The interplay between Soil - Detergent - Enzyme
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1 The interplay between Soil - Detergent - Enzyme to further drive Dish cleaning performance DuPont Industrial Biosciences Dr Roel Hermant, Pieter Augustinus, Monica Ochoa-Ruiz, Dr Arjan Siebum, Hamish Irving 1
2 Sustainability demands ever better cleaning performance Less chemicals Greener chemical Phosphate free DETERGENT MECHANICS Less water TIME TEMPERATURE Machine Lower temperatures Enzymes offer a solution to improve performance further Copyright 2015 DuPont. All rights reserved. 2
3 Hotspot cleaning requires an aligned interplay Enzyme charge charge Hot spot Cleaning charge Detergent Soil Charge-Performance-Triangle model Copyright 2015 DuPont. All rights reserved. 3
4 SOIL 4
5 Dish soils are mainly enzymatic - constantly developing Soil type recent changes or context Tea Bleach - Egg yolk Protease increased from 1 to 1.5 g Crème Brulée Protease replaced Egg Milk Minced meat Protease baking from 120 to 130C Milkskin Protease Tensio consult method, replaced milk Mixed starch Amylase Starch suspension 2.6% to 3.3% Pasta Amylase SGS Fresenius method, replaced Oat Flakes Miele GSL2 G1223 Labor SC plus, 50C normal cycle, 21 dh, 5 repetitions, no rinse aid, ballast soil Copyright 2015 DuPont. All rights reserved. 5
6 Food soils are complex while enzyme action is specific Granular starch alphaamylase alphaamylase Acc. Voltage 5 kv Magnification 5K Scale mm 1-10 mm mm Copyright 2015 DuPont. All rights reserved. 6 6
7 and different starch soils can give opposite positions 100 Cleaning Soil Removal Index Amylase A Amylase B Pasta Miele 6382/ 50 C/21 GH (IKW) Mixed starch 4X Copyright 2015 DuPont. All rights reserved. 7
8 Screening monitors are not yet fully representative 100 Cleaning Soil Removal Index Mixed starch 4X DM Amylase A Miele 6382/ 50 C/21 GH (IKW) Amylase B Copyright 2015 DuPont. All rights reserved. 8
9 Soil monitor barriers to hotspot cleaning Intrinsic differences between soils even for the same type Develop more Dish soils to represent consumer reality Especially in wider (global) geographical context Alignment (Industry) on soil selection for cleaning remains essential High resource - expertise requirements to make IKW soils No (high throughput) screening possible for most soils Available screening monitors are not yet fully representative Copyright 2015 DuPont. All rights reserved. 9
10 DETERGENT 10
11 Different detergents have different in-wash conditions Ionic strength (in wash) 2.0 Commercial ADW Detergent product ph (in wash) Copyright 2015 DuPont. All rights reserved. 11
12 small changes can significantly change performance 4 I (ms) Miele 6382/ 50 C/21 GH (IKW) SR Mixed Starch 3 ph SR Amylase B Amylase A Copyright 2015 DuPont. All rights reserved. 12
13 potential detergent formulation tools to boost cleaning % SR Mixed starch Increase beyond plateau >> 3 X enzyme dosage + 20% carbonate Amylase B % w/w of enzyme Miele 6382, 50 C,21 GH (IKW) Copyright 2015 DuPont. All rights reserved. 13
14 B : C o n d u c tiv ity ( m S ) Cleaning hotspots exist and can provide direction CS28 (%SR) amylase performance Laundry Liquids % NaCl Low performance Benchscale T = 20ºC A: ph (ph) commercial HDL liquid Copyright 2015 DuPont. All rights reserved. 14
15 SUMMARY 15
16 Pushing cleaning further to the limit: hotspot guidance 5 4 I (conductivity) Amylase X new monitor?? Amylase X t Pasta Amylase X mix Starch 3 2 Liquid (Handdish) 1 ADW Gels Amylase Y CS28 Laundry Liquids Enzyme Detergent design Laundry & ADW Powders 0 ph Copyright 2015 DuPont. All rights reserved. 16
17 What we bring to the table Test institutes Monitor suppliers Consumer Organisations Detergent producers Enzyme suppliers Industry Organisations Options for formulation optimization to boost cleaning performance Soil-monitor co-development with SGS Fresenius and CFT Competitive solutions to match specific customer performance needs Options for DEMO-claim support development Copyright 2015 DuPont. All rights reserved. 17
18 fhc.biosciences.dupont.com Copyright 2015 DuPont. All rights reserved., DuPont, and all products with or are registered trademarks or trademarks of E. I. du Pont de Nemours and Company or its affiliates. Copyright 2015 DuPont. All rights reserved. 18
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