Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet NFPA HMIS Personal Protective Equipment 2 0 Health Hazard Fire Hazard 2 0 See Section 5. Section. Chemical Product and Company Identification Common Name/ Trade Name Manufacturer Commercial Name(s) Synonym Chemical Name Naphazoline HCl SPECTRUM LABORATORY PRODUCTS INC S. SAN PEDRO STREET GARDENA, CA Clera; Coldan; Naphcon; Naphcon forte; Naphthasolium chloride; Niazol; Privine hydrochloride; Prizole hydrochloride; Rhinantin; Rhinoperd; Stricylon; Vasocon 4,5-Dihydro-2-(-naphthalenylmethyl)-H-imidazole; H-Imidazole, 4,5-dihydro-2-(-naphthalenylmethyl)-, monohydrochloride; 2 - ( - N a p h t h y l m e t h y l ) i m i d a z o l i n e h y d r o c h l o r i d e ; 2-(-Naphthylmethyl)imidazoline hydrochloride 2-Imidazoline, 2-(-naphthylmethyl)-, monohydrochloride Catalog Number(s). CAS# RTECS TSCA CI# NA NJ Page Number: TSCA 8(b) inventory: No products were found. IN CASE OF EMERGENCY CHEMTREC (24hr) Chemical Family Chemical Formula Supplier C4H4N2.HCl SPECTRUM LABORATORY PRODUCTS INC S. SAN PEDRO STREET GARDENA, CA CALL (30) Section 2.Composition and Information on Ingredients Name CAS # Exposure Limits TWA (mg/m 3 ) STEL (mg/m 3 ) CEIL (mg/m 3 ) % by Weight ) Naphazoline HCl Toxicological Data on Ingredients Naphazoline HCl: ORAL (LD50): Acute: 50 mg/kg [Rabbit]. Section 3. Hazards Identification Potential Acute Health Effects Potential Chronic Health Effects Hazardous in case of ingestion, of inhalation. Slightly hazardous in case of skin contact (irritant), of eye contact (irritant). Severe over-exposure can result in death. CARCINOGENIC EFFECTS: MUTAGENIC EFFECTS: TERATOGENIC EFFECTS: DEVELOPMENTAL TOXICITY: The substance may be toxic to heart, central nervous system (CNS). Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many human organs.

2 Naphazoline HCl Page Number: 2 Section 4. First Aid Measures Eye Contact Skin Contact Serious Skin Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 5 minutes. Cold water may be used. Get medical attention if irritation occurs. Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water may be used. Inhalation Serious Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Ingestion Serious Ingestion If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. Section 5. Fire and Explosion Data Flammability of the Product Auto-Ignition Temperature Flash Points Flammable Limits Products of Combustion Fire Hazards in Presence of Various Substances May be combustible at high temperature. These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...). Slightly flammable to flammable in presence of heat. Explosion Hazards in Presence of Various Substances Risks of explosion of the product in presence of mechanical impact: Risks of explosion of the product in presence of static discharge: Fire Fighting Media and Instructions Fire Hazards Explosion Hazards SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. As with most organic solids, fire is possible at elevated temperatures Material in powder form, capable of creating a dust explosion. Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Section 6. Accidental Release Measures Small Spill Large Spill Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Poisonous solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call for assistance on disposal. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system.

3 Naphazoline HCl Page Number: 3 Section 7. Handling and Storage Precautions Storage Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable protective clothing. If ingested, seek medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizing agents, metals. Keep container tightly closed. Keep container in a cool, well-ventilated area. Sensitive to light. Store in light-resistant containers. Section 8. Exposure Controls/Personal Protection Engineering Controls Personal Protection Personal Protection in Case of a Large Spill Exposure Limits Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Section 9. Physical and Chemical Properties Physical state and appearance Solid. (Solid crystalline powder.) Odor Odorless. Molecular Weight ph (% soln/water) g/mole 6.2 [Acidic.] Taste Color Bitter. White. Boiling Point Melting Point Critical Temperature Specific Gravity Vapor Pressure Vapor Density Volatility Odor Threshold Water/Oil Dist. Coeff. Ionicity (in Water) Dispersion Properties Solubility Decomposition temperature: 253 C (487.4 F) C. Not applicable. See solubility in water. Easily soluble in cold water. Solubility in Water: deg. C. Section 0. Stability and Data Stability Instability Temperature Conditions of Instability Incompatibility with various substances Corrosivity The product is stable. Excess heat, incompatible materials, light Reactive with oxidizing agents, metals. Non-corrosive in presence of glass. Sensitive to light. Incompatible with aluminum.

4 Naphazoline HCl Page Number: 4 Corrosivity Polymerization Will not occur. Section. Toxicological Information Routes of Entry Toxicity to Animals Chronic Effects on Humans Other Toxic Effects on Humans Toxicity to Animals Chronic Effects on Humans other Toxic Effects on Humans Inhalation. Ingestion. Acute oral toxicity (LD50): 50 mg/kg [Rabbit]. May cause damage to the following organs: heart, central nervous system (CNS). Hazardous in case of ingestion, of inhalation. Slightly hazardous in case of skin contact (irritant). Acute Potential Health Effects: Skin: May cause skin irritation. Eyes: May cause eye irritation. Inhalation: Inhalation of dust may cause respiratory tract irritation. Ingestion: Harmful if swallowed. Ingestion or inhalation may cause sweating, nausea, and common sympathetic actions such as prolonged hypertension with peripheral vasoconstriction, rebound hypotension followed by hypertension and bradycardia, mild cortical stimulation or excitement followed by central nervous system effects (headache, insomnia, convulsions, drowsiness, dizziness, weakness somnolence, deep sleep/unconciousness, or possible coma). It may also affect respiration (respiratory stimulation, dyspnea), and cause blurred vision. Chronic Potential Health Effects: Inhalation/Ingestion: Prolonged or repeated ingestion or inhalation may affect the heart, central nervous system. Prolonged or repeated inhalation may cause impairment of smell due to paralysis of nasal cilia. Section 2. Ecological Information Ecotoxicity BOD5 and COD Products of Biodegradation Toxicity of the Products of Biodegradation the Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. The products of degradation are more toxic. Section 3. Disposal Considerations Waste Disposal Waste must be disposed of in accordance with federal, state and local environmental control regulations. Section 4. Transport Information DOT Classification Identification CLASS 6.: Poisonous material.r68- UNNA: 28 : Toxic Solid, organic, n.o.s.(naphazoline Hydrochloride) PG: III Special Provisions for Transport

5 Naphazoline HCl Page Number: 5 DOT Section 5. Other Regulatory Information and Pictograms Federal and State Regulations California Proposition 65 Warnings Other Regulations No products were found. California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: No products were found. California prop. 65: This product contains the following ingredients for which the State of California has found to cause birth defects which would require a warning under the statute: No products were found. OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR ). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No ). Canada: Llisted on Canadian Domestic Substance List (DSL). China: Not listed on National Inventory. Japan: Listed on National Inventory (ENCS). Korea: Not listed on National Inventory (KECI). Philippines: Not listed on National Inventory (PICCS). Australia: Listed on AICS. Other Classifications WHMIS (Canada) CLASS D-B: Material causing immediate and serious toxic effects (TOXIC). DSCL (EEC) R25- Toxic if swallowed. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). HMIS (U.S.A.) Health Hazard Fire Hazard Personal Protection 2 0 E National Fire Protection Association (U.S.A.) Health 2 0 Flammability Specific hazard WHMIS (Canada) DSCL (Europe) TDG (Canada) ADR (Europe) Protective Equipment Gloves.

6 Naphazoline HCl Page Number: 6 Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Safety glasses. Section 6. Other Information MSDS Code References Other Special Considerations N300 Validated by Sonia Owen on 7/24/203. Verified by Sonia Owen. Printed 7/25/203. CALL (30) Notice to Reader All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products, Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.