1. Restricted Substance List (RSL)

Transcription

1 1. Restricted Substance List (RSL) Articles produced for C&A must meet all European legal restrictions and as well all C&A RSL requirements regarding chemical substances. Extract of Supplier Quality Manual V 02 Effective date: 01/01/2018 1

2 1 ALKYLPHENOLS (AP) / ALKYLPHENOL ETHOXYLATES (APEO) Solvent Temperature [ C] Time [min] Sample Weight [g] Analytical Instrument Textiles, Plastics ISO :2016 Methanol 70 (ultrasonic bath) 60 1 LC-MS/MS Leather ISO :2015 Methanol 70 (ultrasonic bath) 60 1 LC-MS/MS 1 Nonylphenol (NP) , , , , Octylphenol (OP) , , Nonylphenol ethoxylates (NPEO) , , , , Octylphenol ethoxylates (OPEO) , , C&A LIMIT REPORTING LIMIT <10 3 C&A LIMIT REPORTING LIMIT * < * C&A commits to eliminate the intentional use of APEO from all C&A products latest by All C&A products have to comply latest by 1st season 2017 with the APEO limit value of 100 mg/kg, or the end of the grace period for C&A products to be fully compliant is season 1 (SN1) The U.S. EPA (Environmental Protection Agency) identified suitable safer alternative surfactants /detergents to substitute APEO in the Program Design for the Environment (DfE). The related list is available on the safer chemical ingredients list (SCIL) at the following link: Extract of Supplier Quality Manual V 02 Effective date: 01/01/2018 2

3 2 AZO DYES Textile Leather * Para-phenylenediamine (No. 25) * Aniline (No. 26) DIN EN ISO :2017, DIN EN ISO :2017 ISO :2015, ISO :2011 * REMARK: Only free (unbonded) Para-phenylenediamine and Aniline Extract of Supplier Quality Manual V 02 Effective date: 01/01/ Solvent Temperature [ C] Time [min] Sample Weight [g] Analytical Instrument Xylene (extraction) boiling (138) 40 1 GC-MS, LC-MS Aqueous buffer solution (direct ) GC-MS, LC-MS Aqueous buffer solution (direct) GC-FID or GC-MSD In-house 3% aqueous acetic acid solution hours 1 LC-MS/MS 1 4-Aminobiphenyl Benzidine Chloro-o-toluidine Naphthylamine o-aminoazotoluene Nitro-o-toluidine Chloroaniline ,4-Diaminoanisole ,4'-Diaminodiphenylmethane (4,4 -MDA) ,3'-Dichlorobenzidine ,3'-Dimethoxybenzidine ,3'-Dimethylbenzidine ,4'-Methylenedi-o-toluidine p-cresidine ,4'-Methylene-bis-(2-Chloroaniline) ,4'-Oxydianiline ,4'-Thiodianiline o-toluidine ,4-Toluenediamine (2,4-TDA) ,4,5-Trimethylaniline o-anisidine ,4-Xylidine ,6-Xylidine Aminoazobenzene (4-AAB) * Para-phenylenediamine (PPD) * Aniline C&A LIMIT REPORTING LIMIT <20 5 <20 15

4 3 DISPERSE DYES Solvent Temperature [ C] Time [min] Sample Weight [g] Analytical Instrument Textile DIN 54231:2005 Methanol (ultrasonic bath) LC-MS 1 Disperse Blue Disperse Blue Disperse Blue Disperse Blue Disperse Blue , Disperse Blue Disperse Blue Disperse Blue Disperse Brown Disperse Orange Disperse Orange Disperse Orange 37/76/ Disperse Orange Disperse Red Disperse Red Disperse Red Disperse Yellow Disperse Yellow Disperse Yellow Disperse Yellow Disperse Yellow Disperse Yellow C&A LIMIT REPORTING LIMIT <50 15 Extract of Supplier Quality Manual V 02 Effective date: 01/01/2018 4

5 4 CARCINOGENIC AND OTHER HARMFUL DYES Solvent Temperature [ C] Time [min] Sample Weight [g] Analytical Instrument Textile DIN 54231:2005 Methanol (ultrasonic bath) LC-MS 1 Acid Red Basic Red Basic Violet Direct Red Direct Black Direct Blue Disperse Blue Disperse Orange Disperse Organge Disperse Yellow Disperse Yellow Direct Brown Solvent Yellow Solvent Yellow Solvent Yellow Disperse Navy Blue (Component 1, Component 2) Basic Violet Basic Blue Basic Green 4 (malachite green, malachite green chloride, malachite green oxalate) , , C&A LIMIT REPORTING LIMIT <50 15 < Extract of Supplier Quality Manual V 02 Effective date: 01/01/2018 5

6 5 BIOCIDES Solvent Temperature [ C] Time [min] Sample Weight [g] Analytical Instrument No.1 (Triclosan) ISO 13365:2011 Acetonitrile (ultrasonic bath) RT 60 1 HPLC No. 2 (DMFu) CEN ISO/TS 16186:2012; DIN SPEC 53280:2012 Acetone (ultrasonic bath) GC-MS or LC-MS No. 3 (BAC) In-house Methanol LC-MS/MS No. 4 8 (CPs) ISO 17070:2015 No (OPP, PCMC, TCMTB, OIT) Aqueous sulfuric acid distillation, liquidliquid extraction and acetylation boiling 30 1 GC-MS/ECD ISO 13365:2011 Acetonitrile (ultrasonic bath) RT 60 1 HPLC C&A LIMIT REPORTING LIMIT 1 Triclosan Usage ban 1 2 Dimethyl fumarate (DMFu) Usage ban Benzalkonium chloride (BAC) Usage ban 1 4 Pentachlorophenol (PCP) Tetrachlorophenols (2,3,4,6-TeCP, 2,3,5,6-TeCP, 2,3,4,5-TeCP) , , Trichlorophenols (2,3,4-TriCP, 2,3,5-TriCP, 2,3,6-TriCP, 2,4,5-TriCP, 2,4,6-TriCP, 3,4,5-TriCP) , , , , , Dichlorophenols (2,3-DiCP, 2,4-DiCP, 2,5-DiCP, 2,6-DiCP, 3,4-DiCP, 3,5-DiCP) , , , , , Monochlorophenols (2-CP, 3-CP, 4-CP) , , o-phenylphenol (OPP) Chloro-3-methylphenol (PCMC) (Thiocyanomethylthio)benzothiazol (TCMTB) Octylisothiazol-3(2H)-on (OIT) < Textile: <50 (baby), other 100, Leather: 250 (baby), other 750 Leather: 250 (baby), other 500 Leather: 250 (baby), other 500 Leather: 250 (baby), other Extract of Supplier Quality Manual V 02 Effective date: 01/01/2018 6

7 6 Textile, Leather PESTICIDES EN ISO 15913:2003, DIN 38407, EPA 8081/EPA 8151A, BVL L :2010 Solvent Temperature [ C] Time [min] Sample Weight [g] Analytical Instrument Acetone/Dichloromethane RT 30 4 GC-MS/ECD or LC-MS/MS C&A LIMIT REPORTING LIMIT 1 2,4,5-Trichlorophenoxyacetic acid (2,4,5-T) ,4-Dichlorophenoxyacetic acid (2,4-D) Acetamiprid , Aldicarb Azinophosmethyl Azinophosethyl Aldrin Bromophos-ethyl Captafol Carbaryl Chlordane Chlordimeform Chlorfenvinphos Clothianidin Coumaphos Cyfluthrin Cyhalothrin <0.5 (baby), 18 Cypermethrin <1 (other) ,2,4-Tributylphosphorotrithioate (DEF) Deltamethrin Mitotan, 1,1-Dichlor- 2-(2-chlorphenyl)- 2-(4-chlorphenyl)ethane (DDD) , Chlor-4-[2,2-dichlor-1-(4-chlorphenyl)ethenyl]benzene (DDE) , ,1,1-Trichlor-2,2-bis-(4-chlorophenyl)ethane (DDT) , Diazinon Dichlorprop Dicrotophos Dieldrin Dimethoat Dinoseb, Salze und Acetat et al 30 Dinotefuran Endosulfan, α Endosulfan, β Endrin Esfenvalerat Continued on next page Extract of Supplier Quality Manual V 02 Effective date: 01/01/2018 7

8 6 Cont. PESTICIDES (continued) Textile, Leather EN ISO 15913:2003, DIN 38407, EPA 8081/EPA 8151A, BVL L :2010 Solvent Temperature [ C] Time [min] Sample Weight [g] Analytical Instrument Acetone/Dichloromethane RT 30 4 GC-MS/ECD or LC-MS/MS 35 Fenvalerat Heptachlor Heptachlorepoxid Hexachlorbenzol Hexachlorcyclohexan, α Hexachlorcyclohexan, β Hexachlorcyclohexan, δ Imidacloprid , Isodrin Kelevan Kepon Lindan Malathion Methyl-4-chlorophenoxyacetic acid (2-Methyl-4-chlorophenoxy) butyric acid Mecoprop Metamidophos Methoxychlor Mirex Monocrotophos Nitenpyram Parathion Parathion-methyl Perthan Phosdrin/Mevinphos Propethamphos Profenophos Quinalphos Stroban Telodrin Thiacloprid Thiamethoxam Toxaphen (Camphechlor) Trifluralin Extract of Supplier Quality Manual V 02 Effective date: 01/01/ C&A LIMIT <0.5 (baby), <1 (other) REPORTING LIMIT 0.2

9 7 CHLORINATED BENZENES and TOLUENES (INCLUDING CARRIERS) Solvent Temperature [ C] Time [min] Sample Weight [g] Analytical Instrument Polyester DIN 54232:2010 Dichloromethane RT 30 2 GC-MS 1 Chlorobenzene Dichlorobenzenes (1,2-DiCB, 1,3-DiCB, 1,4-DiCB) , , Trichlorobenzenes (1,2,3-TriCB, 1,2,4-TriCB, 1,3,5-TriCB) , , Tetrachlorobenzenes (1,2,3,4-TeCB, 1,2,3,5-TeCB, 1,2,4,5-TeCB) , , Pentachlorobenzene (PCB) Hexachlorobenzene (HCB) Monochlorotoluenes (2-CT, 3-CT, 4-CT) , , Dichlorotoluenes (2,3-DiCT, 2,4-DiCT, 2,5-DiCT, 2,6-DiCT, 3,4-DiCT, 3,5-DiCT) , , , , , Trichlorotoluenes (2,3,6-TriCT, 2,4,5-TriCT) , Tetrachlorotoluenes (2,3,4,5-TetraCT, 2,3,4,6-TetraCT, 2,3,5,6-TetraCT) , , , Pentachlorotoluene (PCT) C&A LIMIT REPORTING LIMIT <1 (sum) CHLORINATED PARAFFINS Solvent Temperature [ C] Time [min] Sample Weight [g] Analytical Instrument Leather ISO 18219:2015 n-hexane (ultrasonic bath) GC-MS/NCI C&A LIMIT REPORTING LIMIT 1 Short chain chlorinated paraffin (C10 - C13) (SCCP) < Medium chain chlorinated paraffin (C14 - C17) (MCCP) < Extract of Supplier Quality Manual V 02 Effective date: 01/01/2018 9

10 9 FLAME RETARDANTS Solvent Temperature [ C] Time [min] Sample Weight [g] Analytical Instrument No.1 No. 8 DIN EN ISO :2016 Toluene RT 30 1 GC-MS or LC-MS/MS No. 9 No. 16 DIN EN ISO :2016 Toluene GC-MS No. 17 (Boric Acid) In-house, EN :2015 Microwave digestion reflux 40 1 ICP-MS C&A LIMIT REPORTING LIMIT 1 Pentabromodiphenyl Ether (PentaBDE) Octabromodiphenyl Ether (OctaBDE) Decabromodiphenyl Ether (DecaBDE) Tetrabromobisphenol A (TBBP A) Bis(2,3-dibromopropylether) oftetrabromobisphenol (BDBPT) Polybromobiphenyls (PBB) Hexabromocyclododecane (HBCDD) , ,2-Bis(bromomethyl)-1,3-propanediol (BBMP) Usage ban 10 9 Tris(1,3-dichloro-propyl)-phospate (TDCPP) Trixylyl phosphate (TXP) Tris-(2,3-dibromopropyl)-phosphate (TRIS) Tris(aziridinyl)-phosphineoxide (TEPA) Tris-(2-chloroethyl)-phosphate (TCEP) Bis(2,3-dibromopropyl)phosphate (BBP) Triphenyl phosphate (TPP) < Tricresyl phosphate (all 10 isomers) (o-o-o-tcp, o-o-m-tcp, o-o-p-tcp, o-m-m-tcp, o-p-p-tcp, o-m-p-tcp, m-m-m-tcp, m-m-p-tcp, p-p-p-tcp, p-p-m-tcp) Usage ban Boric Acid , < Extract of Supplier Quality Manual V 02 Effective date: 01/01/

11 10 FORMALDEHYDE Solvent Temperature [ C] Time [min] Sample Weight [g] Analytical Instrument Textile, Wood, Paper EN ISO :2011 Water (sealed vessel) UV/VIS (412nm) Leather, other EN ISO :2008 Detergent solution (sealed vessel) HPLC- UV (360nm) 1 Formaldehyde C&A LIMIT <16 (baby and toddler) <75 (skin contact) <300 (without skin contact) REPORTING LIMIT 5 11 HEAVY METALS (TEXTILES, TRIMS and LEATHER ITEMS) Solvent Temperature [ C] Time [min] Sample Weight [g] Analytical Instrument Textiles, Trims DIN EN :2016 Acid perspiration ICP-MS DIN EN ISO :2017 (colorimetric), Aqueous buffer Leather: Chromium (VI) DIN EN ISO :2017 (chromatographic) solution (ph 8.0) RT Photometer (540nm) * REMARK: no requirements for accessories made from metallic materials Applicable for Textiles & Trims Extract of Supplier Quality Manual V 02 Effective date: 01/01/ C&A LIMIT REPORTING LIMIT 1 Antimony (Sb) < Arsenic (As) <0.2 (baby), <1 (other) Cadmium (Cd) < Chromium (Cr) <1 (baby), <2 (other) Cobalt (Co) <1 (baby), <4 (other) Copper *) (Cu) * <25 (baby), * <50 (other) 5 7 Lead (Pb) <0.2 (baby), <1 (other) Mercury (Hg) < Nickel (Ni) <1 (baby), <4 (other) 0.1 Applicable for Leather Items 10 Chromium (VI) <3 1

12 12 HEAVY METALS (TOYS) Solvent Temperature [ C] Time [min] Sample Weight [g] Analytical Instrument Toys EN 71-3:2013+A1:2014 Simulated gastric solution ICP-MS Applicable for Toys C&A LIMIT REPORTING LIMIT Category I Category II Category III Category I Category II Category III Solid materials which may leave residues on the hands Fluid or viscous materials which can be ingested or have skin contact Solid materials which can be ingested by biting, tooth scraping, sucking or licking Solid materials which may leave residues on the hands Fluid or viscous materials which can be ingested or have skin contact Solid materials which can be ingested by biting, tooth scraping, sucking or licking 1 Aluminium (Al) Antimony (Sb) Arsenic (As) Barium (Ba) Boron (B) Cadmium (Cd) Chromium (III) (Cr(III)) Chromium (VI) (Cr(VI)) Cobalt (Co) Copper (Cu) Lead (Pb) Manganese (Mg) Mercury (Hg) Nickel (Ni) Selenium (Se) Strontium (Sr) Tin (Sn) Organic Tin (Sn) various Zinc (Zn) Extract of Supplier Quality Manual V 02 Effective date: 01/01/

13 13 HEAVY METALS (GARMENT COMPONENTS) Solvent Temperature [ C] Time [min] Sample Weight [g] Analytical Instrument Garment Components EN 71-3:1995 Simulated gastric solution ICP-MS C&A LIMIT REPORTING LIMIT 1 Antimony (Sb) < Arsenic (As) < Barium (Ba) < Cadmium (Cd) < Chromium (Cr) < Lead (Pb) < Mercury (Hg) < Selenium (Se) < HEAVY METALS (NICKEL) Solvent Temperature [ C] Time Sample Weight Analytical Instrument Preliminary Nickel Test CR 12471:2002 (Nickel rubbing) not applicable Metal items * EN 1811:2015, EN 12472:2009 Perspiration RT week 1 piece ICP-MS Spectacle frames and sunglasses EN 16128:2016, EN 12472:2009 Perspiration RT week 1 piece EIS * REMARK: uncertainty included 1 Nickel (Ni) C&A LIMIT [µg/cm²/week] * <0.35 (Body piercings) * <0.88 (Direct and prolonged skin contact) <0.50 (Spectacle frames and sunglasses) REPORTING LIMIT [µg/cm²/week] 0.1 Extract of Supplier Quality Manual V 02 Effective date: 01/01/

14 15 HEAVY METALS (TOTAL CONTENT) Solvent Temperature [ C] Time [min] Sample Weight [g] Analytical Instrument Cadmium DIN EN 14602:2012 Aqueous acid solution, microwave digestion reflux ICP-MS or AAS Chromium DIN EN ISO :2011 Aqueous acid solution, microwave digestion reflux 40 1 ICP-MS or AAS Lead DIN EN 14602:2012 Aqueous acid solution, microwave digestion reflux 40 1 ICP-MS or AAS * Cobalt dichloride DIN EN 14602:2012 Aqueous acid solution, microwave digestion reflux 40 1 ICP-MS Electronic components, packaging materials IEC ICP-MS or AAS * REMARK: only for desiccants, Cobalt dichloride is calculated form the Cobalt content C&A LIMIT 1 Cadmium (Cd) <40 (polymers and metals) 3 2 Chromium (Cr) <1000 (chromium free tanned leather) 1 3 Lead (Pb) < Cobalt dichloride (Co) Usage ban 1 REPORTING LIMIT 16 ISOCYANATES Solvent Temperature [ C] Time Sample Weight [g] Analytical Instrument Polyurethane DIN EN :2004 Dichloromethane RT 24 hours 2 LC-MS * REMARK: no standard available, screened by MDI C&A LIMIT 1 Hexamethylene diisocyanate (HDI) <50 2 Isophorone diisocyanate (IPDI) <20 3 2,4-Toluene diisocyanate (2,4-TDI) <5 4 2,6-Toluene diisocyanate (2,6-TDI) <5 5 * 2,2 -Diphenylmethane diisocyanate (2,2 -MDI) <5 6 * 2,4 -Diphenylmethane diisocyanate (2,4 -MDI) <5 7 4,4 -Diphenylmethane diisocyanate (4,4 -MDI) <5 8 Tetramethylxylene diisocyanate (TMXD) <20 REPORTING LIMIT 5 Extract of Supplier Quality Manual V 02 Effective date: 01/01/

15 17 ORGANOTIN COMPOUNDS Solvent Temperature [ C] Time [min] Sample Weight [g] Analytical Instrument * Pre-test on total tin DIN EN 14602:2012 Aqueous acid solution, microwave digestion reflux 40 1 ICP-MS Rubber, plastics, coatings CEN ISO/TS 16179:2012; DIN SPEC 91179:2012 Methanol/Ethanol (80/20) (ultrasonic bath) GC-MS * REMARK: Preliminary test on tin (total content), individual testing is only needed, if tin content was detected above the reporting limit (0.1 mg/kg) 1 Monobutyltin (MBT) Monooctyltin (MOT) Monomethyltin (MMT) Monophenyltin (MPhT) Diphenyltin (DPhT) Dibutyltin (DBT) Dioctyltin (DOT) , Dimethyltin (DMT) Dipropyltin (DPT) Tributyltin (TBT) Triphenyltin (TPhT) Tricyclohexyltin (TCyHT) Trioctyltin (TOT) Tripropyltin (TPT) Trimethyltin (TMT) Tetrabutyltin (TebT) Tetraethyltin (TeET) C&A LIMIT <0.5 (baby), <1.0 (other) REPORTING LIMIT 0.1 Extract of Supplier Quality Manual V 02 Effective date: 01/01/

16 18 ph VALUE ACIDIC AND ALKALINE SUBSTANCES Solvent Temperature [ C] Time [min] Sample Weight [g] Analytical Instrument Textile ISO 3071:2006 Potassium chloride solution RT ph-meter Leather ISO 4045: 2008 De-ionized water RT ph-meter No. RESTRICTED SUBSTANCE C&A LIMIT [ph value] REPORTING LIMIT 1 ph value (Acidic and alkaline substances) (baby articles and articles with direct skin contact) (articles without direct skin contact) Extract of Supplier Quality Manual V 02 Effective date: 01/01/

17 19 PHTHALATE and NON-PHTHALATE PLASTICIZERS Solvent Temperature [ C] Time [min] Sample Weight [g] Analytical Instrument 60 Textile ISO 14389:2014 Tetrahydrofurane (THF) GC-MS (ultrasonic bath) Tetrahydrofurane (THF); 60 Plastics ISO 14389: GC-MS precipitation with Acetonitrile (ultrasonic bath) TPP, TCP DIN EN ISO :2016 Toluene 100 C GC-MS PHTHALATES 1 Di-methylphthalate (DMP) C&A LIMIT REPORTING LIMIT 2 Di-ethyl phthalate (DEP) Bis-(2-methoxy-ethyl) phthalate (BMEP) Di-n-propyl phthalate (DPRP) Di-butyl phthalate (DBP) Di-iso-butyl phthalate (DIBP) Di-pentyl phthalate (DPP) Di-iso-pentyl phthalate (DIPP) N-pentyl-iso-pentyl phthalate (PIPP) ,2-Benzenedicarboxylic acid, di-pentyl ester, branched & linear (DPP-MIX) Di-n-hexyl phthalate (DHP) Di-iso-hexyl phthalate (DIHxP) ,2-Benzenedicarboxylic acid - di-hexyl ester branched & linear (DHxP) <1000 (sum) Di-(2-ethyl-hexyl) phthalate (DEHP) Di-n-octyl phthalate (DNOP) Di-iso-octyl phthalate (DIOP) Di-nonyl phthalate (DNP) Di-iso-nonyl phthalate (DINP) Di-iso-decyl phthalate (DIDP) Di-(C6-C8 alkyl) phthalate branched (DIHP) ,2-benzenedicarboxylic acid, di-c6-10-alkyl esters Di-(C7-C11 alkyl) phthalate linear and branched (DHNUP) ,2-benzenedicarboxylic acid, mixed decyl and hexyl and octyl diesters with 0.3% of dihexyl phthalate Butyl-benzyl phthalate (BBP) Di-cyclohexyl phthalate (DCHP) NON-PHTHALATE PLASTICIZERS 26 Triphenyl phosphate (TPP) < Tricresyl phosphate (TCP) Usage ban 10 Extract of Supplier Quality Manual V 02 Effective date: 01/01/

18 20 PERFLUORINATED COMPOUNDS Solvent Temperature [ C] Time [min] Sample Weight [g] Analytical Instrument No CEN/TS 15968:2014 MTBE (ultrasonic bath) LC-MS No CEN/TS 15968:2014 MTBE (ultrasonic bath) GC-MS (GC inlet 130 C), LC-MS/MS (confirmation for No.30-33) 1 Perfluoro-octanoic acid and salts (PFOA) Perfluoro-octane sulfonic acid (PFOS) , , H,1H,2H,2H-Perfluoro-octane sulfonic acid (1H, 1H, 2H,2H-PFOS) Perfluoro-butane sulfonic acid (PFBS) , Perfluoro-hexane sulfonic acid and salts (PFHxS) , Perfluoro-heptane sulfonic acid (PFHpS) Perfluoro-decane sulfonic acid (PFDS) Perfluoro-octane sulphonamide 1H,1H,2H,2H H4PFOS; 6:2 (PFOSA) N-methylperfluoro-1-octanesulfonamide (MeFOSA) N-ethylperfluoro-1-octanesulfonamide (EtFOSA) (N-methylperfluoro-FASE 1- octanesulfonamido)-ethanol (MeFOSA) (N-ethylperfluoro-1-octanesulfonamido)- ethanol (EtFOSA) Perfluoro-butanoic acid (PFBA) Perfluoro-pentanoic acid (PFPA) Perfluoro-hexanoic acid (PFHxA) Perfluoro-heptanoic acid (PFHpA) Perfluoro-nonanoic acid (PFNA) Perfluoro-decanoic acid (PFDA) Perfluoro-undecanoic acid (PFUnA) , Perfluoro-dodecanoic acid (PFDOA) Perfluoro-tridecanoic acid (PFTrA) Perfluoro-tetradecanoic acid (PFTeA) Perfluoro-3,7-dimethyl-octanoic acid (PF-3,7-DMOA) H-Dodecanefluoro-heptanoic acid (HPFHpA) H,2H-Perfluoro-decanoic acid (H2PFDA) H,2H,3H,3H-Perfluoro-undecanoic acid (H4PFUnA) H,1H,2H,2H-Perfluoro-octylacrylate (6:2 FTA) H,1H,2H,2H-Perfluoro decylacrylate (8:2 FTA) H,1H,2H,2H-Perfluoro-dodecylacrylate (10:2 FTA) H,1H,2H,2H-Perfluoro-1-hexanol (4:2 FTOH) H,1H,2H,2H-Perfluoro-1-oktanol (6:2 FTOH) H,1H,2H,2H-Perfluoro-1-decanol (8:2 FTOH) H,1H,2H,2H-Perfluoro-1-dodecanol (10:2 FTOH) C&A LIMIT REPORTING LIMIT [µg/m²] [µg/m²] <1 1 <10 10 Extract of Supplier Quality Manual V 02 Effective date: 01/01/

19 21 POLYCYCLIC AROMATIC HYDROCARBONS (PAH) Solvent Temperature [ C] Time [min] Sample Weight [g] Analytical Instrument Rubber, plastics AfPS GS 2014 Toluene (ultrasonic bath) GC-MS (after column clean up) 1 Benzo(a)pyrene Benzo(e)pyrene Benzo(a)anthracene Chrysene Dibenzo(a,h)anthracene Benzo(b)fluoranthene Benzo(j)fluoranthene Benzo(k)fluoranthene Acenaphthene Acenaphthylene Anthracene Fluoranthene Fluorene Indeno(1,2,3-c,d)pyrene Napthalene Phenanthrene Pyrene Benzo(g,h,i)perylene Cyclopenta[c,d]pyrene Dibenzo[a,e]pyrene Dibenzo[a,h]pyrene Dibenzo[a,i]pyrene Dibenzo[a,l]pyrene Methylpyrene C&A LIMIT <0.5 (toys and childcare), <1 (other), <10 (sum) REPORTING LIMIT 0.2 Extract of Supplier Quality Manual V 02 Effective date: 01/01/

20 22 POLYMERS & POLYMER AUXILIARIES Solvent Temperature [ C] Time [min] Sample Weight [g] Analytical Instrument No. 1 (Polystyrene) In-house Not applicable FTIR No. 2 (PVC) Pre-test (Beilstein), confirmation by Infrared Spectroscopy (FTIR) Not applicable FTIR No. 3 (Technical MDA) Ethyl acetate GC-MS or LC-MS No. 4 (Latex, Natural Rubber) Latex Test Kit, Protn-LatexTM (G- Biosciences) or comparable test Not applicable No. 5 9: Bisphenols (food contact) DIN CEN/TS :2005 Food simulant 1 LC-MS/MS No. 5 9: Bisphenols (paper) DIN EN ISO : LC-MS/MS No. 10 (2-MBT) child care EN :2004 Food simulant hours 1 HPLC No. 10 (2-MBT) rubber In-house Acetone HPLC-DAD UV STABILIZIER In-house Acetonitrile/Methanol LC-MS C&A LIMIT REPORTING LIMIT 1 Polystyrene Usage ban (only for dry clean items) 2 Polyvinyl chloride Usage ban 3 Formaldehyde, oligomeric reaction products with aniline (technical MDA) < Natural Rubber Latex Usage ban 5 Bisphenol A Bisphenol B Bisphenol E Usage ban Bisphenol F Bisphenol S Mercaptobenzothiazole Usage ban 10 UV STABILIZIER 11 2-Benzotriazol-2-yl-4,6-di-tert-butylphenol ,4-Di-tert-butyl-6-(5-chlorobenzotriazol-2-yl)phenol (2H-Benzotriazol-2-yl)-4,6-di-tert-pentylphenol < (2H-Benzotriazol-2-yl)-4-(tert-butyl)-6-(sec-butyl)phenol Extract of Supplier Quality Manual V 02 Effective date: 01/01/

21 23 VOLATILE ORGANIC COMPOUNDS (VOC) Solvent Temperature [ C] Time [min] Sample Weight [g] Analytical Instrument No. 1 to No. 35 Pre-test: Odour test according to SNV , only pre-fail (grade 2-3) needs VOC Headspace testing GC-MS Headspace No. 36 DMFa ISO/TS 16189:2013 Methanol GC-MS C&A LIMIT REPORTING LIMIT 1 Benzene <1 1 2 Ethylbenzene < Styrene < Toluene <5 5 5 Xylenes (ortho, meta, para) , , , < Cresols (ortho, meta, para) , , < Naphthalene < Acetophenone < Phenyl-2-propanole < Chloroform < Carbon tetrachloride < Methylene chloride < ,2-Dichloroethane < ,1,1-Trichloroethane < ,1,2-Trichloroethane < ,1,1,2-Tetrachloroethane < ,1,2,2-Tetrachloroethane < Pentachloroethane < ,1-Dichloroethylene < Trichloroethylene < Tetrachloroethylene < ,2,3-Trichloropropane < Cyclohexanone < Methyl-Ethyl-Ketone (MEK) < Ethoxyethanol < Methoxyethanol < ,2-Dimethoxyethane (DME) < Methoxyethyl acetate < Methoxypropyl acetate < Triethylene glycol dimethyl ether (TEGDME) < Ethoxyethyl acetate < Methyl-2-pyrrolidone (NMP) < Bis-(2-methoxyethyl) ether < N,N-dimethyl acetamide (DMAC) < Formamide < N,N-Dimethyl formamide (DMFa) < Continued on next page Extract of Supplier Quality Manual V 02 Effective date: 01/01/

22 23 cont. VOLATILE ORGANIC COMPOUNDS (VOC) continued Water based PU Material: Water based Polyurethane (PU) is waterborne & Dimethylformamide (DMFa) solvent-free PU = sustainable PU leather C&A recommends to our suppliers to used water based polyurethane dispersions (PUDs), which show all the properties of regular PU leather but that eliminates the use of organic solvents (DMFa) and processes that consume considerable amounts of water and energy from the manufacturing process. Elimination of the hazardous chemical DMFa: Conventional PU leather is processed in DMFa, a solvent which is classified as a substance of very high concern (Restricted in table 4.22 Chemical No. 34), whereas water based produced PU requires no organic solvents like DMFa for manufacture or processing, eliminating potential worker and consumer exposure. Reduction of the water consumption (less water): The conventional PU leather production process consumes large quantities of water to rinse away the solvent from the synthetic material, whereas the water based PU dispersion technology does not require the use of water baths for the processing. Energy consumption: The conventional PU leather process employs washing baths that are constantly heated to facilitate the process. The wet product must be dried completely. Finally, DMFa is reclaimed from contaminated water in a an energy intensive process. In contrast, water based PU production does not need washing baths, follow up drying of wet synthetic leather and final reclaiming of the DMFa, which saves a lot of energy. 24 N-NITROSAMINE & N-NITROSAMINE CONVERTIBLE SUBSTANCES Solvent Temperature [ C] Time [min] Sample Weight [g] Analytical Instrument Rubber DIN EN 12868:2017 Dichloromethane boiling 10 GC-TEA or GC-MS or LC-MS/MS Toys EN 71-12:2017 Salvia test solution HPLC-MS/MS C&A LIMIT REPORTING LIMIT 1 N-Nitroso-dimethylamine (NDMA) N-Nitroso-diethylamine (NDEA) N-Nitroso-dipropylamine (NDPA) N-Nitroso-dibutylamine (NDBA) N-Nitroso-morpholine (NMOR) N-Nitroso-piperidine (NPIP) < N-Nitroso-pyrrolidine (NPYR) N-Nitroso-dibenzylamine (NDBA) N-Nitroso-methyl-N-phenylamine (NMPhA) N-Nitroso-ethyl-N-phenylamine (NEPhA) N-Nitrosamine convertible substances various < Extract of Supplier Quality Manual V 02 Effective date: 01/01/

23 2. Manufacturing Restricted Substance List (MRSL) Extract of Supplier Quality Manual V 02 Effective date: 01/01/

24 About the Manufacturing Restricted Substance List (MRSL) C&A is one of the founding members of the Zero Discharge of Hazardous Chemicals (ZDHC) brand collaboration. In the ZDHC Joint Roadmap, ZDHC brands committed to define and develop a Manufacturing Restricted Substances List (MRSL) for the apparel and footwear industry. The ZDHC MRSL, which has been adopted by C&A, has defined usage bans and a common set of limits for chemical formulations used in apparel and footwear production. The purpose of the ZDHC MRSL is to provide the industry with a harmonized approach to managing hazardous chemicals used during the processing of raw materials. The requirement is to prevent these listed hazardous substances, which maybe of a concern to occupational safety and the environment, from being intentionally used during manufacturing and related processes. The ZDHC MRSL goes beyond the requirements of the C&A RSL which only limits those substances that are not to be present in finished products. The ZDHC MRSL should be communicated widely across the supply chain including raw material suppliers, all sub-contractors and factories assembling or manufacturing garments and footwear for C&A. C&A expect that suppliers and factories work in partnership with their chemical suppliers to ensure that listed substances are not presented in chemical formulations above set limits. C&A suppliers and factories are expected to, at a minimum, obtain self-declarations from chemical suppliers stating clear conformance to the ZDHC MRSL. More information on C&A s work in the area of chemicals management can be found in the most recent Corporate Responsibility (CR) report or on-line at If you have questions concerning the ZDHC MRSL and its implementation please e- mail ssc-scm.sourcing@canda.com Note: The ZDHC MRSL does not replace our C&A Restricted Substances List (RSL). Chemical formulations also must fully comply with all C&A RSL requirements and all applicable legal restrictions, including any subsequent restrictions that establish more strict limits. C&A will require factories with wet-processing, specifically those involved with dyeing, finishing, printing and washing, to conduct, on request, wastewater sampling to screen for hazardous substances listed on the MRSL and a sustainable chemical management audit including an in-depth review of the chemical inventory. If you are found to contravene any element of this MRSL policy or your on-site chemical management performance is not meeting C&A standards then a shortterm corrective action plan will be put into place with approval from the factories top management and C&A stating necessary remediation actions and timelines. At the time of writing, the current version of the ZDHC MRSL is Version 1.1 (page 25). The ZDHC MRSL is a living document and will be updated frequently. To check your adherence to the latest version of the MRSL visit Extract of Supplier Quality Manual V 02 Effective date: 01/01/

25 Manufacturing Restricted Substance List (MRSL) Version 1.1 (2015) of the Zero Discharge of Hazardous Chemicals (ZDHC) Programme On the following pages you will find the Manufacturing Restricted Substance List (MRSL) Version 1.1 from 2015 from the ZDHC (Zero Discharge of Hazardous Chemicals Programme). This MRSL & Conformance Guidance comprises the same content as the MRSL & Conformance Guidance available under Extract of Supplier Quality Manual V 02 Effective date: 01/01/

26 Manufacturing Restricted Substances List Version 1.1 Zero Discharge of Hazardous Chemicals Programme 1 Background In the Zero Discharge of Hazardous Chemicals (ZDHC) Joint Roadmap, Version 2, ZDHC brands committed to define and develop a Manufacturing Restricted Substances List (MRSL) for the apparel and footwear industry. In doing so, brands recognised the value of addressing hazardous substances potentially used and discharged into the environment during manufacturing and related processes deep within our supply chain not just those substances that could be present in finished products. In June 2014, the ZDHC brands achieved a significant milestone and published the first version of the ZDHC MRSL. 2 Purpose The intent of the ZDHC MRSL is to provide brands and suppliers with a harmonised approach to managing chemicals during the processing of raw materials within the apparel and footwear supply chain. The ZDHC MRSL achieves this by providing a clear list of priority chemicals and specifying the maximum concentration limit of each substance within commercial chemical formulations. The ZDHC MRSL is divided into sections that focus on a specific raw material. This accounts for the differences between the creation and processing of the material types used within our industry and the need to set applicable limits to reflect the functional use of these chemicals. The MRSL should be communicated to raw material suppliers, including subcontractors and factories assembling or manufacturing garments and footwear. To support our goal of using MRSL compliant chemical formulations, ZDHC brands also expect that material suppliers and factories will communicate with their chemical suppliers to ensure that listed substances are not present in chemical formulations above established limits. Note: The ZDHC MRSL does not replace applicable national environmental or workplace safety restrictions. Worker exposure to chemical substances listed in this document, along with other hazardous substances, must not exceed occupational exposure limits. Chemical formulations also must comply with all applicable legal restrictions, including any subsequent restrictions that establish more strict limits. The ZDHC MRSL does not replace legal or brand-specific restrictions on hazardous substances in finished products. 3 Definitions MRSL The ZDHC MRSL is a list of chemical substances subject to a usage ban (see Usage Ban, page 2). The MRSL applies to chemicals used in facilities that process materials and trim parts for use in apparel and footwear. Chemicals in the ZDHC MRSL include solvents, cleaners, adhesives, paints, inks, detergents, dyes, colourants, auxiliaries, coatings and finishing agents used during raw material production, wet-processing, maintenance, wastewater treatment, sanitation and pest control. There should be no intentional use of MRSL-listed substances in facilities that process materials used in the production of apparel and footwear. MRSL limits apply to substances in commercially available chemical formulations and not those from earlier stages of chemical synthesis. Note: Threshold Limit values on restricted substances in chemical formulations are in some cases substantially higher than limits on restricted substances in finished products. This is because restricted substances in finished products are almost always found in smaller concentrations than in the chemical formulations used to produce them. Chemical formulations are highly concentrated before being diluted upon application to textiles and other materials. DECEMBER 2015 LEADERS IN ADVANCING ENVIRONMENTAL RESPONSIBILITY 1 Extract of Supplier Quality Manual V 02 Effective date: 01/01/

27 Chemical Substance A chemical substance is a chemical element and its compounds in the natural state or obtained by any manufacturing process (REACH, 2014)( 1 ). A chemical substance is usually identifiable by a single, unique Chemical Abstracts Service (CAS) number or Colour Index (CI) number. The ZDHC MRSL will primarily focus on chemical substances listed by CAS number and CI number, but also will include groups of substances for which listing individual substances is not practical. Commercial Chemical Formulation A commercial chemical formulation is usually a proprietary blend of several chemical substances that is available for purchase from chemical suppliers under their own trade name. Usage Ban A usage ban indicates that the ZDHC MRSL-listed chemical substance or group of substances may not be used to achieve a desired function or effect during production of the raw material or product (that is, no intentional use). This usage ban extends to other uses within a facility like cleaning and maintenance. Due to the existence of manufacturing impurities in chemical formulations, a minor or trace amount of the restricted substance is permitted. Chemical formulations containing restricted substances that exceed limits are not compliant with the ZDHC MRSL. 4 MRSL Creation Process The ZDHC MRSL includes relevant substances from the original 11 priority chemical groups in the Joint Roadmap ( 2 ) along with additional substances discussed with qualified experts from the ZDHC Technical Advisory Committee (TAC) and signatory brands. Several of the listed substances are regulated in finished products and have been successfully restricted by ZDHC brands for years. Though already restricted by ZDHC brands, their inclusion on the list keep it consistent with existing industry standards. Where possible, the content of the ZDHC MRSL was peer-reviewed by independent third-party technical experts and industry associations related to the production of our key raw materials. Collaboration with leading technical experts allows the ZDHC Programme to develop a MRSL that pragmatically represents progress and supports our long-term goal of zero discharge. 5 MRSL Instructions MRSL Chapters Chapter 1: MRSL for Textiles and Synthetic Leather Processing This section applies to chemical formulations and substances used during the creation and wet processing of textile fibres and during the creation and processing of synthetic leather. Chapter 2: MRSL for Natural leather Processing This section applies to chemical formulations and substances used throughout the production of natural leather, from raw-hide to finished leather. (1) A chemical element and its compounds in the natural state or obtained by any manufacturing process, including any additive necessary to preserve its stability and any impurity deriving from the process used, but excluding any solvent which may be separated without affecting the stability of the substance or changing its composition. Accessed May 8, (2) These are alkylphenol ethoxylates/alkylphenols (APEOs/APEs), brominated and chlorinated flame retardants, chlorinated solvents, chlorobenzenes, chlorophenols, heavy metals, organotin compounds (e.g., TBT), perfluorinated and polyfluorinated chemicals (PFCs), phthalates (ortho-phthalates), short-chain chlorinated paraffins (SCCPs) and azo dyes that may release carcinogenic amines as defined in Annex XVII of REACH. DECEMBER 2015 LEADERS IN ADVANCING ENVIRONMENTAL RESPONSIBILITY 1 Extract of Supplier Quality Manual V 02 Effective date: 01/01/

28 MRSL Groups Group A: Raw Material and Finished Product Supplier Guidance Group A substances are banned from intentional use in facilities that process raw materials and manufacture finished products. Please refer to the AFIRM guidance document for the lowest agreed upon material or finished product limits among AFIRM brands: See brand RSLs for individual requirements. Group B: Chemical Supplier Formulation Limit Group B substances are restricted to concentration limits in chemical formulations commercially available from chemical suppliers. These limits ban intentional use while allowing for reasonable expected manufacturing impurities that should be consistently achievable by responsible chemical manufacturers( 3 ). (3) Safety Data Sheets (SDS) only list substances present at concentrations of 1000 ppm or greater. Suppliers must communicate with chemical suppliers to ensure MRSL limits are met. DECEMBER 2015 LEADERS IN ADVANCING ENVIRONMENTAL RESPONSIBILITY 1 Extract of Supplier Quality Manual V 02 Effective date: 01/01/

29 CHAPTER 1: MRSL for Textiles and Synthetic Leather Processing CAS No. Substance Alkylphenol (AP) and Alkylphenol Ethoxylates (APEOs): including all isomers Chlorobenzenes and Chlorotoluenes Nonylphenol (NP), mixed isomers Octylphenol (OP), mixed isomers Octylphenol ethoxylates (OPEO) Nonylphenol ethoxylates (NPEO) ,2-dichlorobenzene Other isomers of mono-, di-, tri-, tetra-, penta- and hexa- chlorobenzene and mono-, di-, tri-, tetra- and penta- chlorotoluene Group A: Raw Material and Finished Product Supplier Guidance Group B: Chemical Supplier Commercial Formulation Limit 250 ppm 250 ppm 500 ppm 500 ppm Potential Uses in Apparel and Footwear Textile Processing APEOs can be used as or found in: detergents, scouring agents, spinning oils, wetting agents, softeners, emulsifier/dispersing agents for dyes and prints, impregnating agents, de-gumming for silk production, dyes and pigment preparations, polyester padding and down/feather fillings ppm Chlorobenzenes and chlorotoluenes (chlorinated aromatic hydrocarbons) can be used as carriers in the dyeing process of Sum = 200 ppm polyester or wool/polyester fibres. They can also be used as solvents. General Techniques for Analysing Chemicals Liquid chromatography-mass spectrometry (LC-MS), gas chromatography-mass spectrometry (GC-MS) GC-MS DECEMBER 2015 LEADERS IN ADVANCING ENVIRONMENTAL RESPONSIBILITY 1 Extract of Supplier Quality Manual V 02 Effective date: 01/01/

30 CAS No. Substance Group A: Raw Material and Finished Product Supplier Guidance Group B: Chemical Supplier Commercial Formulation Limit Potential Uses in Apparel and Footwear Textile Processing General Techniques for Analysing Chemicals Chlorophenols Tetrachlorophenol (TeCP) Sum = 20 ppm Pentachlorophenol (PCP) ,3,4,5-tetrachlorophenol ,3,4,6-tetrachlorophenol ,3,5,6-tetrachlorophenol chlorophenol ,4-dichlorophenol ,5-dichlorophenol Chlorophenols are polychlorinated compounds used as preservatives or pesticides ,6-dichlorophenol ,4,5-trichlorophenol ,4,6-trichlorophenol ,5-dichlorophenol ,3-dichlorophenol ,4-dichlorophenol Sum = 50 ppm Pentachlorophenol (PCP) and tetrachlorophenol (TeCP) have been used in the past to prevent mould when storing/ transporting, raw hides and leather. They are now regulated and should not be used. GC-MS EN ISO chlorophenol chlorophenol ,3,4-trichlorophenol ,3,5-trichlorophenol ,4,5-trichlorophenol DECEMBER 2015 LEADERS IN ADVANCING ENVIRONMENTAL RESPONSIBILITY 1 Extract of Supplier Quality Manual V 02 Effective date: 01/01/

31 CAS No. Substance Group A: Raw Material and Finished Product Supplier Guidance Group B: Chemical Supplier Commercial Formulation Limit Potential Uses in Apparel and Footwear Textile Processing General Techniques for Analysing Chemicals Dyes Azo (Forming Restricted Amines) ,4 -methylene-bis-(2-chloro-aniline) 150 ppm ,4 -methylenedianiline 150 ppm ,4 -oxydianiline 150 ppm chloroaniline 150 ppm ,3 -dimethoxylbenzidine 150 ppm ,3 -dimethylbenzidine 150 ppm methoxy-m-toluidine 150 ppm ,4,5-trimethylaniline 150 ppm ,4 -thiodianiline 150 ppm aminoazobenzene 150 ppm methoxy-m-phenylenediamine 150 ppm ,4 -methylenedi-o-toluidine 150 ppm ,6-xylidine 150 ppm o-anisidine 150 ppm naphthylamine 150 ppm , 3-dichlorobenzidine 150 ppm aminodiphenyl 150 ppm Benzidine 150 ppm o-toluidine 150 ppm ,4-xylidine 150 ppm chloro-o-toluidine 150 ppm methyl-m-phenylenediamine 150 ppm o-aminoazotoluene 150 ppm nitro-o-toluidine 150 ppm Dyes Navy Blue Colourant Component 1: C39H23ClCrN7O12S 2Na Not Allocated Component 2: C46H30CrN10O20S2 3Na 250 ppm Azo dyes and pigments are colourants that incorporate one or several azo groups (-N=N- ) bound with aromatic compounds. Thousands of azo dyes exist, but only those that degrade to form the listed cleavable amines are restricted. Azo dyes that release these amines are regulated and should no longer be used for dyeing of textiles. Navy Blue colourants are regulated and should no longer be used for dyeing of textiles. LC, GC LC DECEMBER 2015 LEADERS IN ADVANCING ENVIRONMENTAL RESPONSIBILITY 1 Extract of Supplier Quality Manual V 02 Effective date: 01/01/

32 CAS No. Substance Group A: Raw Material and Finished Product Supplier Guidance Group B: Chemical Supplier Commercial Formulation Limit Potential Uses in Apparel and Footwear Textile Processing General Techniques for Analysing Chemicals Dyes Carcinogenic or Equivalent Concern C.I. Direct Black ppm C.I. Direct Blue ppm C.I. Acid Red ppm C.I. Basic Red ppm C.I. Direct Red ppm C.I. Basic Violet ppm C.I. Disperse Blue ppm C.I. Disperse Blue ppm C.I. Basic Blue 26 (with Michler s Ketone > 0.1%) 250 ppm C.I. Basic Green 4 (malachite green chloride) 250 ppm C.I. Basic Green 4 (malachite green oxalate) 250 ppm C.I. Basic Green 4 (malachite green) 250 ppm Disperse Orange ppm Dyes Disperse (Sensitising) Disperse Yellow ppm Disperse Blue ppm Disperse Blue ppm Disperse Yellow ppm Disperse Orange 37/59/ ppm Disperse Brown ppm Disperse Orange ppm Disperse Yellow ppm Disperse Red ppm Disperse Red ppm Disperse Red ppm Disperse Blue ppm Disperse Blue ppm Disperse Yellow ppm Disperse Blue ppm Disperse Blue ppm Disperse Yellow ppm Disperse Orange ppm Disperse Blue ppm Most of these substances are regulated and should no longer be used for dyeing of textiles. Disperse dyes are a class of water-insoluble dyes that penetrate the fibre system of synthetic or manufactured fibres and are held in place by physical forces without forming chemical bonds. Disperse dyes are used in synthetic fibre (e.g., polyester, acetate, polyamide). Restricted disperse dyes are suspected of causing allergic reactions and should no longer be used for dyeing of textiles. LC LC DECEMBER 2015 LEADERS IN ADVANCING ENVIRONMENTAL RESPONSIBILITY 1 Extract of Supplier Quality Manual V 02 Effective date: 01/01/

33 CAS No. Substance Group A: Raw Material and Finished Product Supplier Guidance Group B: Chemical Supplier Commercial Formulation Limit Potential Uses in Apparel and Footwear Textile Processing General Techniques for Analysing Chemicals Flame Retardants Glycols Tris(2-chloroethyl)phosphate (TCEP) 250 ppm Decabromodiphenyl ether (DecaBDE) 250 ppm Tris(2,3,-dibromopropyl)-phosphate (TRIS) 250 ppm Pentabromodiphenyl ether (PentaBDE) 250 ppm Octabromodiphenyl ether (OctaBDE) 250 ppm Bis(2,3-dibromopropyl)phosphate (BIS) 250 ppm Tris(1-aziridinyl)phosphine oxide) (TEPA) 250 ppm Polybromobiphenyls (PBB) 250 ppm Tetrabromobisphenol A (TBBPA) 250 ppm Hexabromocyclodecane (HBCDD) 250 ppm ,2-bis(bromomethyl)-1,3-propanediol (BBMP) 250 ppm Tris(1,3-dichloro-isopropyl) phosphate (TDCP) 250 ppm Short-chain chlorinated Paraffins (SCCP) (C10-C13) 50 ppm Bis(2-methoxyethyl)-ether 50 ppm ethoxyethanol 50 ppm ethoxyethyl acetate 50 ppm Ethylene glycol dimethyl ether 50 ppm methoxyethanol 50 ppm methoxyethylacetate 50 ppm methoxypropylacetate 50 ppm Triethylene glycol dimethyl ether 50 ppm Halogenated Solvents Flame retardant chemicals are rarely used to meet flammability requirements in children s clothing and adult products. They should no longer be used in apparel and footwear. In apparel and footwear, glycols have a wide range of uses including as solvents for finishing/cleaning, printing agents, and dissolving and diluting fats, oils and adhesives (e.g., in degreasing or cleaning operations) ,2-dichloroethane 5 ppm In apparel and footwear, solvents are used as Methylene chloride 5 ppm finishing/cleaning and printing agents, for Trichloroethylene 40 ppm dissolving and diluting fats, oils and adhesives Tetrachloroethylene 5 ppm (e.g., in degreasing or cleaning operations). GC-MS High-performance liquid chromatography (HPLC), LC-MS GC-MS DECEMBER 2015 LEADERS IN ADVANCING ENVIRONMENTAL RESPONSIBILITY 1 Extract of Supplier Quality Manual V 02 Effective date: 01/01/