Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet NFPA HMIS Personal Protective Equipment 0 Health Hazard Fire Hazard 0 See Section 5. Section. Chemical Product and Company Identification Common Name/ Trade Name Manufacturer Commercial Name(s) Synonym Vitamin A Palmitate, million IU/g SPECTRUM LABORATORY PRODUCTS INC S. SAN PEDRO STREET GARDENA, CA Catalog Number(s). CAS# RTECS CI# V VH TSCA T S C A 8 ( b ) i n v e n t o r y : V i t a m i n A P a l m i t a t e, million IU/g Vitamin A Palmitate, Liquid in Oil, million IU/g; Retinol Palmitate million IU/g without stabilizers; all-trans Vitamin A Palmitate; IN CASE OF EMERGENCY 3,7-Dimethyl-9-(2,6,6-trimethyl--cyclohexene--yl)2,4,6,8-nonatetraCHEMTREC (24hr) yl-palmitate; Retinol Palmitate; Retinyl Palmitate; all-trans Retinyl Palmitate; Retinol hexadecanoate Page Number: Chemical Name Chemical Family Chemical Formula Supplier Vitamin A Palmitate C36-H60-O2 SPECTRUM LABORATORY PRODUCTS INC S. SAN PEDRO STREET GARDENA, CA CALL (30) Section 2.Composition and Information on Ingredients Name CAS # Exposure Limits TWA (mg/m 3 ) STEL (mg/m 3 ) CEIL (mg/m 3 ) % by Weight ) Vitamin A Palmitate, million IU/g Toxicological Data on Ingredients Vitamin A Palmitate, Liquid in Oil: ORAL (LD50): Acute: 790 mg/kg [Rat] mg/kg [Mouse]. Section 3. Hazards Identification Potential Acute Health Effects Potential Chronic Health Effects Slightly hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of ingestion, of inhalation. CARCINOGENIC EFFECTS: MUTAGENIC EFFECTS: TERATOGENIC EFFECTS: Classified POSSIBLE for human. DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female, Development toxin [POSSIBLE]. The substance may be toxic to liver, gastrointestinal tract, skin, central nervous system (CNS). Repeated or prolonged exposure to the substance can produce target organs damage.

2 Vitamin A Palmitate, million IU/g Page Number: 2 Section 4. First Aid Measures Eye Contact Skin Contact Serious Skin Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 5 minutes. Get medical attention if irritation occurs. Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Inhalation Serious Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Ingestion Serious Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear. Section 5. Fire and Explosion Data Flammability of the Product Auto-Ignition Temperature Flash Points Flammable Limits Products of Combustion Fire Hazards in Presence of Various Substances Explosion Hazards in Presence of Various Substances Fire Fighting Media and Instructions May be combustible at high temperature. 280 C (536 F) CLOSED CUP: 93 C (379.4 F). These products are carbon oxides (CO, CO2). Slightly flammable to flammable in presence of heat, of combustible materials. Non-flammable in presence of shocks. Risks of explosion of the product in presence of mechanical impact: Risks of explosion of the product in presence of static discharge: SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. Fire Hazards Explosion Hazards Spontaneous iginition may occur when exposed to air and in contact with other materials such as cloth, paper, wood, insulation. Section 6. Accidental Release Measures Small Spill Large Spill Absorb with an inert material and put the spilled material in an appropriate waste disposal. If the product is in its solid form: Use a shovel to put the material into a convenient waste disposal container. If the product is in its liquid form: Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Section 7. Handling and Storage Precautions Storage Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. If ingested, seek medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizing agents, metals, acids, alkalis. Store away from light preferably in light resistant containers. Keep container tightly closed. Keep container in a cool, well-ventilated area. Store at temperatures from 2-5 C. Refrigerate. Air Sensitive

3 Vitamin A Palmitate, million IU/g Page Number: 3 Section 8. Exposure Controls/Personal Protection Engineering Controls Personal Protection Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. Safety glasses. Lab coat. Gloves (impervious). Personal Protection in Case of a Large Spill Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Exposure Limits Section 9. Physical and Chemical Properties Physical state and appearance Liquid. (Oily liquid.) Odor Characteristic. (Slight.) Molecular Weight ph (% soln/water) g/mole Taste Color bland, oily Golden Yellow. Boiling Point Melting Point 28.5 C (83.3 F) Critical Temperature Specific Gravity 0.92 (Water = ) Vapor Pressure Vapor Density Volatility Odor Threshold Water/Oil Dist. Coeff. Ionicity (in Water) Dispersion Properties See solubility in water, diethyl ether. Solubility Soluble in diethyl ether. Insoluble in cold water, hot water. Section 0. Stability and Data Stability Instability Temperature Conditions of Instability Incompatibility with various substances Corrosivity The product is stable. Excess heat, light, air, incompatible materials Reactive with oxidizing agents, metals, acids, alkalis. Corrosivity Polymerization Protect from light and air to avoid gradual decompostion. Incompatible with copper, copper alloys, iron, iron salts, strong oxidizing agents, peroxides, strong inorganic acids, strong bases. Will not occur.

4 Vitamin A Palmitate, million IU/g Page Number: 4 Section. Toxicological Information Routes of Entry Toxicity to Animals Chronic Effects on Humans Other Toxic Effects on Humans Toxicity to Animals Chronic Effects on Humans other Toxic Effects on Humans Absorbed through skin. Eye contact. Acute oral toxicity (LD50): 6060 mg/kg [Mouse]. TERATOGENIC EFFECTS: Classified POSSIBLE for human. DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female, Development toxin [POSSIBLE]. May cause damage to the following organs: liver, gastrointestinal tract, skin, central nervous system (CNS). Slightly hazardous in case of skin contact (irritant, permeator), of ingestion, of inhalation. May cause adverse reproductive effects and birth defects (teratogenic/developmental toxin). May affect genetic material. Acute Potential Health Effects: Skin: May cause skin irritation and dermatitis, and chapped lips. It may be absorbed through the skin. Eyes: May cause eye irritation. Inhalation: May cause irritation of the respiratory tract. Ingestion: May cause irritation of the gastrointestinal tract. Symptoms of GI tract irritation may include nausea, vomiting, diarrhea, constipation, cramps and loss of appetite. May also afect behavior/central Nervous System (symptoms may include headache, dizziness, drowsiness, fatigue, lack of muscular coordination), liver (symptoms may include jaundice, and elevation of liver enzyme levels), and metabolism. Chronic Potential Health Effects: Syptoms of chronic exposure may be similar to those of acute overexposure. Chronic exposure may also cause adverse reproductive effects, and birth defects and may affect genetic material. Section 2. Ecological Information Ecotoxicity BOD5 and COD Products of Biodegradation Toxicity of the Products of Biodegradation the Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. The product itself and its products of degradation are not toxic. Section 3. Disposal Considerations Waste Disposal Waste must be disposed of in accordance with federal, state and local environmental control regulations. Section 4. Transport Information DOT Classification Identification Not a DOT controlled material (United States). Special Provisions for Transport DOT

5 Vitamin A Palmitate, million IU/g Page Number: 5 Section 5. Other Regulatory Information and Pictograms Federal and State Regulations California Proposition 65 Warnings Other Regulations found to cause cancer, birth defects or other reproductive harm, which would require a warning under the statute: Vitamin A Palmitate, million IU/g found to cause birth defects which would require a warning under the statute: Vitamin A Palmitate, million IU/g TSCA 8(b) inventory: Vitamin A Palmitate, million IU/g found to cause cancer which would require a warning under the statute: No products were found. found to cause birth defects which would require a warning under the statute: Vitamin A Palmitate, million IU/g OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR ). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No ). Canada: Listed on Canadian Domestic Substance List (DSL). China: Listed on National Inventory. Japan: Listed on National Inventory (ENCS). Korea: Not listed on National Inventory (KECI). Philippines: Listed on National Inventory (PICCS). Australia: Listed on AICS. Other Classifications WHMIS (Canada) Not controlled under WHMIS (Canada). DSCL (EEC) Not available HMIS (U.S.A.) Health Hazard Fire Hazard Personal Protection 0 B National Fire Protection Association (U.S.A.) Health 0 Flammability Specific hazard WHMIS (Canada) DSCL (Europe) TDG (Canada) ADR (Europe) Protective Equipment Gloves (impervious). Lab coat.

6 Vitamin A Palmitate, million IU/g Page Number: 6 Safety glasses. Section 6. Other Information MSDS Code References Other Special Considerations V0004 Validated by Sonia Owen on 5/26/200. Verified by Sonia Owen. Printed 5/26/200. CALL (30) Notice to Reader All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products, Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.