Ontario Co. LF Phase III Expansion Wells Ontario, New York

Transcription

1 pstate Laboratories, Inc Corporate Drive East Syracse, New York Sample Data Package Case Narrative, Chain of Cstody Docmentation and VOC Data Volme 2 of 4 SDG No. CAS120 Project: Ontario Co. LF Phase III Expansion Wells Ontario, New York iliiijiiiimiiim Ms. Carla Canjar Casella c/o Ontario Co. Recycling & LF Mgmt State Rote and 20 Stanley, New York 1461 Samples Collected: November 22, 2009 New York Lab Code

2 NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION pstate Laboratories, Inc 6034 Corporate Drive East Syracse, New York 1307 Cstomer Sample Code MW-28 MW-29 MW-29 MS MW-29 MSD MW-29 DPE MW-Z LI TRIP BLANK HOLDING BLANK Laboratory Sample Code MS MSD DP SAMPLE IDENTIFICATION AND ANALYTICAL REQIREMENT SMMARY VOA GC/MS Method # Analytical Reqirements BNA Pest Herb GC/MS PCBs GC/MS Method Method Method # # # - - _ - - _ - - _ - - _ -. _ «- -. Metals Baseline + Dissolveo Baseline + Dissolved Baseline + Dissolved Baseline + Dissolved Baseline. _ Wet Chemistry and Other Baseline Baseline Baseline Baseline Baseline B

3 1.0 Smmary Narrative This report presents the sample test reslts and qality control reslts for two water locations collected from the Ontario Co LF Phase III Expansion Wells project, Ontario, New York. The samples were analyzed for the parameters listed in Section 3.0, below. This report is divided into two packages and for volmes. The Sample Data Smmary Package (Volme 1) presents a smmary ofthe test reslts and qality control data. This abbreviated format is sefl to engineers and environmental scientists. The Sample Data Package (Volmes 2-4) is a comprehensive report containing instrment raw data. It is formatted for validation by an independent third party. 2.0 Chain of Cstody The samples were collected by Barton and Logidice, PC personnel on November 22, 2009, and were delivered to pstate Laboratories, Inc., Syracse, New York. The Chain of Cstody Docmentation is presented in Volmes 1 and Methodology The analyses were performed sing test methods developed by the SEPA. The specific method nmbers are: Parameter Volatile Organics Alminm Antimony Arsenic Barim Beryllim Boron Cadmim Calcim Chromim Cobalt Copper Iron Lead Magnesim Manganese Mercry Nickel Selenim Potassim Silver Sodim Thallim Vanadim Zinc Method Reference 0) (1) (1) (1) (1) (1) (1) (1) (1) (1) (1) (1) (1) (1) (1) (1) (1) (1) 0) (1) (1) (1) (1) (1) (1) -17- The total nmber of pages in this Data Package is:

4 Total Alkalinity Ammonia-Nitrogen BOD Bromide Chloride COD Color Cyanide Hexavalent Chromim Nitrate-Nitrogen Phenols Slfate TDS TKN TOC SM (1) (1) (1) (1) (1) (1) (1) (1) 0) (1) (1) (1) (1) (1) (1) (1) New York State Department of Environmental Conservation Analytical Services Protocol (ASP), 7/0 revision. 4.0 Qality Control Qality control data incldes method blanks, reference samples, matrix spikes, matrix spike dplicates, dplicates and srrogate recoveries. For wet chemistry, the association of QC data with sample data is made throgh the se ofthe "File No." fond on both the final report pages and the QC smmary pages..0 Internal Validation The following observations are offered: Volatiles by GC/MS Holding Time : Criteria were satisfied. Calibration Method Blanks MSB MS/MSD Srrogates Inter. Stds. : Several target componds were manally integrated in the IC and CC. All other criteria were satisfied. : Criteria were satisfied. : Criteria were satisfied. : Criteria were satisfied. : Criteria were satisfied. : Criteria were satisfied. Trace Metals (Total and Dissolved) and Cyanides Data Holding Time : Criteria were satisfied. Calibration Method Blanks : The ICV recovery for Selenim was below QC acceptance limits. The CCV1, CCV2 and CCV3 recoveries for Antimony and Selenim were above QC acceptance limits. The CCV1 recovery for Antimony was above QC acceptance limits. The initial and final CRDL Standard recoveries for Lead were above QC acceptance limits. The initial CRDL Standard recovery for Selenim was below QC acceptance limits. The initial CRDL Standard recovery for Antimony was above QC acceptance limits. All other criteria were satisfied. : Lead was detected at a concentration above the CRDL in CCB3 for analytical seqence R4807. Antimony was detected at a concentration above the CRDL in the ICB for analytical seqence -18-

5 R4829. Selenim was detected at concentrations above the CRDL for the ICB, CCBl, CCB2 and CCB3 for analytical seqence R4829. All associated sample locations ran ND for Antimony and Selenim; therefore, the data shold be considered valid. All other criteria were satisfied. Reference Sample Matrix Spikes Dplicates : The LCS recovery for Antimony was above QC acceptance limits for LCS All other criteria were satisfied. : The MS recoveries for Antimony and Silver were otside QC acceptance limits for the MS performed on sample location MW-29 (Diss). The MS recoveries for Alminm, Iron and Silver were otside QC acceptance limits for the MS performed on sample location MW-29. The concentrations of Alminm and Iron in sample location MW-29 were greater than 4X the SPK vale; therefore, the data shold be considered valid. All other criteria were satisfied. : Criteria were satisfied. Wet Chemistry Data Holding Time Calibration Method Blanks Reference Samples Matrix Spikes Dplicates : Criteria were satisfied. : The CCV4, CCV10 and CCV13 recoveries for Total Alkalinity were otside QC acceptance limits for analytical seqence R474. The CCV4 recovery for Chloride was below QC acceptance limits for analytical seqence R4744. All other criteria were satisfied. : Criteria were satisfied. : Criteria were satisfied. : Criteria were satisfied. : Criteria were satisfied. I certify that this data package is in compliance with the terms and conditions ofthe Contract, both technically and for completeness, for other than the conditions detailed above. Release ofthe data contained in this hardcopy data package and/or in the compter-readable data sbmitted on floppy diskette has been athorized by the Laboratory Manager or his designee, as verified by the following signatre. A PP roved Ch±h/jr)jj.p. A rnjn QCCAS120B Anthony J. Scala, Director -19-

6 Chain-of-Cstody pstate Laboratories, Inc

7 pstate Laboratories, Lnc Corporate Drive Syracse New York 1307 (31)43702 Fax Client "" ~~~ Chain of Cstody Record 1) HELP n./ra/ip-eiiapec romn THKn.nwi (w= g ) 2)BODS,COLOR,CR+6,NQ3,TDS,S04,CL-.BROMIDE 3)TKN,NH3,COD 4) ALKALINITY )T-CN 6)T-PHENOLS 7) TOC 8)T-AL,SB*.AS*,BA-BE-CD.CA,CR.CO,C.FE,PB*,MG. B,MN.HG,MA.NI,K,SE»AG.TL«,V-ZN + HARDNESS 9)D-AL,SB*-AS*,BA,BE,CD,CA,CR,CQ,C,FE.PB*.IVIG B,MN,HG,NA,NI,K.SE*.AG.TL*,V_ZN ~ ~ 10 EPA 8260^ASgqWE-yST" " A Syracse ) Rochester ~ N/A PLASTIC PLASTIC GLASS PLASTIC AMBER PLASTIC PLASTIC PLASTIC GLASS Bffalo 2000ml 00ml 8oz 2000ml 32oz 120ml 00ml 00ml 40 ML NONE H2SQ4 NONE NOAH H2S04 1:1 HCL HNQ3 HNQ3 1:1 HCL Albany Sampled by (Print) g.-.-** &<>Gr*(k Company: j&yh^. Relinqished by:(sign) Relinqished by:(si Relinqished by:(sign) Date Time Time Name of Corier Received by: (sign) Received by: (sign) JlAJ^f Binghamton Fair Lawn (NJ) I^J/AQ HW\

8 pstate Laboratories, (ne r* rna( L*".««oiy Sign-Ot Log J0-03 Revised 8/QQ Project: SDG No.: LI ID No.: *S* i&

9 pstate Laboratories, Inc. Sample Receipt Checklist Client Name CASELLA-MAIN Work Order Nmbe Date and Time Receive Received by TC 11/24/ :00:00 AM c te «s,co mpteiby ^(1 t_ CN p new Revi_ dby pff H-74-rtQ I I Da,e Initials 1 Dale Matrix: Carrier name: Client Shipping container/cooler in good condition? Cstody seals intact on shippping container/cooler? Cstody seals intact on sample bottles? Chain of cstody present? Chain of cstody signed when relinqished and received? Chain of cstody agrees with sample labels? Samples in proper container/bottle? Sample containers intact? Sfficient sample volme for indicated test? All samples received within holding time? Container/Temp Blank temperatre in compliance? Water - VOA vials have zero headspace? Water-pH acceptable pon receipt? < *L, Yes 0 Yes Yes Yes 0 Yes 0 Yes No VOA vials sbmitted Adjsted? Yes 0 Yes 0 Yes 0 Yes 0 Yes 0 Yes 0 NoD NoD NoD NoD NoD No0 NoD NoD NoD NoD NoD NoD Checked by Yes 0 Not Presen D Not Presen 0 Not Presen 0 NoD Any No and/or NA (not applicable) response mst be detailed in the comments section be Client contacted Contacted by: Comments: Date contacted: Regarding: Person contacted Corrective Action r/y f ri <M niaow xhs Cjcre

10 GC/MS Volatiles pstate Laboratories, Inc. 164-

11 Qality Control Data pstate Laboratories, Inc. -16-

12 2A WATER VOLATILE SYSTEM MONITORING COMPOND RECOVERY Lab Name: pstate Labs Inc. Contract: CASELLA Lab Code: Case No.: SAS No. SDG No.: CAS EPA SAMPLE NO. VMBS01 " VBLK01 '" MW-28 ^ MW-29 MW-29 MS MW-29 MSD MW-Z I LI TRIP BLAN HOLDING BLAN SMC1 # _ _ SMC2 # ' "" SMC3 # TOT OT _o SMC1 SMC2 SMC3 1,2-Dichloroethane-d4 Tolene-d8 Bromoflorobenzene QC LIMITS (76-114) (88-110) (86-11) # Colmn to be sed to flag recovery vales * Vales otside of contract reqired QC limits D System Monitoring Compond dilted ot page 1 of 1 FORM II VOA-1 3/

13 3A WATER VOLATILE MATRIX SPIKE/MATRIX SPIKE DPLICATE RECOVERY Lab Name: pstate Labs Inc. Contract: CASELLA Lab Code: Case No.: Matrix Spike- EPA Sample No. MW-29 SAS No.: SDG No.: CAS120 COMPOND 1,1-Dichloroethene Benzene Trichloroethene Tolene Chlorobenzene ~'SPJKE" ADDED (g/l) 0 _ SAMPLE MS CONCENTRATION CONCENTRATION (g/l) (g/l) _ 6 7 MS % REC# 124 I?T QC LIMITS REC COMPOND 1,1-Dichloroethene Benzene Trichloroethene Tolene Chlorobenzene SPIKE ADDED (g/l) 0 0 *~ MSD CONCENTRATION (g/l) 62 MSD % REC# ^jy % RPD# QC LIMITS RPD REC n7t^ # Colmn to be sed to flag recovery and RPD vales with an asterisk * Vales otside of QC limits RPD: 0 ot of otside limits Spike Recovery; 0 ot of 10 otside limits COMMENTS: FORM III VOA /90

14 F:\DATA\C16272.D WATER VOLATILE MATRIX SPIKE BLANK RECOVERY Lab Name: pstate Labs Inc. Contract: Casella Lab c de: Case I SAS No.: SDGNo.:CAS120 Matrix Spike-EPA Sample No.: YBLK01 Level (low/med): Low COMPOND 1,1-Dichloroethene Benzene Trichloroethene Tolene Chlorobenzene SPIKE ADDED (g/l) SAMPLE CONCENTRATION (g/l) MS MS CONCENTRATIO % (g/l) REC QC LIMITS Page 1 of 1 VWMBS60.XLS /7/2009 3:7 PM

15 4A EPA SAMPLE NO. VOLATILE METHOD BLANK SMMARY Lab Name: pstate Labs Inc. Contract: CASELLA VBLK01 Lab Code: Case No.: SAS No.: SDG No.: CAS120 Lab File ID: C318.D Lab Sample ID: MB-474 Date Analyzed: 11/30/2009 Time Analyzed: 23:30 GC Colmn: RTX-VO ID: 0.3 (mm) Heated Prge: (Y/N) N Instrment ID: 12.0 THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS AND MSD: EPA SAMPLE NO. VMBS01 MW-28 MW HMW^IJMS 0 MW-29 MSD 06 MW-Z 0/ LI TRIP BLANK 08 HOLDING BLANK LAB SAMPLE ID LCS H H HMS HMSD H A A LAB FILE ID C3184.D C3186.D C3187.D C3188.D C3189.D C31860.D C31861.D C31862.D TIME ANALYZED 22:2 0:08 0:47 1:2 2:03 2:42 3:21 4:00 COMMENTS: page 1 of 1 FORM IV VOA /90

16 LabName: 1A VOLATILE ORGANICS ANALYSIS DATA SHEET pstate Labs Inc. Contract: CASELLA EPA SAMPLE NO. VBLK01 Lab Code: Case No.: SAS No.: SDG No.: CAS120 Matrix: (soil/water) WATER Lab Sample ID: MB-474 Sample wt/vol:.0 (g/ml) ML Lab File ID: C318.D Level: (low/med) LOW Date Received: 11 /24/2009 % Moistre: not dec. Date Analyzed: 11/30/2009 GC Colmn RTX-VO ID: 0.3 (mm) Diltion Factor: 1.0 Soil Extract Volme: (L) Soil Aliqot Volme: (L) CAS NO. COMPOND CONCENTRATION NITS: (g/l or g/kg) G/L Q Chloromethane Vinyl Chloride _Bromomethane _Chloroethane Trichlorofloromethane Acetone 1,1-Dichloroethene lodomethane Carbon Dislfide Methylene Chloride Acrylonitrile trans-1.2-dichloroethene 1,1-Dichloroethane Vinyl Acetate 2-Btanone cis-1,2-dichloroethene Chloroform Bromochloromethane 1,1,1-Trichloroethane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene 1,2-Dichloropropane Bromodichloromethane Dibromomethane 4-Methvl-2-pentanone^ cis-1,3-dichloropropene^ Tolene trans-1,3-dichloropropene 1,1,2-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene 1,1,1,2-Tetrachloroethane Ethyl benzene m,p-xylene FORM I VOA -nolo /90

17 LabName: 1A EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET VBLK01 pstatej-^bsjno Contract: CASELLA Lab Code: Case No.: SAS No.: SDG No.: CAS120 Matrix: (soil/water) WATER Lab Sample ID: MB-474 Sample wt/vol:,0 (g/ml) ML Lab File ID: C318.D Level: (low/med) LOW Date Received: 11/24/2009 % Moistre: not dec. Date Analyzed: 11/30/2009 GC Colmn: RTX-VO ID: 0.3 (mm) Diltion Factor: 1.0 Soil Extract Volme: (L) Soil Aliqot Volme: (L) CAS NO. COMPOND CONCENTRATION NITS: (g/l or g/kg) G/L Q & CKXyJene^ Styrene Bromoform 1,1,2,2-Tetrachloroethane 1,2,3-Trichloropropane 1,3-Dichlorobenzene 1,4-Dichlorobenzene JLJL-Dichlorobenzene 1,2-Dibromo-3-chloro-propane 10 AL FORM IVOA /90

18 Lab Name: 1E VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPONDS pstate Labs Inc. Lab Code: Case No.: Matrix: (soil/water) Sample wt/vol:.0 Level: (low/med) % Moistre: not dec. GC Colmn: Soil Extract Volme: WATER LOW (g/ml) ML RTX-VO ID: 0.3 (mm) (L) Contract: SAS No.: CASELLA EPA SAMPLE NO. VBLK01 SDG No.: CAS120 Lab Sample ID: MB-474 Lab File ID: C318.D Date Received: 11 /24/2009 Date Analyzed: 11/30/2009 Diltion Factor: 1.0 Soil Aliqot Volme: (L) Nmber TICs fond: CONCENTRATION NITS: (g/l or g/kg) G/L CAS NO. COMPOND NAME RT EST. CONC. Q FORM I VOA-TIC /90

19 Lab Name: Lab Code: Lab File ID: Instrment ID: A VOLATILE ORGANIC INSTRMENT PERFORMANCE CHECK BROMOFLOROBENZENE (BFB) pstate Labs Inc C31722.D 12.0 GC Colmn: RTX-VOLA ID: 0.3 (mm) Contract: CASELLA Case No.: SAS No.: SDG No.: CAS120 BFB Injection Date: 11/22/2009 BFB Injection Time: 14:8 Heated Prge: (Y/N) N m/e ION ABNDANCE CRITERIA % of mass % of mass 9 _ Base peak, % relative abndance".0-9.0% of mass 9 Less than 2.0% of mass 174 ~~ % of mass % of mass % of mass 174~ZZZZI.0-9.0% of mass Vale is % mass 174 2^Vaie ^mass 176 % RELATIVE ABNDANCE ( 0.0) ( 7.3) (.)1 4.6 ( 6.6)2 THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS: EPA SAMPLE NO. VSTD003 VSTD010 r~vstdi20 VSTD00 VSTD VSTD200 LAB SAMPLE ID ICAL PPB I ICAL PPB ICAL PPB ICAL PPB ICAL-2730 PPB ICAL PPB LAB FILE ID C31723.D C31724.D C3172.D C31726.D C31727.D C31728.D I DATE ANALYZED 11/22/ /22/2009^ 11/22/ /22/ /22/ /22/2009 TIME ANALYZED 1:36 16:1 16:3 17:32 18:11 18:49 page 1 of 1 FORM V VOA /90

20 A VOLATILE ORGANIC INSTRMENT PERFORMANCE CHECK BROMOFLOROBENZENE (BFB) Lab Name: pstate Labs Inc. Contract: CASELLA Lab Code: Case No. SAS No.: SDG No.: CAS120 Lab File ID: C3182.D BFB Injection Date: 11/30/2009 Instrment ID: 12.0 BFB Injection Time: 21:3 GC Colmn: RTX-VOLA ID: 0.3 (mm) Heated Prge: (Y/N) N m/e ION ABNDANCE CRITERIA % of mass % of mass 9 Base peak, % relative abndance.0-9.0% of mass 9 _ Less than 2.0% of mass % of mass 9 _^ % of mass % of mass % of mass Vale is % mass Vale is % mass 176 % RELATIVE ABNDANCE ( 0.0) ( 7.6) (.0)1.0 ( 6.)2 THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS: EPA SAMPLE NO. VSTD00CC01 VMBS01 VBLK01 MW-28 MW-29 MW-29 MS MW-29 MSD MW-Z LI TRIP BLANK HOLDING BLANK VSTD00CC02 LAB SAMPLE ID CCV-474 LCS-474 MB H H HMS HMSD H A A CCV LAB FILE ID C3183.D C3184.D C318.D C3186.D C3187.D C3188.D C3189.D C31860.D C31861.D C31862.D C31871.D DATE ANALYZED 11/30/ /30/ /30/ /1/ /1/ /1/ /1/ /1/ /1/ /1/ /1/2009 TIME ANALYZED 22:13 22:2 23:30 0:08 0:47 1:2 2:03 2:42 3:21 4:00 9:47 page 1 of 1 FORM V VOA /90

21 8A VOLATILE INTERNAL STANDARD AREA AND RT SMMARY LabName: pstate Labs Inc. Contract: CASELLA Lab Code Case No.: SAS No.: Lab File ID (Standard): Instrment ID: 12.0 C3183.D GC Colmn: RTX-VOLAT ID: 0.3 (mm) 12 HOR STD PPER LIMIT LOWER LIMIT EPA SAMPLE NO. VMBS01 VBLK01 MW-28 MW-29 MW-29 MS MW-29 MSD MW-Z LI TRIP BLANK HOLDING BLANK IS1(PFB) AREA # I RT # CD O CD CD CO OO IS2 AREA # ^ ^ SDG No.: CAS120 Date Analyzed: 11/30/2009 Time Analyzed: 22:13 Heated Prge (Y/N): RT # IS3 AREA # N RT # T (PFB) = Pentaflorobenzene 12 = 1,4-Diflorobenzene S3 = Chlorobenzene-d IS4 (DCB) = 1,4-Dichlorobenzene-d4 AREA PPER LIMIT = +% of internal standard area AREA LOWER LIMIT = - 0% of internal standard area RT PPER LIMIT = +0.0 mintes of internal standard RT RT LOWER LIMIT = -0.0 mintes of internal standard RT # Colmn to be sed to flag vales otside QC limit with an asterisk. * Vales otside of contract reqired QC limits page 1 of 2 FORM VIII VOA 3/90 17-

22 8A VOLATILE INTERNAL STANDARD AREA AND RT SMMARY Lab Name: pstate Labs Inc. Lab Code: Case No.: Lab File ID (Standard): C3183.D Instrment ID: 12.0 GC Colmn: RTX-VOLA ID: 0.3 (mm) Contract: CASELLA SAS No.: SDG No.: CAS120 Date Analyzed: 11/30/09 Time Analyzed: 22:13 Heated Prge (Y/N): Y HOR STD PPER LIMIT LOWER LIMIT EPA SAMPLE NO. VMBS01 VBLK01 MW-28 MW-29 MW-29 MS MW-29 MSD MW-Z LI TRIP BLA HOLDING BL IS4(DCB) AREA # RT # AREA # RT # AREA # RT # wmmammmmm ~"~* ~ ~*~~~~~* ' 11 (PFB) = Pentaflorobenzene 12 = 1,4-Diflorobenzene 'S3 = Chlorobenzene-d IS4 (DCB) = 1,4-Dichlorobenzene-d4 AREA PPER LIMIT = +% of internal standard area AREA LOWER LIMIT = - 0% of internal standard area RT PPER LIMIT = +0.0 mintes of internal standard RT RT LOWER LIMIT = -0.0 mintes of internal standard RT # Colmn to be sed to flag vales otside QC limit with an asterisk. * Vales otside of contract reqired QC limits page 2 of 2 FORM VIII VOA 3/

23 Sample Data pstate Laboratories, Inc

24 1A VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: pstate Labs Inc. Contract: CASELLA EPA SAMPLE NO. MW-28 Lab Code: Case No.: SAS No.: SDG No.: CAS120 Matrix: (soil/water) WATER Lab Sample ID: H Sample wt/vol:.0 (g/ml) ML Lab File ID: C3186.D Level: (low/med) LOW Date Received: 11 /24/2009 % Moistre: not dec. Date Analyzed: 12/1/2009 GC Colmn: RTX-VO ID: 0.3 (mm) Diltion Factor: 1.0 Soil Extract Volme: (L) Soil Aliqot Volme: (L) CAS NO. COMPOND CONCENTRATION NITS: (g/l or g/kg) G/L Q Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofloromethane Acetone 1,1-Dichloroethene lodomethane ^Carbon Dislfide Methylene Chloride Acrylonitrile trans-1,2-dichloroethene 1,1-Dichloroethane Vinyl Acetate 2-Btanone cis-1,2-dichloroethene Chloroform Bromochloromethane 1,1,1-Trichloroethane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene 1,2-Dichloropropane Bromodichloromethane Dibromomethane 4-Methyl-2-pentanone cis-1,3-dichloropropene Tolene trans-1,3-dichloropropene 1,1,2-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene 1,1,1,2-Tetrachloroethane Ethylbenzene m,p-xylene FORM IVOA /90

25 1A VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: pstate Labs Inc. Contract: CASELLA EPA SAMPLE NO. MW-28 Lab Code: Case No.: SAS No.: SDG No.: CAS120 Matrix: (soil/water) WATER Lab Sample ID: H Sample wt/vol:.0 (g/ml) ML Lab File ID: C3186.D Level: (low/med) LOW Date Received: 11/24/2009 % Moistre: not dec. _ Date Analyzed: 12/1/2009 GC Colmn: RTX-VO ID: 0.3 (mm) Diltion Factor: 1.0 Soil Extract Volme: (L) Soil Aliqot Volme: (L) CAS NO. COMPOND CONCENTRATION NITS: (g/l or g/kg) G/L Q o-xylene Styrene Bromoform 1,1,2,2-Tetrachloroethane 1,2,3-Trichloropropane jl3-dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-chloro-propane 10 FORM IVOA /90

26 1E VOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. TENTATIVELY IDENTIFIED COMPONDS Lab Name: pstate Labs Inc. Contract: CASELLA MW-28 Lab Code: Case No.: SAS No.: SDG No.: CAS120 Matrix: (soil/water) WATER Lab Sample ID: H Sample wt/vol: JQ (g/ml) ML Lab File ID: C3186.D Level: (low/med) LOW Date Received: 11 /24/2009 % Moistre: not dec. Date Analyzed: 12/1/2009 GC Colmn: RTX-VO ID: 0.3 (mm) Diltion Factor: 1.0 Soil Extract Volme: (L) Soil Aliqot Volme: (L) Nmber TICs fond: CONCENTRATION NITS: (g/l or g/kg) G/L CAS NO. COMPOND NAME RT EST. CONC. Q FORM I VOA-TIC /90

27 Qantitation Report (QT Reviewed) Data File : D:\DATA\C3186.D Vial: 23 Acq On : l Dec :08 am Operator: LEF Sample : H - *J.J,htJ v_ * #12 Misc : 8260ASP_A1_W, SAMP, ml, Casella,MW-28 Mltiplr: 1.00 MS Integration Params: rteint.p Qant Time: Dec 2 10: Qant Reslts File: ASP1122W.RES Qant Method Title Last pdate Response via DataAcq Meth D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Initial Calibration ASP1122W Internal Standards R.T. Qlon Response Cone nits Dev(Min) 1) Pentaflorobenzene 39) 1,4-Diflorobenzene 1) Chlorobenzene-d 67) 1,4-Dichlorobenzene-d4 System Monitoring Componds 34) l,2-dichloroethane-d4 Spiked Amont ) Tolene-d8 Spiked Amont ) Bromoflorobenzene Spiked Amont Target Componds Range Range Range g/l 0.00 g/l 0.00 g/l 0.00 g/l g/l Recovery = 93.08% g/l Recovery =.08% g/l Recovery =.86% Qvale (#) = qalifier ot of range (m) = manal integration C3186.D ASP1122W.M Wed Dec 02 10:: Page 1

28 Data File Acq On Sample Misc D:\DATA\C3186.D 1 Dec :08 am H 8260ASP_A1_W,SAMP,ml,Casella,MW-28 MS Integration Params: rteint.p Qant Time: Dec 2 10: Method Title Last pdate Response via shonaaf ; D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Initial Calibration Qantitation Report Vial: Operator: Inst : Mltiplr: 23 LEF # Qant Reslts File: ASP1122W.RES TIC:C3186.D ; 0000 I CO NJ I ; JL_ -- - ~ 3 ' 00 M m "^ M^«^^ C3186.D ASP1122W.M Wed Dec 02 10:: "" ~" " Page 2

29 LSC Report - Integrated Chromatogram File Operator Acqired Instrment Sample Name Misc Info Vial Nmber Qant File : D:\DATA\C3186.D LEF 1 Dec :08 am sing AcqMethod ASP1122W # H 8260ASP_A1_W,SAMP,ml-Casella,MW ASP1122W.RES (RTE Integrator) TIC:C3186.D ^ MQ 4,0,00,0 6,00 6,0 7, ' lb.00 lasotioolv^ ^ 0 : : TIC:C3186.D " " " {. -"H 1 " '" jsnnirlaiv 0000 J2_ ,0 14,00 1.4, ,0,1,6,00 1.6,0 17'oO 17!0 18!oO TIC:C3186.D 24 24,23 \& ,00 19, cffis^if ^ 1? ^ ^ 23 - %l%i 4 c l 00 0: 2? : : ^ !00 ^ 2 2-3o!o

30 1A VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: pstate Labs Inc. Contract: CASELLA EPA SAMPLE NO. MW-29 Lab Code: Case No.: SAS No.: SDC 3 No.: CAS120 Mat rix: (soil/water) WATER Lab Sample ID: LJ H San iple wt/vol:.0 (g/ml) ML Lab File ID: D Lev el: (low/med) %l\/ loistre: not dec. LOW Date Received: 1 1/24/2009 Date Analvzed: V 2/1/2009 GC Colmn: RTX-VO ID: 0.3 (mm) Diltion Factor: 1.0 Soil Extract Volme: (L) Soil Aliqot Volme: ( L CONCENTRATION NITS: CAS NO. COMPOND (g/l or g/kg) G/L Q Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofloromethane Acetone 1,1-Dichloroethene lodomethane Carbon Dislfide Methylene Chloride Acrylonitrile trans-1,2-dichloroethene 1,1-Dichloroethane Vinyl Acetate 2-Btanone cis-1,2-dichloroethene Chloroform Bromochloromethane 1,1,1-Trichloroethane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene 1,2-DichlororjroDane Bromodichloromethane Dibromomethane 4-Methvl-2-oentanone cis-1,3-dichloropropene Tolene trans-1,3-dichloropropene 1,1,2-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene 1,1,1,2-Tetrachloroethane Ethylbenzene m,p-xylene FORM IVOA /90

31 Lab Name: 1A EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET MW-29 pstate Labs Inc. Contract: CASELLA Lab Code: Case No.: SAS No.: SDG No.: CAS120 Matrix: (soil/water) WATER Lab Sample ID: H Sample wt/vol:.0 (g/ml) ML Lab File ID: C3187.D Level: (low/med) LOW Date Received: 11 /24/2009 % Moistre: not dec. Date Analyzed: 12/1/2009 GC Colmn: RTX-VO ID: 0.3 (mm) Diltion Factor: 1.0 Soil Extract Volme: (L) Soil Aliqot Volme: (L) CAS NO. COMPOND CONCENTRATION NITS: (g/l or g/kg) G/L Q o-xylene Styrene Bromoform 1,1,2,2-Tetrachloroethane 1,2,3-Trichloropropane^ J,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-chloro-propane 10 AL FORM I VOA -18-3/90

32 Lab Name: Lab Code: 1E VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPONDS pstate Labs Inc Matrix: (soil/water) Sample wt/vol:,0 Level: (low/med) WATER LOW % Moistre: not dec. GC Colmn: Soil Extract Volme: Contract: CASELLA EPA SAMPLE NO. MW-29 Case No.: SAS No.: SDG No.: CAS120 (g/ml) ML RTX-VO ID: 0.3 (mm) (L) Lab Sample ID: H Lab File ID: C3187.D Date Received: 11 /24/2009 Date Analyzed: 12/1/2009 Diltion Factor: 1.0 Soil Aliqot Volme: (L) Nmber TICs fond: CONCENTRATION NITS: (g/l or g/kg) G/L CAS NO. COMPOND NAME RT EST. CONC. Q FORM I VOA-TIC /90

33 Data File Acq On Sample Misc Qantitation Report D:\DATA\C3187.D 1 Dec :47 am H 8260ASP_A1_W,SAMP,ml,Casella,MW-29 MS Integration Params: rteint.p Qant Time: Dec 2 10: 2009 Qant Method Title Last pdate Response via DataAcq Meth Internal Standards D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Initial Calibration ASP1122W 1) Pentaflorobenzene 39) 1,4-Diflorobenzene 1) Chlorobenzene-d 67) l,4-dichlorobenzene-d4 System Monitoring Componds 34) l,2-dichloroethane-d4 Spiked Amont ) Tolene-d8 Spiked Amont ) Bromoflorobenzene Spiked Amont Target Componds (QT Reviewed) Vial: 24 Operator: LEF Inst : #12 Mltiplr: 1.00 Qant Reslts File: ASP1122W.RES R.T. Qlon Response Cone nits Dev(Min) Range Range Range g/l 0.00 g/l 0.00 g/l 0.00 g/l g/l Recovery = 92.70% g/l Recovery =.2 6% g/l Recovery = 97.% Qvale (#) = qalifier ot of range (m) = manal integration C3187.D ASP1122W.M Wed Dec 02 10:: Page 1

34 Data File Acq On Sample D:\DATA\C3187.D 1 Dec :47 am H 8260ASP_A1_W,SAMP,ml,Casella,MW-29 Misc MS Integration Params: rteint.p Qant Time: Dec 2 10: Method Title Last pdate Response via ihorksance! D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Initial Calibration Qantitation Report Vial: Operator: Inst : Mltiplr: 24 LEF # Qant Reslts File: ASP1122W.RES flcrc3187.d^ OO DO i l * J- -* :: ' *"--" 400 M «8 -*" - IMP.lis,,s:..»:», :.. J6 :o.!7:o,,.lo,,a.»_»,,# «a -^, 1 ^,, 2,!o a ^ w»' C3187.D ASP1122W.M Wed Dec 02 10:: Page 2

35 LSC Report - Integrated Chromatogra m Pile : D:\DATA\C3187.D Operator : LEF Acqired : l Dec :47 am sing AcqMethod ASP1122W Instrment : #12 Sample Name: H Misc Info : 8260ASP_A1_W,SAMP,ml,Casella,MW-29 Vial Nmber: 24 Qant File :ASP1122W.RES (RTE Integrator) Abndance TIC: C3187.D l " " l ' r 7 * I" 1 1! MO 4,0_,00,0 6,00 6,0 7! bo_7jo_8 : 00.'.'8.3o' ' 9.00 g.r ' '-'-'-' ' > " " ' " ' 0 10,00 10,0 11, Tim* elfish 0 a&s&sf^ss -189-

36 LabName: Lab Code: Matrix: (soil/water) Sample wt/vol:.0 Level: (low/med) % Moistre: not dec. GC Colmn: Soil Extract Volme: 1A VOLATILE ORGANICS ANALYSIS DATA SHEET pstate Labs Inc. Contract: CASELLA WATER LOW Case No.: (g/ml) ML RTX-VO ID: 0.3 (mm) (L) SAS No.: EPA SAMPLE NO. MW-Z SDG No.: CAS120 Lab Sample ID: H Lab File ID: C31860.D Date Received: 11 /24/2009 Date Analyzed: 12/1/2009 Diltion Factor: 1.0 Soil Aliqot Volme: (L) CAS NO. COMPOND CONCENTRATION NITS: (g/l or g/kg) G/L Q Chloromethane J/JOYLChloride^ Bromomethane Chloroethane Trichlorofloromethane Acetone 1,1-Dichloroethene Jodomethane Carbon Dislfide Methylene Chloride Acrylonitrile trans-1,2-dichloroethene 1,1-Dichloroethane Vinyl Acetate 2-Btanone cis-1,2-dichloroethene Chloroform Bromochloromethane 1,1,1-Trichloroethane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene 1,2-Dichloropropane Bromodichloromethane Dibromomethane 4-Methvl-2-pentanone cis-1,3-dichlorodropene Tolene trans-1,3-dichloropropene 1,1,2-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene 1,1,1,2-Tetrachloroethane Ethylbenzene m,p-xylene FORM IVOA AL 3/90

37 LabName: 1A EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET MW-Z EgJate Labs Inc. Contract: CASELLA Lab Code: Case No.: SAS No.: SDG No.: CAS120 Matrix: (soil/water) WATER Lab Sample ID: H Sample wt/vol:,0 (g/ml) ML Lab File ID: C31860.D Level: (low/med) LOW Date Received: 11 /24/2009 % Moistre: not dec. Date Analyzed: 12/1/2009 GC Colmn RTX-VO ID: 0.3 (mm) Diltion Factor: 1.0 Soil Extract Volme: (L) Soil Aliqot Volme: (L) CAS NO. COMPOND CONCENTRATION NITS: (g/l or g/kg) G/L Q l o-xylene Styrene Bromoform 1,1,2,2-Tetrachloroethane 1,2,3-Trichloropropane 1,3-Dichlorobenzene 1,4-Dichlorobenzene_ 1,2-Dichlorobenzene _1 J 2j3ibromo-3-chloro-propane_ 10 AL AL FORM IVOA -1-3/90

38 Lab Name: 1E VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPONDS pstate Labs Inc. Lab Code: Case No.: Matrix: (soil/water) Sample wt/vol: Level: (low/med) % Moistre: not dec. WATER GC Colmn: RTX-VO ID: 0.3 Soil Extract Volme:.0 LOW (g/ml) ML (L) (mm) Contract: SAS No.: CASELLA EPA SAMPLE NO. MW-Z SDG No.: CAS120 Lab Sample ID: H Lab File ID: C31860.D Date Received: 11/24/2009 Date Analyzed: 12/1/2009 Diltion Factor: 1.0 Soil Aliqot Volme: (L) Nmber TICs fond: CONCENTRATION NITS: (g/l or g/kg) G/L CAS NO. COMPOND NAME RT EST. CONC. Q FORM I VOA-TIC /90

39 Data File Acq On Sample Misc Qantitation Report D:\DATA\C31860.D 1 Dec :42 am H 8260ASP_A1_W,SAMP,Sml,Casella,MW-Z MS Integration Params: rteint.p Qant Time: Dec 2 11: Qant Method Title Last pdate Response via DataAcq Meth D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Initial Calibration ASP1122W (QT Reviewed) Vial: Operator: Inst : Mltiplr: 26 LEF # Qant Reslts File: ASP1122W.RES Internal Standards R.T. Qlon Response Cone nits Dev(Min) 1) Pentaflorobenzene 39) 1,4-Diflorobenzene 1) Chlorobenzene-d 67) l,4-dichlorobenzene-d4 System Monitoring Componds 34) 1,2-Dichloroethane-d4 Spiked Amont ) Tolene-d8 Spiked Amont ) Bromoflorobenzene Spiked Amont Target Componds Range Range Range g/l 0.00 g/l 0.00 g/l 0.00 g/l g/l Recovery = 93.28% g/l Recovery =.44% g/l Recovery =.2 6% Qvale (#) = qalifier ot of range (m) = manal integration C31860.D ASP1122W.M Wed Dec 02 11:12: Page 1

40 Qantitation Report Data File : D:\DATA\C31860.D Vial: 26 Acq On : 1 Dec :42 am Operator: LEF Sample : H Inst : #12 Misc : 8260ASP_A1_W,SAMP,ml,Casella,MW-Z Mltiplr: 1.00 MS Integration Params: rteint.p Qant Time: Dec 2 11: Qant Reslts File: ASP1122W.RES Method Title Last pdate Response via SAbn> ce D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Initial Calibration TIC: C31860.D CO 4_» I im,..3,bo;.,.4,bo L. C31860.D ASP1122W.M Wed Dec 02 11:12: Page 2

41 LSC Report - Integrated Chromatogra m File : D:\DATA\C31860.D Operator : LEF Acqired : 1 Dec :42 am sing AcqMethod ASP1122W Instrment : #12 Sample Name: H Misc Info : 8260ASP_A1_W,SAMP,ml,Casella,MW-Z Vial Nmber: 2 6 Qant File :ASP1122W.RES (RTE Integrator) TIC: C31860.D II...2 l""l l Mll l 1 ' I ' ' ' ' I -3^9 42Q i0.,00,.0 6,0.0 6, o' flc:c31860'.d '' " ' mri :± Abndanco < I I I I I I I I I I 'l M I II I I "l V"T'7 I I I I j I I ,00 13,0 14,00 14,0... 1, ,0 16,00 16, ,0 1&00 18!0 moo lb! 0 20, TIC: C31860.D 2308 I I I I I I I I I 'l I I 1 I I I I I I I I I r IL C3T i 2 s 0 BlSw 23 M 00 ^MW% M^02^2i^!Kl^oS 60 ^ ^ ""* *<» ^ -19-

42 1A VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: pstate Labs Inc. Contract: CASELLA EPA SAMPLE NO. LI Trip Blank Lab Code: Case No.: SAS No.: SDG No.: CAS120 Matrix: (soil/water) WATER Sample wt/vol:.0 (g/ml) ML Level: (low/med) LOW % Moistre: not dec. GC Colmn: RTX-VO ID: 0.3 (mm) Soil Extract Volme: (L) Lab Sample ID: A Lab File ID: C31861.D Date Received: 11 /24/2009 Date Analyzed: 12/1/2009 Diltion Factor: 1.0 Soil Aliqot Volme: (L) CAS NO. COMPOND CONCENTRATION NITS: (g/l or g/kg) G/L Q Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofloromethane Acetone 1,1-Dichloroethene lodomethane Carbon Dislfide Methylene Chloride Acrylonitrile trans-1,2-dichloroethene 1,1-Dichloroethane Vinyl Acetate 2-Btanone cis-1,2-dichloroethene Chloroform Bromochloromethane 1,1,1-Trichloroethane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene 1,2-Dichloropropane Bromodichloromethane Dibromomethane 4-Methyl-2-pentanone cis-1,3-dichloroprodene Tolene trans-1,3-dichloropropene 1,1,2-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene 1,1,1,2-Tetrachloroethane Ethyl benzene m,p-xylene FORM IVOA -1-3/90

43 1A VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: pstate Labs Inc. Contract: CASELLA Lab Code: Matrix: (soil/water) Sample wt/vol:.0 Level: (low/med) % Moistre: not dec. GC Colmn: Soil Extract Volme: WATER LOW Case No.: (g/ml) ML_ RTX-VO ID: 0.3 (mm) (L) SAS No.: EPA SAMPLE NO. LI Trip Blank SDG No.: CAS120 Lab Sample ID: A Lab File ID: C31861.D Date Received: 11 /24/2009 Date Analyzed: 12/1/2009 Diltion Factor: 1.0 Soil Aliqot Volme: (L) CAS NO COMPOND CONCENTRATION NITS: (g/l or g/kg) G/L o-xylene Styrene Bromoform 1,1,2,2-Tetrachloroethane 1,2,3-Trichloropropane JL3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-chloro-propane 10 Q FORM IVOA /90

44 Lab Name: 1E VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPONDS pstate Labs Inc. Lab Code: Case No.: Matrix: (soil/water) Sample wt/vol:.0 Level: (low/med) % Moistre: not dec. GC Colmn: Soil Extract Volme: WATER LOW (g/ml) ML RTX-VO ID: 0.3 (mm) (L) Contract: SAS No.: CASELLA EPA SAMPLE NO. LI Trip Blank SDG No.: CAS120 Lab Sample ID: A Lab File ID: C31861.D Date Received: 11 /24/2009 Date Analyzed: 12/1/2009 Diltion Factor: 1.0 Soil Aliqot Volme: (L) Nmber TICs fond: CONCENTRATION NITS: (g/l or g/kg) G/L CAS NO. COMPOND NAME RT EST. CONC. Q FORM I VOA-TIC -1-3/90

45 Qantitation Report (QT Reviewed) Data File : D:\DATA\C31861.D Vial: 27 Acq On : 1 Dec :21 am Operator: LEF Sample : A Inst : #12 Misc : 8260ASP_A1 W, SAMP, ml, Casella,TB Mltiplr: 1.00 MS Integration Params: rteint.p Qant Time: Dec 2 11: Qant Reslts File: ASP1122W.RES Qant Method Last pdate Response via DataAcq Meth D:\METHODS\ASP1122W.M RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Initial Calibration ASP1122W Internal Standards 1) Pentaflorobenzene 39) 1,4-Diflorobenzene 1) Chlorobenzene-d 67) l,4-dichlorobenzene-d4 System Monitoring Componds 34) l,2-dichloroethane-d4 Spiked Amont ) Tolene-d8 Spiked Amont ) Bromoflorobenzene Spiked Amont Target Componds R.T. Qlon Response Cone nits Dev(Min) Range Range Range g/l 0.00 g/l 0.00 g/l 0.00 g/l g/l Recovery = 92.4% g/l Recovery =.2% g/l Recovery =.94% Qvale (#) = qalifier ot of range (m) = manal integration C31861.D ASP1122W.M Wed Dec 02 11:12: Page 1

46 Qantitation Report Data File : D:\DATA\C31861.D Vial: 27 Acq On : l Dec :21 am Operator: LEF Sample : A Inst : #12 Misc : 8260ASP_A1_W,SAMP,ml,Casella,TB Mltiplr: MS Integration Params: rteint.p Qant Time: Dec 2 11: Qant Reslts File: ASP1122W.RES Method Title Last pdate Response via iahndarkx: D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Initial Calibration.. j I N CD o I CIS i MmB:± 2M " 00 ^ 6- T T *-_ V V 7 - a 9 - " ^ C31861.D ASP1122W.M Wed Dec 02 11:12: " ~ _ " Page 2

47 LSC Report - Integrated Chromatogram File : D:\DATA\C31861.D Operator : LEF Acqired : l Dec :21 am sing AcqMethod ASP1122W Instrment : #12 Sample Name: A Misc Info : 8260ASP A1 W, SAMP, ml, Casella, TB Vial Nmber: 27 Qant File :ASP1122W.RES (RTE Integrator) labnclan* TIC: C31861.D ^ 0 ' I ' ' ' ' 1 M I ' ' I I I I I I I I I! I I I ' I I" I j ~ ± ^0,00,0 6,00 6,0 7,00 7, i TIC:C31861.D " " ~ : - " f ^ I I I,, ; 1 1 I , OP. _ ,00,1.4,0... 1,00 1.,0,1,6,00 1.6, &00 Vaiso' l&oo l&so VoIoO TO 22] 09 24, J L msel^ ^i?i^^00 '^^w^ii^ffi^ii 6^^0 27: 28: 28: 29: 29!so 3 : -201

48 Lab Name: pstate Labs Inc. Lab Code: Case No.: Matrix: (soil/water) Sample wt/vol:.0 Level: (low/med) % Moistre: not dec. GC Colmn: Soil Extract Volme: 1A VOLATILE ORGANICS ANALYSIS DATA SHEET WATER LOW (g/ml) ML RTX-VO ID: 0.3 (mm) (L) Contract: SAS No.: CASELLA EPA SAMPLE NO. Holding Blank SDG No.: CAS120 Lab Sample ID: A Lab File ID: Date Received: Date Analyzed Diltion Factor C31862.D 11/24/ /1/ Soil Aliqot Volme: (L) CAS NO. COMPOND CONCENTRATION NITS: (g/l or g/kg) G/L Chloromethane Vinyl Chloride Bromomethane. Chloroethane ^Tlicfeoflorgrnethane Acetone 1,1-Dichloroethene lodomethane Carbon Dislfide Methylene Chloride Acrylonitrile trans-1,2-dichloroethene 1,1-Dichloroethane Vinyl Acetate 2-Btanone cis-1,2-dichloroethene Chloroform Bromochloromethane 1,1,1-Trichloroethane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene 1,2-Dichloropropane Bromodichloromethane Dibromomethane 4-Methyl-2-pentanone cis-1,3-dichloropropene Tolene trans-1,3-dichloropropene_ 1,1,2-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene.1,1,1,2-Tetrachloroethane Ethylbenzene m,p-xylene FORM IVOA jy_ AL 3/90

49 Lab Name: 1A EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET Holding Blank fistatelabsjno Contract: CASELLA Lab Code: Case No.: SAS No.: SDG No.: CAS120 Matrix: (soil/water) WATER Lab Sample ID: A Sample wt/vol:.0 (g/ml) ML Lab File ID: C31862.D Level: (low/med) LOW Date Received: 11/24/2009 % Moistre: not dec. Date Analyzed: 12/1/2009 GC Colmn: RTX-VO ID: 0.3 (mm) Diltion Factor: 1.0 Soil Extract Volme: (L) Soil Aliqot Volme: (L) CAS NO. COMPOND CONCENTRATION NITS: (g/l or g/kg) G/L Q ^42^ o-xylene Styrene Bromoform.1,1,2,2-Tetrachloroethane 1,2,3-Trichloropropane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-chloro-propane_ 10 FORM IVOA /90

50 Lab Name: Lab Code: Matrix: (soil/water) Sample wt/vol: Level: (low/med) % Moistre: not dec. 1E VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPONDS pstate Labs Inc. WATER.0 LOW GC Colmn: RTX-VO ID: 0.3 Soil Extract Volme: Case No.: (g/ml) ML (L) (mm) Contract: SAS No.: CASELLA EPA SAMPLE NO. Holding Blank SDG No.: CAS120 Lab Sample ID: A Lab File ID: C31862.D Date Received: 11/24/2009 Date Analyzed: 12/1/2009 Diltion Factor: 1.0 Soil Aliqot Volme: (L) Nmber TICs fond: 0 CONCENTRATION NITS: (g/l or g/kg) G/L CAS NO. COMPOND NAME RT EST. CONC. Q FORM I VOA-TIC /90

51 Data File Acq On Sample Qantitation Report D:\DATA\C31862.D 1 Dec :00 am A 8260ASP_A1_W,SAMP,ml,Casella,HB Misc MS Integration Params: rteint.p Qant Time: Dec 2 11: Qant Method Title Last pdate Response via DataAcq Meth D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Initial Calibration ASP1122W (QT Reviewed) Vial: 28 Operator: LEF Inst : #12 Mltiplr: 1.00 Qant Reslts File: ASP1122W.RES Internal Standards R.T. Qlon Response Cone nits Dev(Min) 1) Pentaflorobenzene 39) 1,4-Diflorobenzene 1) Chlorobenzene-d 67) 1,4-Dichlorobenzene-d4 System Monitoring Componds 34) 1,2-Dichloroethane-d4 Spiked Amont ) Tolene-d8 Spiked Amont ) Bromoflorobenzene Spiked Amont Target Componds Range Range 22 Range g/l 0.00 g/l 0.00 g/l 0.00 g/l g/l Recovery =.72% g/l Recovery =.26% g/l Recovery =.26% Qvale (#) = qalifier ot of range (m) = manal integration C31862.D ASP1122W.M Wed Dec 02 11:12: Page 1

52 Data File Acq On Sample D:\DATA\C31862.D 1 Dec :00 am A 8260ASP_A1_W,SAMP,ml,Casella,HB Misc MS Integration Params: rteint.p Qant Time: Dec 2 11: Method Title Last pdate Response via D:\METH0DS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Initial Calibration Qantitation Report Vial: Operator: Inst : Mltiplr: 28 LEF # Qant Reslts File: ASP1122W.RES TIC: C31862LD' I NJ O ten Jv L ~- ~ M 4M - a ^8-0 ^00.10, , ^. S M S S 20^0 iilw S S S ^ S S S S ^ S S I ^ ' C31862.D ASP1122W.M Wed Dec 02 11:12: Page 2

53 LSC Report - Integrated Chromatogram Operator Acqired Instrment Sample Name Misc Info Vial Nmber Qant File 0000 D:\DATA\C31862.D LEF 1 Dec :00 am sing AcqMethod ASP1122W A 8260ASP A1_W, SAMP, ml, Casella, HB 28 ASP1122W.RES (RTE Integrator) TIC:C31862.D MO 3,0 4,bg.'..,j,^ '' 8^0'' a' 0 TIC: C31862.D 9,00 9, ,00 10, ( i -S,j~& l" 1 '^!'* l?=- 1.3,00,.13,0 1.4,00 1.4,0 1.00_ is'oo 18.0 YfcOO AOIK.ailCf TIC:C31862.D -fir.'- OTiQoo n " ' o cffie^if fs kl ^23 M wld%i^ffi:^2f :^^0 27! M ^0 2 9 : 00 s^o 3o!oO -20'7-

54 Standards Data pstate Laboratories, Inc

55 Initial Calibration pstate Laboratories, Inc

56 Lab Name: pstate Labs Inc. Lab Code: Case No.: Instrment ID: 12.0 Heated Prge (Y/N): GC Colmn: RTX-VOLA ID: 0.3 N 6A VOLATILE ORGANICS INITIAL CALIBRATION DATA Contract: CASELLA SAS No.: Calibration Date(s): Calibration Times: (mm) SDG No.: CAS120 11/22/2009 1:36 11/22/ :49 LAB FILE ID: RRF20 = C3172. D RRF03 RRF0 = C31723.D = C31726.D RRF10 = C31724.D RRF = C31727.D RRF200 = C31728.D COMPOND Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofloromethane Acetone 1,1-Dichloroethene lodomethane Carbon Dislfide Methylene Chloride^ Acrylonitrile trans-1,2-dichloroethene 1,1-Dichloroethane Vinyl Acetate 2-Btanone cis-1,2-dichloroethene Chloroform Bromochloromethane 1,1,1-Trichloroethane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene 1,2-Dichloropropane Bromodichloromethane Dibromomethane 4-Methvl-2-pentanone cis-1,3-dichlorodrodene Tolene trans-1,3-dichloropropene 1,1,2-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene 1,1,1,2-Tetrachloroethane Ethylbenzene m.p-xylene RRF RRF QJ3J RRF RRF : RRF RRF I RRF % RSD J 3^ LL Componds with reqired minimm RRF and maximm %RSD vales. All other componds mst meet a minimm RRF of FORM VI VOA /90

57 6A VOLATILE ORGANICS INITIAL CALIBRATION DATA Lab Name: pstate Labs Inc Contract: CASELLA Lab Code: Case No. SAS No.: SDG No.: CAS120 Instrment ID: 12.0 Calibration Date(s): 11/22/ /22/2009 Heated Prge (Y/N): N Calibration Times: 1:36 18:49 GC Colmn: RTX-VOLA ID: 0.3 (mm) LAB FILE ID: RRF20 =C3172.D RRF03 RRF0 = C31723.D = C31726.D RRF10 = C31724.D RRF = C31727.D RRF200 = C31728.D COMPOND,o-Xylene Styrene Bromoform ldl2,2-tetrachloroethane 1,2,3-TrichloroDroDane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-chloro-propane 1,2-Dichloroethane-d4 Tolene-d8 Bromoflorobenzene RRF RRF RRF RRF RRF RRF RRF % RSD : Componds with reqired minimm RRF and maximm %RSD vales. All other componds mst meet a minimm RRF of FORM VI VOA /90

58 Response Factor Report #12 Method : D:\METHODS\ASP1122W.M (RTE Integrator) J-ltle : VOA Calibration Last pdate : Mon Nov 23 14:3: Response via : Initial Calibration Calibration Piles 03 =C31723.D 10 =C31724.D 20 =C3172.D 0 =C31726.D =C31727.D 200 =C31728.D Compond Avg %RSD 1) I 2) T 3) T 4) TC ) T 6) T 7) T 8) T 9) T 10) T 11) TC 12) T 13) 14) T 1) T 16) T 17) T 18) T 19) T 20) T 21) T 22) T 23) T 24) T 2) T 26) T 27) T 28) T 29) T 3 0) TC 31) T 32) T 33) T 34) S 3) T 36) T 37) T 38) T 39) I 40) T 41) T 42) TC 43) T 44) T 4) T 46) T 47) T 48) T 49) T 0) S 1) I Pentafliinrnhpn7ono Dichlorodifloromet n ^HR Chloromethane Vinyl Chloride Bromomethane Chioroethane ninfi Trichloroflorometh Acrolein # Acetone # 1,l,2-Trichloro-l,2! ,1-Dichloroethene Acetonitrile t-btanol Iodomethane Methyl acetate Allyl Chloride Carbon Dislfide Methylene Chloride MTBE Acrylonitrile trans-1,2-dichloroe 1,1-Dichloroethane Vinyl Acetate Chloroprene 2-Btanone Propionitrile 2,2-Dichloropropane cis-1,2-dichloroeth Methacrylonitrile Chloroform Bromochloromethane Isobtyl Alcohol Cyclohexane 1,2-Dichloroethane- 1,1,1-Trichloroetha 1,1-Dichloropropene Carbon Tetrachlorid Benzene 1,4-Diflorobenzene 1,2-Dichloroethane Trichloroethene 1,2-Dichloropropane Me thy1eye1ohexane Methyl Methacrylate Bromodichloromethan Dibromomethane 1,4-Dioxane 4-Methyl-2-pentanon cis-1,3-dichloropro Tolene-d8 Chlorobenzene-d # # # # # : #) = Ot : of Range ASP1122W.M Mon Nov 23 14:3: Page 1

59 2) TC 3) T 4) T ) T 6) S 7) T 8) T 9) T 60) T 61) T 62) T 63) T 64) TC 6) T 66) T 67) I 68) T 69) T 70) T 71) T 72) T 73) T 74) 7) 76) 77) 78) 79) 80) 81) 82) T 83) T 84) T 8) T 86) T 87) T Method Title Last pdate Response via Calibration Files 03 =C31723.D 0 =C31726.D T T T T T T T T Compond Response Factor Report #12 : D:\METH0DS\ASP1122W.M (RTE Integrator) : VOA 8260 Calibration : Mon Nov 23 14:3: : Initial Calibration Tolene trans-1,3-dichlorop Ethyl Methacrylate ,1,2-Trichloroetha 0.32 Bromoflorobenzene Hexanone ,3-Dichloropropane 0.0 Tetrachloroethene Dibromochloromethan ,2-Dibromoethane Chlorobenzene ,1,1,2-Tetrachloro Ethylbenzene m,p-xylene o-xylene ,4-Dichlorobenzene Styrene Bromoform IsopropyIbenzene 1,1,2,2-Tetrachloro 1,2,3-Trichloroprop trans-1,4-dichloron-propylbenzene 1,3,-Trimethylbenz tert-btylbenzene 1,2,4-Trimethylbenz sec-btylbenzene 1,3-Dichlorobenzene 4 -isopropyltolene 1,4-Dichlorobenzene n-btylbenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-chlor 1,2,4-trichlorobenz Naphthalene 1,2,3-Trichlorobenz =C31724.D =C31727.D =C3172.D =C31728.D Avg %RSD d ISTD Q , , (#) = Ot of Range ASP1122W.M Mon Nov 23 14:3: Page 2

60 Data Pile Acq On Sample Misc Qantitation Report D:\DATA\C31723.D 22 Nov :36 pm ICAL ppb 8260ASP A2 W, ICAL, ml, VB l MS Integration Params: rteint.p Qant Time: Nov 23 14: Qant Method Last pdate Response via DataAcq Meth D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 16 08:6: Initial Calibration ASP1122W (QT Reviewed) Vial Operator Inst Mltiplr 3 LEF 1.00 Qant Reslts File: ASP1122W.RES Internal Standards R.T. Qlon Response Cone nits Dev(Min) 1) Pentaflorobenzene 39) 1,4-Diflorobenzene 1) Chlorobenzene-d 67) l,4-dichlorobenzene-d4 System Monitoring Componds 34) l,2-dichloroethane-d4 Spiked Amont ) Tolene-d8 Spiked Amont ) Bromoflorobenzene Spiked Amont Range Range Range 86 Target Componds 2) Dichlorodifloromethane 2. 3) Chloromethane 3, 20 4) Vinyl Chloride 3^ 31 ) Bromomethane ) Chloroethane ) Trichlorofloromethane ) Acrolein ) Acetone ) l,l,2-trichloro-l,2,2-trif ) 1,1-Dichloroethene.08 12) Acetonitrile ) t-btanol.26 14) Iodomethane.4 1) Methyl acetate ) Allyl Chloride.64 17) Carbon Dislfide.78 18) Methylene Chloride.78 19) MTBE ) Acrylonitrile.92 21) trans-1,2-dichloroethene ) 1,1-Dichloroethane ) Vinyl Acetate ) Chloroprene ) 2-Btanone ) Propionitrile ) 2,2-Dichloropropane ) cis-1,2-dichloroethene ) Methacrylonitrile ) Chloroform ) Bromochloromethane ) Isobtyl Alcohol ) Cyclohexane ) 1,1,1-Trichloroethane ) 1,1-Dichloropropene ) Carbon Tetrachloride ) Benzene ) 1,2-Dichloroethane g/l g/l g/l g/l g/l 0.03 Recovery = 79.02% g/l Recovery = 9.% g/l Recovery = 90.06% m -T A 3m g/l 3.46 g/l 3.31 g/l 2.6 g/l 3.46 g/l 2.14 g/l 12.7 g/l m if m 462m m * , 22m T g/l.34 g/l. g/l.24 g/l.06 g/l g/l g/l 2..4 g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l 3. 0 g/l 2. 7 g/l g/l g/l # g/l 2. g/l g/l g/l g/l 3 21 g/l g/l Qvale (#) = qalifier ot of range (m) = manal integration C31723.D ASP1122W.M Mon Nov 23 14:36: Page

61 Data File Acq On Sample Qantitation Report D:\DATA\C31723.D 22 Nov :36 pm ICAL ppb 8260ASP_A2JW,ICAL,ml,VB l Misc MS Integration Params: rteint.p Qant Time: Nov 23 14: Qant Method Title Last pdate Response via DataAcq Meth D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 16 08:6: Initial Calibration ASP1122W (QT Reviewed) Operator: LEF Inst : #12 Mltiplr: 1.00 Qant Reslts File: ASP1122W.RES Compond R. T. QIon ReSponse Cone nit Qvale 41) Trichloroethene ) 1,2-Dichloropropane ) Methylcyclohexane ) Methyl Methacrylate ) Bromodichloromethane ) Dibromomethane ) 1,4-Dioxane ) 4-Methyl-2-pentanone 1.'94 49) cis-1,3-dichloropropene ) Tolene ) trans-1,3-dichloropropene ) Ethyl Methacrylate 17.0 ) 1,1,2-Trichloroethane ) 2-Hexanone ) 1,3-Dichloropropane ) Tetrachloroethene ) Dibromochloromethane ) 1,2-Dibromoethane ) Chlorobenzene ) 1,1,1,2-Tetrachloroethane ) Ethylbenzene 19. 6) m,p-xylene ) o-xylene ) Styrene ) Bromoform ) Isopropylbenzene ) 1,1,2,2-Tetrachloroethane ) 1,2,3-Trichloropropane ) trans-1,4-dichloro-2-bten ) n-propylbenzene ) 1,3,-Trimethylbenzene ) tert-btylbenzene ) 1,2,4-Trimethylbenzene ) sec-btylbenzene ) 1,3-Dichlorobenzene ) 4-isopropyltolene ) 1,4-Dichlorobenzene ) n-btylbenzene ) 1,2-Dichlorobenzene ) l,2-dibromo-3-chloro-propa ) 1,2,4-trichlorobenze ) Naphthalene ) 1,2,3-Trichlorobenzene ^ 11447m 0034m 31013m 19406m 30976m 38929m 39738m 7481m m 3746 f m g/l g/l 2.27 g/l 2.77 g/l # 2.63 g/l 2.43 g/l g/l 3.11 g/l 2.86 g/l 3.11 g/l 2.60 g/l 2.6 g/l # 2. g/l 2.49 g/l 2.94 g/l 4.06 g/l 2.63 g/l 2.69 g/l 3.17 g/l 2.9 g/l 3.1 g/l 6.7 g/l 3.19 g/l 3.23 g/l 2.64 g/l 3.00 g/l 2.81 g/l 2.38 g/l 2. g/l 2.69 g/l 2.7 g/l 2.07 g/l 2.3 g/l 2.43 g/l 3.63 g/l 2.09 g/l 3.64 g/l 2.6 g/l 3.44 g/l 2.28 g/l g/l 2.72 g/l 3.06 g/l (#) = qalifier ot of range (m) = manal integration C31723.D ASP1122W.M Mon Nov 23 14:36: 6J. 2 00< Page 2

62 WdilJ.ctV.XIi KepOL Data File : D:\DATA\C31723.D Vial: 3 Acq On : 22 Nov :36 pm Operator: LEF Sample : ICAL ppb Inst : #12 Misc : 8260ASP_A2_W,ICAL,ml,VB l Mltiplr: 1.00 MS Integration Params: rteint.p Qant Time: Nov 23 14: Qant Reslts File: ASP1122W.RES Method D:\METHODS\ASP1122W.M (RTE Integrator) Title VOA 8260 Calibration Last pdate Mon Nov 23 14:3: Response via Initial Calibration Abndance TIC: C31723.D I ro [Time~> 2.00 C31723.D ^ ' ^ ^ ASP1122W.M S p<-. s gg o tso _- T- '-"O T - I- " s Mon Nov 23 14:36: * lij klj P123_00_24.002_.0p ' ' I ' ' ' ' I' ' ' ' i ' Page 3

63 Qantitation Report (QT Reviewed) Data File : D:\DATA\C31724 D Acq On : 22 Nov :1 pm Vial: 4 Sample : ICAL-2730 loppb Operator: LEF Inst : #12 WS S Int -integration Pf7 r-^ionparams: 6 S ASP ~~ A2 rteint.p -- W ' ICAL ' ml ' VB ml Mltiplr: 1.00 Qant Time: Nov 23 14: Qant Reslts File: ASP1122W.RES Qant Method : D:\METHODS\ASP1122W.M (RTE Integrator)!f ltle : VOA 8260 Calibration Last pdate : Mon Nov 23 14: Response via : Initial Calibration DataAcq Meth : ASP1122W Internal Standards 1) Pentaflorobenzene 39) 1,4-Diflorobenzene 1) Chlorobenzene-d 67) l,4-dichlorobenzene-d4 System Monitoring Componds 34)^1,2-Dichloroethane-d4 Spiked Amont ) Tolene-d8 Spiked Amont ) Bromoflorobenzene Spiked Amont Target Componds 2) Dichlorodifloromethane 3) Chloromethane 4) Vinyl Chloride ) Bromomethane 6) Chloroethane 7) Trichlorofloromethane 8) Acrolein 9) Acetone 10) 1,l,2-Trichloro-l,2,2-trif 11) 1,1-Dichloroethene 12) Acetonitrile 13) t-btanol 14) Iodomethane 1) Methyl acetate 16) Allyl Chloride 17) Carbon Dislfide 18) Methylene Chloride 19) MTBE 20) Acrylonitrile 21) trans-1,2-dichloroethene 22) 1,1-Dichloroethane 23) Vinyl Acetate 24) Chloroprene 2) 2-Btanone 26) Propionitrile 27) 2,2-Dichloropropane 28) cis-1,2-dichloroethene 29) Methacrylonitrile 3 0) Chloroform 31) Bromochloromethane 32) Isobtyl Alcohol 33) Cyclohexane 3) 1,1,1-Trichloroethane 3 6) 1,1-Dichloropropene 3 7) Carbon Tetrachloride 3 8) Benzene 40) 1,2-Dichloroethane R.T. Qlon Response Cone nits Dev(Min) Range Range Range g/l g/l g/l g/l g/l 0.00 Recovery = % g/l Recovery =.68% g/l -0.1 Recovery =.44% m m m m 104m (#) = qalifier ot of range (m) = manal integration C31724.D ASP1122W.M Mon Nov 23 14:36: g/l g/l g/l 9.28 g/l g/l g/l g/l 9.18 g/l Qvale g/l g/l g/l g/l 13 g/l g/l 94 p 8.01 g/l 9.93 g/l g/l g/l g/l 9.8 g/l g/l 8.97 g/l g/l g/l g/l g/l 9.73 g/l g/l g/l 8. g/l # g/l # g/l 8.23 g/l 9.47 g/l g/l g/l 8.14 g/l 90 Page 1

64 Data File Acq On Sample Qantitation Report D:\DATA\C31724.D 22 Nov :1 pm ICAL-2730 loppb 8260ASP_A2_W,ICAL,ml,VB ml Misc MS Integration Params: rteint.p Qant Time: Nov 23 14: Qant Method Title Last pdate Response via DataAcq Meth D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:1: Initial Calibration ASP1122W (QT Reviewed) Vial: 4 Operator: LEF Inst : #12 Mltiplr: 1.00 Qant Reslts File: ASP1122W.RES Compond 41) Trichloroethene 42) 1,2-Dichloropropane 43) Methylcyclohexane 44) Methyl Methacrylate 4) Bromodichloromethane 46) Dibromomethane 47) 1,4-Dioxane 48) 4-Methyl-2-pentanone 49) cis-1,3-dichloropropene 2) Tolene 3) trans-1,3-dichloropropene 4) Ethyl Methacrylate ) 1,1,2-Trichloroethane 7) 2-Hexanone 8) 1,3-Dichloropropane 9) Tetrachloroethene 60) Dibromochloromethane 61) 1,2-Dibromoethane 62) Chlorobenzene 63) 1,1,1,2-Tetrachloroethane 64) Ethylbenzene 66) 6) m,p-xylene 68) o-xylene 69) Styrene Bromoform 70) Isopropylbenzene 12) 71) 1,1,2,2-Tetrachloroethane 73) 1,2,3-Trichloropropane trans-1,4-dichloro-2-bten 74) n-propylbenzene 76) 7) 1,3,-Trimethylbenzene 77) tert-btylbenzene 78) 1,2,4-Trimethylbenzene 79) sec-btylbenzene 80) 1,3-Dichlorobenzene 81) 4-isopropyltolene 82) 1,4-Dichlorobenzene 83) n-btylbenzene 84) 1,2-Dichlorobenzene 8) 1, 2-Dibromo-3-chloro-propa 1,2,4-trichlorobenze 86) Naphthalene 87) 1,2,3-Trichlorobenzene R.T Qlon Response Cone nit g/l g/l g/l g/l # g/l g/l g/l # g/l g/l g/l g/l g/l # g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l 7360m if 9.26 g/l 3190m 8.8 g/l g/l g/l ' g/l # g/l g/l m f 9.2 g/l g/l g/l g/l g/l g/l g/l g/l g/l Qvale (#) = qalifier ot of range (m) = manal integration C31724.D ASP1122W.M Mon Nov 23 14:36_^L6 fl 2009 Page 2

65 wctiixctcxii itepx i_ Data File : D:\DATA\C31724.D Vial: 4 Acq On : 22 Nov :1 pm Operator: LEF Sample : ICAL loppb Inst : #12 Misc : 8260ASP_A2_W,ICAL,ml,VB ml Mltiplr: 1.00 MS Integration Params: rteint.p Qant Time: Nov 23 14: Qant R e s l t s F i l e ; MP1122W Method Title Last pdate Response via D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Initial Calibration l i' " i ''' i''' i ' i 1111 itti,.ttt,,,. -.~,Yi i I,,, h-ii. rrh y. H> C31724.D ASP1122W.M Mon Nov 23 14:36: mk > 'vjwiil- n i«l / \ V [ r TT ri 1 i""t~" Page 3

66 Data File Acq On Sample Wise Qantitation Report D:\DATA\C3172.D 22 Nov :3 pm ICAL ppb,8260ASP_A2 W,ICAL,ml,VB793 8 ml IMS Integration Params: rteint.p Qant Time: Nov 23 14: Qant Method Title Last pdate Response via DataAcq Meth D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:17: Initial Calibration ASP1122W (QT Reviewed) Vial: Operator: LEF Inst : #12 Mltiplr: 1.00 Qant Reslts File: ASP1122W.RES Internal Standards 1) Pentaflorobenzene 39) 1,4-Diflorobenzene 1) Chlorobenzene-d 67) l,4-dichlorobenzene-d4 System Monitoring Componds 34) l,2-dichloroethane-d4 Spiked Amont ) Tolene-d8 Spiked Amont ) Bromoflorobenzene Spiked Amont Target Componds 2) Dichlorodifloromethane 3) Chloromethane 4) Vinyl Chloride ) Bromomethane 6) Chloroethane 7) Trichlorofloromethane 8) Acrolein 9) Acetone 10) l,l,2-trichloro-l,2,2-trif 11) 1,1-Dichloroethene 12) Acetonitrile 13) t-btanol 14) Iodomethane 1) Methyl acetate 16) Allyl Chloride 17) Carbon Dislfide 18) Methylene Chloride 19) MTBE 20) Acrylonitrile 21) trans-1,2-dichloroethene 22) 1,1-Dichloroethane 23) Vinyl Acetate 24) Chloroprene 2) 2-Btanone 26) Propionitrile 27) 2,2-Dichloropropane 28) cis-1,2-dichloroethene 29) Methacrylonitrile 30) Chloroform 31) Bromochloromethane 32) Isobtyl Alcohol 33) Cyclohexane 3) 1,1,1-Trichloroethane 36) 1,1-Dichloropropene 37) Carbon Tetrachloride 38) Benzene 40) 1,2-Dichloroethane R.T. Qlon Response Cone nits Dev(Min) Range Range Range if c (#) = qalifier ot of range (m) = manal integration C3172.D ASP1122W.M Mon Nov 23 14:36: g/l 0.00 g/l 0.00 g/l 0.00 g/l q/l 0.02 Recovery = 84.6% q/l Recovery = 97.8% g/l Recovery = % 16.6 g/l g/l g/l g/l g/l 1.88 g/l 9.1 g/l 26714m" 18.6 g/l g/l 721m g/l 670m g/l 7033m 1.19 g/l g/l g/l 68m, g/l m g/l g/l g/l g/l ' g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l Qvale Page 1

67 Qantitation Report (QT Reviewed) Data File : D:\DATA\C3172.D Vial: Acq On : 22 Nov :3 pm Operator: LEF Sample : ICAL ppb Inst : #12 Wise : 8260ASP_A2_W,ICAL,ml,VB7938 ml Mltiplr: WS Integration Params: rteint.p Qant Time: Nov 23 14: Qant Reslts File: ASP1122W.RES Qant Method Title Last pdate Response via DataAcq Meth D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:17: Initial Calibration ASP1122W C m p O n d R - T - Q Ion Response Cone nit Qvale 41) 42) Trichloroethene 1,2-Dichloropropane 43) Methylcyclohexane 44) Methyl Methacrylate 4) Bromodichloromethane 46) Dibromomethane 47) 1,4-Dioxane 48) 4-Methyl-2-pentanone 49) cis-1,3-dichloropropene 2) Tolene 3) trans-1,3-dichloropropene 4) Ethyl Methacrylate ) 1,1,2-Trichloroethane 7) 2-Hexanone 8) 1,3-Dichloropropane 9) Tetrachloroethene 60) Dibromochloromethane 61) 1,2-Dibromoethane 62) Chlorobenzene 63) 1,1,1,2-Tetrachloroethane 64) Ethylbenzene 6) 66) m,p-xylene 68) o-xylene 69) Styrene 70) Bromoform Isopropylbenzene 71) 1,1,2,2-Tetrachloroethane 72) 1,2,3-Trichloropropane 73) trans-1,4-dichloro-2-bten 74) n-propylbenzene 7) 1,3,-Trimethylbenzene 76) tert-btylbenzene 77) 1,2,4-Trimethylbenzene 78) sec-btylbenzene 79) 1,3-Dichlorobenzene 80) 4-isopropyltolene 81) 1,4-Dichlorobenzene 82) n-btylbenzene 83) 1,2-Dichlorobenzene 84) l,2-dibromo-3-chloro-propa 8) 1,2,4-trichlorobenze 86) Naphthalene 87) 1,2,3-Trichlorobenzene g/l g/l g/l g/l # g/l g/l g/l g/l g/l g/l g/l g/l # g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l 1347m if g/l g/l # j g/l g/l g/l # g/l g/l m g/l g/l g/l g/l g/l g/l g/l g/l g/l (#) = qalifier ot of range (m) = manal integration C3172.D ASP1122W.M Mon Nov :36_:A Page 2

68 w.c.iv-xi-c_.i-.xii ixepoil Data File : D:\DATA\C3172.D Acq On : 22 Nov :3 pm Vial: Sample : ICAL ppb Operator: LEF Inst : #12 Misc : 8260ASP_A2_W,ICAL,ml,VB793 8 ml Mltiplr: 1.00 MS Integration Params: rteint.p Qant Time: Nov 23 14: Qant Reslts File: ASP1122W.RES Method D:\METHODS\ASP1122W.M (RTE Integrator) Title VOA 8260 Calibration Last pdate Mon Nov 23 14:3: Response via Initial Calibration ;! (,!^^P 3 ; oo 4-.op..^op epo ZppLaM^mm C3172.D ASP1122W.M Mon Nov 23 14:36: m,0pj9pp2m0.21.pp.22pp.^a.24^^^^ Page 3

69 Qantitation Report (QT Reviewed) Data File : D:\DATA\C31726.D Vial 6 Acq On : 22 Nov 2009 :32 pm Operator LEF Sample : ICAL ppb Inst #12 Wise i 8260ASP_A2_W, ICAL, ml, VB ml Mltiplr 1.00 WS Integration Params: rteint.p Qant Time: Nov 23 14: Qant Reslts File: ASP22W.RES Qant Method : D:\METHODS\ASP1122W.M (RTE Integrator) Title : VOA 8260 Calibration Last pdate : Mon Nov 23 14:19: Response via : Initial Calibration DataAcq Meth : ASP1122W Internal Standards 1) Pentaflorobenzene 39) 1,4-Diflorobenzene 1) Chlorobenzene-d 67) l,4-dichlorobenzene-d4 System Monitoring Componds 34) l,2-dichloroethane-d4 Spiked Amont ) Tolene-d8 Spiked Amont ) ^Bromoflorobenzene Spiked Amont Target Componds 2) Dichlorodifloromethane 3) Chloromethane 4) Vinyl Chloride ) Bromomethane 6) 7) 8) 9) 10) 11) Chloroethane Trichlorofloromethane Acrolein Acetone 1,1,2-Trichloro-l,2,2-trif 1,1-Dichloroethene 12) Acetonitrile 14) 13) t-btanol 1) Iodomethane Methyl acetate 16) Allyl Chloride 18) 17) Carbon Dislfide 19) Methylene Chloride 20) MTBE 21) Acrylonitrile 22) trans-1,2-dichloroethene 23) 1,1-Dichloroethane 24) Vinyl Acetate 2) Chloroprene 26) 2-Btanone 27) Propionitrile 28) 2,2-Dichloropropane 29) cis-1,2-dichloroethene 30) Methacrylonitrile 31) Chloroform 32) Bromochloromethane 33) Isobtyl Alcohol 3) Cyclohexane 36) 1,1,1-Trichloroethane 1,1-Dichloropropene 37) Carbon Tetrachloride 38) Benzene 40) 1,2-Dichloroethane R.T. Qlon Response Cone nits Dev(Min) Range Range Range , g/l 0 0 g/l 00 g/l 00 g/l g/l Recovery = 87.8% g/l Recovery = 97.34% g/l Recovery = 9.02% m m m m m (#) = qalifier ot of range (m) = manal integration C31726.D ASP1122W.M Mon Nov 23 14:36: g/l g/l g/l 3.30 g/l 48. g/l g/l, g/l f g/l 38.6 g/l 4.3 g/l g/l 11.4 g/l g/l g/l g/l g/l 48.1 g/l 47.6 g/l g/l 4.48 g/l g/l 44. g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l 44. g/l g/l 47. g/l g/l Qvale Page 1

70 Data File Acq On Sample Misc Qantitation Report D:\DATA\C31726.D 22 Nov 2009 :32 pm ICAL ppb 8260ASP A2JW,ICAL,ml,VB ml MS Integration Params: rteint.p Qant Time: Nov 23 14: Qant Method Title Last pdate Response via DataAcq Meth D:\METHODS\ASP1122W.M (RTE Integrator) VOA Calibration Mon Nov 23 14:19: Initial Calibration ASP1122W (QT Reviewed) Vial: 6 Operator: LEF Inst : #12 Mltiplr: 1.00 Qant Reslts File: ASP1122W.RES Compond R.T. Qlon Response Cone nit Qvale 41) Trichloroethene 42) 1,2-Dichloropropane 43) Methylcyclohexane 44) Methyl Methacrylate 4) Bromodichloromethane 46) D ibromomethane 47) 48) 49) 2) 3) 4) ) 7) 8) 9) 60) 61) 62) 63) 64) 6) m,p-xylene 66) o-xylene 68) 69) 70) 71) 72) 73) 74) 7) 76) 77) 78) 79) 80) 81) 82) 83) 84) 1,4-Dioxane 4-Methyl-2-pentanone cis-1,3-dichloropropene Tolene trans-1,3-dichloropropene Ethyl Methacrylate 1,1,2-Trichloroethane 2-Hexanone 1,3-Dichloropropane Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene 1,1,1,2-Tetrachloroethane Ethylbenzene Styrene Bromoform Isopropylbenzene 1,1,2,2-Tetrachloroethane 1,2,3-Trichloropropane trans-1,4-dichloro-2-bten n-propylbenzene 1,3,-Trimethylbenzene tert-btylbenzene 1,2,4-Trimethylbenzene sec-btylbenzene 1,3-Dichlorobenzene 4-isopropyltolene 1,4-Dichlorobenzene n-btylbenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-chloro-propa 1,2,4 -trichlorobenze 8) 86) Naphthalene 87) 1,2,3-Trichlorobenzene g/l g/l g/l g/l # g/l g/l g/l g/l g/l g/l g/l g/l # g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l _. 4.0 g/l 3339mf g/l m ' m g/l # g/l 41.3 g/l g/l # ' g/l g/l 44.7 g/l g/l g/l 3.7 g/l 4.4 g/l 41. g/l g/l g/l 43.8 g/l (#) = qalifier ot of range (m) = manal integration C31726.D ASP1122W.M Mon Nov 23 14:36:_ m- Page 2

71 Data File Acq On Sample D:\DATA\C31726.D 22 Nov 2009 :32 pm ICAL ppb 8260ASP_A2_W,ICAL,ml,VB ml Misc MS Integration Params: rteint.p Qant Time: Nov 23 14: Method Title Last pdate Response via D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Initial Calibration diilii-cti Keporc Vial: 6 Operator: LEF Inst : #12 Mltiplr: 1.00 Qant Reslts File: ASP1122W.RES.-Time---' M0 m m M m ^ **^*^^ C31726.D ASP1122W.M ~ ~~ ~ Mon Nov 23 14:36: Page 3

72 Data File Acq On Sample Wise Qantitation Report D:\DATA\C31727.D 22 Nov :11 pm ICAL looppb 8260ASP_A2_W,ICAL,ml,VB ml NS Integration Params: rteint.p Qant Time: Nov 23 14: Qant Method Title Last pdate Response via DataAcq Meth Internal Standards D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:21: Initial Calibration ASP1122W 1) Pentaflorobenzene 39) 1,4-Diflorobenzene 1) Chlorobenzene-d 67) l,4-dichlorobenzene-d4 System Monitoring Componds 34) l,2-dichloroethane-d4 Spiked Amont ) Tolene-d8 Spiked Amont ) Bromoflorobenzene Spiked Amont Target Componds 2) Dichlorodifloromethane 3) Chloromethane 4) Vinyl Chloride ) Bromomethane 6) Chloroethane 7) Trichlorofloromethane 8) Acrolein 9) Acetone 10) l,l,2-trichloro-l,2,2-trif 11) 1,1-Dichloroethene 12) Acetonitrile 13) t-btanol 14) Iodomethane 1) Methyl acetate 16) Allyl Chloride 17) Carbon Dislfide 18) Methylene Chloride 19) MTBE 2 0) Acrylonitrile 21) trans-1,2-dichloroethene 22) 1,1-Dichloroethane 23) Vinyl Acetate 24) Chloroprene 2) 2-Btanone 26) Propionitrile 27) 2,2-Dichloropropane 28) cis-1,2-dichloroethene 29) Methacrylonitrile 3 0) Chloroform 31) Bromochloromethane 32) Isobtyl Alcohol 33) Cyclohexane 3) 1,1,1-Trichloroethane 36) 1,1-Dichloropropene 37) Carbon Tetrachloride 38) Benzene 40) 1,2-Dichloroethane (QT Reviewed) Vial: Operator: Inst : Mltiplr: 7 LEF # Qant Reslts File: ASP1122W.RES R.T. Qlon Response Cone nits Dev(Min) Range Range Range if C g/l 0.00 g/l 0.00 g/l 0.00 g/l g/l Recovery = % g/l Recovery =.24% g/l Recovery = 97.02% g/l g/l g/l g/l g/l g/l g/l m -T 8.42 g/l 7664m m i 401m < (#) = qalifier ot of range (m) = manal integration C31727.D ASP1122W.M Mon Nov 23 14:36: g/l.18 g/l 9.02 g/l 9.92 g/l g/l * g/l 77.3 g/l g/l g/l g/l g/l '.34 g/l 93.9 g/l g/l g/l.94 g/l g/l g/l 94. g/l 97.7 g/l g/l 92.3 g/l g/l g/l g/l g/l 87.8 g/l 92.6 g/l g/l Qvale Page 1

73 Qantitation Report (QT Reviewed) Data File : D:\DATA\C31727.D Vial: 7 Acq On : 22 Nov :11 pm Operator: LEF Sample : ICAL looppb Inst : #12 Wise : 8260ASP_A2^W,ICAL,ml,VB7938 2ml Mltiplr: 1.00 NS Integration Params: rteint.p Qant Time: Nov 23 14: Qant Reslts File: ASP1122W.RES Qant Method Title Last pdate Response via DataAcq Meth D:\METH0DS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:21: Initial Calibration ASP1122W Compond 41) Trichloroethene 42) 1,2-Dichloropropane 43) Methylcyclohexane 44) Methyl Methacrylate 4) Bromodichloromethane 46) Dibromomethane 47) 1,4-Dioxane 48) 4-Methyl-2-pentanone 49) cis-1,3-dichloropropene 2) Tolene 3) trans-1,3-dichloropropene 4) Ethyl Methacrylate ) 1,1,2-Trichloroethane 7) 2-Hexanone 8) 1,3-Dichloropropane 9) Tetrachloroethene 60) Dibromochloromethane 61) 1,2-Dibromoethane 62) Chlorobenzene 63) 1,1,1,2-Tetrachloroethane 64) Ethylbenzene 6) m,p-xylene 66) o-xylene 68) Styrene 69) Bromoform 70) Isopropylbenzene 71) 1,1,2,2-Tetrachloroethane 72) 1,2,3-Trichloropropane 73) trans-1,4-dichloro-2-bten 74) n-propylbenzene 7) 1,3,-Trimethylbenzene 76) tert-btylbenzene 77) 1,2,4-Trimethylbenzene 78) sec-btylbenzene 79) 1,3-Dichlorobenzene 80) 4-isopropyltolene 81) 1,4-Dichlorobenzene 82) n-btylbenzene 83) 1,2-Dichlorobenzene 84) l,2-dibromo-3-chloro-propa 8) 1,2,4-trichlorobenze 86) Naphthalene 87) 1,2,3-Trichlorobenzene R.T Qlon Response Cone nit 88.6 g/l 9.78 g/l g/l g/l # g/l 84.7 g/l g/l g/l g/l g/l.71 g/l g/l # g/l 93. g/l g/l g/l.86 g/l.64 g/l g/l 9.71 g/l g/l g/l g/l g/l.63 g/l 8.22 g/l g/l g/l g/l g/l g/l ' g/l # g/l 82. g/l g/l g/l.40 g/l g/l.69 g/l g/l g/l g/l g/l Qvale (#) = qalifier ot of range (m) = manal integration C31727.D ASP1122W.M Mon Nov 23 14:36: _:2-T2 009 Page 2

74 Data File Acq On Sample Misc D:\DATA\C31727.D 22 Nov :11 pm ICAL-2730 looppb.8260asp_a2_w,ical,ml,vb7938 2ml MS Integration Params: rteint.p Qant Time: Nov 23 14: Method Title Last pdate Response via D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Initial Calibration vfiictiilxlcilxoii Keporc Vial: 7 Operator: LEF Inst : #12 Mltiplr: 1.00 Qant Reslts File: ASP1122W.RES TIC: C31727.D~ -r I «C31727.D ASP1122W.M Mon Mnn Nov *r r 23 si 14:36:23 -i/,.-,,--,-, ~ 2009 ~ ~- Page 3

75 Data File Acq On Sample Qantitation Report D:\DATA\C31728.D 22 Nov :49 pm ICAL ppb 8260ASP_A2_W,ICAL,ml,VB7938 0ml Misc MS Integration Params: rteint.p Qant Time: Nov 23 14: Qant Method Title Last pdate Response via DataAcq Meth D:\METHODS\ASP1122W.M (RTE Integrator) VOA Calibration Mon Nov 23 14:22: Initial Calibration ASP1122W (QT Reviewed) Vial: 8.Operator: LEF Inst : #12 Mltiplr: Qant Reslts File: ASP1122W.RES Internal Standards R.T. Qlon Response Cone nits Dev(Min) 1) Pentaflorobenzene 39) 1,4-Diflorobenzene 1) Chlorobenzene-d 67) l,4-dichlorobenzene-d4 System Monitoring Componds 34) 1,2-Dichloroethane-d4 Spiked Amont ) Tolene-d8 Spiked Amont ) Bromoflorobenzene Spiked Amont Target Componds 2) Dichlorodifloromethane 3) Chloromethane 4) Vinyl Chloride ) Bromomethane 6) 7) 8) 9) 10) 11) 12) 13) 14) Chloroethane Trichlorofloromethane Acrolein Acetone l,l,2-trichloro-l,2,2-trif 1,1-Dichloroethene Acetonitrile t-btanol Iodomethane 1) Methyl acetate 16) Allyl Chloride 17) Carbon Dislfide 18] Methylene Chloride 19) MTBE 2 0) Acrylonitrile 21) trans-1,2-dichloroethene 22) 1,1-Dichloroethane 23) Vinyl Acetate 24) Chloroprene 2) 2-Btanone 26) Propionitrile 27) 2,2-Dichloropropane 28) cis-1,2-dichloroethene 29) Methacrylonitrile 3 0) Chloroform 31) Bromochloromethane 32) Isobtyl Alcohol 3 3) Cyc1ohexane 3) 1,1,1-Trichloroethane 36) 1,1-Dichloropropene 37) Carbon Tetrachloride 38) Benzene 40) 1,2-Dichloroethane Range Range Range if C g/l 0.00 g/l 0.00 g/l 0.00 g/l g/l 0.02 Recovery = % g/l 0.00 Recovery =.22% g/l 0.00 Recovery = % g/l g/l g/l g/l g/l g/l T g/l 21602m m m, m g/l g/l g/l g/l g/l f g/l 184. g/l g/l g/l g/l g/l 82.2 g/l g/l g/l g/l g/l g/l g/l 1.20 g/l g/l g/l 1.62 g/l 1. g/l g/l g/l g/l g/l g/l g/l g/l Qvale IOO (#) = qalifier ot of range (m) = manal :3 integration C31728.D ASP1122W.M Mon Nov 23 14:36^ Page 1 m*

76 Qantitation Report (QT Reviewed) Data File : D:\DATA\C31728.D Vial: 8 Acq On s 22 Nov :49 pm Operator: Sample s ICAL ppb Inst : #12 Wise. 8260ASP_A2_W, ICAL, ml, VB7938 0ml Mltiplr: 1.00 WS Integration Params: rteint.p Qant Time: Nov 23 14: Qant Reslts File: ASP1122W.RES Qant Method D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Last pdate Mon Nov 23 14:22: Response via Initial Calibration DataAcq Meth ASP1122W Compond 41) Trichloroethene 42) 1,2-Dichloropropane 4 3) Methyleye1ohexane 44) Methyl Methacrylate 4) Bromodichloromethane 46) Dibromomethane 47) 1,4-Dioxane 48) 4-Methyl-2-pentanone 49) cis-1,3-dichloropropene 2) 3) Tolene trans-1,3-dichloropropene 4) Ethyl Methacrylate 7) ) 1,1,2-Trichloroethane 8) 2-Hexanone 9) 1,3-Dichloropropane 60) Tetrachloroethene 61) Dibromochlorome thane 62) 1,2-Dibromoethane 63) Chlorobenzene 64) 1,1,1,2-Tetrachloroethane 6) Ethylbenzene 66) m,p-xylene 68) o-xylene Styrene 69) Bromoform 71) 70) Isopropylbenzene 72) 1,1,2,2-Tetrachloroethane 73) 1,2,3-Trichloropropane trans-1,4-dichloro-2-bten 74) n-propylbenzene 7) 1,3,-Trimethylbenzene 76 tert-btylbenzene 77) 1,2,4-Trimethylbenzene 78) sec-btylbenzene 79) 1,3-Dichlorobenzene 80) 4 -isopropyltolene 81) 1,4-Dichlorobenzene 82) n-btylbenzene 83) 1,2-Dichlorobenzene 84) 1,2-Dibromo-3-chloro-propa 8) 1,2,4-trichlorobenze 86) Naphthalene 87) 1,2,3-Trichlorobenzene R.T. Qlon Response Cone nit Qvale g/l g/l 206. g/l g/l # g/l g/l g/l 1.47 g/l g/l g/l g/l g/l # 1.61 g/l g/l 1.07 g/l g/l g/l g/l g/l g/l 1.40 g/l g/l g/l 1.18 g/l g/l g/l 197. g/l g/l g/l 180. g/l g/l g/l # g/l g/l g/l g/l g/l g/l g/l g/l g/l 1.38 g/l 1.06 g/l (#) - qalifier ot of range (m) = manal integration C31728.D ASP1122W.M Mon Nov 23 14:36: Page 2

77 W-lcliil_Xt_c<.l_Xii MjpiL Data File : D:\DATA\C31728.D Vial: 8 Acq On : 22 Nov :49 pm Operator: LEF Sample : ICAL ppb Inst : #12 Misc : 8260ASP_A2_W,ICAL,ml,VB7938 0ml Mltiplr: 1.00 MS Integration Params: rteint.p Qant Reslts File: ASP1122W.RES Qant Time: Nov 23 14: Method D:\METHODS\ASP1122W.M (RTE Integrator) Title VOA 8260 Calibration Last pdate. Mon Nov 23 14:3: Response via Initial Calibration [Time- ^1 3JP 4-go spp e-gp j-oo acxlppo mmm LwnM_g^ r C31728.D ASP1122W.M Mon Nov 23 14:36: Page 3

78 Contining Calibration pstate Laboratories; Inc

79 7A VOLATILE CONTINING CALIBRATION CHECK Lab Name: pstate Labs Inc. Lab Code: Case No.: Instrment ID: 12.0 Lab File ID: C3183.D Heated Prge: (Y/N) N GC Colmn: RTX-VOLA ID: 0.3 (mm) Contract: CASELLA SAS No. SDG No.: CAS120 Calibration Date: 11/30/2009 Time: 22:13 Init. Calib. Date(s): 11/22/ /22/2009 Init. Calib. Times: 1:36 18:49 COMPOND Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofloromethane Acetone JLJ_:Dichlgroethene lodomethane Carbon Dislfide Methylene Chloride Acrylonitrile Jrans-1,2-Dichloroethene 1,1-Dichloroethane.Vinyl Acetate 2-Btanone cis-1,2-dichloroethene Chloroform --l^imiochloroitiethane^ 1,1,1-Trichloroethane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene 1,2-Dichloropropane Bromodichloromethane Dibromomethane 4-Methvl-2-pentanone cis-1,3-dichloropropene Tolene Jrans-1,3-Dichloropropene_ 1,1,2-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene 1,1,1,2-Tetrachloroethane Ethylbenzene JXLfcXyfen^ RRF A J RRF MIN RRF %D MAX %D *40"b All other componds mst meet a minimm RRF of FORM VII VOA /90

80 7A VOLATILE CONTINING CALIBRATION CHECK Lab Name: pstate Labs Inc _ Contract: CASELLA Lab Code: Case No.: SAS No.: SDG No.: CAS120 Instrment ID: 12.0 Lab File ID: C3183.D Heated Prge: (Y/N) GC Colmn: RTX-VOLA ID: 0.3 (mm) N Calibration Date: 11/30/2009 Time: 22:13 Init. Calib. Date(s): 11/22/2009 Init. Calib. Times: 1:36 11/22/ :49 COMPOND j^yjene Styrene Bromoform -lj.i2x2j[etrach!o^ JAIHJJchlgroproBane. -li 1-PJch[probenzene_ 1,4-Dlchlorgbenzene li^djchlorobenzene 1,2-Dibromo-3-chloro-propane J.,2-Dichloroethane-d4 Tolene-d8 Bromoflorobenzene tntzstrr KRF RRF JL MIN RRF %D MAX %D All other componds mst meet a minimm RRF of FORM VII VOA /90

81 1 I 2 T 3 T 4 TC T 6 T 7 T 8 T 9 T 10 T 11 TC 12 T T 1 T 16 T 17 T 18 T 19 T 20 T 21 T 22 T 23 T 24 T 2 T 26 T 27 T 28 T 29 T 3 0 TC 31 T 32 T 33 T 34 S 3 T 36 T 37 T 38 T 39 I 40 T 41 T 42 TC 43 T 44 T 4 T 46 T 47 T 48 T 49 T Data File Acq on Sample Misc Evalate Contining Calibration Report D:\DATA\C3183.D 30 Nov :13 pm CCV ASP_A2_W,CCV,ml,VB793 8 MS Integration Params: rteint.p Method Title Last pdate Response via : Min. RRF : Max. RRF Dev : Compond D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Mltiple Level Calibration % Pentaflorobenzene Dichlorodifloromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Tri chlorofloromethane Acrolein Acetone 1,1,2-Trichloro-1,2,2 -trif1 1,1-Dichloroethene Acetonitrile t-btanol Iodomethane Methyl acetate Allyl Chloride Carbon Dislfide Methylene Chloride MTBE Acrylonitrile trans-1,2-dichloroethene 1,1-Dichloroethane Vinyl Acetate Chloroprene 2-Btanone Propionitrile 2,2-Dichloropropane cis-1,2-dichloroethene Methacrylonitrile Chloroform Bromochloromethane Isobtyl Alcohol Cyclohexane 1,2-Dichloroethane-d4 1,1,1-Trichloroethane 1,1-Dichloropropene Carbon Tetrachloride Benzene 1,4-Diflorobenzene 1,2-Dichloroethane Trichloroethene 1,2-Dichloropropane Methylcyclohexane Methyl Methacrylate Bromodichloromethane Dibromomethane 1,4-Dioxane 4-Methyl-2-pentanone cis-1,3-dichloropropene Min. Rel. Area : 0% Max. Rel. Area : 10% Vial: 2 0 Operator: LEF Inst : #12 Mltiplr: 1.00 Max. R.T. Dev 0.0min AvgRF CCRF %Dev Area% Dev(min) # 0.049# # 0.013# # # # # # (#) = Ot of Range C3183.D ASP1122W.M Te Dec 01 11:21:2' 09 Page 1

82 Data File Acq On Sample Misc Evalate Contining Calibration Report D:\DATA\C3183.D 30 Nov :13 pm CCV ASP_A2_W,CCV,ml,VB793 8 MS Integration Params: rteint.p Vial: 20 Operator: LEF Inst : #12 Mltiplr: 1.00 Method Title Last pdate Response via D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Mltiple Level Calibration Min. RRF ; Max. RRF Dev : Compond 0 S Tolene-d8 1 I Chlorobenzene-d 2 TC 3 T 4 T T 6 S 7 T 8 T 9 T 60 T 0.00 Min. Rel. Area 2% Max. Rel. Area Tolene trans-1,3-dichloropropene Ethyl Methacrylate 1,1,2-Trichloroethane Bromoflorobenzene 2-Hexanone 1,3-Dichloropropane Tetrachloroethene Dibromochloromethane 61 T 1,2-Dibromoethane 62 T Chlorobenzene 63 T 1,1,1,2-Tetrachloroethane 64 TC Ethylbenzene 6 T m,p-xylene 66 T o-xylene 67 I l,4-dichlorobenzene-d4 68 T Styrene 69 T Bromoform 70 T Isopropylbenzene 71 1,1,2,2-Tetrachloroethane 72 T 1,2,3-Trichloropropane 73 T trans-1,4-dichloro-2-btene 74 T n-propylbenzene 7 T 1,3,-Trimethylbenzene 76 T tert-btylbenzene 77 T 1,2, 4-Trimethylbenzene 78 T sec-btylbenzene 79 T 1,3-Dichlorobenzene 80 T 4 -isopropyltolene 81 T 1,4-Dichlorobenzene 82 T n-btylbenzene 83 T 1,2-Dichlorobenzene 84 T 1,2-Dibromo-3-chloro-propan 8 T 1,2,4-trichlorobenze 86 T Naphthalene 87 T 1,2,3-Trichlorobenzene 0% 10% Max. R.T. Dev 0.0min AvgRF CCRF %Dev Area% Dev(min) , , (#) = Ot of Range C3183.D ASP1122W.M SPCC's ot = 0 CCC's ot Te Dec 01 11:21:2^,2^09 Page 2

83 Qantitation Report Data File : D:\DATA\C3183.D Acq On : 30 Nov :13 pm Sample : CCV-474 Wise : 8260ASP_A2_W,CCV,ml,VB7938 MS Integration Params: rteint.p Qant Time: Dec 1 11: Qant Method Title Last pdate Response via DataAcq Meth D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Initial Calibration ASP1122W (QT Reviewed) Vial: 2 0 Operator: LEF Inst : #12 Mltiplr: 1.00 Qant Reslts File: ASP1122W.RES Internal Standards R.T. QIon Response Cone nits Dev(Min) 1) Pentaflorobenzene 39) 1,4-Diflorobenzene 1) Chlorobenzene-d 67) l,4-dichlorobenzene-d4 System Monitoring Componds 34) l,2-dichloroethane-d4 Spiked Amont ) Tolene-d8 Spiked Amont ) Bromoflorobenzene Spiked Amont Target Componds 2) Dichlorodifloromethane 3) Chloromethane 4) Vinyl Chloride ) Bromomethane 6) Chloroethane 7) Trichlorofloromethane 8) Acrolein 9) Acetone 10) l,l,2-trichloro-l,2,2-tr 11) 1,1-Dichloroethene 12) Acetonitrile 13) t-btanol 14) Iodomethane 1) Methyl acetate 16) Allyl Chloride 17) Carbon Dislfide 18) Methylene Chloride 19) MTBE 20) Acrylonitrile 21) trans-1,2-dichloroethene 22) 1,1-Dichloroethane 23) Vinyl Acetate 24) Chloroprene 2) 2-Btanone 26) Propionitrile 27) 2,2-Dichloropropane 28) cis-1,2-dichloroethene 29) Methacrylonitrile 3 0) Chloroform 31) Bromochloromethane 32) Isobtyl Alcohol 3 3) Cyc1ohexane 3) 1,1,1-Trichloroethane 36) 1,1-Dichloropropene 37) Carbon Tetrachloride 38) Benzene 40) 1,2-Dichloroethane Range Range Range if m' g/l 0.00 g/l 0.00 g/l 0.00 g/l g/l Recovery =.66% g/l Recovery =.44% g/l Recovery = 97.2% g/l g/l 4.68 g/l g/l 47.2 g/l g/l g/l 49.9 g/l 49.8 g/l 0.48 g/l g/l g/l # g/l g/l *" g/l g/l 1.06 g/l g/l g/l g/l g/l 40.3 g/l g/l g/l g/l g/l 0.27 g/l 4.19 g/l g/l g/l g/l g/l g/l 4.47 g/l g/l g/l g/l Qvale (#) = qalifier ot of range (m) = manal integration C3183.D ASP1122W.M Te Dec 01 11:21:2^,^009 L:^f00i Page

84 Qantitation Report Data File : D:\DATA\C3183.D Acq On : 30 Nov :13 pm Sample : CCV-474 Misc : 8260ASP_A2_W,CCV,ml,VB7938 MS Integration Params: rteint.p Qant Time: Dec 1 11: Qant Method Last pdate Response via DataAcq Meth D:\METH0DS\ASP1122W.M RTE Integrator) VOA Calibration Mon Nov 23 14:3: Initial Calibration ASP1122W (QT Reviewed) Vial: 2 0 Operator: LEF Inst : #12 Mltiplr: 1.00 Qant Reslts File: ASP1122W.RES Compond 41) Trichloroethene 42) 1,2-Dichloropropane 43) Methylcyclohexane 44) Methyl Methacrylate 4) Bromodichloromethane 46) Dibromomethane 47) 1,4-Dioxane 48) 4-Methyl-2-pentanone 49) cis-1,3-dichloropropene 2) Tolene 3) trans-1,3-dichloropropene 4) Ethyl Methacrylate ) 1,1,2-Trichloroethane 7) 2-Hexanone 8) 1,3-Dichloropropane 9) Tetrachloroethene 60) Dibromochloromethane 61) 1,2-Dibromoethane 62) Chlorobenzene 63) 1,1,1,2-Tetrachloroethane 64) Ethylbenzene 6) m,p-xylene 66) o-xylene 68) Styrene 69) Bromoform 70) Isopropylbenzene 71) 1,1,2,2-Tetrachloroethane 72) 1,2,3-Trichloropropane 73) trans-1,4-dichloro-2-bten 74) n-propylbenzene 7) 1, 3,-Trimethylbenzene 76) tert-btylbenzene 77) 1,2,4-Trimethylbenzene 78) sec-btylbenzene 79) 1, 3-Dichlorobenzene 80) 4-isopropyltolene 81) 1,4-Dichlorobenzene 82) n-btylbenzene 83) 1,2-Dichlorobenzene 84) 1,2-Dibromo-3-chloro-propa 8) 1,2,4-trichlorobenze 86) Naphthalene 87) 1,2,3-Trichlorobenzene R.T Qlon Response Cone nit Qvale fc 38823m nr g/l g/l 4.78 g/l g/l # g/l g/l g/l g/l g/l g/l g/l 44.6 g/l # g/l g/l 46.7 g/l.3 0 g/l 0.67 g/l g/l g/l 1.18 g/l g/l g/l 47.8 g/l 47.2 g/l 0.36 g/l 46.8 g/l 4.32 g/l 4.10 g/l g/l # g/l g/l g/l # g/l g/l 47.1 g/l g/l 47.7 g/l g/l g/l g/l 0.1 g/l g/l g/l (#) = qalifier ot of range (m) = manal integration C3183.D ASP1122W.M Te Dec 01 11:21: Page 2

85 Data File Acq On Sample Misc D:\DATA\C3183.D 30 Nov :13 pm CCV ASP_A2_W,CCV,ml,VB7938 MS Integration Params: rteint.p Qant Time: Dec 1 11: Method Title Last pdate Response via D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Initial Calibration ancitation Report Vial: 2 0 Operator: LEF Inst : #12 Mltiplr: l.oo Qant Reslts File: ASP1122W.RES» i '' i' i **~" T r '~ r r I VrTfiVrY, V.V.,VrrV"VV.,V". "V" ^y^-v...v-t J. V."... LJ. ^JL ~ ' l I Lit " ~ m m M *&- m^mjomnm ElMiMmooM laoolig^oo ^MlM^^}^^^ ^0 ao.'oo ' C3183.D ASP1122W.M Te Dec 01 11:21: Page 3

86 7A VOLATILE CONTINING CALIBRATION CHECK Lab Name: pstate Labs Inc _ Contract: CASELLA Lab Code Case No.: SAS No.: SDG No.: CAS120 Instrment ID: 12.0 Calibration Date: 12/1/2009 Time: Lab File ID: C31871.D Init. Calib. Date(s): 11/22/2009 Heated Prge: (Y/N) N_ Init. Calib. Times: 1:36 GC Colmn: RTX-VOLA ID: 0.3 (mm) 9:47 11/22/ :49 COMPOND Chloromethane _Vinyl Chloride Bromomethane Chloroethane Trichlorofloromethane Acetone 1,1-Dichloroethene lodomethane Carbon Dislfide.Methylene Chloride Acrylonitrjje^ Jransr.l,2-Dichloroethene 1,1-Dichloroethane -VoryLAcetete, 2-Btanone cis-1,2-dichloroethene Chloroform Bromochloromethane 1,1,1-Trichloroethane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene 1,2-Dichloropropane^ Bromodichioromethane Dibromomethane 4-Methvl-2-pentanone cis-1,3-dichloropropene Tolene trans-1,3-dichloropropene 1,1,2-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene 1,1,1,2-Tetrachloroethane Ethylbenzene m.p-xylene RRF RRF J-L MIN RRF [ % D MAX %D All other componds mst meet a minimm RRF of FORM VII VOA /90

87 Lab Name: Lab Code: Instrment ID: 12.0 Lab File ID: pstate Labs Inc C31871.D Heated Prge: (Y/N) N_ GC Colmn: RTX-VOLA ID: 0.3 (mm) 7A VOLATILE CONTINING CALIBRATION CHECK Contract: CASELLA Case No.: SAS No.: SDG No.: CAS120 Calibration Date: 12/1/2009 Time: 9:47 Init. Calib. Date(s): 11/22/ /22/2009 Init. Calib. Times: 1:36 18:49 COMPOND o-xylene ^Styrene Bromoform -JLl,2,2-Tetrachloroethane - 1 ^13-Trichloropropane. 1 ^-Dichlorobenzene 1,4-Dichlorobenzene, 1,2-Dichlorobenzene 1,2-Dibromo-3-chloro-propane _1 J 2 r Dichloroethane-d4 Tolene-d8 Bromoflorobenzene RRF I RRF ^Q MIN RRF %D MAX %D All other componds mst meet a minimm RRF of FORM VII VOA /90

88 Data File Acq On Sample Misc Evalate Contining Calibration Report D:\DATA\C31871.D 1 Dec :47 am CCV ASP A2 W, CCV, ml, VB793 8 MS Integration Params: rteint.p Vial: 3 Operator: LEF Inst : #12 Mltiplr: I 2 T 3 T 4 TC T 6 T 7 T 8 T 9 T 10 T 11 TC 12 T T 1 T 16 T 17 T 18 T 19 T 20 T 21 T 22 T 23 T 24 T 2 T 26 T 27 T 28 T 29 T 3 0 TC 31 T 32 T 33 T 34 S 3 T 36 T 37 T 38 T 39 I 40 T 41 T 42 TC 43 T 44 T 4 T 46 T 47 T 48 T 49 T Method Title Last pdate Response via Min. RRF : Max. RRF Dev : Compond D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Mltiple Level Calibration 0.00 Min. Rel. Area 2% Max. Rel. Area Pentaflorobenzene Di chlorodi floromethane Chiorome thane Vinyl Chloride Bromomethane Chloroethane Trichlorofloromethane Acrolein Acetone l,l,2-trichloro-l,2,2-trifl 1,1-Dichloroethene Acetonitrile t-btanol Iodomethane Methyl acetate Allyl Chloride Carbon Dislfide Methylene Chloride MTBE Acrylonitrile trans-1,2-dichloroethene 1,1-Dichloroethane Vinyl Acetate Chloroprene 2-Btanone Propionitrile 2,2-Dichloropropane cis-1,2-dichloroethene Methacrylonitrile Chloroform Bromochloromethane Isobtyl Alcohol Cyclohexane l,2-dichloroethane-d4 1,1,1-Trichloroethane 1,1-Dichloropropene Carbon Tetrachloride Benzene 1,4-Diflorobenzene 1,2-Dichloroethane Trichloroethene 1,2-Dichloropropane Methylcyclohexane Methyl Methacrylate Bromodichloromethane D ibromome thane 1,4-Dioxane 4-Methyl-2-pentanone cis-1,3-dichloropropene AvgRF % Max. R.T. Dev O.SOmin 10% CCRF # 0.046# # 0.012# # # # # (#) = Ot of Range C31871.D ASP1122W.M Wed Dec 02 11:23: %Dev Area% Dev(min) # Page 1

89 Evalate Contining Calibration Report Data File : D:\DATA\C31871.D Acq On : 1 Dec :47 am Sample : CCV Misc : 8260ASP_A2_W,CCV,ml,VB7938 MS Integration Params: rteint.p Vial: Operator: Inst. Mltiplr: 3 LEF # S 1 I 2 TC 3 T 4 T T 6 S 7 T 8 T 9 T 60 T 61 T 62 T 63 T 64 TC 6 T 66 T 67 I 68 T 69 T 70 T 71 T 72 T 73 T 74 T 7 T 76 T 77 T 78 T 79 T 80 T 81 T 82 T 83 T 84 T 8 T 86 T 87 T Method : D:\METHODS\ASP1122W.M (RTE Integrator) Title : VOA Calibrat..on Last pdate : Mon Nov 23 14:3: Response via : Mltiple Level Calibration Min RRF : 0.00 Min. Rel Max. RRF Dev : 2% Max. Rel Compond Tolene-d8 Chlorobenzene-d Tolene trans -1,3-Dichloropropene Ethyl Methacrylate 1,1,2-Trichloroethane Bromoflorobenzene 2-Hexanone 1,3-Dichloropropane Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene 1,1,1,2-Tetrachloroethane Ethylbenzene m,p-xylene o-xylene 1,4-Dichlorobenzene-d4 Styrene Bromoform Isopropylbenzene 1,1,2,2-Tetrachloroethane 1,2,3-Trichloropropane trans-1,4-dichloro-2-btene n-propylbenzene 1,3,-Trimethylbenzene tert-btylbenzene 1,2,4-Trimethylbenzene sec-btylbenzene 1,3-Dichlorobenzene 4 -isopropyltolene 1,4-Dichlorobenzene n-btylbenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-chloro-propan 1,2,4-trichlorobenze Naphthalene 1,2,3-Trichlorobenzene Area : Area : AvgRF % Max. 10% CCRF R.T. Dev 0. 0min %Dev Area i Dev(min) (#) = Ot of Range C31871.D ASP1122W.M SPCC's ot = 0 CCC's ot Wed Dec 02 11:23: Page 2

90 Qantitation Report Data Pile : D:\DATA\C31871.D Acq On : 1 Dec :47 am Sample : CCV Misc : 8260ASP A2_W,CCV,ml,VB793 8 MS Integration Params: rteint.p Qant Time: Dec 2 11: Qant Method Title Last pdate Response via DataAcq Meth D:\METH0DS\ASP1122W.M RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Initial Calibration ASP1122W (QT Reviewed) Vial: 3 Operator: LEF Inst : #12 Mltiplr: 1.00 Qant Reslts File: ASP1122W.RES Internal Standards R.T. Qlon Response Cone nits Dev(Min) 1) Pentaflorobenzene 3 9) 1,4-Diflorobenzene 1) Chlorobenzene-d 67) l,4-dichlorobenzene-d4 System Monitoring Componds 34) l,2-dichloroethane-d4 Spiked Amont ) Tolene-d8 Spiked Amont ) Bromoflorobenzene Spiked Amont Range Range Range 86 Target Componds 2) Dichlorodifloromethane 2. 3) Chloromethane ) Vinyl Chloride 3.33 ) Bromomethane ) Chioroe thane 3. 7) Trichlorofloromethane ) Acrolein ) Acetone ) l,l,2-trichloro-l,2,2-trif ) 1,1-Dichloroethene 12) Acetonitrile 13) t-btanol 14) Iodomethane 1) Methyl acetate 16) Allyl Chloride 17) Carbon Dislfide 18) Methylene Chloride 19) MTBE 20) Acrylonitrile 21) trans-1,2-dichloroethene 22) 1,1-Dichloroethane 23) Vinyl Acetate 24) Chloroprene 2) 2-Btanone 26) Propionitrile 2 7) 2,2-Dichloropropane 28) cis-1,2-dichloroethene 29) Methacrylonitrile 30) Chloroform 31) Bromochloromethane 32) Isobtyl Alcohol 3 3) Cyc1ohexane 3) 1,1,1-Trichloroethane 36) 1,1-Dichloropropene 37) Carbon Tetrachloride 3 8) Benzene 40) 1,2-Dichloroethane c 86094m'T m l p m*' m*' g/l 0.00 g/l 0.00 g/l 0.00 g/l q/l 0.0 Recovery = % q/l 0.0 Recovery =.26% q/l 0.10 Recovery = 94.8% g/l 41. g/l g/l g/l g/l g/l 1.60 g/l 4.79 g/l 0.24 g/l 2.41 g/l g/l g/l g/l 43. g/l.44 g/l # 0.03 g/l g/l 4.41 g/l g/l g/l 49.4 g/l g/l g/l g/l 76m ^ m g/l g/l g/l g/l g/l , c q/l m q/l (#) = qalifier ot of range (m) = manal integration C31871.D ASP1122W.M Wed Dec 02 11:23: g/l g/l g/l 49. g/l 0.01 g/l 4.76 g/l Ovale Page 1

91 Qantitation Report Data File : D:\DATA\C31871.D Acq On : 1 Dec :47 am Sample : CCV Misc : 8260ASP_A2_W,CCV,ml,VB793 8 MS Integration Params: rteint.p Qant Time: Dec 2 11: Qant Method : D:\METHODS\ASP1122W.M (RTE Integrator) Title : VOA 8260 Calibration Last pdate : Mon Nov 23 14:3: Response via : Initial Calibration DataAcq Meth : ASP1122W (QT Reviewed) Vial: 3 Operator.- LEF Inst : #12 Mltiplr: 1.00 Qant Reslts File: ASP1122W.RES Compond R.T. Qlon Response Cone nit Qvale 41) Trichloroethene ) 1,2-Dichloropropane ) Methylcyclohexane ) Methyl Methacrylate ) Bromodichloromethane ] Dibromomethane ) 1,4-Dioxane ) 4-Methyl-2-pentanone ) cis-1,3-dichloropropene ) Tolene ) trans-1,3-dichloropropene ) Ethyl Methacrylate 17.6 ) 1,1,2-Trichloroethane ) 2 -Hexanone ) 1,3-Dichloropropane ) Tetrachloroethene ) Dibromochloromethane ) 1,2-Dibromoethane ; Chlorobenzene ) 1,1,1,2-Tetrachloroethane ) Ethylbenzene ) m.p-xylene ) o-xylene ) Styrene ) Bromoform ) Isopropylbenzene ) 1,1,2,2-Tetrachloroethane ) 1,2,3-Trichloropropane ) trans-1,4-dichloro-2-bten ) n-propylbenzene ) 1,3,-Trimethylbenzene ) tert-btylbenzene ) 1,2,4-Trimethylbenzene ) sec-btylbenzene ) 1,3-Dichlorobenzene ) 4-isopropyltolene ) 1,4-Dichlorobenzene ) n-btylbenzene ) 1,2-Dichlorobenzene ) l,2-dibromo-3-chloro-propa ) 1,2,4-trichlorobenze ) Naphthalene 87) 1,2,3-Trichlorobenzene yc m m tf m K " m 1 ' j m , , , g/l g/l g/l g/l # g/l g/l g/l g/l g/l g/l g/l g/l # g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l #' g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l (#) = qalifier ot of range (m) = manal integration C31871.D ASP1122W.M Wed Dec 02 11:23: Page 2

92 Data File D:\DATA\C31871.D Acq On 1 Dec :47 am Sample CCV Misc 8260ASP_A2_W,CCV,ml,VB7938 MS Integration Params: rteint.p Qant Time: Dec 2 11: Method Title Last pdate Response via Abndance D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Initial Calibration Vial: 3 Operator: LEF Inst : #12 Mltiplr: 1.00 Qant Reslts File: ASP1122W.RES ISO cn ^ ^^ ^1M ^ C31871.D ASP1122W.M Wed Dec 02 11:23: Page 3

93 Raw Qality Control Data pstate Laboratories, Inc. 247-

94 BFB Data File : D:\DATA\C31722.D Acq On : 22 Nov :8 pm Sample «BFB Misc : VB78- MS Integration Params: rteint.p Method : D:\METHODS\ASP1122W.M (RTE Integrator) Title : VOA 8260 Calibration Vial: 2 Operator: LEF Inst : #12 Mltiplr: 1.00 ASP ItKj C^H. (Abndance TIC:C31722.D j i I (Time > Average of to " min.: C31722~.D (-) ~ ~ ttz~> "l""l"" mim.,,,..,!.,..,,,..!,,!.,,,. p,,,,,,,^,^, tffwjfi III!,, _3QLi0_JL^JlJ0-6_7g AtoFind: Scans 2060, 2061, 2062; Backgrond Corrected with Scan 200 Target Mass Rel. to Mass Lower Limit% pper Limit? Rel. Abnl C31722.D ASP1122W.M Mon Nov 23 14:12: Raw Abn Reslt Pass/Fail PASS PASS PASS PASS PASS PASS PASS PASS PASS

95 BFB Data File : D:\DATA\C3182.D Acq On : 30 Nov :3 pm Sample : BFB Misc : VB78 MS Integration Params: rteint.p Method : D:\METHODS\ASP1122W.M (RTE Integrator) Title : VOA 8260 Calibration Vial: 19 Operator: LEF Inst : #12 Mltiplr: 1.00 Abndance TIC: C3182.D I I ' i I i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i ) i i i i i i i i i i i i i i, i j i i i i i i i i!, i Tlr l ' '..2QM2^MMMMM21.-^^-?^.^-^ , ; labndance Average of to min.: C3182.D (-) Y /^...> AtoFind: Scans 2066, 2067, 2068; Backgrond Corrected with Scan 20 Target Mass Rel. to Mass Lower Limit% pper Limit% Rel. Abn% Raw Abn Reslt Pass/Fail PASS PASS PASS PASS PASS PASS PASS PASS PASS C3182.D ASP1122W.M Te Dec 01 08:01:

96 Lab Name: pstate Labs Inc. Lab Code: Case No.: Matrix: (soil/water) Sample wt/vol:.0 Level: (low/med) % Moistre: not dec. GC Colmn: Soil Extract Volme: 1A VOLATILE ORGANICS ANALYSIS DATA SHEET WATER LOW (g/ml) ML RTX-VO ID: 0.3 (mm) (L) Contract: SAS No.: CASELLA EPA SAMPLE NO. VBLK01 SDG No.: CAS120 Lab Sample ID: MB-474 Lab File ID: C318.D Date Received: 11 /24/2009 Date Analyzed: 11/30/2009 Diltion Factor: 1.0 Soil Aliqot Volme: (L) CAS NO. COMPOND CONCENTRATION NITS: (g/l or g/kg) G/L Q Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofloromethane Acetone 1,1-Dichloroethene lodomethane Carbon Dislfide Methylene Chloride Acrylonitrile trans-1,2-dichloroethene 1,1-Dichloroethane Vinyl Acetate 2-Btanone cis-1,2-dichloroethene Chloroform Bromochloromethane 1,1,1-Trichloroethane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene 1,2-Dichloropropane Bromodichloromethane Dibromomethane 4-Methyl-2-pentanone cis-1,3-dichloropropene Tolene trans-1,3-dichloropropene 1,1,2-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene 1,1,1,2-Tetrachloroethane Ethylbenzene m,p-xylene J! FORM IVOA -20-3/90

97 1A EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: pstate Labs Inc. Contract: CASELLA VBLK01 Lab Code: Case No.: SAS No.: SDG No.: CAS120 Matrix: (soil/water) WATER Lab Sample ID: MB-474 Sample wt/vol:.0 (g/ml) ML Lab File ID: C318.D Level: (low/med) LOW Date Received: 11/24/2009 % Moistre: not dec. Date Analyzed: 11/30/2009 GC Colmn: RTX-VO ID: 0.3 (mm) Diltion Factor: 1.0 Soil Extract Volme: (L) Soil Aliqot Volme: (L) CAS NO. COMPOND CONCENTRATION NITS: (g/l or g/kg) G/L Q o-xylene Styrene Bromoform 1,1,2,2-Tetrachloroethane 1,2,3-Trichloropropane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-chloro-propane 10 FORM I VOA -21-3/90

98 Lab Name: 1E VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPONDS pstate Labs Inc. Lab Code: Case No.: Matrix: (soil/water) Sample wt/vol:.0 Level: (low/med) % Moistre: not dec. GC Colmn: Soil Extract Volme: WATER LOW (g/ml) ML RTX-VO ID: 0.3 (mm) (L) Contract: SAS No.: CASELLA EPA SAMPLE NO. VBLK01 SDG No.: CAS120 Lab Sample ID: MB-474 Lab File ID: C318.D Date Received: 11 /24/2009 Date Analyzed: 11/30/2009 Diltion Factor: 1.0 Soil Aliqot Volme: (L) Nmber TICs fond: 0 CONCENTRATION NITS: (g/l or g/kg) G/L CAS NO. COMPOND NAME RT EST. CONC. Q FORM I VOA-TIC -22-3/90

99 Data File Acq On Sample Misc Qantitation Report D:\DATA\C318.D 30 Nov :30 pm MB ASP_A1_W,MBLK,ml,VB7928 -MS Integration Params: rteint.p Qant Time: Dec 1 11: Qant Method Title Last pdate Response via DataAcq Meth D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Initial Calibration ASP1122W (QT Reviewed) Vial: 22 Operator: LEF Inst : #12 Mltiplr: 1.00 Qant Reslts File: ASP1122W.RES Internal Standards R.T. Qlon Response Cone nits Dev(Min) 1) Pentaflorobenzene 39) 1,4-Diflorobenzene 1) Chlorobenzene-d 67) l,4-dichlorobenzene-d4 System Monitoring Componds 34) 1,2-Dichloroethane-d4 Spiked Amont ) Tolene-d8 Spiked Amont ) Bromoflorobenzene Spiked Amont Target Componds Range Range Range g/l 0.00 g/l 0.00 g/l 0.00 g/l g/l Recovery =.8% g/l Recovery =.14% g/l Recovery =.2 6% Qvale (#) = qalifier ot of range (m) = manal integration C318.D ASP1122W.M Te Dec 01 11:26: Page 1

100 Data File D:\DATA\C318.D Acq On 30 Nov :30 pm Sample MB-474 Misc 8260ASP_A1_W,MBLK,ml,VB7928 MS Integration Params: rteint.p Qant Time: Dec 1 11: Method Title Last pdate Response via Abndance Qantitation Report Vial: 22 Operator: LEF Inst : #12 Mltiplr: 1.00 Qant Reslts File: D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Initial Calibration TIC: C318JD" ASP1122W.RES HO cn *-- ' [ i i i. j I I i r- IL Jl_A_A_ m 3-0 m M 6 M m 8M ^ ^ o ^ ^ 23; ; 00 2 ; 00 ^ ^-^^^ 30 m C318.D ASP1122W.M Te Dec 01 11:26: 2009 Page 2

101 LSC Report - Integrated Chromatogram File Operator Acqired Instrment Sample Name Misc Info Vial Nmber Qant File D:\DATA\C318.D LEF 30 Nov :30 pm sing AcqMethod ASP1122W #12 MB ASP_A1_W,MBLK,ml,VB ASP1122W.RES (RTE Integrator) (Abndance TIC: C3i8lT 1 oooooo H^= "T Effi±±_.3,oo_.3^o 4,og_ 4jg_! bo_jg 6,bo e.so ' ' Yo.'0 'n!oo _ [Abndance """" TIC: C318.D I j I I : I I I! I I 1 IT I I i I l l l l l l l l l [Tinie : JJ^_Q_l^Q-_13.Oj4M _ ^ , jabndance TIC:"C318JD " ~ ~~ -'"" , /1 \ (J t.~'l ".' rs. ss /\ jtime-o. 21^ Te Dec 01 11:22^

102 1A EPA SAMPLE NO. vw/^i ILC -JPi-JttlNIV-,D MINMLYIS AIASHfctr Lab Name: pstate Labs Inc. Contract: CASELLA VMBS01 Lab Code: Case No.: SAS No SDC 3 No.: CAS120 Mat rix: (soil/water) WATER Lab Sample ID: L CS-47^ 1 Sar nple wt/vol:.0 (g/ml) ML Lab File ID: C 3184 D Lev el: (low/med) LOW Date Received: 1 1/24/2C 09 %N/loistre: not dec. Date Analvzed: V I/30/2C 09 GC Colmn: RTX-VO ID: 0.3 (mm) Diltion Fantnr in Soil Extract Volme: (L) Soil Aliqi mt Vnh im«- L, CONCENTRATION NITS: CAS NO. COMPOND (g/l or g/kg) G/L Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofloromethane Acetone 1,1-Dichloroethene lodomethane Carbon Dislfide Methylene Chloride Acrylonitrile trans-1,2-dichloroethene 1,1-Dichloroethane Vinyl Acetate 2-Btanone cis-1,2-dichloroethene Chloroform Bromochloromethane 1,1,1-Trichloroethane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene 1,2-DichloroDroDane Bromodichloromethane Dibromomethane 4-Methvl-2-pentanone cis-1,3-dichloropropene Tolene trans-1,3-dichloropropene 1,1,2-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene 1,1,1,2-Tetrachloroethane Ethylbenzene m,p-xylene FORM IVOA Q 3/90

103 1A VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: pstate Labs Inc. Contract: CASELLA EPA SAMPLE NO. VMBS01 Lab Code: Case No.: SAS No.: SDG No.: CAS120 Matrix: (soil/water) WATER Lab Sample ID: LCS-474 Sample wt/vol:.0 (g/ml) ML_ Lab File ID: C3184.D Level: (low/med) LOW Date Received: 11 /24/2009 % Moistre: not dec. Date Analyzed: 11/30/2009 GC Colmn: RTX-VO ID: 0.3 (mm) Diltion Factor: 1.0 Soil Extract Volme: (L) Soil Aliqot Volme: (L) CAS NO. COMPOND CONCENTRATION NITS: (g/l or g/kg) G/L Q o-xylene Styrene Bromoform 1,1,2,2-Tetrachloroethane JL2,3-Trichloroprpp_ane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Jj2-Dichlorobenzene 1,2-Dibromo-3-chloro-propane 10 JL FORM IVOA -27-3/90

104 Qantitation Report Data File : D:\DATA\C3184.D Acq On : 30 Nov :2 pm Sample : LCS-474 -Misc : 8260ASP_Al_W,LCS,ml,VB7940 -MS Integration Params: rteint.p Qant Time: Dec 1 11: Qant Method : D:\METHODS\ASP1122W.M (RTE Integrator) Title : VOA 8260 Calibration Last pdate : Mon Nov 23 14:3: Response via : Initial Calibration DataAcq Meth : ASP1122W (QT Reviewed) Vial: 21 Operator: LEF Inst : #12 Mltiplr: 1.00 Qant Reslts File: ASP1122W.RES Internal Standards 1) Pentaflorobenzene 39) 1,4-Diflorobenzene 1) Chlorobenzene-d 67) l,4-dichlorobenzene-d4 System Monitoring Componds 34) l,2-dichloroethane-d4 Spiked Amont ) Tolene-d8 Spiked Amont ) Bromoflorobenzene Spiked Amont Target Componds 11) 1,1-Dichloroethene 3 8) Benzene 41) Trichloroethene 2) Tolene 62) Chlorobenzene R.T Qlon Range Range Range Response Cone nits Dev(Min) Recovery = Recovery = Recovery = g/l g/l g/l g/l g/l.00% g/l.92% g/l.86% g/l g/l g/l g/l g/l Qvale 92 (#) = qalifier ot of range (m) = manal integration C3184.D ASP1122W.M Te Dec 01 11:26: Page 1

105 Data File Acq On Sample Misc D:\DATA\C3184.D 30 Nov :2 pm LCS ASP_Al_W,LCS,ml,VB7940 rteint.p MS Integration Params: Qant Time: Dec 1 11: Method Title Last pdate Response via Abndance Qantitation Report Vial: 21 Operator: LEF Inst : #12 Mltiplr: 1.00 Qant Reslts File: D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Initial Calibration TIC: C3184.D~ ASP1122W.RES ) io I « _o as a flltiie- J HI 2M ,0, ,00 8, , J 2, ,00,14,00.1,00 16, , ,00 22^0 2^00 2^00 2:002a00 2Z00 2a00 2^00 30^ C3184.D ASP1122W.M Te Dec 01 11:26: Page 2

106 1A EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: pstate Labs Inc.. Contract: CASELLA MW-29 MS Lab Code: Case No.: SAS No.: SDG No.: CAS120 Matrix: (soil/water) WATER Lab Sample ID: HMS Sample wt/vol:.0 (g/ml) ML Lab File ID: C3188.D Level: (low/med) LOW Date Received: 11/24/2009 % Moistre: not dec. Date Analyzed: 12/1/2009 GC Colmn: RTX-VO ID: 0.3 (mm) Diltion Factor: 1.0 Soil Extract Volme: (L) Soil Aliqot Volme: (L) CAS NO. COMPOND CONCENTRATION NITS: (g/l or g/kg) G/L Q JOQ Chloromethane Vinyl Chloride Bromomethane Chloroethane ^Irighlorofloromethane Acetone 1,1-Dichloroethene lodomethane Carbon Dislfide Methylene Chloride Acrylonitrile trans-1,2-dichloroethene 1,1-Dichloroethane Vinyl Acetate 2-Btanone cis-1,2-dichloroethene Chloroform Bromochloromethane 1,1,1-Trichloroethane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene 1,2-Dichloroprppane Bromodichloromethane Dibromomethane 4-Methvl-2-pentanone cis-1,3-dichloropropene^ Tolene trans-1,3-dichloropropene 1,1,2-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene 1,1,1,2-Tetrachloroethane Ethylbenzene m,p-xylene FORM VOA /90

107 LabName: 1A EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET MW-29 MS fi^tej-absjnc. Contract: CASELLA Lab Code: Case No.: SAS No.: SDG No.: CAS120 Matrix: (soil/water) WATER Lab Sample ID: HMS Sample wt/vol:.0 (g/ml) ML Lab File ID: C3188.D Level: (low/med) LOW Date Received: 11 /24/2009 % Moistre: not dec. Date Analyzed: 12/1/2009 GC Colmn: RTX-VO ID: 0.3 (mm) Diltion Factor: 1.0 Soil Extract Volme: (L) Soil Aliqot Volme: (L) CAS NO. COMPOND CONCENTRATION NITS: (g/l or g/kg) G/L Q , o-xylene Styrene Bromoform J-tL2i2-Tetrachloroethane 1,2,3-Trichloropropane 1,3-Dichlorobenzene 1,4-Dichlorobenzene JL,2-Dichlorobenzene 1,2-Dibromo-3-chloro-propane 10 AL FORM I VOA /90

108 Qantitation Report (QT Reviewed) Data File : D:\DATA\C3188.D Vial: 2 Acq On : l Dec :2 am Operator: LEF Sample : HMS inbt ; #12 Mise : 8260ASP A1_W,MS, ml, Casella,MW-29 Mltiplr: 1.00 MS Integration Params: rteint.p Qant Time: Dec 2 10: Qant Reslts File: ASP1122W.RES Qant Method Last pdate Response via DataAcq Meth D : \METHODS\ASP1122W.M RTE Integrator) VOA Calibration Mon Nov 23 14:3: Initial Calibration ASP1122W Internal Standards R.T. Qlon Response Cone nits Dev(Min) 1) Pentaflorobenzene 39) 1,4-Diflorobenzene 1) Chlorobenzene-d 67) l,4-dichlorobenzene-d4 System Monitoring Componds 34) l,2-dichloroethane-d4 Spiked Amont ) Tolene-d8 Spiked Amont ) Bromoflorobenzene Spiked Amont Target Componds 11) 1,1-Dichloroethene 38) Benzene 41) Trichloroethene 2) Tolene 62) Chlorobenzene 11 Range 16 Range 22 Range Recovery = Recovery = ,.6 Recovery = g/l g/l g/l g/l g/l 93.28% g/l.44% g/l.30% g/l g/l g/l g/l g/l Qvale (#) = qalifier ot of range (m) = manal integration C3188.D ASP1122W.M Wed Dec 02 10:7: Page 1

109 Qantitation Report Data File : D:\DATA\C3188.D Vial: 2 Acq On : l Dec :2 am Operator: LEF Sample : HMS Inst : #12 Mis c : 8260ASP_Al_W,MS,ml,Casella,MW-29 Mltiplr: 1.00 MS Integration Params: rteint.p Qant Time: Dec 2 10: Qant Reslts File: ASP1122W.RES Method Title Last pdate Response via pibncance ; D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Initial Calibration TIC: C3188.D i 1000 I 0000 i I i > CO I I a *,W ' > -^ 3^ 4^ ^0^ ^^^ _ C3188.D ASP1122W.M Wed Dec 02 10:7: Page 2

110 1A VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: pstate Labs Inc. Contract: CASELLA EPA SAMPLE NO. MW-29 MSD Lab Code: Case No.: SAS No.: SDG No.: CAS120 Matrix: (soil/water) WATER Sample wt/vol:.0 (g/ml) ML Level: (low/med) LOW % Moistre: not dec. GC Colmn: RTX-VO ID: 0.3 (mm) Soil Extract Volme: (L) Lab Sample ID: HMS Lab File ID: C3189.D Date Received: 11 /24/2009 Date Analyzed: 12/1/2009 Diltion Factor: 1.0 Soil Aliqot Volme: (L) CAS NO. COMPOND CONCENTRATION NITS: (g/l or g/kg) G/L Q Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofloromethane Acetone 1,1-Dichloroethene lodomethane Carbon Dislfide Methylene Chloride Acrylonitrile trans-1,2-dichloroethene 1,1-Dichloroethane Vinyl Acetate 2-Btanone cis-1,2-dichloroethene Chloroform Bromochloromethane 1,1,1-Trichloroethane Carbon Tetrachloride Benzene 1,2-Dlchloroethane Trichloroethene 1,2-Dichloropropane Bromodichloromethane Dibromomethane 4-Methyi-2-pentanone cis-1,3-dichloropropene Tolene trans-1,3-dichlcropropene 1,1,2-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene 1,1,1,2-Tetrachloroethane Ethylbenzene m,p-xylene FORM I VOA /90

111 1A VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: pstate Labs Inc. Contract: CASELLA EPA SAMPLE NO. MW-29 MSD Lab Code: Case No.: SAS No.: SDG No.: CAS120 Matrix: (soil/water) WATER Sample wt/vol:.0 (g/ml) ML Level: (low/med) LOW % Moistre: not dec. GC Colmn: RTX-VO ID: 0.3 (mm) Soil Extract Volme: (L) Lab Sample ID: HMS Lab File ID: C3189.D Date Received: 11/24/2009 Date Analyzed 12/1/2009 Diltion Factor 1.0 Soil Aliqot Volme: (L) CAS NO. COMPOND CONCENTRATION NITS: (g/l or g/kg) G/L Q o-xylene Styrene Bromoform 1,1,2,2-Tetrachloroethane 1,2,3-Trichloropropane J,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-chloro-propane 10 il FORM IVOA -26-3/90

112 Data File Acq On Sample Misc Qantitation Report D:\DATA\C3189.D 1 Dec :03 am HMSD 8260ASP_A1_W,MSD, ml, Casella,MW-29 MS Integration Params.- rteint.p Qant Time: Dec 2 11: Qant Method Title Last pdate Response via DataAcq Meth D:\METH0DS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon NOV 23 14:3: Initial Calibration ASP1122W (QT Reviewed) Vial Operator Inst Mltiplr 2 LEF # Qant Reslts File: ASP1122W.RES Internal Standards R.T. Qlon Response Cone nits Dev(Min) 1) Pentaflorobenzene 39) 1,4-Diflorobenzene 1) Chlorobenzene-d 67) l,4-dichlorobenzene-d4 System Monitoring Componds 34) l,2-dichloroethane-d4 Spiked Amont ) Tolene-d8 Spiked Amont ) Bromoflorobenzene Spiked Amont Target Componds 11) 1,1-Dichloroethene 38) Benzene 41) Trichloroethene 2) Tolene 62) Chlorobenzene Range Range 88 22,.08 Range 86., Recovery = ,.30 Recovery = Recovery = g/l g/l g/l g/l g/l 92.6% g/l.60% g/l.92% g/l g/l g/l g/l g/l Qvale 92 (#) = qalifier ot of range (m) = manal integration C3189.D ASP1122W.M Wed Dec 02 11:09: Page 1

113 Qantitation Report Data File : D:\DATA\C3189.D Vial: 2 Acq On : l Dec :03 am Operator: LEF Sample : HMSD Inst : #12 Misc : 8260ASP_A1_W,MSD,ml,Casella,MW-29 Mltiplr: 1.00 MS Integration Params: rteint.p Qant Time: Dec 2 11: Qant Reslts File: ASP1122W.RES Method Title Last pdate Response via [Abndance \ D:\METHODS\ASP1122W.M (RTE Integrator) VOA 8260 Calibration Mon Nov 23 14:3: Initial Calibration TIC: C3189JJT ' ! ! 1000 ; 0000 I sen i I % ^- - ^ ^ ' ' ^ C3189.D ASP1122W.M Wed Dec 02 11:09: ,00 21,00 22,00 23, J! &00 29J30 3o!oO ' Page 2

114 Copy of Calclations pstate Laboratories, Inc

115 il Gideline* fnrr-*-,, ' 'nesrar making tentative identification: ' Relative intensities nfr-in,' Oons greater than 1?o p^-tn " "" "'! " WM 'P"" shold ba p rssent ln, / - ^» ^ «abndant ion, ". I ns relative intensities of th-,-,. ±2ao percent. ( E x ^. ^ ^ o n s shold agree within -0.0 percent of the standitso^rt" 3 " abnda "«.of the sample ion abndance T St St *' corrss P nding mst a Percent.) D srween 30.0 and 70.0 " Mo!ec larionspres-nt'nrp--=r Present in sample spec^m "^ SPeCtmm Sho,d bs ' ' ns present in ths samol* 3D=cV,^.. tt not in ^Ps-rm shold be i ^ t ^ t the -fe- n - contamination or ores-n- r" I '?. lbie back 9rona ' n "~ 0? -eltmg componds * ' ns present in 'the referent SDe_-*. spectrm shold be r«vl-^ < P m bt not in ths ssmpf* sample spectrm becase?^rf 0 "^ sbtracf^n from th* e'ting componds. Da.;~sys"rfr'"^^ Gonta^'naHon or cc~- «n sometimes create th~~ ^ j ' ^ redction Programs lfrin-thetachn\r-n,-ri interpretation specialist, no vafich ^ * ' the mass sc^raf compond shold be reports ~ s nnt,gsnnc s«on can be m ^ <h. shold give additional ^ ^ ^ J* 6 mass S P sctra < **<*Z Le., nknown Somatic, nknot l l ^ 9 ^ l f " nknown chlorinated co mpond)n ^yr C r r n Carbon h ' ""known acid tyoe aisng/shed, inclde them. Pr bad,s m 'eclar weights can be f-m Calclations Target Componds internal standard mjih^ltnot^ fdentffied snail be qantified bv <h sed shall be that which f, -L tric fp ^ns below. Tn^ intnm-tcf far*nr'vddc\ - ^ L fnicn ls ^signed n Tsbi» i T- '-.'niernal stanaard ac l0r (RRF) rrom the contining cailb- in ' ns re,at,ve rss oonse al,on concentration in the sample. 3Iandard ''s calclate the Water Eqation Concentration pg/l = _Jijf2_2f)_(DQ_ " " ' (Ai.) (RRF) Vo) 1n/or

116 Where, A - A i3 = Area of the characteristic ion (E\CP\ mr m- be measred (see Tabte 2 impond : Area of the characterise ion ~'Pira\.- H. internal standard ai IarQ (See fs- -i r!w ables f 3 and 4) ror ths specirlc i _ Amont of internal =:f=--<»~rw - ^ n "' ai= ',ard acasd in nanograms (ng) RF= Relative response factor fmn m=., prga of the calibrated s S ^ ' ^ " " ^ h " Df = Volme of water prged in milliliia-sfml) Diltion factor Th«Hi'inSnr,---. of Water samples for v o l ^ ^ T ^ f. ^ as ths ratio ofthe nmber o n f f c " n ^ ^ (i.e., VoaboveTto fte ^ t r V f nv f -^ater P^ed sample sed for pre r^ ^ ^ 1 = ' ^f ^ ^" P ml of sample is dilted to ml ws Z ' ' Df = ml/2.0 ml = 2 - V '.^^nr warer and prged. _ m L 2..., no ailnon is performed, Df = Low Soil/Sediment Eqation 6 Concentration pg/kg (dry weight basis) = - ~ - i ^ L Where, A x, - s, Aj S are as given for water. r\, sf = Relative resnnnc= f-^«-. - D =» - >- i=aiiss lact^r rrnm fh~ '-.--.i calibration standard. "1 - /o_moistr=: (^)(RRF)(W S )(D) r " =ated prge of the W. VVeigM of samp(e ^ fa ^ ^ ^, ^ D-ll-37

117 11.2,1.4 Medim Soil/Sediment eqation 7.Concentration pg/kg (Dry weight basis) = ^ T L t l M i i m A ^ Where, Ax, f A,_- are as given for water. RRF= Relative resdonse farfnr rv«p-ge of the c S ~ -blent temperatre V, " a NOTC^m"?" m lha ' ^act in mi!!fer-,,.. ^ -. in 'S Volme is tvdic?llw-in m/ v " )' < ml is transferred to th= J,al n I f' T? ' tho^ n.'y, l ~ Vla ''n Section 10,1,,6 w 3 = D = Df =.«"«<,L> ^ c ^ S ^ f h = ' **-.< t: Tor prging. ( ' ^ addsd to reagent water Weight of scji/sediment =*>r=c-h " -x.r=c. = d, m grams (g). l Oj_J^TToistr S ' ' Diltion factor Th«rMi.*! - _ soil/sediment samol-=" n r, actorfor a na'ysis of method is defined as ' r V m a b * the tedim l e,el \. r-l most cone eyfr~-fi,r. _J * ^ ^ ^ ^ S 0 ' V n t M- Diltion of the ixtr-c^ h ^ msthano ' e^ct (Section 10,1.,7)!s">p s W r * d When the X ^-tor nmerator.converts th^v-lj n n / ' f 1 ' D in the _ cn- vale or V, rrom ml to L. ' For vva.-=r 'awlai/-/- samples xylenes (o-, m. and ^ So,W a t M ^ ' S " S ' solfe <* nt (total). Becase the o- and D-M nlt ^reported as xylen-s ' _and the, and p., ylene» ^» co-elte on.pack/d coi mns -sntcn mst be given to the oanti^ 0 f f f i *!!! " «P«*I ' ">e xylenes, i he relative em-

118 11.2,2 Non-iargetComponds An estimafed conranfrafio^ ' tentatively identified shall be d e t e r S ^ ^ ^ ; om P ds. ^qantitation, the nearest interna, ^ ^ r ^ ^ t - ^ ^ same as & ^ 3 a ^ - «*. are the. ar " conts peak heights) from the total ion chrorr-w-1,' '' Cr compond to be measred ans h^nnrna T H "??" '. Se ' f r b!h "», factor (RRF) of one (1) s to be ass'l'd T '" d : A r!ativs res P nse be qalified as -J- (estlrna ed d ~ k 0 - " " ^ «"c«nt^o shall factor), and "N-" (presmptive»vhen C. 0 f 0-?f- n J." 3peoific res? nss qantitative and qalitative «* * S S *? ' "" component. An elated concentration S ^ ^ f ^.emativeiy loentmed componds as sell «thn 7-, - ' sen as those identmeo as nknowns., CRQL Calclations MOTE: If the adjsted CRQL is ioas fhsn fho r-arm <,,' repcrtthe CRQL listed in ExhIM C ^ 1 ^. " '" ^ (Vo " rt,9!, >' Water Eqation 8 ' Adjsted CRQL = Protocol CRQL Where, Vs X 77". X Df Vo V 0 and Df are as given in Eqation V* = Contract Sample Volme ( ml) Low Level Soil/Sediment Eqation 9 Adjsted CRQL = Protocol CRQL - LY^L * (W.) (D) D-ll-40

119 Where, W s and D are as given in Eqation 6 W x = Contract Sample Weight ( g) Medim Level Soil/Sediment Eqation 10 _ Where, Adjsted CRQL = Protocol CRQL x ^ ^ ^. (W.) (Vc) (Va) (D) V,/Df, W s, V a, and D ar» as aiv^n in Po,,-- - i -- " yiven in eqation i W x = Contract Sample Weight (4 g) (D!l V ' = W SOii A,lqOt V ime fram ««methanol extract V c = Contract So,] Methanol Extract Vclme (10,C:o p L ) System Monitoring Compond Recoveries V Calclate the recovery of each cw^- m... m compond in all samples, blanks m-r,v LZ mon;i nng and matrix spike blanks Dete minmr' h P m3inx spfke *' ^ates, h Table 7), anlporton a p p S ^ K ^ ^ Withfn " m * ^ compond^ the " j ^ * * *. " do s =c ror iai get componds 11,2.4.3 Calclate the recovprv of =*rh n-,^- n compond as follows: ^ a y% m mor.::onng Eqation 11 %Recover/ = - rj ritration_^ont) fond Concentration (amont) spike; X -H& IR1 10/3S

120 9,3.3 Procedre for Initial Calibration cn - f 9,3 ' 3,1 0 Assemble a prge and trap device ths? me-ts th tne P specmcations in Section'6 4 CnnHiHon «,«J -/ condition the device as described in Section Connect the prge and trao devi>- to m* o-c chromatograpn The gas chromatograoh mst be otratd siho temperatre and flow rate parameters eqivalent to ^osefn 9 1 I. '724 3.'to-rhL 'h Ad - d 1 ML f the intemal stand rd soltion (Senior ' confafninath v V h8 nve.! qs0s ca,ibrati n.standard soltions con.ain ng the system monitoring comoonds (Section 7 2 d nr concentration of 0 pg/l at time of pree. Ana^*T C 'ctorf.. standard according to Section 10. " ^ cdioration ', 'p^^x? *ja^7^r.(nhealed prge vs. heated prge). S & " TO,-*, samples may be analyzed sinn,ho,-.,»!, m - m '- v -' ^on/sediment /.d iy^ a sing the calioraons of water samples. 9.3,4 Calclations for Initial Calibration \ \ volatile tamei^d syssm mttorinn^n ^ T ^ ^ ^ (RRF) f r ac " primary characteristic o ss S '? 9 EqSti n 1 ' The,, - _. ea l0r qant tation ar= ; <;ffah in T^K n. i aole 4. Ass,gn the target.componds, and system monit and to an internal standard according to Tabic 3 i^ntn-sl- 9 Compa^ the se of a primary ion for a giv"en internal-stand*ht * PrBVents listed in Table 4. NOTE- nless othl? stand f d <- S9 a secondary icnthe primary character^ ^ n " ^ S. ^ TO *"»"» <* Eqation 1, RRF = ^- A js x Si C x Where: A = x = ^rea ofthe characteristic inn larni,- ',, _,, d - nstlc. IQ n (ticp) ror the compond to b= measred (see i able 2). A is = Area of the characteristic ion- rpirp\ -,. * -.-.., ll&iarr t=icp) iorthe soecinc hternal standard (see Tables 3 and 4), c = a = Concentration of the internal standard (pg/ml). Concentration of the compond to be measred (pg/ml).!74- D-li j - ' in/c=

121 ?: 3 '4;2 Calclating the relative response factor of the xvnes and the cis- and trans- isomers of 1,2-dichloroethena reaires D4l attention. On packed colmns, o- and p-xylene isomers co-lj>tn ' capillary co mns tne m- and P- Xy lene isomers co-slts. Ther-fore when response (A s ) «nd --oncsntranon (CJ of the peak that reore^ isomer on the Go colmn sed for analysis. its tne sinale whirh **'?,,,. r0f th " Cis " and trans " i3 mers of 1,2-dichloroeth=n= wnich may co-elte on packed colmns bt not on caoii any colmn both isomers mst oe present in the standards. If the two isomers S ^ ^ ^ * t^- * 9 T k 3nd ths t0tal ""cantratlon of the to ' isomers in the standard to determine the relative resoons= facw If f-p two isomers do not co-elte, sm the areas ofthe two peaks ana t = conoerra ens or tne two isomers in the standard to determine th 7il=tiv= esponse ractor i he mean relative response factor ( RRF ) mst b= calclated for all componds.,., n^_ 3 ' 4, Ca, clate the % Relative Standard Deviation f ',pc.n, ( ofthe RRi- vales over the working range ofthe cr^e * Eqation 2 n/dcn - s fe ndar Q deviation /orsd Z x mean Where: \ Standard Deviation = Where: W< - ;y I-I ( n - 1) x, = each individal vale sed to calclate the mean X = n = the mean cf n vales the total nmber of vales -27- D-II-P3

122 Injection Log pstate Laboratories, Inc

123 Sample List for Grop: Printing Date VOA_DeeJT_2009 Dec Lab File ID EPA SAMPLE NO. Lab Sample ID Date Acq. Date Rec. Date De C31722.D C31723.D~ " C31724.D C3172.D C31726.D C31727.D C31728.D C3182.D C3183.D C3184.D C318.D C3186.D C3187.D C3188.D C3189.D C31860.D C31861.D C31862.D C31871.D VTN01 VSTD003 VSTD010 VSTD020 VSTD00 VSTD VSTD200 VTN02 VSTD00CC01 VMBS01 VBLK01 MW-28 MW-29 MW-29 MS MW-29 MSD MW-Z LI Trip Blank Holding Blank VSTD00CC02 BFB ICAL ppb ICAL ppb ICAL ppb ICAL ppb ICAL-2730 pp ICAL pp BFB CCV-474 LCS-474 MB H H HMS HMS H A A CCV /22/ :8 11/22/2009 1:36 11/22/ :1 11/22/ :3 11/22/ :32 11/22/ :11 11/22/ :49 11/30/ :3 11/30/ :13 11/30/ :2 11/30/ :30 12/1/2009 0:08 12/1/2009 0:47 12/1/2009 1:2 12/1/2009 2:03 12/1/2009 2:42 12/1/2009 3:21 12/1/2009 4:00 12/1/2009 9:47 11/24/ /24/ /24/ /24/ /24/ /24/ /24/ /24/ /24/ /24/ /24/ /24/ /24/ /24/ /24/ /24/ /24/ /24/ /24/ /17/ /17/ /17/ /17/ /17/ /17/ /17/ /17/ /17/ /17/ /17/ /17/ /17/ /17/ /17/ /17/ /17/ /17/ /17/2009 Dec Page 1 of VOA_Dec_7_2009 CAS120.ERM

124 SDG Seqence Smmary Instrment Name: 12.0 Sample List Name: VOA_Dec_7_ / lb lb 1/ j Contining Calibration/Tne Date Time File Name 11/22/ :8 C31722.D, 11/22/ :32 C31726.D 11/30/ :3 C3182.D 11/30/ :13 C3183.D _ 12/1/2009 9:47 C31871.D Calibration File Name C31723.D C31724.D C3172.D C31727.D C31728.D Sample File Name C3184.D C318.D C3186.D C3187.D C3188.D C3189.D C31860.D C31861.D C31862.D Ref. Blank File Name C318.D C318.D C318.D C318.D C318.D C318.D C318.D C318.D Misc. TN STD STD STD ICCAL STD STD TN CCAL SMP MBLK SMP SMP MS MSD SMP SMP SMP CCAL Acqisition Date 11/22/ /22/ /22/ /22/ /22/ /22/ /22/ /30/ /30/ /30/ /30/ /1/ /1/ /1/ /1/ /1/ /1/ /1/ /1/2009 Time 14:8 1:36 16:1 16:3 17:32 18:11 18:49 21:3 22:13 22:2 23:30 0:08 0:47 1:2 2:03 2:42 3:21 4:00 9:47 Dec Page 1 of VOA_Dec_7_2009 CAS120.ERM

125 VOLATILE GC/MS INJECTION LOG Instrment: HP971 #12.0 GC Colmn: RTX-Volatile 60m X 0.3mm Client Calibration Method File/Cal.Date: ASP1122W 11/22/09 Method: 8260 Sample ID. BFB ICAL ppb ICAL-2730 IQppb ICAL ppb ICAL ppb ICAL-2730 ppb ICAL ppb Data File Date and Time 11/22/2009 2:8 11/22/2009 3:36 11/22/2009 4:1 11/22/2009 4:3 11/22/2009 :32 11/22/2009 6:11 11/22/2009 6:49 Data Rle C31722.D C31723.D C31724.D C3172.D C31726.D C31727.D C31728.D List fll fll fll fll fll fll fll Matrix W w w w w w Weight/ Volme ml ml ml ml ml ml ml I Analyst: L. Flvnn [ LIMS Seqence: 47306C Dil. Factor IntStd. # IntStd. # I 1193 IntStd. # IntStd. # Pre-Rn Maintenance Prge & Bake system Change trap Change colmn Clean Sorce Change He tank Srr. # Srr. # L.22 Srr. # Comments I N) ~-J CO I Client Name 1.LI 2. Dane 3. NYSDEC-Watertown 4. Casella ASPCL Sorce FedReg,Vol49,#209 SEPA SWB46, Rev 2 SEPA SWB46, Rev w/mtd extraction SEPA CLP OLM03.0 DEC Sperfnd-9-1. B&L 6. Oneida-Herkimer 7. Oswego Conty 8. Steams & Wheler Date 10/26/14 9/1/14 9/1/14 High Low Internal Standard Recovery Limits !S #1 = Pentaflorobenzene IS #2 = 1,4 Diflorobenzene IS #3 = Chlorobenzene- IS #4 = 1,4-d!chlorobenzene-d4 Srr#1 % Recovery Srr #2% Recovery Srr #3 % Recovery ASP Limits Water m«s Method Srrogate Recovery Limits Recoveries limits in Bold Halle Srr#1 = 1,2-DicMoroethane-d4 Srr #2 = Tolene-d8 Srr #3 = Bromoflorobenzene SoB Limits Water Limits Limits I I