CHROM Amphetamine. Methamphetamine. Propylamphetamine Ephedrine

Transcription

1 DRUGS ABUSED DRUGS CHROM ABUSED DRUGS CHROM Amphetamines Club Drugs Methamphetamine -Methoxyamphetamine,-MDA,-MDA,-MDMA,-MDMA -Bromo-, -dimethoxyphenethylamine. Ketamine. Phencyclidine. Cocaine. Flunitazepam.... Amphetamine Methamphetamine Propylamphetamine Ephedrine Min. Econo-Cap EC -, m x.mm x.µm (Part No. ) C Helium at.ml/min ABUSED DRUGS CHROM Heliflex AT -ms, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min (cm/sec) at C ABUSED DRUGS CHROM Drug Mixture Drug Mixture. enedioxymethamphetamine(mdma). Benzocaine. Meperidine. Phencyclidine(PCP). Caffeine. Procaine. Mepivacaine. Methadone. Atropine. Cocaine. Oxazepam. Codeine. Diazepam Heliflex Drug Two, m x.mm x.µm (Part No. ) C to C at C/min Helium at.ml/min Min. ABUSED DRUGS Caffeine Glutethimide Lidocaine Primary Methadone Metabolite Methadone Cocaine Desipramine Min. Econo-Cap EC -, m x.mm x.µm (Part No. ) C Helium at cm/sec CHROM Horse Racing Drug Mixture. Amobarbital. Pentobarbital. Caffeine. Diphenhydramine. Trimipramine. Pentazocine. Phenytoin. Diazepam. Nordiazepam. Boldenone a- Heliflex AT -ms, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min, then to C at C/min Helium at.ml/min..

2 GC APPLICATIONS CHROMATOGRAM DRUGS ABUSED DRUGS CHROM ABUSED DRUGS Ephedra Standards via MSTFA MDMA & MDA Analogs ephedrine Norpseudoephedrine Norephedrine Ephedrine Pseudoephedrine Synephrine Heliflex AT -ms, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min (cm/sec) at C ABUSED DRUGS CHROM.... Min. Heliflex AT -ms, m x.mm x.µm (Part No. ) C Helium at.ml/min (cm/sec) ABUSED DRUGS Meperidine and Metabolite CHROM Nicotine and Metabolite. Meperidine. Normeperidine. Nicotine. Cotinine Econo-Cap EC -, m x.mm x.µm (Part No. ) C Helium at.ml/min Min. Econo-Cap EC -, m x.mm x.µm (Part No. ) C Helium at.ml/min ABUSED DRUGS CHROM Drug Screening. Methoxyflurane. Trimethadione. Amphetamine. Methamphetamine. αα,α α -Dimethyl-β-methylsuccinimide. Ethosuximide. Propylamphetamine.,-Dimethylbarbituric Acid. Nicotine. Ethinamate. Metharbital. Phendimetrazine. Barbital. Methyprylon. Aprobarbital. Methsuximide. Butabarbital. Phenacetin. Amobarbital. Pentobarbital Meperidine Secobarbital Ethotoin Benzphetamine Hexobarbital Lidocaine Mephobarbital Doxylamine Tripelennamine Chlorpheniramine Brompheniramine Cocaine Imipramine Econo-Cap EC -, m x.mm x.µm (Part No. ) C to C at C/min Helium at.ml/min Min.,-MDA,-MDA,-MDMA,-MDMA gc chromatogram CHROM

3 DRUGS ABUSED DRUGS CHROM Stimulant Drug Mixture ABUSED DRUGS CHROM Heliflex AT -ms, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min (cm/sec) ABUSED DRUGS Stimulants CHROM Underivatized Basic Drugs..... Amphetamine Methamphetamine phenidate Caffeine Cocaine Amphetamine Methamphetamine Nicotine Ephedrine Benzocaine Benzphetamine. Phencyclidine. Doxylamine. Procaine. Methadone. Imipramine. Cocaine. Desipramine. Scopolamine. Codeine. Norcodeine. Morphine. Heroin Min. Min. Econo-Cap EC -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min Amphetamine Methamphetamine phenidate Caffeine Cocaine Min. Econo-Cap EC -, m x.mm x.µm (Part No. ) C Helium at.ml/min Acetylcodeine. -Monoacetylmorphine. Diacetylmorphine (Heroin) CHROM Opiates ABUSED DRUGS NUTRACEUTICALS Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min NUTRACEUTICALS CHROM Sterols in Saw Palmetto CHROM Kava-Kava Lactones. Campesterol. Stigmasterol. Sitosterol Dihydrokavain Kavain Desmethoxyyangonin Dihydromethysticin Yangonin Methysticin a- Min. Heliflex AT -ms, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min (cm/sec) at C Min. Heliflex AT -ms, m x.mm x.µm (Part No. ) C to C at C/min Helium at.ml/min (cm/sec)..

4 GC APPLICATIONS CHROMATOGRAM DRUGS ORGANIC VOLATILE IMPURITIES ORGANIC VOLATILE IMPURITIES CHROM USP Trace Volatiles Ethylene Oxide Impurity ene Chloride Chloroform Benzene Trichloroethylene,-Dioxane Dimethyl Sulfoxide Min. Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at cm/sec at C Min. Heliflex AT -, m x.mm x.µm (Part No. ) C Helium at cm/sec ORGANIC VOLATILE IMPURITIES CHROM Pharmaceutical Solvents (Class ) Composite Mix, Min. Heliflex AT -ms, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min, then to C at C/min Helium at.ml/min (cm/sec) BLOOD ALCOHOLS PHARMACEUTICALS Blood Alcohol Test Mix CHROM. Methanol. Acetonitrile. Dichloromethane. Nitromethane. trans-,-dichoroethene. Hexane. cis-,-dichloroethene. Chloroform. -Methoxyethanol.,-Dimethoxyethane. Cyclohexane. Formamide. Ethylene Glycol.,,-Trichloroethene.,-Dioxane Ethoxyethanol cyclohexane Pyridine Toluene N,N-Dimethylformamide butyl Ketone Chlorobenzene N,N-Dimethylacetamide Ethylbenzene m-xylene p-xylene o-xylene N-pyrrolidone Tetralin Sulfolane CHROM Sedatives..... Acetaldehyde Acetone Methanol -Propanol Ethanol. Alprazolam. Triazolam Min. Econo-Cap EC -Wax m x.mm x.µm (Part No. ) C Helium at.ml/min Econo-Cap EC -, m x.mm x.µm (Part No. ) C Helium at.ml/min Ethylene Oxide ene Chloride Chloroform Benzene Trichloroethylene,-Dioxane gc chromatogram USP Method V CHROM

5 DRUGS PHARMACEUTICALS Depressants..... CHROM a- Heliflex AT -ms, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min (cm/sec) CHROM Hypnotics Min. Min. PHARMACEUTICALS Pheniramine Doxylamine Orphenadrine Methapyraline Chlorpheniramine Diphenylpyraline Pheniramine Doxylamine Orphenadrine Methapyraline Chlorpheniramine Diphenylpyraline Promethazine Econo-Cap EC -, m x.mm x.µm (Part No. ) C Helium at.ml/min Min. CHROM Antihistamines Ethosuximide Methsuximide Normethsuximide Mephenytoin PEMA MPEMA Antihistamines CHROM Min. PHARMACEUTICALS PHARMACEUTICALS Amitriptyline Trimipramine Doxepin (cis-doxepin) Imipramine Doxepin (trans-doxepin) Desipramine Maprotyline Clomipramine Econo-Cap AT -, m x.mm x.µm (Part No. ) C Helium at cm/sec Heliflex AT -ms, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min (cm/sec) Antidepressants Min. PHARMACEUTICALS Glutethimide Methaqualone Diazepam Chlorpromazine Flurazepam Heliflex AT -ms, m x.mm x.µm (Part No. ) C Helium at.ml/min (cm/sec) CHROM Anticonvulsants PHARMACEUTICALS CHROM..... Trichloroethanol Allobarbital Butabarbital Secobarbital Methaqualone Min. Econo-Cap EC -, m x.mm x.µm (Part No. ) C to C at C/min Helium at.ml/min..

6 GC APPLICATIONS CHROMATOGRAM DRUGS PHARMACEUTICALS PHARMACEUTICALS CHROM Fast GC Drug Analysis CHROM Fluoxetine and Metabolite. Ethosuximide. αα --αα-propylsuccinimide. Metharbital. Barbital. Methsuximide. Phensuximide. N-Normethsuximide. Mephenytoin. Ethotoin. Mephobarbital. -Ethyl--phenylmalonamide. Phenobarbital. PEMA Heliflex AT -, m x.mm x.µm (Part No. ) C Helium at.ml/min Heliflex AT -, m x.mm x.µm (Part No. ) C Helium at.ml/min PHARMACEUTICALS CHROM Sedatives Ethchlorvynol Ethinamate Methyprylon Aprobarbital Butalbital Amobarbital Pentobarbital Meprobamate Prazepam PHARMACEUTICALS Econo-Cap EC -, m x.mm x.µm (Part No. ) C to C at C/min Helium at.ml/min Min. CHROM STEROIDS Nitrazepam and ANB Metabolite CHROM Steroids, TMS Derivatives. Androsterone. Estrone. Estradiol. Testosterone. Progesterone. -αα-cholestane (underivatized). Estriol. Coprostanol. Cholesterol. Campesterol. Stigmasterol. β-sitosterol. Nitrazepam. -Amino--nitrobenzophenone Heliflex AT -ms, m x.mm x.µm (Part No. ) C Helium at.ml/min (cm/sec) Min. Econo-Cap EC -, m x.mm x.µm (Part No. ) C Helium at.ml/min Hexobarbital Alphenal Methaqualone Halazepam Chlordiazepoxide Triazolam gc chromatogram. Norfluoxetine. Fluoxetine

7 DRUGS STEROIDS CHROM DRUGS Anabolic Steroids Conjugated Estrogens Nandrolone Testosterone Norethandrolone Clostebol Fluoxymesterone αα-estradiol α-α Dihydroequilin Estrone Equilin Estrone methyl ether Min. Econo-Cap EC -, m x.mm x.µm (Part No. ) C Helium at.ml/min Meter x. mm OV -. Micron Film (Catalog Number: -) Helium Oven: C Isothermal Injector: C C F.I.D. Split Injection: : Instrument: CARLO ERBA Minutes DRUGS Pain Killers (Derivatized with BSTFA)..... Nicotine Aspirin Ibuprofen Acetaminophen Caffeine Meter x.mm OV -,. Micron Film (Catalog Number: -) C C at C/minute Injection Temperature C, Split : Detector Temperature C, Detector F.I.D. DRUGS Headspace Analysis - USP Solvents..... ene Chloride Chloroform Benzene Trichloroethylene,-Dioxane Meters x. mm OV -,. Micron Film (Catalog Number: -) Headspace Temperature C Oven: C (Hold minutes) C at C/minute Detector Temperature C, Detector F.I.D. Minutes a-..

8 GC APPLICATIONS CHROMATOGRAM CHLORINATED DISINFECTION CHROM HALOACETIC ACIDS EPA Method : Chlorinated Disinfection Byproducts by NPD.... CHROM EPA Method.: Haloacetic Acids Trichloroacetonitrile Dichloroacetonitrile Bromochloroacetonitrile Dibromoacetonitrile Monochloroacetic Acid Monobromoacetic Acid Dalapon Dichloroacetic Acid Trichloroacetic Acid Bromochloroacetic Acid Dibromoacetic Acid Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min NPD PESTICIDES CHROM Min. Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at cm/sec ECD CHROM Naled Metacil Zectran Carbaryl. TEPP. Carbophenothion. Sulfotepp. Phosmet. Monocrotophos. EPN. Dimethoate. Leptophos. Dioxathion. Azinphos-ethyl. Terbufos. Phosphamidon. Malathion. Parathion. cis-chlorfenvinphos. trans-chlorfenvinphos. Ethion. Famphur Min. Heliflex AT -Pesticide m x.mm x.µm (Part No. ) C Helium at.ml/min ECD Min. Heliflex AT -ms, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at cm/sec MSD PESTICIDES CHROM Chlorinated and Organophosphorus Pesticides. TEPP. Monocrotophos. α α -BHC. Sulfotep. Dimethoate. β-bhc. γ-bhc. δ δ -BHC. Heptachlor. Aldrin. Malathion. Parathion Heptachlor Epoxide Endosulfan I Dieldrin p,p'-dde Endrin Endosulfan II p,p'-ddd Endrin Aldehyde Endosulfan Sulfate p,p'-ddt EPN Methoxychlor Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at ml/min NPD Organophosphorus Pesticides PESTICIDES Carbamates gc chromatogram

9 PESTICIDES CHROM Chlorinated Pesticides. Etridiazole. Chloroneb. Propachlor. Trifluralin. α-α BHC. β-bhc. Pentachloronitro-benzene. γ-bhc. Diclone. Chlorothalonil. δδ -BHC. Alachlor. Heptachlor PESTICIDES CHROM Chlorinated Pesticides PESTICIDES. α-αbhc. γ-bhc. β-bhc. δ-bhc. Heptachlor. Aldrin. Heptachlor Epoxide. Endosulfan I. p,p'-dde. Dieldrin. Endrin. p,p -DDD. Endosulfan II. p,p -DDT. Endrin Aldehyde. Endosulfan Sulfate Diazinon Dimethoate Lorsban Malathion Parathion Ethion Heliflex AT -Pesticide m x.mm x.µm (Part No. ) C Helium at ml/min (.cm/sec) ECD Heliflex AT -Pesticide m x.mm x.µm (Part No. ) C to C at C/min Helium at.ml/min ECD PESTICIDES CHROM EPA Method Chlorinated Pesticides (Chlordane) CHROM EPA Method Organohalide Pesticides a- Endosulfan II p,p -DDD Endrin Aldehyde p,p -DDT Endosulfan Sulfate Captafol Endrin Ketone Methoxychlor Kelthane Mirex cis-permethrin CHROM Pesticide Mix Heliflex AT -ms, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min, to C at C/min, to C at C/min Helium at cm/sec MSD at C PESTICIDES. Aldrin. Dacathal. Heptachlor Epoxide. γ-chlordane. α-α Chlordane. Endosulfan I. trans-nonachlor. p,p -DDE. Dieldrin. Perthane. Nitrofen. Endrin. Chloropropylate Econo-Cap EC -, m x.mm x.µm (Part No. ) C to C at C/min Helium at.ml/min ECD. Hexachlorocyclopentadiene. Simazine. Atrazine. Hexachlorobenzene. Lindane. Alachlor. Heptachlor. Aldrin. Heptachlor Epoxide. γ-chlordane. αα -Chlordane. Dieldrin. Endrin. Methoxychlor Min. Econo-Cap EC -, m x.mm x.µm (Part No. ) C to C at C/min Helium at.ml/min ECD..

10 GC APPLICATIONS CHROMATOGRAM PESTICIDES CHROM EPA Method, Nitrogen and Phosphorus Containing Pesticides by GC/NPD Econo-Cap EC - m x.mm x.µm (Part No. ) C to C at C/min Helium at.ml/min NPD Min. Pronamid Disulfoton Alachlor Ametryn Terbutryn Metolachlor MGK (Peak ) MGK (Peak ) Merphos (Peak ) Butylate Napropamide Merphos (Peak ) Fenarimol PESTICIDES gc chromatogram. Dichlorvos. EPTC. Vernolate. Pebulate. Tebuthiuron. Molinate. Ethoprop. Atraton. Simazine. Atrazine. Propazine. Terbufos CHROM EPA Method Chlorinated Pesticides in Water SEMIVOLATILES CHROM Min. SEMIVOLATILES CHROM Phenols..... Phenol -Chlorophenol -Nitrophenol,-Dimethylphenol,-Dichlorophenol Econo-Cap EC - m x.mm x.µm (Part No. ) C to C at C/min Helium at.ml/min ECD Base/Neutral Mix. -Chloro--phenol.,,-Trichlorophenol.,-Dinitrophenol. -Nitrophenol. --,-Dinitrophenol. Pentachlorophenol Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min....,-dichlorobenzene,-dichlorobenzene,-dichlorobenzene Hexachloroethane. Nitrobenzene. Isophorone.,,-Trichlorobenzene. Hexachlorobutadiene. Hexachlorocyclopentadiene. -Chloronaphthalene.,-Dinitrotoluene.,-Dinitrotoluene. Azobenzene. Hexachlorobenzene Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min αα -Chlordane. Dieldrin. p,p'-dde. Endrin. p,p'-ddd. Endrin Aldehyde. Endosulfan Sulfate. p,p'-ddt. Methoxychlor. cis-permethrin. trans-permethrin. Propachlor. Trifluralin. αα -HCH. Hexachlorobenzene. β-hch. γ-hch. δδ -HCH. Heptachlor. Aldrin. DCPA. Heptachlor Epoxide. γ-chlordane

11 SEMIVOLATILES SEMIVOLATILES CHROM Phthalate and Adipate Esters CHROM EPA Method - Phthalates Dimethyl Phthalate Diethyl Phthalate Di-n-Butyl Phthalate Butylbenzyl Phthalate Di(-ethylhexyl) Adipate Di(-ethylhexyl) Phthalate Di-n-Octyl Phthalate Min. Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at cm/sec at C SEMIVOLATILES CHROM. Isophorone. Nitrobenzene.,-Napthoquinone Min. Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min (cm/sec) SEMIVOLATILES EPA SW Method Nitroaromatics and Cyclic Ketones CHROM EPA Method : Chlorinated Hydrocarbons.,-Dinitrotoluene.,-Dinitrobenzene.,-Dinitrotoluene Min. Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.cm/sec SEMIVOLATILES CHROM.... Naphthalene Acenaphthylene Acenaphthene Fluorene,-Dichlorobenzene,-Dichlorobenzene,-Dichlorobenzene Hexachloroethane,,-Trichlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene -Chloronaphthalene Hexachlorobenzene Min. Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min CHROM Fast PAH Analysis. Phenanthrene. Anthracene. Fluoranthene. Pyrene. Benz[a]anthracene. Chrysene. Benzo[b]fluoranthene. Benzo[k]fluoranthene. Benzo[a]pyrene. Indeno[,,-c,d]pyrene. Dibenz[a,h]anthracene. Benzo[g,h,i]perylene Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min SEMIVOLATILES EPA Method : Polynuclear Aromatic Hydrocarbons a- Dimethylphthalate (ng) Diethylphthalate (ng) Di-n-butylphthalate (ng) Butylbenzyl Phthalate (ng) Bis(-ethylhexyl)phthalate (ng) Di-n-octylphthalate (ng) Naphthalene Acenaphthylene Acenaphthene Fluorene Phenanthrene Anthracene. Fluoranthene. Pyrene. Benz[a]anthracene. Chrysene. Benzo[b]fluoranthene. Benzo[k]fluoranthene. Benzo[a]pyrene. Indeno[,,-c,d]pyrene. Dibenz[a,h]anthracene. Benzo[g,h,i]perylene Heliflex AT -, m x.mm x.µm (Part No. ) C to C at C/min Helium at.ml/min ( cm/sec)..

12 GC APPLICATIONS CHROMATOGRAM SEMIVOLATILES CHROM PAHs Naphthalene Acenaphthylene Acenaphthene Fluorene Phenanthrene Anthracene Fluoranthene Pyrene. Benz[a]anthracene. Chrysene. Benzo[b]fluoranthene. Benzo[k]fluoranthene. Benzo[a]pyrene. Indeno[,,-c,d]pyrene. Dibenz[a,h]anthracene. Benzo[g,h,i]perylene Heliflex AT -ms, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min, to C at C min, to C at C/min Helium at.ml/min (cm/sec) SEMIVOLATILES gc chromatogram CHROM Phenols Mix on AT -ms Chloro--methylphenol.,,-trichlorophenol.,,-Trichlorophenol.,-Dinitrophenol. -Nitrophenol.,,,-Tetrachlorophenol. --,-dinitrophenol. Pentachlorophenol Heliflex AT -ms, m x.mm x.µm (Part No. ) C (. min hold) to C at C/min Helium at ml/min (cm/sec) at C VOLATILES CHROM Aromatic Solvents,. Benzene. Toluene. Chlorobenzene. Ethylbenzene. m-xylene. p-xylene. o-xylene.,-dichlorobenzene.,-dichlorobenzene.,,-trichlorobenzene. Napthalene.,,-Trichlorobenzene Min. Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min (cm/sec) Phenol -Chlorophenol o-cresol m & p-cresol -Nitrophenol,-Dimethylphenol,-Dichlorophenol,-Dichlorophenol

13 VOLATILES CHROM OSHA Method : Organic Vapors. Pentane. Hexane. Isopropyl Ether. Isooctane. Heptane. Cyclohexane. Carbon Disulfide. cyclohexane. trans-,-dichloroethene. Ethyl Acetate. tert-butyl Alcohol. Isopropyl Acetate, Propyl Acetate cis-,-dichloroethene Isobutyl Acetate,-Dioxane Butyl Acetate -Butanol Cumene Chlorobenzene Heliflex AT -Wax, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min (cm/sec) Min VOLATILES CHROM OSHA Method : Organic Vapors,. Pentane. tert-butyl Alcohol. Carbon Disulfide. trans-,-dichloroethene. Hexane. Isopropyl Ether. cis-,-dichloroethene. Ethyl Acetate. -Butanol. Cyclohexane. Isopropyl Acetate. Isooctane Heptane,-Dioxane Propyl Acetate cyclohexane Isobutyl Acetate Butyl Acetate Chlorobenzene Cumene VOLATILES Min. VOLATILES CHROM EPA Method Purgeable Halocarbons Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min (cm/sec) CHROM EPA Method Purgeable Aromatics Benzene Toluene Ethylbenzene Chlorobenzene,-Dichlorobenzene,-Dichlorobenzene,-Dichlorobenzene a- Chloride Vinyl Chloride Dichlorofluoromethane Bromide Ethyl Chloride Trichlorofluoromethane ene Chloride Min. Heliflex AT -, m x.mm x.µm (Part No. ) C Helium at ml/min Min. Heliflex AT -WAX, m x.mm x.µm (Part No. ) C to C at C/min Helium at ml/min..

14 GC APPLICATIONS CHROMATOGRAM VOLATILES CHROM Min cis-,-dichloropropene trans-,-dichloropropene,,-trichloroethane Tetrachloroethene Chlorodibromomethane Chlorobenzene Bromoform,,,-Tetrachloroethane m-dichlorobenzene p-dichlorobenzene o-dichlorobenzene Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at ml/min VOLATILES gc chromatogram. Methane. Chloromethane. Chloroethane. ene Chloride. Bromochloromethane. Chloroform.,,-Trichloroethane. Carbon Tetrachloride.,-Dichloroethane. Trichloroethylene.,-Dichloropropane. Bromodichloromethane Priority Pollutant Analysis CHROM EPA Method Purge & Trap Volatiles Sample: Trap: Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at ml/min ppb in ml H Purge min at ml/min, Desorb at C for min MSD Chloromethane. Vinyl Chloride. Bromomethane. Chloroethane. Trichlorofluoromethane.,-Dichloroethane. ene Chloride. trans-,-dichloroethane.,-dichloroethane. Chloroform.,,-Trichloroethane. Carbon Tetrachloride. Benzene.,-Dichloroethane. Trichloroethene.,-Dichloropropane. Bromodichloromethane. cis-,-dichloropropene. Toluene. trans-,-dichloropropene. Tetrachloroethene +,,-Trichloroethane. Dibromochloromethane. Chlorobenzene. Ethylbenzene. Bromoform.,,,-Tetrachloroethane. m-dichlorobenzene. p-dichlorobenzene. o-dichlorobenzene

15 VOLATILES CHROM Halocarbons.,-Dichloroethane. Chloroform.,-Dichloroethane.,,-Trichloroethane. Carbon Tetrachloride.,-Dichloropropane. Bromodichloromethane + Trichloroethene. -Chloroethyl Vinyl Ether. trans-,-dichloropropene. cis-,-dichloropropene VOLATILES Min. VOLATILES. Ethyl Acetate. tert-butyl acetate. Propyl Acetate. sec-butyl acetate. Ethyl Acrylate. Isobutyl Acetate. Butyl Acetate. Isoamyl Acetate. Amyl Acetate. -Ethoxyethyl Acetate Min. Heliflex AT -Wax, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min (cm/sec) VOLATILES CHROM a-. Vinyl Chloride.,-Dichloroethene. -Butanone. Chloroform. Carbon Tetrachloride. Benzene +,-Dichloroethene. Trichloroethene. Tetrachloroethene. Chlorobenzene., -Dichlorobenzene Min. Heliflex AT -., m x.mm x.µm (Part No. ) C (min hold) to C at C/min Helium at cm/sec UST CHROM TRPH Standard (Florida).... Benzene Toluene Chlorobenzene Ethylbenzene,-Dichlorobenzene,-Dichlorobenzene,-Dichlorobenzene Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min TCLP Volatiles Mix EPA Method Purgeable Aromatics CHROM NIOSH Acetates CHROM Heliflex AT - m x.mm x.µm (Part No. ) C ( min hold) to C/min at C/min Helium at ml/min,,-trichloroethane Dibromochloromethane Tetrachloroethene Chlorobenzene Bromoform,,,-Tetrachloroethane m-dichlorobenzene p-dichlorobenzene o-dichlorobenzene n-octane n-decane n-dodecane n-tetradecane. n-hexadecane. n-octadecane. n-eicosane. n-docosane. n-tetracosane. n-hexacosane. n-octacosane. n-triacontane. n-dotriacontane. n-tetratriacontane. n-hexatriacontane. n-octatriacontane. n-tetracontane Heliflex AT -ht, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at ml/min (cm/sec) at C..

16 GC APPLICATIONS CHROMATOGRAM Arochlor, Arochlor ppm each Meter x. mm OV -,. Micron Film (Catalog Number: -) C (Hold minute) C at C/minute gc chromatogram minutes Arochlor, PPM % TOT : : : : : Meter x. mm OV -,. Micron Film (Catalog Number: -) C C at C/minute. µl Injection : split

17 . dichlorodifluoromethane. chloromethane. vinyl chloride. bromomethane. chloroethane. trichlorofluoromethane.,-dichloroethene. methylene chloride. trans-,-dichloroethene.,-dichloroethane. cis-,-dichloroethene.,-dichloropropane. bromochloromethane. chloroform.,,-trichloroethane ,-dichloroethane,-dichloropropene benzene carbon tetrachloride fluorobenzene,-dichloropropane trichloroethene dibromomethane bromodichloromethane trans-,-dichloropropene cis-,-dichloropropene,,-trichloroethane toluene,-dichloropropane dibromochloromethane,-dibromoethane tetrachloroethene chlorobenzene,,,-tetrachloroethane ethylbenzene p,m-xylene bromoform styrene o-xylene,,,-tetrachloroethane,,-trichloropropane isopropylbenzene -bromofluorobenzene bromobenzene n-propylbenzene -chlorotoluene -chlorotoluene Meter x. mm, OV -,. µm (Catalog Number: -) C (Hold minutes) C at C/ minute (hold minutes) HP Series II with A MS Detector,,-trimethylbenzene tert-butylbenzene,,-trimethylbenzene sec-butylbenzene,-dichlorobenzene,-dichlorobenzene -isopropyltoluene,-dichlorobenzene-d,-dichlorobenzene n-butylbenzene,-dibromo--chloropropane,,-trichlorobenzene naphthalene hexachlorobutadiene,,-trichlorobenzene. Purgable Organics Chromatogram Courtesy: Mr. Michael Tedrick, Special Analytical Services, Parkersburg, WV EDB, DBVCP, Trihalomethane Meter x. mm x. µm OV - (Catalog Number: -) C (Hold minutes) C at C/minute Injector and Detector Temperature Direct Injection Helium. cm/minute a- Chloroform Bromodichloromethane Dibromochloromethane Dibromomethane Bromoform, Dibromo Chloropropane..

18 GC APPLICATIONS CHROMATOGRAM Endocrine Disruptors - Alkyl Phenol Meter x. mm OV -,. Micron Film (Catalog Number: -) Oven: C C at C/minute (Hold minutes) gc chromatogram Tert-butyl phenol n-pentyl phenol n-hexyl phenol n-heptyl phenol Tert-octyl phenol n-octyl phenol n-nonyl Bisphenol A Minutes Meter x. mm OV -,. Micron Film (Catalog Number: -) Oven: C (Hold minutes) C at C/minute (Hold minutes) (All Compounds ated). Monochloroacetic acid (MCAA). Monobromoacetic acid (MBAA). Dichloroacetic acid (DCAA). Dalapon. Bromochloroacetic acid (BCAA). Trichloroacetic acid (TCAA). Dibromoacetic acid (DBAA). Bromodichloroacetic acid (BDCAA). Chlorodibromoacetic acid (CDBAA). Tribromoacetic acid (TBAA) Minutes EPA Method.

19 EPA Method Phthalates Meter x. mm OV -,. Micron Film (Catalog Number: -) C C at C/minute (Hold minutes) Injection Temperature C Detector Temperature C, Detector F.I.D Methanol Dimethyl Phthalate Di-N-Butyl Phthalate Butyl Benzyl Phthalate Bis(-Ethylhexyl) Phthalate Di-N-Octyl Phthalate Minutes EPA Method Pesticides Meter x. mm OV -,. Micron Film (Catalog Number: -) Helium C C at C/minute. αα -BHC. β-bhc. γ-bhc. ζ-bhc. Heptachlor. Aldrin. Heptachlor epoxide. Endosulfan I., ' DDE Dieldrin Endrin Endosulfan II, ' DDD Endrin Aldehyde Endosulfan sulfate, ' DDT Dibutyl chlorendate minutes EPA Method Halocarbons Meter x. mm OV -,. Micron Film (Catalog Number: -) Temperature Program C C at C/minute Injection Temperature C Detector Temperature C, Detector F.I.D Bis (-Chloroethyl) Ether Bis (-Chloroisopropyl) Ether Bis (-Chloroethoxy) Methane -Chlorophenyl Phenyl Ether -Bromophenyl Phenyl Ether Minutes a-..

20 GC APPLICATIONS CHROMATOGRAM EPA Method Chlorinated Hydrocarbons Meter x. mm OV -,. Micron Film (Catalog Number: -) Temperature Program C C at C/minute Injection Temperature C Detector Temperature C, Detector F.I.D Minutes, -Dichlorobenzene, -Dichlorobenzene, -Dichlorobenzene Hexachloroethane,, -Trichlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene -Chloronapthalene Hexachlorobenzene EPA Method Meter x. mm OV -,. Micron Film (Catalog Number: -) C C at /minute Phenol -Chlorophenol -Nitrophenol,-Dimethylphenol,-Dichlorophenol -Chloro m-cresol.,,-trichlorophenol.,-dinitrophenol. -Nitrophenol.,-Dinitro o-cresol. Pentachlorophenol minutes EPA Methods / Meter x.mm OV -,. Micron Film (Catalog Number: -) C C at C/minute Injection Temperature C Split :, Detector MSD Transfer C gc chromatogram Ethanol Diethyl Ether Acrolein Acetonitrile Acrylonitrile -Butanone (MEK) Isobutyl Ketone (MIBK) Paraldehyde Acrylamide Minutes

21 Phenols (EPA ) Meter x. mm OV -,. Micron Film (Catalog Number: -) Oven: C (Hold minutes) C at C/minute Injection Temperature C, Split :,. ul Split Detector Temperature C Helium at psi. Phenol. -Chlorophenol. -Nitrophenol.,-Dimethylphenol.,-Dichlorophenol. -Chloro--methylphenol.,,-Trichlorophenol.,-Dinitrophenol. -Nitrophenol. -,-Dinitrophenol. Pentachlorophenol Minutes Hazardous Substance Mix Meter x. mm OV -,. Micron Film (Catalog Number: -) Oven: C C at C/minute (Hold minutes) Injection Temperature C Detector Temperature C. Aniline. Benzyl Alcohol. -phenol. -phenol. -Chloroaniline. -naphthalene.,,-trichlorophenol. -Nitroaniline. -Nitroaniline. Dibenzofuran. -Nitroaniline Minutes a-..

22 GC APPLICATIONS CHROMATOGRAM EPA Method - Aromatics % TOT. Benzene. Toluene. Chlorobenzene. Ethylbenzene., -Xylene., -Xylene., -Xylene., Dichlorobenzene., Dichlorobenzene., Dichlorobenzene : gc chromatogram Meter x. mm x. µm OV - (Catalog Number: -) C ( minutes) C at C/minute (Hold minutes) Purge and Trap Injection : : : European Red List Volatiles ,-Dichloroethylene,-Dichloroethane Chloroform,,-Trichloroethane,-Dichloroethane Carbon Tetrachloride Trichloroethylene Tetrachloroethylene. Minutes Meter x.mm OV -,. Micron Film (Catalog Number: -) C C at C/minute Injection Temperature Split : - Headspace Injector Detector Temperature C, Detector F.I.D.

23 Organochlorine Pesticides Meter x. mm x. µm OV - (Catalog Number: -) C C at C/minute (Hold minute) C C at C/minute (Hold minutes). αα -hexachlorocyclohexane. Lindane. Heptachlor. Aldrin. β-hexachlorocyclohexane. δ-δ hexachlorocyclohexane. Heptachlor epoxide. Endosulphan I., ' DDE. Dieldrin. Endrin. Endosulphan II., ' DDD., ' DDT. Endrin aldehyde. Endosulfan sulfate Organophosphorus Pesticides Meter x. mm OV -,. Micron Film (Catalog Number: -) C (Hold minutes) C at C/minute Helium at cm/second. Mevinphos. Demeton-O. Phorate. Demeton-S. Monocrotophos. Disulfoton. parathion. Merphos. Ethyl parathion. Fenthion. Fensulfothion Minutes a-..

24 GC APPLICATIONS CHROMATOGRAM Pesticides Meter x.mm OV -,. Micron Film (Catalog Number: -) C C at C/minute Injection Temperature: C Detector Temperature: C E.C.D. gc chromatogram. Alpha-BHC. Gamma-BHC. Beta-BHC. Delta-BHC. Heptachlor. Aldrin. Heptachlor Epoxide. Gamma-Chlordane. Alpha-Chlordane.,'-DDE. Endosulfan. Dieldrin. Endrin.,'-DDD. Endosulfan II.,'-DDT. Endrin Aldehyde. Methoxychlor. Endosulfan Sulfate. Endrin Ketone Minutes Pesticides - Packed Port.,,, Tetrachlorometaxylene (is). α-α BHC. υ-bhc. Heptachlor. Aldrin. β-bhc. ξ-bhc. Heptachlor epoxide. Endosulphin I. γ-chlordane. α α -chlordane. DDE. Dieldrin. Endrin. DDD. Endosulphin II. DDT. Endrin aldehyde. Methoxyclor. Endosulphin sulfate. Endrin Ketone. Decachlorobiphenyl (is) Meter x. mm x. µm OV - (Catalog Number: -) C C at C/minute (Hold minutes) Flow cm/sec

25 Volatiles Meter x. mm OV -,. Micron Film (Catalog Number: -) Direct injection,µl (split) Oven: C (Hold min.) C at C/min.,µl Temp C Detector Temp GC/MS Detector Chloroform Bromodichloromethane Dibromochloromethane, Dibromoethane Bromoform, Dibromo Chloropropane Phthalate Esthers Meter x. mm x. µm OV - (Catalog Number: -) C C at C/minute (Hold minutes). Dimethyl phthalate. Diethyl phthalate. Di-isobutyl phthalate. Di n-butyl phthalate. bis (methoxyethyl) phthalate. bis (-methyl--pentyl) phthalate. bis (ethoxyethyl) phthalate. Di-amyl phthalate. Hexyl -ethylhexyl phthalate. Di-n-hexyl phthalate. Butylbenzyl phthalate. bis (-n-butoxyethyl) phthalate. Dicyclohexyl phthalate. bis (-ethylhexyl) phthalate. Di-nodyl phthalate. Di-nonyl phthalate Nitroaromatics Meter x.mm OV -,. Micron Film (Catalog Number: -).µl split injection Oven: C C at C/min. µl Temp C Detector Temp F.l.D..... a- minutes Nitrobenzene Isophorone, -Dinitrotoluene, -Dinitrotoluene minutes..

26 GC APPLICATIONS CHROMATOGRAM Polynuclear Aromatic Hydrocarbons Meter x. mm OV -,. Micron Film (Catalog Number: -) C (Hold minutes) then C/ minute to C (Hold minutes) Helium, Sample: µg/ml each in ml methylene chloride:benzene (:) C F.I.D. gc chromatogram. Naphthalene. Acenaphthylene. Acenaphthene. Fluorene. Phenanthrene. Anthracene. Fluoranthene. Pyrene. Benzo (a) anthracene. Chrysene. Benzo (a) fluoranthene. Benzo (k) fluoranthene. Benzo (a) Pyrene. Indeno (-cd) pyrene. Dibenzo (ah) anthracene. Benzo (ghi) perylene TCLP Mix. Vinyl Chloride., -Dichloroethane. -Butanone. Chloroform., -Dichloroethane. Benzene/cc. Fluorobenzene (IS#). Trichloroethane. -Bromo--chloropropane (IS #). Tetrachloroethene. Chlorobenzene., -dichlorobenzene minutes minutes Meter x.mm OV -,. Micron Film (Catalog Number: -).,µl split injection (:split) Concentration,µl/ml Oven: C (hold min) C at /min. µl Temp C Detector Temp Helium GC/MS

27 Various Volatiles Compounds Meter x.mm, OV -,. µm (Catalog Number: -) C (Hold minutes) C at C/ minute (hold. minute) Flow:.ml/minute Split Injection : Injector: C Transfer Line C Chromatogram Courtesy: Mr Michael Tedrick, Special Analytical Services, Parkersburg, WV Fluorobenzene. dichlorodifluoromethane. chloromethane. vinyl chloride. bromomethane. chloroethane. trichlorofluoromethane., -dichloroethene. methylene chloride. trans-, -dichloroethene., -dichloroethane., -dichloropropane. cis- -dichloroethene bromochloromethane chloroform,, -trichloroethane, -dichloroethane, -dichloropropene benzene carbon tetrachloride, -dichloropropane trichloroethene dibromomethane bromodichloromethane trans-, -dichloropropene. cis-, -dichloropropene.,, -trichloroethane. toluene., -dichloropropane. dibromochloromethane., -dibromoethane. tetrachloroethene. chlorobenzene.,,, -tetrachloroethane ethylbenzene. m, p-xylene bromoform. styrene o-xylene.,, -tetrachloroethane.,, -trichloropropane. isopropylbenzene. -bromofluorobenzene. bromobenzene. n-propylbenzene. -chlorotoluene. -chlorotoluene.,, -trimethylbenzene. tert-butylbenzene.,, -trimethylbenzene. sec-butylbenzene., -dichlorobenzene., -dichlorobenzene. -isopropyltoluene., -dichlorobenzene-d., -dichlorobenzene. n-butylbenzene., -dibromo--chloropropane.,, -trichlorobenzene. naphthalene. hexachlorobutadiene.,, -trichlorobenzene Phenols Mix Solvent Meter x.mm OV -. Micron Film (Catalog Number: -).µl split injection - µg/µl per component Oven: C (Hold minutes) C at /minute µl Temp C Detector Temp Split Injection (:). Phenol. -Chlorophenol. -Nitrophenol., -Dimethylphenol., -Dichlorophenol. -Chloro--methylphenol.,, -Trichlorophenol., -Dinitrophenol. -Nitrophenol. -, -Dinitrophenol. Pentachloropheno minutes a- minutes minutes..

28 GC APPLICATIONS CHROMATOGRAM Volatile Organic Compounds (VOC) Purge & Trap gc chromatogram Meter x. mm OV -,. Micron Film (Catalog Number: -) Oven: C (Hold minutes) C at C/minute Injection Temperature C Detector Temperature C, Detector F.I.D..,-Dichloroethene. ene Chloride.,-Dichloroethane. Carbon Tetrachloride. Benzene. Trichloroethene.,-Dichloropropane. -Chloroethyl Vinyl Ether.,,-Trichloroethane. Tetrachloroethene. Dibromochloromethane. Chlorobenzene Minutes Meter x.mm OV -,. Micron Film (Catalog Number: -) Temperature Program C (Hold minute) C at C/minute Injection Temperature C, Split : Detector MSD Transfer C.,-Dichloroethene. ene Chloride. -Butanone (MEK). Chloroform.,-Dichloroethane. Benzene. Carbon Tetrachloride. Trichloroethene. Pyridine. Tetrachloroethene. Chlorobenzene Minutes Volatile Organic Compounds (VOC)

29 Headspace Analysis of Volatile Aromatics Meters x. mm OV -,. Micron Film (Catalog Number: -) Headspace Temperature C Oven: C (Hold minutes) C at C/minute (Hold minutes) Detector Temperature C, Detector F.I.D.. p-xylene. Isopropyl benzene. o-xylene. n-propyl benzene. Chlorobenzene. Tert-butyl benzene. Sec-butyl benzene. -Chlorotoluene. -Chlorotoluene.,-Dichlorobenzene.,-Dichlorobenzene.,-Dichlorobenzene Minutes Nitroaromatics Meter x. mm OV -,. Micron Film (Catalog Number: -) Oven: C C at C/minute Injection Temperature C Detector Temperature C Helium at linear velocity of cm/second.... Nitrobenzene Isophorone,-Dinitrotoluene,-Dinitrotoluene Minutes a-..

30 GC APPLICATIONS CHROMATOGRAM FOODS FLAVORS FRAGRANCES FREE FATTY ACIDS FREE FATTY ACIDS CHROM Free Fatty Acids Heliflex AT -AquaWax-DA m x.mm x.µm (Part No. ) C Helium at cm/sec FREE FATTY ACIDS Propionic Acid Butyric Acid Valeric Acid Caproic Acid Heptanoic Acid Caprylic Acid Min. Short Chain Free Fatty Acids Acetic Acid Propionic Acid Isobutyric Acid n-butyric Acid Isovaleric Acid n-valeric Acid Caproic Acid Heptanoic Acid Min. Econo-Cap EC - m x.mm x.µm (Part No. ) C Helium at ml/min FREE FATTY ACIDS CHROM C-C Acids (Aqueous) gc chromatogram CHROM CHROM Low Molecular Weight Acids Water Formic Acid Acetic Acid Propionic Acid ft x mm i.d., Glass Porapak QS, / (Part No. ) C Helium at ml/min TCD ALCOHOLS Min. Heliflex AT -AquaWax m x.mm x.µm (Part No. ) C ( min hold) to C at C/min, then to C at C/min Helium at cm/sec Min. m x mm i.d., Glass % Carbowax M on Carbograph -DA, / (Part No. ) C Nitrogen at ml/min ALCOHOLS CHROM The Glenlivet Scotch CHROM Red Wine Spiked with Off Flavor, Ethyl Acetate Methanol Ethanol -Propanol Isobutanol ---butanol ---butanol -Ethylguaiacol -Ethylphenol Min. Heliflex AT -AquaWax-DA m x.mm x.µm (Part No. ) C( min hold) to C at C/min Helium at cm/sec Formic Acid Acetic Acid Propionic Acid Isobutyric Acid Butyric Acid Isovaleric Acid Lactic Acid Valeric Acid

31 FOODS FLAVORS FRAGRANCES ALCOHOLS ALCOHOLS CHROM Scotch Whiskey Acetaldehyde Ethyl Acetate Methanol Ethanol n-propanol Isobutanol Amyl Alcohol Isoamyl Alcohol Acetic Acid Econo-Cap EC -Wax m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at ml/minute ALCOHOLS C-C Alcohols CHROM CHROM. -Butanol. ---butanol.,-dimethyl--propanol. ---butanol. -Pentanol. -Pentanol. ---butanol. ---butanol. -Pentanol Min. ft x mm i.d., Glass,.% Carbowax Carbograph, / (Part No. ) C Nitrogen at ml/min ALCOHOLS CHROM Scotch Whiskey Methanol Ethanol -Propanol -Propanol ---propanol -Butanol ---propanol Irish Whiskey Acetaldehyde Methanol Ethanol Ethyl Acetate n-propanol Isobutanol Pentanol Isopentanol Acetic Acid m x mm i.d., Glass Carbograph AW, / C to C at C/min Nitrogen at ml/min Heliflex AT -AquaWax m x.mm x.µm (Part No. ) C ( min hold) to C at C/min, then to C at C/min Helium at cm/sec at C AMINO ACIDS CHROM N(O,S)-Heptafluorobutyl-isobutyl Esters of Amino Acids from Soy Protein Hydrolysate Alanine Glycine Valine Threonine Serine Leucine Isoleucine Proline Cystine a Methionine Aspartic Acid Phenylalanine Glutamic Acid Lysine Tyrosine Arginine Histidine Tryptophan Heliflex AT -Amino Acid m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at ml/min..

32 GC APPLICATIONS CHROMATOGRAM FOODS FLAVORS FRAGRANCES ANTIOXIDANTS ESSENTIAL OILS CHROM Phenolic Antioxidants Min. CHROM trans--hexenal p-cymene cis--hexenol trans--hexenol Ethyl Octanoate -Octene--ol Benzaldehyde. Pentadecane. Linalool. Acetophenone. Carvone. Hexadecane. Salicylate. Benzyl Alcohol Min. Heliflex AT -, m x.mm x.µm (Part No. ) C to C at C/min Hydrogen at.ml/min ESSENTIAL OILS CHROM Citrus Reference Mix Peppermint Oil. α-α Pinene. Camphene. β-pinene. p-cymene. Limonene. Nonanal + Linalool. Terpen--ol. γ-terpineol. Neryl Acetate. Geranyl Acetate Min. Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at ml/min Min. Heliflex AT -AquaWax m x.mm x.µm (Part No. ) C to C at C/min Helium at cm/sec ESSENTIAL OILS CHROM Lemon Oil. α-α Thujene. α-α Pinene. Camphene. Sabinene. β-pinene. ---hepten--one. Myrcene. Octanol. αα -Phellandrene. -Carene. αα -Terpinene. p-cymene. Limonene. γ-terpinene. Terpindene. Linalool. Nonanal. Citronellal. Terpinen--ol. α-α Terpineol. Neral. Gerinal. Neryl Acetate. Geranyl Acetate. β-caryophyllene. trans-α α -Bergamotene. β-bisabolene Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min gc chromatogram ESSENTIAL OILS Aroma Test Mix CHROM. BHA. BHT. TBHQ.,-Di-tert-butyl-Hydroxybenzyl Alcohol. THBP. Propyl Gallate

33 FOODS FLAVORS FRAGRANCES FAMES FAMES CHROM CHROM C:-C: Fatty Acid Esters Myristate (C:) Palmitate (C:) Palmitoleate (C: cis) Stearate (C:) Oleate (C: cis) Linoleate (C: cis,cis) Linolenate (C: cis,cis,cis) Arachidate (C:) Min. Heliflex AT -Wax, m x.mm x.µm (Part No. ) C to C at C/min Hydrogen at.ml/min Myristate (C:). Palmitate (C:). Stearate (C:). Oleate (C: cis). Linoleate (C: cis,cis). Linolenate (C: cis,cis,cis). Arachidate (C:). Behenate (C:). Erucate (C: cis). Lignocerate (C:) Canola Oil Econo-Cap EC -Wax m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min FAMES CHROM PUFA (Animal Source) C: C: C: C: C: C: C: C: C: ω ω ω ω ω ω Min C: C: C: C: C: C: C: C: ω ω ω ω ω ω ω ω Heliflex AT -Wax m x.mm x.µm (Part No. ) C to C at C/min Helium at.ml/min FAMES CHROM PUFA (Marine Source) a- C: C: C: C: C: C: C: C: ω ω ω ω ω ω. C: ω. C: ω. C: ω. C: ω. C: ω. C: ω. C: ω. C: ω C: C: C: C: C: C: C: ω ω ω ω ω ω ω Min. Heliflex AT -Wax m x.mm x.µm (Part No. ) C to C at C/min Helium at.ml/min..

34 GC APPLICATIONS CHROMATOGRAM FOODS FLAVORS FRAGRANCES FAMES FAMES CHROM Corn Oil..... FAMES CHROM.... C: C: C: C: Ester Ester Ester Ester Min. Heliflex AT -FAME m x.mm x.µm (Part No. ) C Helium at cm/sec FAMES Sesame Oil Safflower Oil gc chromatogram Econo-Cap EC -Wax m x.mm x.µm (Part No. ) C Helium at.ml/min Palmitate [C:] Stearate [C:] Oleate [C: cis] Linoleate [C: cis,cis] Linolenate [C: cis,cis,cis] CHROM CHROM Olive Oil Econo-Cap EC -Wax m x.mm x.µm (Part No. ) C Helium at.ml/min CHROM Econo-Cap EC -Wax m x.mm x.µm (Part No. ) C Helium at.ml/min WAX TMS Sugars Palmitate [C:] Palmitoleate [C:] Stearate [C:] Oleate [C: cis] Linoleate [C: cis,cis] Linolenate [C: cis,cis,cis] Min. SUGARS CHROM Carnuba Wax l-arabinose d-xylose β-d-fructose -α d-fructose β-d-glucose d-galactose ft x mm i.d., Glass % OV - on Chromosorb W-HP, / (Part No. ) C to C at C/min Nitrogen at ml/min Heliflex AT -ht, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min (cm/sec) at C Palmitate [C:] Palmitoleate [C:] Stearate [C:] Oleate [C: cis] Linoleate [C: cis,cis] Linolenate [C: cis,cis,cis]

35 FOODS FLAVORS FRAGRANCES FOODS/FLAVORS/FRAGRANCE FAME Meter x. mm Carbowax M,. Micron Film (Catalog Number: -) Oven: C C at C/minute (Hold minutes). Caproic acid methyl ester (C:). Caprylic acid methyl ester (C:). Nonanoic acid (C). Capric acid methyl ester (C:). Lauric acid methyl ester (C:). Tridecanoic acid methyl ester (C:). Myristic acid methyl ester (C:). Palmitic acid methyl ester (C:). Heptadecanoic acid methyl ester (C:). Stearic acid methyl ester (C:). Oleic acid methyl ester (C:nc). Linoleic acid methyl ester (C:nc). Linolenic acid methyl ester (C:n) Minutes FOODS/FLAVORS/FRAGRANCE Flavors Meter x. mm OV -,. Micron Film (Catalog Number: -).µl split injection (: ) Oven C C at C/minute µl Temp C Detector Temp F.I.D ene chloride Propylene glycol Eucalyptol Menthol salicylate minutes a-..

36 GC APPLICATIONS CHROMATOGRAM FOODS FLAVORS FRAGRANCES FOODS/FLAVORS/FRAGRANCE Orange Oil gc chromatogram Meter x. mm OV -,. Micron Film (Catalog Number: -) C (Hold minutes) C at C/minute Split Injection F.I.D. minutes FOODS/FLAVORS/FRAGRANCE Peppermint Oil Meter x. mm OV -,. Micron Film (Catalog Number: -) C (Hold minutes) C at C/ minute Split Injection F.I.D. FOODS/FLAVORS/FRAGRANCE Spearmint Oil Meter x. mm OV -,. Micron Film (Catalog Number: -) C C at C/minute minutes minutes

37 FOODS FLAVORS FRAGRANCES FOODS/FLAVORS/FRAGRANCE % Alcohol Mix Meter x. mm x. µm OV - (Catalog Number: -) C/minute C at C/minute Purge and Trap Injection. Methanol. Ethanol. Acetone. Isopropanol. -Propanol. Ethyl Acetate. -, -Propanol. -Butanol. -Pentanol. -, -Butanol. -, -Butanol TOT : : : : : FOODS/FLAVORS/FRAGRANCE Bacterial Acid Esters Meter x. mm OV -,. Micron Film (Catalog Number: -) C (Hold minutes) C at C/minute, F.I.D.. undecanoate. -hydroxydecanoate. laurate. tridecanoate. -hydroxydodecanoate. -hydroxydodecanoate. myristate. -methyltetradecanoate. pentadecanoate. -hydroxytetradecanoate. -hydroxytetradecanoate palmitoleate palmitate -methylhexadecanoate Me. dl-cis-, -methylene hexadecanoate heptadecanoate -hydroxyhexadecanoate oleate stearate Me. dl-cis-, -methylene octadecanoate nonadecanoate arachidate minutes a-..

38 GC APPLICATIONS CHROMATOGRAM FOODS FLAVORS FRAGRANCES FOODS/FLAVORS/FRAGRANCE Cholesterol gc chromatogram Hexane Octane Decane Palmitic acid Stearic acid Cholesterol Minutes FOODS/FLAVORS/FRAGRANCE Sugars (As Alditol Acetates) Rhamnitol Fucitol Ribitol Arabinitol Mannitol Galactitol Glucitol Inositol Minutes Meter x. mm, OV -,. Micron Film (Catalog Number: -) Oven: C (Hold minutes) C at C/minute (Hold minutes) Injection Temperature C Detector Temperature C Meter x. mm OV -,. Micron Film (Catalog Number: -) C C at C/minute Injection Temperature C Detector Temperature C

39 PETROLEUM & PETROCHEMICAL AROMATICS AROMATICS CHROM CHROM BTEX Aromatics and MTBE Benzene Toluene Ethylbenzene p-xylene m-xylene o-xylene Econo-Cap EC-Wax m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min (. cm/sec) at C AROMATICS Econo-Cap EC -Wax m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min AROMATICS CHROM Substituted Benzenes CHROM Substituted Benzenes Min. SULFUR GASES a-. Benzene. Toluene. Ethylbenzene. p-xylene. m-xylene. o-xylene. Isopropylbenzene. Propylbenzene.,,-Trimethylbenzene.,,-Trimethylbenzene Min. Heliflex AT -Wax, m x.mm x.µm (Part No. ) C to C at C/min Hydrogen at ml/min FUEL Sulfur Gases in Air CHROM Toluene Ethylbenzene p-xylene m-xylene Isopropylbenzene o-xylene Heliflex AT -, m x.mm x.µm (Part No. ) C Helium at.ml/min MTBE Methanol Benzene Toluene Ethylbenzene p-xylene m-xylene o-xylene Styrene CHROM Diesel Fuel Hydrogen Sulfide Carbonyl Sulfide Sulfur Dioxide Mercaptan Sulfide Dimethyl Disulfide n-decane n-dodecane n-tetradecane n-hexadecane n-octadecane n-eicosane n-docosane n-tetracosane Min. " x /" o.d., PTFE (Part No. ) " Super Q, / (Part No. ) C ( min hold) to C at C/min Helium at ml/min FPD Heliflex AT -ht, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at ml/min (cm/sec) at C..

40 GC APPLICATIONS CHROMATOGRAM PETROLEUM & PETROCHEMICAL FUEL FUEL CHROM CHROM Jet Fuel A n-nonane (C) n-decane (C) n-undecane (C) n-dodecane(c) n-tridecane (C) n-tetradecane (C) n-pentadecane (C) n-hexadecane (C) Heliflex AT -ht, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at ml/min (cm/sec) at C n-nonane (C) n-decane (C) n-undecane (C) n-dodecane(c) n-tridecane (C) n-tetradecane (C) n-pentadecane (C) n-hexadecane (C) Heliflex AT -ht, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at ml/min (cm/sec) at C FUEL gc chromatogram Kerosene CHROM Texas Crude Oil n-decane n-undecane n-dodecane n-tridecane n-tetradecane n-pentadecane n-hexadecane n-heptadecane Pristane n-octadecane Phytane n-nonadecane n-eicosane n-heneicosane n-docosane n-tricosane n-tetracosane n-pentacosane n-hexacosane n-heptacosane n-octacosane n-nonacosane n-triacontane n-hentriacontane n-dotriacontane n-tritriacontane n-tetratriacontane n-pentatriacontane n-hexatriacontane n-heptatriacontane n-octatriacontane n-nonatriacontane n-tetracontane Heliflex AT -ht m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min (cm/sec) at C FUEL CHROM Unleaded Gasoline Isobutane n-butane Isopentane Pentane,-Dimethylbutane -pentane -pentane Hexane Min..,-Dimethylpentane. Benzene. -hexane. -hexane. n-heptane. Toluene. Ethylbenzene. m-xylene p-xylene o-xylene ---Ethylbenzene,,-Trimethylbenzene,,-Trimethylbenzene,,-Trimethylbenzene Naphthalene -naphthalene -naphthalene Heliflex AT -Petro m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min

41 PETROLEUM & PETROCHEMICAL FUEL CHROM Unleaded Gasoline n-butane Isobutane n-pentane -pentane -pentane n-hexane cyclopentane,-dimethylpentane Benzene Split Ratio: GASES CHROM n-nonane Propylbenzene,,-Trimethylbenzene n-decane n-undecane -naphthalene -naphthalene Dimethylnaphthalenes CHROM C-C Paraffins Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min : -hexane -hexane n-heptane Toluene Ethylbenzene m-xylene p-xylene -octane o-xylene GASES C-C Hydrocarbons Air Methane Carbon Dioxide Ethylene Ethane Acetylene Methane (.%) Ethane (.%) Propane (.%) Isobutane (.%) Butane (.%) n-pentane (.%) Min. ft x /" o.d., SS (Custom Part No. C-*) HayeSep T, / (Part No. ) C Helium at ml/min TCD at C Min. ft x /" o.d., SS (Part No. PC) HayeSep D, / (Part No. ) C to C at C/min Helium at ml/min *Custom column. Must specifiy dimensions, packing and GC a-..

42 GC APPLICATIONS CHROMATOGRAM PETROLEUM & PETROCHEMICAL GASES CHROM C-C Hydrocarbons.... GASES CHROM Hydrocarbons, Sulfur Gases Methane (%) Acetylene (%) Ethylene (%) Ethane (%) ft x /" o.d., SS (Part No. PC) HayeSep D, / (Part No. ) C Helium at ml/min GASES CHROM GASES CHROM CHROM Hydrocarbons, Sulfur Gases Min. ft x /" o.d., SS (Part No. PC) HayeSep Q, / (Part No. ) C Helium at ml/min TCD at C GASES CHROM Gas Mixture Air. Methane. Carbon Dioxide. Ethylene. Acetylene. Ethane. Hydrogen Sulfide. Carbonyl Sulfide. Propylene. Propane. Propadiene Scott Mix ft x /" o.d., SS (Part No. PC) HayeSep Dip, / (Part No. ) C Helium at ml/min TCD Nitrogen (Balance) Carbon Monoxide (%) Methane (%) Carbon Dioxide (%) Acetylene (%) Ethylene (%) Ethane (%) Nitrogen Carbon Monoxide Methane Carbon Dioxide Acetylene Ethylene Water Ethane Min. ft x /" o.d., Nickel (Part No. PC) HayeSep D, / (Part No. ) C ( min hold) to C at C/min Helium at ml/min TCD at C ft x /" o.d., SS (Part No. PC) Hayesep DB, / (Part No. ) C Helium at ml/min TCD m x mm i.d., Glass.% Picric Acid on Carbograph, / (Part No. ) C Nitrogen at ml/min TCD Min. GASES. Propane. Propylene. Isobutane. -Butene. n-butane. Isobutylene. cis--butene. trans--butene.,-butadiene. Isopentane. n-pentane Hydrocarbons gc chromatogram. Air. Methane. Carbon Dioxide. Acetylene. Ethylene. Ethane. Water. Hydrogen Sulfide. Carbonyl Sulfide. Propylene. Propane

43 PETROLEUM & PETROCHEMICAL PETROLEUM/PETROCHEMICAL Diesel Range Organics Mix Meter x.mm OV -,. Micron Film (Catalog Number: -) C C at C/minute (Hold minutes) Injection Temperature C, Detector Temperature C, Detector F.I.D.. Decane. Dodecane. Tetradecane. Hexadecane. Octadecane. Eicosane. Docosane. Tetracosane. Hexacosane. Octacosane Minutes PETROLEUM/PETROCHEMICAL Gasoline. Methane. Ethane. Propane. Butane. Pentane. Hexane. Benzene. Heptane. Octane. Nonane. Decane. Undecane. Dodecane. Tridecane. Tetradecane Meter x.mm OV -,. Micron Film (Catalog Number: -) C (Hold minutes) C at C/minute (At C, hold minutes) Injection Temperature C, Detector Temperature C, Detector F.I.D. a- Minutes..

44 GC APPLICATIONS CHROMATOGRAM PETROLEUM & PETROCHEMICAL PETROLEUM/PETROCHEMICAL Substituted Benzenes gc chromatogram. Benzene. Toluene. Ethyl Benzene., Xylene., Xylene., Xylene. Isopropyl Benzene. Styrene. Propyl Benzene. Mesitylene. sec-butyl Benzene., Cymene. Isobutyl Benzene. Butyl Benzene. B- Styrene., Diisopropyl Benzene Meter x. mm x.µm OV - (Catalog Number: -) /min,. cm/min flow Helium Injector Temp., µl injection Split : Detector, Run Time minutes

45 SOLVENTS & CHEMICALS ALCOHOLS ALCOHOLS CHROM Blood Test Mix CHROM Bourbon Acetaldehyde Acetone Methanol Isopropanol Ethanol n-propanol Heliflex AT -Wax, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Hydrogen at.ml/min. Acetaldehyde. Ethyl Acetate. Methanol. Ethanol. n-propanol. Isobutanol. Amyl Alcohol + Isoamyl Alcohol. Acetic Acid Min. Heliflex AT -Wax, m x.mm x.µm (Part No. ) C ( min hold) to C ( min hold) at C/min, then to C ( min hold) at C/min Helium at.ml/min ALCOHOLS CHROM C-C Alcohols. n-pentane (solvent). Methanol. Ethanol. ---butanol. -Butanol. -Propanol. ---propanol. -Propen--ol. -Butanol. ---pentanol ALCOHOLS Min Econo-Cap EC -Wax m x.mm x.µm (Part No. ) C ( min hold), C/min to C Helium at.ml/min ALCOHOLS CHROM CHROM C-C Alcohols. Methanol. -Propanol. -Propanol. -Butanol. ---propanol. -Butanol. ---butanol. -Pentanol. -Ethyl--butanol. -Hexanol. Cyclohexanol. -cyclohexanol. -Heptanol a- Econo-Cap EC - m x.mm x.µm (Part No. ) C to C at C/min Helium at.ml/min (.cm/sec) ---butanol -Pentanol -Ethyl--butanol -Hexanol -Octanol -Heptanol -Ethyl--hexanol -Octanol -Decanol C-C Alcohols..... Methanol Ethanol -Propanol ---propanol -Propanol. -Butanol. ---propanol. ---butanol. -Butanol.,-Dimethyl--propanol. ---butanol. -Pentanol + -Pentanol. ---butanol. ---butanol. ---pentanol. -Pentanol. -Hexanol. Cyclohexanol Min. Heliflex AT -, m x.mm x.µm (Part No. ) C to C at C/min Helium at ml/min..

46 GC APPLICATIONS CHROMATOGRAM SOLVENTS & CHEMICALS ALCOHOLS CHROM ALCOHOLS C-C Alcohols Methanol Ethanol -Propanol ---propanol -Butanol ---pentanol -Pentanol -Ethyl--butanol -Hexanol Min. Heliflex AT -Wax, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min (cm/sec) at C ALCOHOLS CHROM Aliphatic Amines Min. Heliflex AT -, m x.mm x.µm (Part No. ) C to C at C/min Helium at.ml/min (cm/sec) at C ANIMES CHROM Min. m x mm i.d., Glass % Carbowax M +.% KOH on Carbograph, / (Part No. ) C to C at C/min Nitrogen at ml/min ANIMES CHROM Ethylamines. Putrecine. Cadaverine..... * Heliflex AT -CAM, m x.mm x.µm (Part No. ) C Helium at cm/sec * Polyamines Ammonia Ethylamine Ethanol Diethylamine Triethylamine Min. ft x mm i.d., Glass % AT - + % KOH on Gas Chrom R, / (Part No. ) C Helium at ml/min TCD amine. Dimethylamine. Ethylamine. Trimethylamine. Isopropylamine. n-propylamine. t-butylamine. Diethylamine. sec-butylamine. Isobutylamine. n-butylamine * Impurity Methanol Ethanol -Propanol -Propanol ---propanol -Butanol ---butanol -Pentanol -Hexanol Min. Heliflex AT -Wax, m x.mm x.µm (Part No. ) C to C at C/min Helium at ml/min ANIMES C-C Alcohols CHROM. αα α, -α Dimethylbenzyl Alcohol. dl-α-α benzyl Alcohol. Benzyl Alcohol. -Phenylethyl Alcohol. -Phenyl--propanol. Cinnamyl Alcohol. Phenyl-,-ethanediol. Benzhydrol Aromatic Alcohols gc chromatogram CHROM

47 SOLVENTS & CHEMICALS GASES GASES CHROM Ammonia CHROM Sulfur Compounds..... Air. Ammonia (%). Water (%) Hydrogen Sulfide Carbonyl Sulfide Sulfur Dioxide Mercaptan Min. ft x /" o.d., SS (Part No. PC) HayeSep P, / (Part No. ) C Helium at ml/min TCD GASES m x mm i.d., Glass Carbograph SC, / (Part No. ) C Nitrogen at ml/min FPD GASES CHROM CHROM Carbon Dioxide and Nitrous Oxide Permanent Gases Air. Carbon Dioxide. Nitrous Oxide Hydrogen Oxygen Nitrogen Methane Carbon Monoxide Min. ft x /" o.d., SS (Custom Part No. C-*) Chromosorb, / (Part No. ) C Helium at ml/min TCD Min. ft x /" o.d., SS (Part No. PC) Molecular Sieve X, / (Part No. ) C Helium at ml/min TCD *Custom column. Must specifiy dimensions, packing and GC. GASES CHROM CTR I - Air, Permanent Gases CO, CH, CO, O, N Outer Inner a- N, CO, NO, HS. Air and Carbon Monoxide (Inner Column). Methane (Inner Column). Carbon Dioxide (Inner Column). Oxygen (Outer Column). Nitrogen (Outer Column). Methane (Outer Column). Carbon Monoxide (Outer Column)..... CHROM GASES Nitrogen (Balance) Carbon Dioxide (%) Nitrous Oxide (%) Water (.%) Hydrogen Sulfide (%) Min. CTR I (Part No. ) ft x /" Packed with Activated Molecular Sieve ft x /" Packed with Porous Polymer Mixture Ambient Helium at ml/min TCD Min. ft x /" o.d., SS (Part No. PC) HayeSep D, / (Part No. ) C Helium at ml/min TCD..

48 GC APPLICATIONS CHROMATOGRAM SOLVENTS & CHEMICALS GASES GASES CHROM CO, COS, SO..... CH, CO, NO Air, Carbon Monoxide Carbon Dioxide Water Carbonyl Sulfide Sulfur Dioxide.... Min. ft x /" o.d., SS (Part No. PC) Carbosphere, / (Part No. ) C Helium at ml/min TCD GASES CHROM MAPP Gas Min. *Custom column. Must specify dimensions, packing, and GC. Min. ft x /" o.d., SS (Custom Part No. C-*) HayeSep R, / (Part No. ) C Helium at ml/min TCD *Custom column. Must specify dimensions, packing, and GC. GASES CHROM Nitric Oxide CHROM Permanent Gases. Nitrogen (Balance). Argon. Nitric Oxide (.%)..... Nitrogen Oxygen Carbon Monoxide Methane Carbon Dioxide Min. ft x /" o.d., SS (Part No. PC) HayeSep DB, / (Part No. ) C Helium at ml/min TCD at C Min. ft x /" o.d., Ni (Part No. PC) HayeSep D, / (Part No. ) C Helium at ml/min TCD ft x /" o.d., SS (Custom Part No. C-*) HayeSep D, / (Part No. ) C Helium at ml/min TCD GASES Air Methane Carbon Dioxide Ethane Propylene Propane Propadiene Acetylene Hydrogen Nitrogen Oxygen Argon gc chromatogram CHROM Hydrogen/Air Air Methane Carbon Dioxide Nitrous Oxide ft x mm i.d., Glass Porapak Q, / (Part No. ) C Helium at ml/min TCD GASES.... CHROM

49 SOLVENTS & CHEMICALS GASES Reactive Gas Mixture GASES CHROM CHROM Room Air Air Methane Carbon Dioxide Nitrous Oxide Ammonia Ethane Hydrogen Sulfide Carbonyl Sulfide. Nitrogen (%). Oxygen (%). Argon (.%) Min. ft x /" o.d., SS (Part No. PC) HayeSep Q, / (Part No. ) C Helium at ml/min TCD GASES Min. ft x /" o.d., SS (Part No. PC) Hayesep DB, / (Part No. ) - C Helium at ml/min TCD GLYCOLS/DIOLS CHROM Scott Mix CHROM Diols.... Helium (Balance) Hydrogen (%) Oxygen (%) Methane (%) ft x /" o.d., SS (Part No. PC) HayeSep DB, / (Part No. ) C Nitrogen at ml/min TCD GLYCOLS/DIOLS,-Butanediol,-Propanediol Ethylene Glycol,-Butanediol,-Propanediol,-Butanediol,-Pentanediol Min. Heliflex AT -Wax m x.mm x.µm (Part No. ) C Hydrogen at.ml/min GLYCOLS/DIOLS CHROM EG and Diols CHROM Ethylene Glycol/-Chloroethanol.... Ethylene Glycol,-Propanediol, Butanediol,-Butanediol. Water. -Chloroethanol. Ethylene Glycol Min. a- Heliflex AT -Wax m x.mm x.µm (Part No. ) C Helium at ml/min Min. Econo-Cap EC - m x.mm x.µm (Part No. ) C Helium at ml/min..

50 GC APPLICATIONS CHROMATOGRAM SOLVENTS & CHEMICALS GLYCOLS/DIOLS GLYCOLS/DIOLS CHROM CHROM Glycol Amines Glycol-Diol Mix..... Ethanolamine Ethylene Glycol Diethylene Glycol Diethanolamine Triethylene Glycol Ethylene Glycol,-Propanediol,-Butanediol,-Propanediol,-Butanediol,-Butanediol Diethylene Glycol Glycerol. Min. Heliflex AT -Wax, m x.mm x.µm (Part No. ) C to C at C/min Helium at ml/min SOLVENTS CHROM SOLVENTS CHROM Volatile Organics min.. Benzene. Toluene. Ethylbenzene. p-xylene. m-xylene. o-xylene. Chlorobenzene.,-Dichlorobenzene.,-Dichlorobenzene.,,-Trichlorobenzene.,,-Trichlorobenzene. Napthalene Heliflex AT -Wax, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min (cm/sec) SOLVENTS CHROM. ene Chloride. Chloroform. Carbon Tetrachloride.,-Dichloropropane. Benzene. Toluene. Chlorobenzene. Ethylbenzene.,-Dichlorobenzene.,-Dichlorobenzene Min. m x mm i.d., Glass % AT - on Carbograph / (Part No. ) C ( min hold) to C at C/min Nitrogen at ml/min SOLVENTS CHROM Aromatics. Benzene. Toluene. Chlorobenzene. Ethylbenzene. m-xylene. p-xylene. o-xylene.,-dichlorobenzene.,-dichlorobenzene.,,-trichlorobenzene. Napthalene.,,-Trichlorobenzene..... Glycol Ethers Cellosolve Acetate Carbitol Carbitol n-decane Butyl Carbitol Min. Heliflex AT -, m x.mm x.µm (Part No. ) C to C at C/min Helium at ml/min Heliflex AT -, m x.mm x.µm (Part No. ) C( min hold) to C at C/min Helium at.ml/min Min. ft x mm i.d., Glass Chromosorb, / (Part No. ) C Helium at ml/min Aromatics gc chromatogram

51 SOLVENTS & CHEMICALS SOLVENTS SOLVENTS CHROM Impurities in Ethyl Ketone CHROM Ethylene Glycol, Ethylene Oxide and -Chloroethanol in DMF. Methanol. Ethanol. -Propanol. ---propanol. n-propanol. -Butanol. Acetone. -Octene. Ethyl Acetate. Ethyl Ketone Min. Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/minute Helium at.ml/min. Ethylene Oxide. Methanol. N,N-Dimethylformamide (solvent). -Chloroethanol. Impurity in Solvent. Ethylene Glycol Min. Econo-Cap EC -Wax m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min SOLVENTS CHROM Halogenated Aromatics.... -Bromobutane -Bromobutane Chlorobenzene,-Dichlorobutane.... -Bromohexane Bromocyclohexane o-chlorotoluene Benzyl Chloride Min. Heliflex AT -, m x.mm x.µm (Part No. ) C Helium at ml/min SOLVENTS CHROM Industrial Solvent Mix a-. Pentane.,,-Trimethylpentane. Cyclohexane. Formate. Acetone. Tetrahydrofuran. Ethyl Acetate. -Butanone. -Propanol. Benzene Min Trichloroethene ---pentanone -Butanol Toluene Butyl Acetate ---propanol -Nitropropane Ethylbenzene,-Xylene,-Xylene Butanol Nitromethane,-Xylene ---butanol -Ethoxyethanol -Pentanol Cyclohexanol -Ethoxyethyl Acetate -Hexanol -Butoxyethanol -Heptanol Econo-Cap EC -Wax m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min..

52 GC APPLICATIONS CHROMATOGRAM SOLVENTS & CHEMICALS SOLVENTS CHROM Substituted Aromatics Isopropyl--methylbenzene -α Chlorotoluene,-Dichlorobenzene -Bromo--methylbenzene -Chlorostyrene -Bromo--chlorobenzene,,,-Tetramethylbenzene,-Dichlorotoluene -Iodo--methylbenzene Tetrahydronaphthalene,,-Trichlorobenzene Naphthalene Hexachlorobutadiene,,,-Tetrachlorobenzene -Chloronaphthalene Min. Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min SOLVENTS gc chromatogram. Benzene. Trifluoromethylbenzene. Toluene. Chlorobenzene. Ethylbenzene.,-Xylene.,-Xylene. Isopropylbenzene. Bromobenzene. -Chloro--methylbenzene. -Chloro--methylbenzene.,,-Trimethylbenzene. ---phenylpropane.,,-trimethylbenzene.,-dichlorobenzene CHROM NIOSH Solvents. Chloroform. Tetrachloroethylene. Toluene. p-dioxane + Ethylene dichloride. p-xylene. m-xylene. o-xylene.,,-trichloroethane Carbon Disulfide Acetone Carbon Tetrachloride,,-Trichloroethane Ethyl Ketone ene Chloride Benzene Trichloroethylene Min. ft x /" o.d., SS (Part No. C-*) % AT - on Chromosorb W-AW, / (Part No. ) C ( min hold) to C at C/minute Nitrogen at ml/min *Custom column. Must specifiy dimensions, packing and GC. TEST MIXES TEST MIXES CHROM AT -ms Test Chromatogram Grob Mix Heliflex AT -ms, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min (.cm/sec). n-decane. n-undecane. Nonanal.,-Butanediol. -Octanol. Decanoate. Dicyclohexylamine. Undecanoate. Dodecanoate.,-Dimethylaniline.,-Dimethylphenol. -Ethylhexanoic Acid -Ethylhexanoic Acid -Chlorophenol,-Heptanediol n-tridecane -Undecanol n-tetradecane Dicyclohexylamine Acenaphthylene n-pentadecane CHROM Min. Econo-Cap EC -Wax m x.mm x.µm (Part No. ) C to C at C/min Helium at.ml/min

53 SOLVENTS & CHEMICALS SOLVENTS CHROM Pyrolysis - ABS Plastic ,-Butadiene Acrylonitrile Benzene Toluene Vinyl Cyclohexene Styrene α α -styrene Benzenepropanenitrile -Benzyl Pyrrole Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min MSD SOLVENTS CHROM Pyrolysis - Isoprene Rubber Butene,-Pentadiene Toluene p-xylene Styrene -Ethyl--methylbenzene Limonene -naphthalene Heliflex AT -, m x.mm x.µm (Part No. ) C ( min hold) to C at C/min Helium at.ml/min MSD SOLVENTS/CHEMICALS Aldehydes Meters x. mm, OV -,. Micron Film (Catalog Number: -) C C at C/minute Injection Temperature C, Detector Temperature C. Ethanol. Propanol. Butanol. Pentanol. Hexanol. Heptanol. Octanol. Nonanol. Decanol. Undecanol Minutes a-..

54 GC APPLICATIONS CHROMATOGRAM SOLVENTS & CHEMICALS SOLVENTS/CHEMICALS Alcohols/Hydrocarbons Ethanol Iso-Propanol N-Pentane Tert-Butanol N-Propanol Tert-Butyl Ether Sec-Butanol N-Hexane Iso-Butanol N-Butanol Benzene Meter x.mm OV -,. Micron Film (Catalog Number: -) Helium Injection Temperature C (Hold minute) C at C/minute Split :, µl, Detector F.I.D. gc chromatogram. Methane. Ethylene. Ethane. Propylene. Propane. Propadiene. Iso-Butane. Methanol. Iso-Butene. N-Butane. Cis--Butene Minutes SOLVENTS/CHEMICALS Ethylene Glycol Mixture..... Diethylene glycol Triethylene glycol Polyethylene glycol Polyethylene glycol Polyethylene glycol Minutes Meter x. mm OV -,. Micron Film (Catalog Number: -) Oven: C C at C/minute Injection Temperature C, Split : Detector Temperature C

55 SOLVENTS & CHEMICALS SOLVENTS/CHEMICALS Industrial Solvent Mix Meter x. mm OV -,. Micron Film (Catalog Number: -) Oven: C C at C/minute Injection Temperature C Detector Temperature C. Methanol. formate. Ethanol. Acetone. Isopropanol. ene Chloride. n-propanol. Ethyl Keytone (MEK). Sec-butanol. Ethyl acetate. -Butanol. Isopropylacetate. Nitropropane.,-Dioxane. Acetonitrile. Toluene. Mesityl oxide. Diacetone alcohol. m-xylene. Cyclohexanone Minutes SOLVENTS/CHEMICALS Nitrogen Based Solvents Meter x.mm OV -,. Micron Film (Catalog Number: -) Temperature Program C (Hold minute) C at C/minute Helium Injection Temperature C, Split : Detector Temperature C. Acetonitrile. Acrolein. Acrylonitrile. Propionitrile. Methacrolein. Methacrylonitrile. Triethylamine. Ethyl Acrylate. Pyridine. Dimethylformamide (DMF). Dimethylsulfoxide (DMSO). Benzonitrile. --Pyrolidinone a-..

56 GC APPLICATIONS CHROMATOGRAM SOLVENTS & CHEMICALS SOLVENTS/CHEMICALS Residual Solvents Meter x. mm OV -,. Micron Film (Catalog Number: -) Oven: C C at C/minute Injection Temperature C Detector Temperature C..... Ethanol Acetonitrile,-Dichloroethane ene chloride Hexane. Chloroform. Carbon tetrachloride. Benzene. Trichloroethylene.,-Dioxane. Pyridine gc chromatogram Minutes SOLVENTS/CHEMICALS Solvent Mix Meter x. mm x. µm OV - (Catalog Number: -). µl Slit : C (Hold minutes) C at C/minute. Methanol. Ethanol. Acetone. Isopropanol. -Propanol. Ethyl Acetate. -, -Propanol. -Butanol. -Pentanol. -, -Butanol. -, -Butanol

57 SOLVENTS & CHEMICALS SOLVENTS/CHEMICALS Solvents Meter x.mm OV -,. Micron Film (Catalog Number: -) C Isothermal Injection Temperature C Detector Temperature C Detector F.I.D.. Methanol. Ethanol. Acetone. ethylketone. Isobutanol. Ethyl Acetate. Cyclo C-. isobutylketone. Toluene. Butyl Cellosolve. Cellosolve Acetate. Ethyl Benzene. o-xylene Minutes SOLVENTS/CHEMICALS Standard Mix Meter x. mm OV -,. Micron Film (Catalog Number: -) Helium Oven: C Isothermal Injector: C C F.I.D. Instrument: CARLO ERBA Proprietary Internal Standard Decane -Octanol, -Dimethylphenol, -Dimethylaniline Naphthalene -Decanol Tridecane Decanoate minutes a-..