Intermediates 3. Intermediates 4. Intermediates 5. Mono glycerides (f) Synthetic Chemicals 6. Acetic Anhydride

Transcription

1 Agro Chemicals & Synthetic Organic Chemicals by M/s Manbro Polymers Limited, Plot No. D- ANNEXURE A DETAILS OF PRODUCTS Sr. Name of the Products CAS NO. Quantity LD50 Category End Use No. MT/Month 1. 5-Chloro-8- Hydroxyquinoline [5- HQ] mg/kg 5(b) Agro chemical Intermediates 2. 8-Hydroxyquinoline [ (b) Agro chemical HQ] mg/kg Intermediates 3. 2,3 Dichloro Phenol [2, (b) Agro chemical DCP] mg/kg Intermediates 4. 3, 4 Dichloro Phenol [3, (b) Agro chemical DCP] mg/kg Intermediates 5. Mono glycerides (f) Synthetic Chemicals 6. Acetic Anhydride (f) Synthetic Organic mg/kg Chemicals Acetem 5(f) Synthetic Organic 7. (I)Acetic Acid ester of Monoglyceride Chemicals 8. Ethyl Acetate 1s Total 940 MT/Month 5620 mg/kg 5(f) Synthetic Organic Chemicals

2 Agro Chemicals & Synthetic Organic Chemicals by M/s Manbro Polymers Limited, Plot No. D- Sr. No ANNEXURE B DETAILS OF PRODUCT WISE RAW MATERIAL CONSUMPTION Product Name Raw material CAS No. MT/MT 5-Chloro-8- Hydroxyquinoline [5- CHQ] 8-Hydroxyquinoline [8- HQ] 2,3 Dichloro Phenol [2,3 DCP] 3, 4 Dichloro Phenol [3,4 DCP] 5. Mono glycerides 6. Acetic Anhydride 7. Acetem (I)Acetic Acid ester of Monoglyceride 8. Ethyle Acetate 4-CAP Glycerine Sulfuric Acid Acetic Acid C S Lye Amino Phenol Glycerine Sulfuric Acid Acetic Acid C S Lye ,3 DCA Sulfuric Acid Nitrosyl Sulfuric Acid ,4 DCA Sulfuric Acid Nitrosyl Sulfuric Acid Fatty acid Glycerol Potassium hydroxide Acetic Acid Phosphorus penta Chloride Monoglyceride Acetic Anhydride Sodium acetate anhydrous Ethanol Acetic Acid Potassium hydroxide

3 ANNEXURE C DETAILS OF MANUFACTURING PROCESS 1. 5-CHLORO-8-HYDROXYQUINOLINE [5-CHQ]: PROCESS DESCRIPTION: 4-Chloro-2-Amino Phenol is reacted with Glycerine leading to cyclization in presence of Sulfuric Acid. The reaction leads to form 5-Chloro-8-Hydroxyquinoline; the excess of 4-CAP is removed by distillation. The residual mass diluted with water and ph adjusted with C S Lye followed by filtration and washing. The wet cake dried to obtain product 5-Chloro-8-Hydroxyquinoline [5-CHQ]. CHEMICAL REACTION: PROCESS FLOW DIAGRAM:

4 2. 8-HYDROXYQUINOLINE [8-HQ]: PROCESS DESCRIPTION: 2-Amino Phenol is reacted with Glycerine leading to cyclization in presence of Sulfuric Acid. The reaction leads to form 8-Hydroxyquinoline; the excess of 2-Amino Phenol is removed by distillation. The residual mass diluted with water and ph adjusted with C S Lye followed by filtration and washing. The wet cake dried to obtain product 8-Hydroxyquinoline [8- HQ] CHEMICAL REACTION: PROCESS FLOW DIAGRAM:

5 3. 2,3 DICHLORO PHENOL [2,3 DCP]: PROCESS DESCRIPTION: 2,3Dichloro Aniline [2,3 DCA] is converted to its diazonium compound with Nitrosyl Sulfuric Acid in presence of Sulfuric Acid. The reaction is carried out under very controlled condition of temperature. The Diazonium salt formed is further subjected to acidic hydrolysis leading to formation of the product 2,3Dichloro Phenol. The product formed is isolated by means of distillation. CHEMICAL REACTION: PROCESS FLOW DIAGRAM:

6 4. 3, 4 DICHLORO PHENOL [3,4 DCP]: Process Description: 3,4Dichloro Aniline [3,4 DCA] is converted to its diazonium compound with Nitrosyl Sulfuric Acid in presence of Sulfuric Acid. The reaction is carried out under very controlled condition of temperature. The Diazonium salt formed is further subjected to acidic hydrolysis leading to formation of the product 3,4Dichloro Phenol. The product formed is isolated by means of distillation. CHEMICAL REACTION: PROCESS FLOW DIAGRAM:

7 5. MONOGLYCERIDES PROCESS DESCRIPTION: Monoglycerides are a class of glycerides which are composed of a molecule of glycerol linked to a fatty acid. Monoglycerides are produced biologically or industrially. They are naturally present at very low level in seeds. They are synthesized by enzymatic triglyceride. Production is primarily achieved by a glycerolysis reaction between Triglycerides and glycerol. CHEMICAL REACTION: + -H2O Glycerol 92 Fatty Acid 200 Monoglyceride 274 PROCESS FLOW DIAGRAM:

8 6. ACETIC ANHYDRIDE PROCESS DESCRIPTION: Acetic anhydride is two stage process. First, charge acetic acid and phosphorus Pentachloride in reactor for preparation of acetic chloride. Generated Phosporyl chloride with hydrochloric acid separated from acetyl chloride, dry it and sell it to authorize vendor After mixing, carryout acetic chloride in reactor and add acetic acid for mixing. After completion of reaction, filter product and pack it. CHEMICAL REACTION: PROCESS FLOW DIAGRAM:

9 7. ACETEM PROCESS DESCRIPTION: Acetem is an organic compound. It is produced by esterification of monoglycerides and acetic anhydride. CHEMICAL REACTION: Sodium acetate anhydrous + + CH 3COOH Monoglyceride 176 Acetic Anhydride 102 Acetem 218 Acetic Acid 60 PROCESS FLOW DIAGRAM:

10 8. ETHYL ACETATE PROCESS DESCRIPTION: Ethyl acetate is organic compound. It is colorless with sweet smell. Ethyl acetate is the ester of acetic acid and ethanol. Ethyl acetate is synthesized in industry mainly via the classic Fischer esterification reaction of ethanol and acetic acid. The reaction can be accelerated by acid catalysis and the equilibrium can be shifted to the right by removal of water. CHEMICAL REACTION: CH3CH2OH + CH3COOH CH3COOCH2CH3 + H2O Ethanol Acetic Acid Ethyl Acetate Water PROCESS FLOW DIAGRAM:

11 Annexures to Form 1 & PFR for Proposed Project for manufacturing of Speciality chemicals by M/s Manbro Polymers Limited, Plot No. D- ANNEXURE D Recycle Water KL/Day Total Water Requirement 38 KL/Day [Fresh water KLD + Recycle water KLD] Gardening 3 KL/Day Domestic 4 KL/Day Boiler Scrubber 2 KL/Day Washing 3KL/Day Process 15 KL/Day Boiler 5 KL/Day Cooling 6 KL/Day Boiler Scrubber 0.5 KL/Day Washing 3 KL/Day Process 18 KL/Day Boiler blowdown 1.0 KL/Day Cooling bleed off 1.5 KL/Day Septic/Soak pit tank 3 KL/Day Effluent Treatment plant 24 KL/Day ETP Sludge TSDF 1.0 MT/Day Recycle Water KL/Day Multi Effective Evoprator 22.8 KL/Day Salt along with Moisture to TSDF [3.84 MT/Day] (Salt 1.14 MT KL)

12 Annexures to Form 1 & PFR for Proposed Project for manufacturing of Speciality chemicals by M/s Manbro Polymers Limited, Plot No. D- ANNEXURE D EFFLUENT TREATEMENT PLANT Waste water Collection cum Equalization tank Neutralizer tank Filtration Final holding tank MEE ETP sludge MEE salt Condensate Recovery

13 ANNEXURE E DETAILS OF HAZARDOUS WASTE Sr. Name of Hazardous Category Quantity Mode of Disposal No. Waste [MT/Annum] 1. Used/Spent oil Collection, Storage, Transportation and send to PCB registered reprocessor. 2. Discarded drums Discarded Bags/Liners Collection, Storage, Decontamination Transportation and Sold to GPCB authorized users. 3. Distillation Residue Collection, Storage, Transportation and Disposal to Co- Processing/CHWIF Incineration 4. Hydrochloric Acid Collection, Storage, captive consumption, Transportation or sale to authorized end users 5. Phosphoryl Chloride Collection, Storage, captive consumption, Transportation or sale to authorized end users 6. Acetic Acid Collection, Storage, captive consumption, Transportation or sale to authorized end users 7. Spent sulphuric Acid Collection, Storage, Transportation or sale to authorized users 8. Fly-Ash Collection, Storage, Transportation and send to Brick manufacturer or Low lying area.

14 Agro Chemicals & Synthetic Organic Chemicals by M/s Manbro Polymers Limited, Plot No. D- ANNEXURE F DETAILS OF AIR POLLUTION CONTROL MEASURES DETAILS OF FLUE GAS EMISSION Sr. No. Stack attached to Capacity Name of fuel & its consumption 1. Boiler 0.9 MT Briquettes 3000 Kg/Day. 2. Thermic Fluid 2 Lac Heater kcal/hr. 2. DG Set [ For Emergency purpose only] 200 KVA Diesel 40 Ltr./Hr APCM Stack Height Cyclone 12 m Separator + 6 m Water scrubber m Parameter SPM 150mg/Nm 3 SO2 100 mg/nm 3 NOx 50 mg/nm 3 DETAILS OF PROCESS GAS EMISSION Sr. No. Stack Attached to Stack Height in Meter Control Measures Type of Pollutants 1. Process reactor 1 10 Two stage scrubber HCl Cl2 Permissible Limit < 20 mg/nm 3 < 09 mg/nm 3

15 AUTHORITY SIGN PATTA PLOT BOUNDARY PATTA P X7.00 P X MT. WIDE PARKING ROAD P X P X6.00 P X BLOCK-3 FECTORY STORAGE SHED MT. WIDE APPROCH ROAD 8.02 OPEN SPACE BLOCK-5 WORKING AREA 4.50 MT. WIDE APPROCH ROAD BLOCK-4 PLANT BUILDING 4.50 MT. WIDE APPROCH ROAD BLOCK-2 STORAGE SHED PLOT BOUNDARY PATTA PLOT D-2 CH-274 OWNERS SIGN. OUT SIDE FRONT GL PL. LVL 1.50 IN SIDE REAR 1.80 PROPOSED BOUNDARY WALL FRONT, REAR SIDE SCALE:- 1.00CM=1.00MT MTR. Ø SIZE : X 1.50 X 2.50MT. DEPTH TYPICAL SECTION FOR RAIN WATER HARVESTING ARCHITECTS SIGN. PROPOSED FACTORY BUILDING PLAN ON PLOT NO -D-2-CH-275 AT - G.I.D.C. ESTATE AREA, DAHEJ-2 TAL.-VAGRA. DIST.- BHARUCH. FOR. "M/S JDB PHARMACEUTICAL PROJECT(P)LTD." PLOT D-2 CH-227 PLOT D-2 CH-228 PLOT D-2 CH-229 PLOT D-2 CH MT. WIDE ROAD NO. SIZE SILL LINTEL RS 2.00 X D 1.20 X D X W 1.50 X V X V 1.50 X PLOT BOUNDARY LINE 2 SET BACK LINE (MARGIN) 3 PROPOSED WORK 4 DRAINAGE LINE 5 PARKING AREA 6 COMMON OPEN PLOT 7 ETP & SEWAGE LINE 8 APPROCH ROAD 9 GIDC ROAD 10 RAIN WATER HARVESTING PROPOSED SITE BLOCK-1 (F.F.) OFFICE BLDG G 1.50 R.C.C. SLAB R.C.C. SLAB L SOAK-PIT PLAN 1: M.H MT. WIDE APPROCH ROAD 6.00 PER. WELL PLAN 1: MAIN ENTRY GATE 3.00 BLOCK-6 SECURITY 3.33X3.00 BLOCK P X5.00 PLOT BOUNDARY PATTA ROAD LENGTH MT. WIDE ROAD N SITE PLAN & KEY PLAN DRAWN BY HARSHAD MAIL :- helloparmar797@gmail.com M DATE- SHEET:-1 OF 1

16 Agro Chemicals & Synthetic Organic Chemicals by M/s Manbro Polymers Limited, Plot No. D- ANNEXURE H PROPOSED TERMS OF REFERENCE The generic structure of Environment Impact Assessment Study Report will be as under: 1. Introduction This will cover the location and justification of the proposed project and scoping and methodology for the EIA study. 2. Project Description It will include the below mention details. Location of the project Product profile Resources requirement Manufacturing process and raw material requirement Material handling and storage Details on proposed Environmental Management System and Monitoring. Storage and handling of hazardous chemicals 3. Baseline Environmental Description The data regarding baseline environmental conditions will be collected /generated as per the guidelines of MoEF. The methodology for collection of baseline data for each of the component/environmental attribute is as follows: 1. Air a. The study area will be of 5 Km radius considering the project site as center and study period will be of one season except monsoon. b. For estimation of back ground concentration of PM10, PM2.5, Oxides of Nitrogen (NO x), Sulphur Dioxide (SO 2), within study area, and 6 monitoring stations will be established as per the guidelines of CPCB and Ministry of Environment & Forest, Government of India. At each station monitoring will be carried out on 24 hourly bases twice in a week for entire study period except monsoon.

17 Agro Chemicals & Synthetic Organic Chemicals by M/s Manbro Polymers Limited, Plot No. D- 2. Meteorology Meteorological data like wind speed, wind direction, humidity, temperature, will be collected at the location under consideration / from authorized agency, so as to prepare wind-rose diagram and to predict the concentration of pollutants using dispersion models. These data will be collected for a period of 12 weeks. 3. Water Water samples will be collected and analyzed of raw water supply of the Notified area. 4. Noise The noise level will be measured once in a study period in Leq. at least at 6 different location within study area using an integrated sound level meter. 4. Identification and Assessment of the Impacts The activities having the potential to cause environmental impact will be identified and the degree of impact will be assessed using standard matrix methods. The following environmental attributes will be considered to establish the cause-effect relationship with the various activities of the proposed project. 5. Environmental Management and Monitoring Plan Environmental Management and Monitoring Plan will be prepared based on the anticipated environmental impact. It will also cover details on Occupational Health programs and as well as for corporate social responsibilities. 6. Risk Assessment: The study will include risk assessment for storage, handling, transportation etc. for the raw material(s) and products to be used in the plant. Occupational risk involved during operational phase of the plant will be assessed and necessary safety and protective measures will be recommended.