Kemlercode : 30 UN number : Code : F1 Special provisions : 640E LQ 7 E 1 Tunnel restriction code : D/E Proper shipping name PAINT Packaging Packaging group : Label : III 3 / (N) Maritime transport IMDG/GGVSea IMDG-Code : 3 EmS number : F-E / S-E UN number : 1263 Marine Poll. : P LQ 5 l E 1 Proper shipping name PAINT ( HYDROCARBONS, C9, AROMATES ZINC OXIDE TRIZINKBIS (ORTHOPHOSPHAT) ) Packaging Page : 3 / 6

4 Packaging group : Label : III 3 / N Air transport ICAO-TI and IATA-DGR Class : 3 UN number : 1263 E 1 Proper shipping name PAINT Packaging Packaging group : III Label : Regulatory information Labelling (67/548/EEC or 1999/45/EC) Danger symbol and danger designation N ; Dangerous for the environment R-phrases 10 Flammable. 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 67 Vapours may cause drowsiness and dizziness. S-phrases 29/35 Do not empty into drains; dispose of this material and its container in a safe way. 61 Avoid release to the environment. Refer to special instructions/safety data sheet. 2 Keep out of the reach of children. 51 Use only in well-ventilated areas. 46 If swallowed, seek medical advice immediately and show this container or label. Special designation for certain preparations 99 Contains 2-BUTANONE OXIME.May produce an allergic reaction. Regulation (EC) No 1272/2008 (GHS) Hazard classes and hazard categories Flam. Liq. 3 Skin Irrit. 2 STOT SE 3 STOT SE 3 Skin Sens. 2 Aquatic Chronic 2 Labelling Hazard pictograms Signal word Warning Hazard statements H226 Flammable liquid and vapour. H315 Causes skin irritation. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H411 Toxic to aquatic life with long lasting effects. Precautionary statements Page : 4 / 6

5 P102 Keep out of reach of children. P101 If medical advice is needed, have product container or label at hand. P280 Wear protective gloves/protective clothing/eye protection/face protection. P304/340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P405 Store locked up. P501 Dispose of contents/container according to local regulations Special rules for supplemental label elements for certain mixtures EUH208 Contains 2-BUTANONE OXIME.May produce an allergic reaction. National regulatory information Emission control act ("TA-Luft") Weight fraction (Number I) : < 5 % Weight fraction (Number I) : < 1 % Water pollution classification Class : 2 according to VwVwS 16. Other information Further information Relevant changes 03. Hazardous components 07. Information about separation of incompatible products *Phrase not found* 15. GHS - Hazard statements 15. GHS - Precautionary statements 02. Labelling according to Regulation (EC) No. 1272/2008 [CLP] 02. Special rules for supplemental label elements for certain mixtures 03. Hazardous ingredients 07. Hints on joint storage - Storage class R-Phrases of components 10 Flammable. 11 Highly flammable. 20 Harmful by inhalation. 20/21 Harmful by inhalation and in contact with skin. 21 Harmful in contact with skin. 37 Irritating to respiratory system. 38 Irritating to skin. 40 Limited evidence of a carcinogenic effect. 41 Risk of serious damage to eyes. 43 May cause sensitization by skin contact. 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 65 Harmful: may cause lung damage if swallowed. 66 Repeated exposure may cause skin dryness or cracking. 67 Vapours may cause drowsiness and dizziness. GHS Hazard statements of components H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H312 Harmful in contact with skin. H312/332 Harmful in contact with skin or if inhaled. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. Page : 5 / 6

6 H411 Toxic to aquatic life with long lasting effects. These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Page : 6 / 6