: Sodium hydroxide, volumetric solution 0.5 M (0.5 N) VSA

Transcription

1 Sodium hydroxide, volumetric solution 0.5 M (0.5 N) VSA Date of issue 01/02/2013 Revision date 05/12/2016 Supersedes 07/05/2013 Version 2.1 SECTION 1 Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Trade name Substance EC no CAS No Product code Sodium hydroxide, volumetric solution 0.5 M (0.5 N) VSA SOHY-05V 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Laboratory use Uses advised against 1.3. Details of the supplier of the safety data sheet labbox labware s.l. Joan Peiró i Belis, Vilassar de Dalt - ES T F info@labkem.com Emergency telephone number Emergency number ( Office Hours) SECTION 2 Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances SDS EU 2015 According to Regulation (EU) 2015/830 (REACH Annex II) Skin corrosion/irritation, Category 1A H314 Full text of H statements see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) Danger GHS05 H314 - Causes severe skin burns and eye damage P301+P330+P331 - IF SWALLOWED rinse mouth. Do NOT induce vomiting P303+P361+P353 - IF ON SKIN (or hair) Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - IF INHALED remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 - IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician 2.3. Other hazards 05/12/2016 EN (English) 1/8

2 SECTION 3 Composition/information on ingredients 3.1. Substances Name Sodium hydroxide, volumetric solutions CAS No EC no Name Product identifier % SODIUM HYDROXIDE (CAS No) (EC no) (EC index no) (REACH-no) Full text of H-statements see section Mixtures Not applicable 1-10 SECTION 4 First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion Remove person to fresh air and keep comfortable for breathing. Remove person to fresh air and keep comfortable for breathing. Call a physician immediately. Wash contaminated clothing before reuse. Take off contaminated clothing and wash it before reuse. If skin irritation or rash occurs Get medical advice/attention. Wash skin with plenty of water. Rinse eyes with water as a precaution. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention. Rinse mouth. Do not induce vomiting. Give nothing or a little water to drink. Obtain emergency medical attention. Go into open air and ventilate suspected area Most important symptoms and effects, both acute and delayed Symptoms/injuries Causes severe skin burns and eye damage. Symptoms/injuries after inhalation May cause respiratory irritation. Symptoms/injuries after skin contact Causes severe burns. Symptoms/injuries after eye contact Serious damage to eyes Indication of any immediate medical attention and special treatment needed Never give anything by mouth to an unconscious person. SECTION 5 Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Water spray. Dry powder. Carbon dioxide Special hazards arising from the substance or mixture 5.3. Advice for firefighters Precautionary measures fire Protection during firefighting Stop leak if safe to do so. Do not attempt to take action without suitable protective equipment. SECTION 6 Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures Absorb spillage to prevent material damage For non-emergency personnel Emergency procedures Notify police and fire brigade as soon as possible For emergency responders 6.2. Environmental precautions Avoid release to the environment. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up For containment Collect spillage. Methods for cleaning up Take up liquid spill into absorbent material. Store away from other materials. 05/12/2016 EN (English) 2/8

3 6.4. Reference to other sections SECTION 7 Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Remove contaminated clothes Conditions for safe storage, including any incompatibilities Storage area 7.3. Specific end use(s) SECTION 8 Exposure controls/personal protection 8.1. Control parameters Sodium hydroxide, volumetric solution 0.5 M (0.5 N) VSA ( ) Store in a well-ventilated place. Store away from heat. France Local name Hydroxyde de sodium France VME (mg/m³) 2 mg/m³ France Note (FR) Valeurs recommandées/admises Portugal Local name Hidróxido de sódio Portugal OEL - Ceilings (mg/m³) 2 mg/m³ Spain Local name Hidróxido de sodio Spain VLA-EC (mg/m³) 2 mg/m³ United Kingdom Local name Sodium hydroxide United Kingdom WEL STEL (mg/m³) 2 mg/m³ SODIUM HYDROXIDE ( ) France Local name Hydroxyde de sodium France VME (mg/m³) 2 mg/m³ France Note (FR) Valeurs recommandées/admises Portugal Local name Hidróxido de sódio Portugal OEL - Ceilings (mg/m³) 2 mg/m³ Spain Local name Hidróxido de sodio Spain VLA-EC (mg/m³) 2 mg/m³ United Kingdom Local name Sodium hydroxide United Kingdom WEL STEL (mg/m³) 2 mg/m³ Sodium hydroxide, volumetric solution 0.5 M (0.5 N) VSA ( ) DNEL/DMEL (Workers) Acute - systemic effects, dermal mg/kg bodyweight/day 8.2. Exposure controls Appropriate engineering controls Ensure good ventilation of the work station. Hand protection Nitrile rubber (NBR) / Eye protection Safety glasses Skin and body protection Wear suitable protective clothing SECTION 9 Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid Colour Colourless. Odour odourless. Odour threshold 05/12/2016 EN (English) 3/8

4 ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10 Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Heat Incompatible materials Acids. metals. Organic peroxides Hazardous decomposition products SECTION 11 Toxicological information Information on toxicological effects Acute toxicity Sodium hydroxide, volumetric solution 0.5 M (0.5 N) VSA ( ) LD50 oral rat 40 mg/kg Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard Causes severe skin burns and eye damage. Serious eye damage, category 1, implicit SECTION 12 Ecological information Toxicity 05/12/2016 EN (English) 4/8

5 Sodium hydroxide, volumetric solution 0.5 M (0.5 N) VSA ( ) EC50 Daphnia mg/l 48h Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13 Disposal considerations Waste treatment methods Waste treatment methods Dispose of contents/container in accordance with licensed collector s sorting instructions. SECTION 14 Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) 1824 UN-No. (IMDG) 1824 UN-No. (IATA) 1824 UN-No. (ADN) 1824 UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport document description (ADR) Transport document description (IMDG) Transport document description (IATA) Transport document description (ADN) Transport document description (RID) SODIUM HYDROXIDE SOLUTION SODIUM HYDROXIDE SOLUTION Sodium hydroxide solution SODIUM HYDROXIDE SOLUTION SODIUM HYDROXIDE SOLUTION UN 1824 SODIUM HYDROXIDE SOLUTION, 8, III, (E) UN 1824 SODIUM HYDROXIDE SOLUTION, 8, III UN 1824 Sodium hydroxide solution, 8, III UN 1824 SODIUM HYDROXIDE SOLUTION, 8, III UN 1824 SODIUM HYDROXIDE SOLUTION, 8, III Transport hazard class(es) ADR Transport hazard class(es) (ADR) 8 Danger labels (ADR) 8 IMDG Transport hazard class(es) (IMDG) 8 Danger labels (IMDG) 8 05/12/2016 EN (English) 5/8

6 IATA Transport hazard class(es) (IATA) 8 Hazard labels (IATA) 8 ADN Transport hazard class(es) (ADN) 8 Danger labels (ADN) 8 RID Transport hazard class(es) (RID) 8 Danger labels (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information No No No supplementary information available Special precautions for user - Overland transport Classification code (ADR) Limited quantities (ADR) Excepted quantities (ADR) Packing instructions (ADR) Special packing provisions (ADR) Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Vehicle for tank carriage C5 5l P001, IBC03, LP01, R001 B4 MP19 T4 TP1 L4BN AT Transport category (ADR) 3 Special provisions for carriage - Packages (ADR) V12 Hazard identification number (Kemler No.) 80 05/12/2016 EN (English) 6/8

7 Orange plates Tunnel restriction code (ADR) EAC code E 2R - Transport by sea Special provisions (IMDG) 223 Limited quantities (IMDG) Excepted quantities (IMDG) Packing instructions (IMDG) IBC packing instructions (IMDG) Tank instructions (IMDG) Tank special provisions (IMDG) EmS-No. (Fire) EmS-No. (Spillage) Stowage category (IMDG) Segregation (IMDG) Properties and observations (IMDG) - Air transport PCA Excepted quantities (IATA) PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) 5 L P001, LP01 IBC03 T4 TP1 F-A S-B A SG35 Colourless liquid. Colourless liquid. Reacts with ammonium salts, evolving ammonia gas. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. Y841 1L PCA packing instructions (IATA) 852 PCA max net quantity (IATA) 5L CAO packing instructions (IATA) 856 CAO max net quantity (IATA) Special provisions (IATA) ERG code (IATA) - Inland waterway transport Classification code (ADN) Limited quantities (ADN) Excepted quantities (ADN) Carriage permitted (ADN) Equipment required (ADN) 60L A3 8L C5 5 L T Number of blue cones/lights (ADN) 0 - Rail transport Classification code (RID) Limited quantities (RID) Excepted quantities (RID) Packing instructions (RID) Mixed packing provisions (RID) Portable tank and bulk container instructions (RID) Portable tank and bulk container special provisions (RID) Tank codes for RID tanks (RID) PP, EP C5 5L P001, IBC03, LP01, R001 MP19 T4 TP1 Transport category (RID) 3 Special provisions for carriage Packages (RID) Colis express (express parcels) (RID) L4BN W12 CE8 Hazard identification number (RID) Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable 05/12/2016 EN (English) 7/8

8 SECTION 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions Sodium hydroxide, volumetric solution 0.5 M (0.5 N) VSA is not on the REACH Candidate List Sodium hydroxide, volumetric solution 0.5 M (0.5 N) VSA is not on the REACH Annex XIV List National regulations Germany VwVwS Annex reference 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling Denmark Recommendations Danish Regulation Water hazard class (WGK) 1, low hazard to waters (Classification according to VwVwS, Annex 1 or 2; ID No. 142) Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Young people below the age of 18 years are not allowed to use the product Chemical safety assessment SECTION 16 Other information Full text of H- and EUH-statements Skin Corr. 1A H314 Skin corrosion/irritation, Category 1A Causes severe skin burns and eye damage SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 05/12/2016 EN (English) 8/8