ALIMENTI E AGRICOLTURA

Transcription

1 ALIMENTI E AGRICOLTURA indice Standard di latte e derivati 37 Standard in matrici di cereali e derivati 47 Standard di carni 59 Standard di pesci, crostacei e molluschi 69 Standard di frutti, ortaggi e vegetali 8 Standard di fertilizzanti 87 Standard di bevande e soluzioni alcoliche 9 Standard di oli vegetali 93 Miscellanea di standard in matrici alimentari 97 i di riferimento per microbiologia 309 Standard di lipidi puri 33

2 37 Standard di latte e derivati NIST SRM549 RM8435 SRM840 Non-fat milk powder Whole milk powder Infant formula (milk-based) 3 00 g 40 g 0x30 g Certified Costituent Concentrations (mg/kg, unless otherwise stated) Aluminium () (0,9) Antimony (0,0007) Arsenic (0,009) (0,00) Barium (0,58) Boron (,) Bromine () (0) Cadmium 0,0005 (0,000) Calcium,30 Wt% (90) (3670) Chlorine,09 Wt% (840) Chromium 0,006 (0,5) Cobalt (0,004) (0,003) Copper 0,7 (0,46) (5,04) Fluorine (0,0) (0,7) Iodine 3,38 (,3), Iron,78 (,8) (63,) Lead 0,09 (0,l) Magnesium 0,0 Wt% (84) (538) Manganese 0,6 (0,7) (0,4) Mercury 0,0003 Molybdenum (0,34) (0,9) Nickel (0,0) Nitrogen (4870) Phosphorus,06 Wt% (7800) (60) Potassium,69 Wt% (3630) (760) Rubidium () (6) Selenium 0, (0,3) (0,08) Silver (<0,0003) Sodium 0,497 Wt% (3560) (30) Strontium (4,35) Sulphur 0,35 Wt% (650) Tin (<0,0) Titanium (4) Tungsten (0,00) Zinc 46, (8,0) (60,0)

3 38 LATTE E DERIVATI LATTE E DERIVATI 39 NIST AGRICULTURAL RESEARCH CENTRE SRM549 RM8435 SRM846 Non-fat milk powder Whole milk powder Infant formula (milk-based) 3 00 g 40 g 0x30 g Certified Costituent Concentrations (mg/kg, unless otherwise stated) Chloride 490 Vitamin A (trans) (,9) 5,84 Vitamin E 7 Vitamin C (53) 46 Vitamin B (0,6) 7,4 Vitamin B6 (,86) 8,4 Niacin (7,35) 63,3 Vitamin D (0,039) (07) -Tocopherol (7,99) γ-tocopherol (73,5) Vitamin B (,80) (0,9) Vitamin B (0,07) (0,039) Folic acid (,9) Pantothenic acid (5,6) (48,7) Biotin (0,5) (0,4) Choline (940) (50) Inositol (30) (940) Lactose (49) Vitamin K (0,944) Solids (96,46) % (98,0) % Ash (5,97) % (,93) % Fat (,3) % (7,) % Nitrogen (4,87) % (,739) % Protein (5,86) % (,0) % Carbohydrates (by difference) (43,4) % (57,) % Calories (470) Kcal/00g (55,5) Kcal/00g Moisture (3,54) % Values in brackets are not certified. Reference concentrations for Fatty Acids C4-C0 (as Triglycerides) are also given in the certificate. 3 Reference concentrations for Fatty Acids C-C (as Triglycerides) are also given in the certificate. Cat.No. ARC/CL- Skim milk powder 50 g Certified Concentration Constituent (µg/g, unless otherwise stated) Cadmium <5 ng/g Calcium 3,00 mg/g Copper 0,59 Iron 4,54 Lead 6 ng/g Magnesium,3 mg/g Manganese 0,44 Mercury < ng/g Molybdenum 0,49 Selenium 8 ng/g Zinc 4,68 IAEA Cat.No. IAEA-53 IAEA-5 IAEA-3 Milk powder Milk powder Milk powder 50 g 50 g 50 g Certified values* (g/kg, unless otherwise stated) Arsenic Bromine,3 mg/kg Cadmium Calcium 870 mg/kg Iron,53 mg/kg Magnesium,060 Manganese (0,9) mg/kg Molybdenum (0,3) mg/kg Phosphorus 0, Potassium 7,6 Sodium 4,80 Strontium (4,09) mg/kg Rubidium 4,03 mg/kg Zinc 39,56 mg/kg Potassium Bq/kg 55 Bq/kg Strontium-90 7,7 Bq/kg 3,3 Bq/kg Caesium Bq/kg 5,5 Bq/kg Caesium Bq/kg 7,6 Bq/kg * Values in brackets are information values.

4 40 LATTE E DERIVATI LATTE E DERIVATI 4 IAEA IRMM, EUROPEAN COMMISSION Cat.No. IAEA-54 IAEA-55 Whey powder Whey powder 50 g 50 g Certified Certified values* Constituent (mg/kg, unless otherwise stated) Potassium Bq/kg Strontium-90 6,9 Bq/kg Caesium Bq/kg Caesium Bq/kg Aluminium (5,9) Arsenic (49) µg/kg Boron (5,) Bromine 39, Cadmium 6,0 µg/kg Caesium 86 µg/kg Calcium (4,) g/kg Chlorine 69, g/kg Chromium 0,59 Cobalt 43 µg/kg Copper (0,57) Iron (6) Lead 04 µg/kg Magnesium 3,9 g/kg Manganese 9,30 Mercury 3 µg/kg Nickel 0,54 Phosphorus 6, g/kg Potassium (4,7) g/kg Sodium 5,8 Sulphur (3,0) g/kg Rubidium 39, Scandium 8 µg/kg Selenium 64 µg/kg Strontium (0,5) Zinc 034,3 * Values in brackets are information values. CRM063R CRM50 CRM5 Skim milk powder Skim milk powder Skim milk powder (natural) (spiked) (spiked) 50 g 3 g 3 g Concentrations* (µg/kg, unless otherwise stated) Cadmium,8 0,0 Calcium 3,49 g/kg Chlorine 9,94 g/kg Cobalt (6,4) (6,0) Copper 0,60 mg/kg,3 mg/kg 5,3 mg/kg lodine 0,8 mg/kg,9 mg/kg 5,35 mg/kg Iron,3 mg/kg,8 mg/kg 50, mg/kg Lead 8, Magnesium,63 g/kg Manganese (36) mg/kg (3) mg/kg Mercury 9,4 0 Molybdenum (0,33) mg/kg Nickel (6,5) (56) Nitrogen (total) 6,3 g/kg Nitrogen (Kjeldahl) (60,87) g/kg Phosphorus,0 g/kg Potassium 7,68 g/kg Selenium (9) (7) (5) Sodium 4,37 g/kg Thallium (,0) (0,8) Zinc 49,0 mg/kg (49) mg/kg (50) mg/kg CRM CRM4 Margarine Milk powder 00 g 50 g Concentrations (mg/kg) Vitamins B (thiamin) 6,5 B (riboflavin) 4,5 B 6 (total pyridoxine) 6,66 B 0,034 C (total ascorbate) 769 D 3 (cholecalciferol) 0,5 0,43 E (tocopherol) 4 99 Folate (total),4 Niacin 68 Vitamins: information on nutritional composition of foods is essential for studies investigating the relationship between diet and health or disease. The importance of reliable food composition data in the European Union is reflected in the issuing of Council Directive 90/496/Cee on the Nutritional Labelling of Foodstuffs.

5 4 LATTE E DERIVATI LATTE E DERIVATI 43 IRMM, EUROPEAN COMMISSION IRMM, EUROPEAN COMMISSION CRM64 Anhydrous milk fat x5 g Certified Values (g/00 g) Butyric Acid 3,49 OTHER FATTY ACIDS 6:0,36 8:0,36 0:0,89 0: ω (0,3) :0 4,03 : ω9 (0,) 4:0 iso (0,) 4:0 0,79 4: ω5 (,) 5:0 iso (0,3) 5:0 anti-iso (0,5) 5:0 (,0) 6:0 iso (0,) CRM87 CRM88 CRM450 Milk powder (spiked) Milk powder Natural milk powder 0 g 0 g 0 g Concentrations (µg/kg) HCB,5 37,4 alpha-hch,80 0,0 beta-hch,0 gamma-hch 5,7 45,4 beta-hepo (,4) 3,0 p,p -DDE 6,6 5,3 Dieldrin (,3) 36, Endrin 6, p,p -DDT 69,0 PCB 5,6 PCB 8 3,3 PCB 53 9,0 PCB 56,6 PCB 70 4,8 PCB 80,0 6:0 total 6,9 6: ω7 (,5) 6: total (,5) 7:0 iso (0,5) 7:0 anti-iso (0,4) 7:0 (0,5) 7: (0,3) 8:0 iso (0,) 8:0 total 0,5 8: total 4,8 8: ω6 cis (incl. isomers) (,8) 8: conj (0,9) 8: total,68 8:3 ω3 cis 0,5 0:0 (0,) 0: ω9 cis (0,) Other (,5) STEROLS Cholesterol 47,7 ß-Sitosterol 5,9 Campesterol 35,6 Stigmasterol 0,3 Cat.No. CRM53 CRM533 CRM534 CRM607 Unspiked Spiked milk powder Spiked milk Natural spray milk powder (lower level) powder dried dried milk powder (higher level) 65 g 65 g 65 g 00 g Concentrations* (ng/kg),3,7,8-tcdd (D48) (0,0) (0,4) (0,65) 0,5,,3,7,8-PCDD (D54) (0,9) (0,86) (,44) 0,79,,3,4,7,8-HCDD (D66) (0,7) (0,56) (0,80) 0,4,,3,6,7,8-HCDD (D67) (0,43) (,7) (,9) 0,98,,3,7,8,9-HCDD (D70) (0,6) (0,47) (0,80) 0,34,3,7,8-TCDF (F83) (0,6) (0,39) (0,65) 0,05,,3,7,8-PCDF (F94) (0,) (0,) (0,5) 0,054,3,4,7,8-PCDF (F4) (0,67) (,96) (3,6),8,,3,4,7,8-HCDF (F8) (0,34) (,06) (,75) 0,94,,3,6,7,8-HCDF (F) (0,34) (,03) (,55),0,3,4,6,7,8-HCDF (F30) (0,39) (,) (,90),07 Values in brackets are not certified Milk fat is virtually the only naturally occurring lipid to contain significant amounts of butyric acid. The butyric acid content is a useful indicator of the quality of milk. For customs classification purposes, the omount of butyric acid in chocolate confectionery is used to estimate the amount of milk-fat in the product.

6 44 LATTE E DERIVATI LATTE E DERIVATI 45 IRMM, EUROPEAN COMMISSION Cat.No. CRM59 Anhydrous butter fat* x5 g (sealed ampules) Concentrations (%) Chol 0,30 C4 0,05 C6 0,5 C8 0,59 C30,5 C3,43 C34 5,64 C36 0,47 C38,53 C40 0,03 C4 6,69 C44 6, C46 6,86 C48 8,69 C50,40 C5 0,96 C54 5,89 * Butter fat: the adulteration of butter with fat of plant and animal origin can be detected by using the reference method given in the European Commision s Regulation (EC) N. 454/95. CRM59 was certified using this reference method. LGC Cat.No. LGC7006 LGC7007 Milk powder Milk drink powder 5 g 5 g Certified Value (g/00 g) Total fat 6, 5,8 Butter fat in fat,0 3, Buner fat in sample 0,53 8, Cat.No. LGC04 LGC06 Sterilised cream* Processed cheese 5x70 g 5x0 g Concentrations (g/00 g, unless otherwise stated) Calcium 845 mg/kg Magnesium 84 mg/kg Phosphorus 83 mg/kg Potassium 60 mg/kg Sodium 505 mg/kg Zinc 3, mg/kg Moisture 70, 46, Nitrogen 0,40,98 Total fat,7 7,0 Ash 0,58 5,3 * Indicative concentrations for Cl and Lactose are also given in the certificate. Cat.No. CRM599 Mixture of ewes and goats milk x5 g of lyophilised curd powder (in glass vials under Argon) Concentration (%) NOT ADULTERATED MILK ADULTERATED MILK Cows Milk 0 % % CRM8 CRM83 CRM84 CRM85 Whole milk powder Whole milk powder Whole milk powder Whole milk powder (very low level) (low level) (medium level) (high level) 5 g 5 g in Prep 5 g Concentrations (µg/kg) Aflatoxin M <0,05 0,09 0,76 CRMs 83, 84 and 85 have aflatoxin M contents corresponding to the limits of this compound in milk imposed by EU Member State. CRM8 is a near - blank material and is intended for investigation of limits of detection and recovery experiments. The four CRMs provide a convenient means of checking the reliability of immuno assay techniques which are of rapidly growing importance for the determination of aflatoxin M Probable content is in the range 0,0 to 0,0 µg/kg. Standard non inclusi nel catalogo sono disponibili su richiesta. Contattateci!

7 47 Standard di cereali e derivati NIST SRM567a SRM568a Wheat flour Rice flour 80 g 80 g Concentrations* (mg/kg, unless otherwise stated) Aluminium 5,7 4,4 Antimony (0,0005) Arsenic (0,006) 0,9 Bromine (6) (8) Cadmium 0,06 0,0 Calcium 0,09 Wt % 0,0 Wt% Chlorine (565) (300) Cobalt (0,006) (0,08) Copper,,4 lodine (0,0009) (0,009) Iron 4, 7,4 Lead (<0,00) (<0,00) Magnesium 0,040 Wt % 0,056 Wt% Manganese 9,4 0,0 Mercury (0,0005) 0,0058 Molybdenum 0,48,46 Nickel (0,6) Phosphorus 0,34 Wt% 0,53 Wt% Potassium 0,33 Wt% 0,80 Wt% Rubidium 0,68 6,4 Selenium, 0,38 Sodium 6, 6,6 Sulphur 0,65 Wt% 0,0 Wt% Tellurium (<0,00) Tin (0,0033) (0,0047) Uranium (0,0003) (0,0003) Vanadium (0,0) (0,007) Zinc,6 9,4

8 48 CEREALI E DERIVATI CEREALI E DERIVATI 49 NIST NIST RM84 RM843 RM848 RM843 Com stalk Com kernel Wheat Corn (Zea Mays) (Zea Mays) gluten starch 34 g 47 g 50 g 50 g Concentrations (mg/kg) RM8433 RM8436 RM8437 RM8438 Corn bran Durum Hard red spring Soft winter wheat flour wheat flour wheat flour 50 g 50 g 50 g 50 g Concentrations (mg/kg) Aluminium 4 0,8,9 Aluminium,0,7,,3 Antimony 0,0 Antimony 0,004 Arsenic 0,0 Arsenic 0,00 0,03 Barium,53 Barium,40, 0,4 Boron 0,4 Boron,8 0, 0, Bromine 3,6 Bromine,3 6,6 Cadmium 0,064 0,0003 Cadmium 0,0 0, 0,0 0,03 Calcium Calcium Chlorine Chlorine ) Chromium 0,053 0,0 Chromium 0,0 0,03 0,06 0,03 Cobalt 0,00 0,00 Cobalt 0,006 0,008 Copper 8 3,0 5,94 0,06 Copper,47 4,30,0, Fluorine 0,65 0,4 0,43 0,0 Fluorine 0, 0,0 0,04 lodine 0,060 lodine 0,06 0,006 Iron ,3 5 Iron 4,8 4,5 3 9 Lead 0,0 0,007 Lead 0,40 0,03 Magnesium Magnesium Manganese 5 4,0 4,3 0,0 Manganese,55 6,0 4,50 5,4 Mercury 0,009 0,00 Mercury 0,003 0,0004 0,004 0,00 Molybdenum 0,76 0,0 Molybdenum 0,5 0,70 0,55 0,9 Nickel 0,3 0,0 Nickel 0,58 0,7 0, Nitrogen Nitrogen Phosphorus Phosphorus Potassium Potassium Rubidium 0,4) Rubidium 0,5,0 Selenium 0,06 0,004,58 0,0009 Selenium 0,045,3 0,56 0,076 Sodium Sodium 430 6,0 7 7 Strontium,7 0,8 Strontium 4,6,9 4 Sulphur Sulphur Titanium Titanium 5 Tungsten 0,00 Vanadium 0,04 Tungsten 0,0 Vanadium 0,005 0,0 0,0 0,03 Zinc 3 5,7 53,8 0, Zinc 8,6, 0,6 5,8

9 50 CEREALI E DERIVATI CEREALI E DERIVATI 5 NIST IAEA Cat.No. Certified Property RM844 Wheat (0 types) Set of 50x0 g (5 of each wheat) Hardness Score* Cat.No. IAEA-V-8 Rye flour 50 g Concentration* (mg/kg) WHEAT TYPE: CERTIFIED VALUE Hard- 74,7 Hard- 75,8 Hard-3 63,7 Hard-4 77,5 Hard-5 9,8 Soft- 30,0 Soft- 9,9 Soft-3 3, Soft-4 9,8 Soft-5 3,5 * This RM is intended primarly for calibrating instruments used to determine the hardness of bulk of single kernel wheat. Aluminium (,6) Antimony (0,006) Barium (0,) Bromine 0,38 Calcium 49 Cadmium (0,07) Chlorine 570 Cobalt (0,003) Caesium (0,00) Copper 0,95 Iron 4, Magnesium Manganese,06 Molybdenum (0,) Phosphorus 59 AGRICULTURAL RESEARCH CENTRE Potassium 95 Rubidium 0,48 Cat.No. ARC/CL-3 Wheat flour 50 g Concentration (mg/kg, unless otherwise stated) Sodium (,6) Zinc,53 * Values in brackets are not certified and are given for information only. Cadmium 39 ng/kg Calcium 0,08 g/kg Chromium 8 µg/kg Copper,35 Iron 5 Lead 8 ng/kg Magnesium 0,56 g/kg Mercury < ng/kg Manganese,87 Molybdenum 0,5 Nickel 53 µg/kg Phosphorus,09 g/kg Potassium,0 g/kg Selenium 57 µg/kg Zinc 4,6 Standard non inclusi nel catalogo sono disponibili su richiesta. Contattateci!

10 5 CEREALI E DERIVATI CEREALI E DERIVATI 53 IRMM, EUROPEAN COMMISSION IRMM, EUROPEAN COMMISSION CRM89 CRM9 CRM5 Wholemeal flour Brown bread Animal feed 40 g 40 g 30 g Concentrations* (µg/kg unless otherwise stated) CRM38 CRM38 CRM58 Rye flour Wheat flour Bran breakfast cereal 00 g 00 g 5 g Certilied Constituent Concentrations* (g/00g, unless otherwise stated) Arsenic (3) Kjeldahl nitrogen,3, Cadmium 7,3 8,4 Fat,,3 Calcium (0,5) g/kg (0,4) g/kg Starch (75,9) (79,6) Chlorine (0,7) g/kg (6,5) g/kg Starch & sugars (90) (89) Chromium (57-73) (68-360) Dietary fibre (Englyst) (7,7) (3,) Copper 6,4 mg/kg,6 mg/kg Dietary fibre (AOAC 985/988) 8, 3,3 Iron 68,3 mg/kg 40,7 mg/kg Ash at 550 C 0,9 0,9 Lead Calcium 0, g/kg (,5) g/kg Magnesium (,9) g/kg (0,5) g/kg Chlorine 0,46 g/kg (0,7) g/kg Manganese 63,3 mg/kg 0,3 mg/kg Potassium,9 g/kg (,8) g/kg Mercury () () Magnesium 0,43 g/kg (0,) g/kg Nickel (380) (440) Sodium 0,09 g/kg Phosphorus (5,3) g/kg (,) Phosphorus (,6) g/kg (,) g/kg Potassium (6,3) g/kg (3,) g/kg DIETARY FIBRE, BY METHOD Selenium 3 (5) AOAC , Sodium (0,04) g/kg (0) g/kg Englyst (by gas chromatography) 4, Zinc 56,5 mg/kg 9,5 mg/kg Uppsala 7,6 HCB 0,094 mg/kg AOAC 99 MES-TRIS 30,5 β-hch 0,03 mg/kg Englyst (by colorimetry) 5,0 γ-hch Heptachlor 0,08 mg/kg 0,090 mg/kg γ-chlordane 0,048 mg/kg α-endosulphan 0,046 mg/kg Dieldrin 0,08 mg/kg Endrin o,p -DDT p,p -DDT 0,046 mg/kg 0,046 mg/kg 0,047 mg/kg CRM375 CRM376 CRM377 CRM378 Compound Compound Maize flour Maize feed (very feed (low level) (very low flour low level blank) level blank) (medium level) 50 g 50 g 50 g 50 g Concentrations (µg/kg, unless otherwise stated) Aflatoxin B < 9,3 Cat.No. CRM Wholemeal flour 50 g Concentration (mg/kg) Deoxynivalenol (DON) <0,05 mg/kg 0,43 mg/kg VITAMINS B (thiamin) 4,63 B 6 (total pyridoxine) 4,0 Folate (total) 0,50

11 54 CEREALI E DERIVATI CEREALI E DERIVATI 55 IRMM, EUROPEAN COMMISSION IRMM, EUROPEAN COMMISSION CRM396 CRM379 CRM47l CRM47 Wheat flour Wheat flour Wheat Wheat (very low (medium level) blank (medium level) level blank) 50 g 50 g 55 g 55 g Concentrations (µg/kg, unless otherwise stated) Deoxynivalenol (DON) <0,05 mg/kg 0,67 mg/kg Ochratoxin A <0,6 8, Cat.No. Certified Property CRM563 Common wheat flour 360 g Certified Value Protein content % (Nx5,7) dry matter basis,7 Ash content % dry matter basis 0,56 Falling numbers/s 39 Zeleny sedimentation volume/ml 44 CHOPIN ALVEOGRAPH P/mmH O (P : mean curve height of Alveograph) 8 L/mm (L : mean curve length) 09 P/L 0,75 W/(0-4 Joules) (W : area under Alveograph curve) 90 BRABENDER FARINOGRAPH Maximum consistency/bu (Brabender Units) 499 Development time / min,7 Stability / min,5 Degree of softening / BU (Brabender Units) 87 BRABENDER EXTENSOGRAPH Maximum resistance / EU (Brabender Extensograph Units) 446 Resistance at 50 mm /EU (Brabender Extensograph Units) 6 Energy /(cm) 9 Extensibility/mm 0 CRM465 CRM466 CMR467 Rice flour (low level) Rice flour (medium level) Rice flour (high level) 0 g 0 g 0 g Concentrations (g/00 g) Amylose 5,4 3, 7,7 Standard di mais in polvere, contenenti una frazione di Mais geneticamente modificato Cat.No. IRMM-4 Dried maize powder, Set component code MZ-0 MZ-0, MZ-0,5 MZ- MZ- MZ-5 g g g g g g Certified Values (%) GM Maize 0 0, 0,5 5 Set of six CRMs of dried maize powder with different mass fractions of genetically modified ( Bt-76 ) maize, intended for the validation of the polymerase chain reaction (PCR) screening method for the detection of genetically modified food. Each set component of IRMM-4 is saleable also separately. Cat.No. IRMM-4 Dried maize powder, Set component code MA-0 MA-0, MA-0,5 g g g Certified Values (%) GM Maize 0 Set of three CRMs of dried maize powder with different mass fractions of genetically modified ( Bt- ) maize, intended for the validation of the polymerase chain reaction (PCR) screening method for the detection of genetically modified food. Each set component of IRMM-4 is saleable also separately. Cat.No. IRMM-43 Dried maize powder, Set component code MZ-0 MZ-0, MZ-0,5 MZ- MZ- MZ-5 g g g g g g Certified Values (%) GM Maize 0 0, 0,5 5 Set of six CRMs of dried maize powder with different mass fractions of genetically modified ( MON80 ) maize, intended for the validation of the polymerase chain reaction (PCR) screening method for the detection of genetically modified food. Each set component of IRMM-43 is saleable also separately.

12 56 CEREALI E DERIVATI CEREALI E DERIVATI 57 KEURINGSDIENST VAN WAREN Concentration Cat.No. Bread Chloride,505 g/00 g 60 g KVW-3a Bread Chloride,479 g/00 g 60 g KVW-3b Rusk (dietary product) Sodium 3,7 mg/kg 70 g KVW-4 LGC LGC7003 LGC703 White bread flour Sweet digestive biscuit 5 g 50 g Certified Value (%, unless otherwise stated) Ash 0,84,7 Fat,7,0 Moisture 3,3 Nitrogen,43,08 Calcium 0mg/kg 788 mg/kg Iron 3 mg/kg Magnesium 5 mg/kg Manganese 5,7 mg/kg Phosphorus 937 mg/kg Potassium 70mg/kg 330 mg/kg Sodium 39mg/kg 6770 mg/kg Zinc mg/kg 6,3 mg/kg Glucose 0,33 Fructose 0,3 Sucrose 5,8 Starch 44,8 Chloride 0,54 NRCCRM GBW0850 GBW08503 GBW08508 GBW0850 GBW085 CBW085 Rice flour Wheat flour Rice Rice Rice Rice 0 g 40 g 40 g 40 g 40 g 40 g Certified Constituent Concentration* (µg/g, unless otherwise stated) Arsenic 0,05 0, Cadmium 0,00 0,03,60 0,504 0,0069 Calcium Copper,6 4,40 3,6 Fluoride 8,0 Iron 5, 39,8 43, Lead 0,75 0,35 Magnesium ,4 Manganese 9,8 9,6 Mercury 0,038 Nitrogen (,39) % Phosphorus (0,5) % Potassium 656 0,98 % Selenium 0,045 (0,0) Sodium 8,4 (0,0) Zinc 4,,7 *Values in brackets are not certified. Standard non inclusi nel catalogo sono disponibili su richiesta. Contattateci!

13 59 Standard di carni NIST SRM577b RM844 Malerial Bovine liver Bovine muscle powder (beef) 50 g x 50 g Concentrations* (mg/kg, unless otherwise stated) Aluminium (3),7 Antimony (0,003) (0,0) Arsenic (0,05) 0,009 Barium (0,05) Boron 0,6 Bromine (9,7), Cadmium 0,50 0,03 Caesium (0,05) Calcium 6 45 Chlorine 0,78 Wt% 880 Chromium 0,07 Cobalt (0,5) 0,007 Copper 60,84 Fluorine (0,) Iodine 0,035 Iron 84 7, Lead 0,9 0,38 Magnesium Manganese 0,5 0,37 Mercury (0,003) 0,005 Molybdenum 3,5 0,08 Niclkel 0,05 Nitrogen Phosphorus,O Wt% 8360 Potassium 0,994 Wt% 570 Rubidium 3,7 8,7 Selenium 0,73 0,076 Silver 0,039 Sodium 0,4 Wt% 00 Strontium 0,36 0,05 Sulphur 0,785 Wt% 7950 Vanadium (0,3) (0,005) Zinc 7 4

14 60 CARNI CARNI 6 NIST IRMM, EUROPEAN COMMISSION SRM546 Meat homogenate 4x85 g Certified Value* (g/kg, unless otherwise stated) Octanoic acid (C 8:0) (0,04) Decanoic acid (C 0:0) 0,7 Dodecanoic acid (C :0) 0,33 Tetradecanoic acid (C 4:4),53 Hexadecanoic acid (C 6:0) 45,6 9 - Hexadecanoic acid (C 6:) (6,83) Octadecanoic acid (C 8:0),7 (Z) Octadecenoic acid (C 8:) 8,0 9, - Octadienoic acid (C 8:) (9,6) 9,,5 - Octadecatrienoic acid (C 8:3) (,4) Eicosanoic acid (C 0:0) 0,35 -Eicosenoic acid (C 0:) (,56) 5,8,,4 - Eicosatetraenoic acid (C 0:4) (0,56) Boron (0,8) mg/kg Calcium 33 mg/kg Copper (0,93) mg/kg Iodine (0,4) mg/kg Iron,4 mg/kg Magnesium (65) mg/kg Manganese (0,9) mg/kg Phosphorus (540) mg/kg Potassium (460) mg/kg Sodium 9990 mg/kg Sulphur (900) mg/kg Zinc (8,5) mg/kg Chloride (500) mg/kg Vitamin B HC (,6) mg/kg Vitamin B (,00) mg/kg Vitamin B 6 (,30) mg/kg Vitamin B (0,006) mg/kg Niacin (36,3) mg/kg Pantothenic acid (5,76) mg/kg Biotin (0,036) mg/kg Solids (40,5) % Ash (3,) % Extractable fat (,0) % Fat as sum of fatty acids (9,7) % Protein (4,9) % Carbohydrates (,77) % Calories (5) kcal/00g Cholesterol 0,750 Sucrose (7,7) Folic acid (0,0) mg/kg Choline (ion) (580) mg/kg Inositol (30) mg/kg Catalogue Number CRM84 CRM85R CRM86 CRM430 Bovine muscle Bovine liver Pig kidney Pork fat 5 g 5 g 5 g 3 g Concentrations* (µg/kg, unless otherwise started) Arsenic Cadmium Calcium (50) mg/kg (95) mg/kg Chlorine (,0) g/kg (9,4) g/kg Chromium Copper,36 mg/kg 77 mg/kg 3,9 mg/kg lodine (40) (45) Iron 79 mg/kg 99 mg/kg Lead Magnesium (00) mg/kg (89) mg/kg Manganese 334 mg/kg,07 mg/kg 8,5 mg/kg Mercury,6 970 Nickel (70) (40) Phosphorus (8,3) g/kg (,) g/kg Potassium (6,6) g/kg (,6) g/kg Selenium Sodium (,0) g/kg (7,) g/kg Zinc 66 mg/kg 38,6 mg/kg 8 mg/kg HCB 39 alpha-hch 40 beta-hch 59 gamma-hch 500 beta-hepo 09 p,p -DDE 80 Dieldrin 4 Endrin 0 p,p -DDT 3400 p,p -TDE (766)

15 6 CARNI CARNI 63 IRMM, EUROPEAN COMMISSION IRMM, EUROPEAN COMMISSION CRM63 Beef-pig fat oil blend x 5 ml Mass fraction* CRM384 Pork muscle 00 g Certified Value* (g/00g, unless otherwise stated) METHYL ESTER OF FATTY ACID METHYL ESTER/ TOTAL FATTY ACID METHYL ESTER (g/00 g) 4:0 n-tetradecanoic acids,9 4: ω5 (0,3) 5:0 (0,3) 6:0 n-hexadecanoic acids 5,96 6: n-hexadecenoicacids,58 6: ω9 (0,3) 7:0 () 7: (0,4) 8:0 n-octadecanoic acids 8,9 Kjeldahl Nitrogen 3,7 Fat 0,8 Ash at 550 C 4,6 Calcium Chlorine Magnesium Phosphorus Potassium Sodium (0,) g/kg (3,0) g/kg,00 g/kg (8,5) g/kg 5,5 g/kg,8 g/kg 8: n-octadecenoic acids 38,34 8: ω7 ( - 3) 8: trans (0,5) 8: n-octadecadienoic acids 7,05 8: trans (0,5) 8: conj. (0,4) 8:3 n-octadecatrienoic acids 0,86 8:3 trans (0,5) 0:0 (0,3) 0: (0,8) 0: (0 3) 0:3 (0,3) :0 (0,5) STEROLS MASS FRACTION IN FAT (mg/00 g) Cholesterol 33,6 Vitamins* CRM487 Pig s liver 75 g Certified Value (mg/kg) B (thiamin) 8,6 B (riboflavin) 06,8 B 6 (total pyridoxine) 9,3 B, Folate (total) 3,3 * Vitamins: information on nutritional composition of foods is essential for studies investigating the relascionship between diet and health or disease. The importance of realiable food composition data in the European Union is reflected in the issuing of Council Directive 90/496/Cee on the Nutritional Labelling of Foodstuffs. * Values in brackets are not certified. The fatty acid (methyl ester) profile was determined by capillary and packed gas chromatography. Although the entire profile is characterised, certified values are only given for the major components (> %) whereas indicative values are given for all minor components detected. Cat.No. IRMM444 IRMM445 IRMM446 Pork fat Pork fat Pork fat 5g 5g 5g Concentrations* (ng/g) PCB CONGENER BLANK VERY LOW LEVEL LOW LEVEL PCB No.8 < 4,8 9,6 PCB No.5 <,9 5,5 PCB No.0 <,5 30,0 PCB No.8 <,7 30, PCB No.38 < 4,6 3,0 PCB No.53 < 3, 30,8 PCB No.80 <,6 9,8 Sum of the above PCBs <4 93, 07,9 Lindane (5,7) (5,6) (4,6) 4,4 -Tetrabromodiphenylether (3,7) (3,9) (6,) * Values in brackets are not certified and are only indicative values

16 64 CARNI CARNI 65 KEURINGSDIENST VAN WAREN KVW-4 Luncheon meat 00 g Certified Value (g/00 g) Moisture 56,65 Starch,3 Crude fat 3,3 Ash 3,054 LGC Catalogue Number LGC7000 LGC700 LGC700 Beef/pork meat Pork meat 3 Pork/chicken meat 4 00 g 00 g 00 g Certified Values (g/00 g, unless otherwise stated) Ash 0,78 0,90,45 Chloride (,0) Fat,4 7,8, Moisture 66,5 68,6 60,6 Nitrogen,96,97,9 Calcium 53 mg/kg 39 mg/kg 95 mg/kg Potassium 590 mg/kg 860 mg/kg 40 mg/kg Sodium 360 mg/kg 50 mg/kg 7500 mg/kg Zinc 4, mg/kg, mg/kg 0,9 mg/kg Values in brackets are not certified. Composed of 45% beef, 0% pork, 0% rusk, 4% fat, 0,5% emulsifier. Made up to 00% with water. 3 Composed of 50% pork leg, % rusk, 4% chicken fat, 0,5% emulsifier. Made up to 00% with water. 4 Composed of 45% pork leg, 5% rusk, 0% chicken fat,,5% salt, 0,5% emulsifier. Made up to 00% with water. LCG7 Pig liver paste 50 g Certified Value *(mg/kg) Aluminium () Cadmium 0,5 Calcium 49,9 Cobalt 0,06 Copper 7 Lead (0,) Magnesium 67 Manganese 3,04 Molybdenum (7 Phosphorus 3430 Potassium 770 Selenium 0,9 Sodium 8 Vanadium (0,0) Zinc 43,0 Standard non inclusi nel catalogo sono disponibili su richiesta. Contattateci!

17 66 CARNI CARNI 67 LGC LGC750 LGC75 LGC75 Pig liver paste Processed meat Processed pork meat Unit or Issue 5x50 g 5x50 g 5x50 g Cerified Values (g/00g) Moisture 65,3 63,6 6,0 Nitrate 0,085 Nitrogen,78,93,38 Salt 4,3 Casein (0,3) Hydroxyproline 0,7 Soya Protein (0,3) Ash 3,37 5,8 4,67 Total Fat 5,0 4,6 5,0 Values in bracked are non certified. The salt content has been calculated from the cloride content of the material. LGC700 LGC70 LGC70 LGC703 LGC704 Beef meat, Beef meat, Lamb meat, Lamb meat, Pork meat, raw cooked raw cooked raw 3 Unit or Issue 30 g 30 g 30 g 30 g 30 g Certified meat species Certified Content Beef meat 00% 00% Lamb meat 00% 00% Pork meat 00% Rump steak from Scottish Aberdeen Angus cattle, aged 0 months, purchased from an organic farm. The cattle had been fed grass rich in clover. Suffolk-cross leg of lamb, aged 9 months, was purchased from an organic meat supplier. 3 Free range Land Race/Large white cross pork leg steak, aged approximately 5 months at slaughter, was purchased from an organic meat supplier. NRCCRM Catalogue Number GBW0855 GBW0855 Pork liver Pork muscle 5 g 0 g Concentrations* (µg/g, unless otherwise stated) Aluminium 0,044 Barium (0,39) Bromine 6, Cadmium 0,067 Caesium (0,4) Calcium Chlorine 0,87 % Chromium (0,0) (0,39) Cobalt (0,00) (0,03) Copper 7, 3,88 Iron 0,05 % 43,6 Lead 0,54 (0,0) Magnesium Manganese 8,3 0,48 Mercury (0,03) Molybdenum 3,8 (0,055) Nitrogen 0,86 %,7 % Phosphorus (,3) % 0,83 % Potassium (,5) %,40 % Selenium 0,94 0,49 Sodium 0,33 % 0,0 % Strontium (0,8) Rubidium 4,7 Zinc 7 94, LGC705 LGC706 LGC707 LGC708 LGC709 Pork meat, Chicken meat, Chicken meat, Turkey meat, Turkey meat, cooked raw cooked raw 3 cooked 3 Unit or Issue 30 g 30 g 30 g 30 g 30 g Certified meat species Certified Content Pork meat 00% Chicken meat 00% 00% Turkey meat 00% 00% Free range Land Race/Large white cross pork leg steak, aged approximately 5 months at slaughter, was purchased from an organic meat supplier. Free range Ross whole chickens, aged 4 to 45 days at slaughter, were purchased from an organic meat supplier. 3 Organic turkeys were purchased from a local butcher's shop.

18 68 CARNI 69 SWEDISH MEAT RESEARCH INSTITUTE SMRI 94- Meat Standard di pesci, crostacei e molluschi 00 g Certified Value* (g/00g, unless otherwise stated) NIST Moisture 6,9 Ash,78 Fat 8,0 Nitrogen, N,68 Protein (Nx6,5) 0,5 Hydroxyproline 0,65 Starch 3,87 Lactose,65 Salt, NaCl 3, Salt, NaCl 4,5 Calcium Phosphorus Sodium 480 mg/kg 30 mg/kg 8470 mg/kg Potassium 390 mg/g Calculated from the glucose content. Calculated from the galactose/glucose content. 3 Calculated from the chloride content. 4 Calculated from the sodium content. Standard non inclusi nel catalogo sono disponibili su richiesta. Contattateci! SRM588a SRM974a SRM974 Cod liver oil Mussel tissue (frozen) Mussel tissue (freeze-dried) 3 5 x, ml 3 x 5 g 8 g Concentrations (µg/kg) Hexachlorobenzene 57,8 Hexachlorobenzene (HCH) 4,9 alpha-hch 85,3 Heptachlor epoxide 3,6 trans-chlordane 85,3,89 6,6 cis-chlordane 67,0,96 7, trans-nonachlor 4,6,05 8,0 cis-nonachlor 94,8 0,78 6,84 Dieldrin 55,9,4 -DDD 36,3 4,4 -DDD 54 4,90 43,0,4 -DDE,0 4,4 -DDE 65 5,84 5,,4 -DDT 56,0 4,4 -DDT 54 0,445 3,9 PCB No. 8 8,3 PCB No. 3 8,33 PCB No , 8,8 7,7 PCB No. 49 9,90 0, 88,8 PCB No. 5 83,3 3, 5 PCB No ,7,54 0,4 PCB No ,3 PCB No ,5 9,5 83 PCB No. 99 8,08 70,9 PCB No. 0 6,5 4,6 8 PCB No , 6,04 53,0 PCB No. 0 76,0 4,5 7,3 PCB No. 8 76,3 4,90 30,8 PCB No. 8 47,0,50,0 PCB No ,5 5, 34 PCB No ,7 9,98 87,6 PCB No. 5 54,8,9 5,6 PCB No ,8 6,54 45, PCB No. 56 7,3 0,85 7,4 PCB No ,5 0,63 5,5 PCB No ,0,95 7, PCB No. 83 3,,8 6,0 PCB No ,3 3,87 34,0 PCB No. 94 5,37 PCB No. 0,8 Naphthalene,68 Phenanthrene,53, Anthracene 0,69 6, Fluoranthene 8,6 63,7

19 70 PESCI, CROSTACEI E MOLLUSCHI PESCI, CROSTACEI E MOLLUSCHI 7 NIST NIST SRM588a SRM974a SRM974 Cod liver oil Mussel tissue (frozen) Mussel tissue (freeze-dried) 3 5 x, ml 3 x 5 g 8 g Concentrations (µg/kg, unless otherwise stated) Pyrene 7,6 5,6 Benz[a]anthracene 3,7 3,5 Chrysene 5,04 44, Triphenylene 5,77 50,7 Benzo[b]fluoranthene 5,8 46,4 Benzo[k[fluoranthene,30 0, Benzo[e]pyrene 9,56 84,0 Benzo[a]pyrene,780 5,63 Perylene 0,874 7,68 Benzo[ghi]perylene,50,0 Indeno[,3-cd]pyrene,6 4, Methylmercury 8,80 77,3 Mercury 0, 76 Reference values are also available for 44 organic contaminants. Reference values are also available for 74 organic contaminants. 3 Reference values are also available for 57 organic contaminants. SRM976 SRM566b Mussel tissue Oyster tissue 5 g 5 g Concentrations (mg/kg, unless otherwise stated) Aluminium (34) 9,7 Antimony (0,0) Arsenic 3,3 7,65 Barium (8,6) Boron (4,5) Bromine (39) Cadmium 0,8,48 Caesium (0,07) Calcium (0,76) % 0,0838 % Cerium (0,09) Chlorine (5,7) % 0,54 % Chormium (0,50) Cobalt (0,6) 0,37 Copper 4,0 7,6 Europium (0,004) Hydrogen (7,) Iron 7,0 05,8 Lead,9 0,308 Magnesium (0,53) % 0,085 % Manganese (33) 8,5 Nickel (0,93),04 Nitrogen (7,6) Phosphorus (0,83) % Potassium (0,97) % 0,65 % Rubidium (4,0) 3,6 Scandium (0,046) Selenium,80,06 Silver (0,0) 0,666 Sodium (3,5) % 0,397 % Strontium (93) (6,8) Sulphur (,9) % 0,6887 % Thallium (,3) µg/kg Thorium (0,0) 0,0367 Tin (0,096) (0,03) Uranium (0,550) Vanadium (0,577) Zinc Total mercury 6,0 µg/kg 0,037 Methylmercury 7,8 µg/kg 0,03 Values in brackets are not certified. The certificate of analysis gives also reference values of Moisture, Solids, Carhohydrates, Ash, Fat, Protein, Protein Nitrogen, Total Dietary Fibers, Caloric Content, 8 fatty acids and indicative values of further 5 fatty acids.

20 7 PESCI, CROSTACEI E MOLLUSCHI PESCI, CROSTACEI E MOLLUSCHI 73 NIST NIST SRM977 Mussel tissue* 0 g Concentration (µg/kg, unless otherwise stated) SRM977 Mussel tissue* 0 g Concentration (µg/kg, unless otherwise stated) PAH ORGANOCHLORINE PESTICIDES Fluorene 0,4 Cis- Chlordane (a- Chlordane),4 Phananthrene 35, Trans-Nonachlor,43 Fluoranthene 38,7 Dieldrin 6,04 Pyrene 78,9 4,4 -DDE,5 Benz(a)anthracene 0,34,4 -DDD 3,3 Benzo(b)fluoranthene,0 4,4 -DDD 4,30 Benzo(e)pyrene 3, 4,4 -DDT,8 Benzo(a)pyrene 8,35 METALS & METHYLMERCURY Perylene 3,50 Cadmium 4 0,79 mg/kg Benzo(ghi)perylene 9,53 Copper 5 9,4 mg/kg Indeno(,,3-cd)pyrene 4,84 Lead 4,7 mg/kg Dibenz(a,h)anthracene,4 Manganese 3,93 mg/kg Benzo(b)chrysene,07 Nickel 4 6,06 mg/kg Picene,9 Strontium 69,3 mg/kg PCB CONGENERS Methylmercury 36, PCB No. 8,0 PCB No. 8,65 * Reference concentrations for further 6 PAHs and 3 inorganic constituents are also given in the certificate. PCB No. 8 5,37 PCB No. 3 3,9 PCB No. 44 3,5 PCB No. 5 8,37 PCB No. 66 3,64 PCB No. 87,5 PCB No. 95 5,39 PCB No. 99,59 PCB No. 0+90, PCB No. 05 3,76 PCB No. 0 4,03 PCB No. 8 0,5 PCB No. 8,49 PCB No ,6 PCB No. 49 9,3 PCB No. 5 3,07 PCB No. 53 4, PCB No. 56 0,960 PCB No. 70,95 PCB No. 80 6,79 PCB No. 83,33 PCB No ,76 PCB No. 94 0,897

21 74 PESCI, CROSTACEI E MOLLUSCHI PESCI, CROSTACEI E MOLLUSCHI 75 NIST IAEA SRM 978 Mussel tissue* 0 g Concentration (µg/kg) PAH Fluoranthene 66 Pyrene 56 Benzo(k)fluoranthene 4, Benzo(e)pyrene 89,3 Perylene 4,09 Benzo(ghi)perylene 9,7 IAEA-35 IAEA-MA-B-3/RN Tuna fish Fish flesh 00 g 50 g Certified Values* (µg/kg) Potassium Strontium-90 (0,) Caesium-37,7 4, Lead-0 0,6 Polonium-0, * The value in brackets is not certified and is only indicative. Indeno(,,3-cd)pyrene, PCB CONGENERS PCB No. 8 7,9 IRMM, EUROPEAN COMMISSION PCB No. 3,40 PCB No. 44,80 PCB No. 49 6,84 PCB No. 5 7,7 PCB No. 66 8,4 PCB No. 87 0,0 PCB No. 95 0,8 PCB No. 99 8,84 PCB No ,9 PCB No. 05 0,85 PCB No. 0 35,34 PCB No. 8 35, PCB No. 8 5,5 PCB No ,7 PCB No ,73 PCB No. 5 0,9 PCB No ,9 PCB No. 56,97 PCB No. 80 7,8 PCB No. 83 5,5 PCB No ,7 ORGANOCHLORINE PESTICIDES Oxychlordane,3 Cis- Chlordane (α- Chlordane) 5,56 Trans-Chlorda (Y- Chlordane),38 Cis-Nonachlor 8,3 Trans-Nonachlor,5 Dieldrin 6,30,4 -DDE 4,4 4,4 -DDE 37,5,4 -DDD 0,5 4,4 -DDD 38,8,4 -DDT 9, 4,4 -DDT 3,84 CRM78R CRM44 CRM4 CRM463 CRM464 CRM477 CRM67 Mussel Plankton Cod Tuna Tuna Mussel Tuna fish tissue muscle fish fish tissue tissue 8 g 5 g 7 g 5 g 5 g 4 g 0 g Certfied Constituent Concentrations* (mg/kg, unless otherwise stated) Arsenic 6,07 6,8, 4,8 Bromine (7) Cadmium 0,348 0,383 0,07 Calcium (330) Chromium 0,78 3,8 Cobalt (,43) (0,05) Copper 9,45 9,5,05 Iodine 4,95 Iron (850) 5,46 Lead,00 3,97 0,085 Magnesium (,4) Manganese 7, ,543 Mercury 0,96 0,76 0,559,85 5,4 Molybdenum (,35) Nickel 8,8 Potassium (7,55) (700) Scandium (0,54) Selenium,84,75,63 Sodium (00) Strontium (6) (0,7) Sulphur (500) Vanadium 8,0 Zinc 83, 9,6 Arsenobetaine Dimethylarsinic acid Methyl mercury (0,43) 3,04 5,50 Tributyltin (TBT),0 Dibutyltin (DBT),54 Monobutyltin (MBT),50 5 µmol/kg,0 µmol/kg * Reference concentrations for further 9 PAHs, Biphenyl and PCB congeners are also given in the certificate.

22 76 PESCI, CROSTACEI E MOLLUSCHI PESCI, CROSTACEI E MOLLUSCHI 77 IRMM, EUROPEAN COMMISSION KEURING DIENST VAN WAREN CRM349 CRM350 CRM598 Cod liver oil Mackerel oil Cod liver oil g g 5 g Certified constituent Concentrations* (µg/kg, unless otherwise stated) KVW-a KVW-b Fish (Mackerel) Fish (Mackerel) 50 g 50 g Concentrations (mg/kg) POLYCHLORINATED BIPHENYLS Histamine PCB No. 8 68,5 PCB No PCB No LGC PCB No PCB No (765) (74) PCB No PCB No PCB No. 44 (75) (44) PCB No. 8 (04) (4) PCB No. 94 (38) ORGANOCHLORINE PESTICIDES HCB 55,7 α - HCH 4 β- HCH 6 γ- HCH 3 γ - Chlordane 6,9 α - Chlordane 4,4 Oxychlordane,0 Transnonachlor 39 Dieldrin 59 p,p - DDE 60 o,p - DDD 30 p,p - DDD 400 p,p - DDT 79 LGC70 LGC760 Mackerel paste Crab paste 00 g 00 g Certified Value* (mg/kg, unless otherwise stated) Moisture 64,5 g/00g Nitrogen,5 g/00g Total fat 0,4 g/00g Chloride 500 Ash 0,83 Aluminium (4) Arsenic Cadmium,85 Calcium (0) 50 Chromium 0,9 Cobalt 0,059 Copper 0,4 Lead (0,06) Magnesium (80) 348 Manganese,77 Mercury 0,096 Molybdenum (0,5) Nickel 0,3 Phosphorus (450) 965 Potassium CRM54 CRM543 Mussel Mussel 5 g 5 g Certified constituent Concentrations (mg/kg) Saxitoxin-Hcl <0,07 <0,07 dc-saxitoxin,59 <0,04 Selenium () Sodium Strontium (30) Vanadium 0,084 Zinc (7) 53,6

23 78 PESCI, CROSTACEI E MOLLUSCHI PESCI, CROSTACEI E MOLLUSCHI 79 NRC NRC DOLT- DORM- LUTS- TORT- Dogfish liver Dogfish muscle Non-defatted lobster Partially-defatted hepatopancreas lobster hepatopancreas 5 g 30 g 6x0,3 g 35 g Certified Consituent Concentrations* (mg/kg) As bottled Dry weight Aluminium 5, 0,9 Arsenic 6,6 8,0,83 9,0,6 Cadmium 0,8 0,043, 4, 6,7 Calcium Chromium 0,37 34,7 0,079 0,53 0,77 Cobalt 0,4 0,8 0,05 0,34 0,5 Copper 5,8,34 5, Iron 03 4,6 77,8 05 Lead 0, 0,065 0,00 0,069 0,35 Magnesium 89,5 60 Manganese 6,88 3,66,0 8,0 3,6 Mercury,99 4,64 0,067 0, 0,7 Molybdenum 0,95 Nickel 0,0 9,4 0,00,34,50 Potassium Selenium 6,06,40 0,64 4,30 5,63 Silver 0,608 0,04 0,580 3,89 Strontium,46 6,5 45, Thallium (0,004) Tin (0,3) (0,03) (0,04) Vanadium,64 Zinc 85,8 5,6,4 8,9 80 Methyl mercury 0,693 4,47 0,0094 0,063 0,5 (as mercury) CARP- Fish (common carp) 6x9 g Concentration (ng/kg, unless otherwise stated) POLYCHLORINATED DIBENZOFURANS,3,7,8-TCDF,9,,3,7,8-PCDF 5,0 POLYCHLORINATED DIBENZO-P-DIOXINS,3,7,8-TCDD 6,6,,3,7,8-PCDD 4,4,,3,4,7,8-HxCDD,9,,3,6,7,8-HxCDD 5,6,,3,7,8,9-HxCDD 0,7,,3,4,6,7,8-HpCDD 6,5 OCDD 6,3 POLYCHLORINATED BIPHENYLS PCB No. 5 4 µg/kg PCB No. 0/90 4 µg/kg PCB No µg/kg PCB No. 8 3 µg/kg PCB No. 38/63/64 0 µg/kg PCB No µg/kg PCB No. 70/90 µg/kg PCB No µg/kg PCB No. 87/8 36 µg/kg MUS- MUS-B MUS- Mussel tissue Mussel tissue Mussel tissue 4xl5 g 4x8 g 4x4 g Concentrations (µg/g) Domoic acid 00 38,3 Okadaic acid Dinophysistoxin-

24 80 PESCI, CROSTACEI E MOLLUSCHI 8 NRCCRM GBW0857 GBW0557 Mussel Prawn g 8 g Concentrations* (µg/g unless otherwise stated) Standard di frutti, ortaggi e vegetali AGRICULTURAL RESEARCH CENTRE Aluminium (3) 0,3 % Arsenic 6,,4 Barium 4,9 Bromine (3,5) Cadmium 4,5 0,03 Calcium 0, % 0,304 % Chromium 0,57 0,4 Cobalt 0,94 (0,09) Copper 7,7 4,66 Fluoride 5,3 Gold (0,) Iron 9,8 Lead,96 0,98 Magnesium 0,97 % 0,60 % Manganese 0,,96 Mercury 0,067 0,0 ARC/CL-4 Carrot powder 60 g Cconcentration (µg/g, unless otherwise stated) Boron 0, Cadmium Calcium 700 Iron,6 Magnesium 350 Manganese 4,90 Molybdenum Potassium Sodium 485 Zinc 6,90 68,6 ng/g 49,5 ng/g 0, mg/g Total dietary fibre 0,93 % Molybdenum (0,6) Nickel,03 Nitrogen 4,3% Phosphorus (,35) % 0,845 % Potassium 0,44 % 0,597 % Selenium 3,65,5 Sodium 0,58 % 0,38 % CRM383 CRM54 CRM55 CRM56 CRM57 Haricots vert Haricot Carrot Apple Full fat (beans) beans soya 00 g 5 g 5 g 5 g 5 g Certified Values (g/00 g unless otherwise stated) Sulphur (0,85) % Glucose (,4) Strontium,8 40,6 Fructose (4,6) Titanium (,05) Sucrose (0,95) Zinc 38 60,8 Kjeldahl nitrogen, Starch & sugars (78,9) Dietary fibre (Englyst) (0,9) Dietary fibre (AOAC 985/988),9 Ash at 550 C,4 Calcium Magnesium,9 g/kg (0,9) g/kg Phosphorus (,8) g/kg Potassium 7,8 g/kg Sodium 0,08 g/kg DIETARY FIBRE, BY METHOD AOAC 990 5,6 3, 6,4,6 Englyst (by gas chromatography) 9,8 7, 3,7,9 Uppsala 3,7 9,8 6,,8 AOAC 99 MES-TRIS 5,9 9,5 4,9,4 Standard non inclusi nel catalogo sono disponibili su richiesta. Contattateci! Englyst (by colorimetry) 0, 5, 3,4,3 Values in brackets are not certified. Mass fraction in dry matter.

25 8 FRUTTI, ORTAGGI E VEGETALI FRUTTI, ORTAGGI E VEGETALI 83 IRMM, EUROPEAN COMMISSION IRMM, EUROPEAN COMMISSION CRM366 CRM90R CRM367 CRM446 CRM447 CRM448 Rapeseed Rapeseed Rapeseed Low oil content Medium oil High oil (colza) (colza) (colza) rapeseed content content rapeseed rapeseed 0 g In Prep 0 g 50 g 50 g 50 g Certified Values* (mmol/kg, unless otherwise stated) Total glucosinolate, 0 Sulphur 3,4 g/kg 0,5 g/kg Progoitrin (6,3) (66,8) Epiprogoitrin (0,) (,4) Sinigrin (0,6) Napoleiferin (0,3) (,3) Glucoalysin (0,) (,0) Gluconapin (,) (5,8) 4-OH Glucobrassicin (3,0) (3,8) Glucobrassicanapin (0,4) (5,3) Glucobrassicin (0,) (0,) Gluconasturtiin (0,) (0,9) 4-CH3O- (0,4) (0,9) Glucobrassicin Neoglucobrassicin (0,06) (0,) As is oil 39,49 g/00g 4,99 g/00g 45,43 g/00g Moisture & volatiles 7,0 g/00g 7,4 g/00g 7,68 g/00g Dry basis oil 4,48 g/00g 45,36 g/00g 49, *Values in brackets are not certified. The official EU method for glucosinolates determination is based on HPLC which determines the total content by a process involving the summation of the individual substances. XRF provides a much faster estimate of total glucosinolate and is extensively used in practice. It depends on the correlation between sulphur content of rapeseed and its total glucosinolate content and is now a draft ISO method. These CRMS provide a means of validating the application of the official HPLC and other methods and provide a common basis for the calibration of the XRF method following a procedure specified in the draft ISO method. These rapeseed CRMS are to be analysed according to the standard solvent procedure EEC, FOSFA or ISO. They can be used to calibrate NMR methods for the analysis of seeds of the same variety. CRM43 CRM485 Brussels sprouts Mixed vegetables 0 g 5 g Certified constituent VITAMINS Concentrations (mg/kg) B (thiamin) 3,07 B 6 (total pyridoxine) 4,8 C (total ascorbate) 4830 Folate (total) 3,5 Niacin 43 Trans-α-carotene 0,5 Trans-β-carotene 3,7 Total-α- carotene 9,8 Total-β-carotene 5,6 Lutein,5 Lutein+zeaxanthin,3 Vitamins: information on nutritional composition of foods is essential for studies investigating the relascionship between diet and health or disease. The importance of realiable food composition data in the European Union is reflected in the issuing of Council Directive 90/496/Cee on the Nutritional Labelling of Foodstuffs. Standard di Soya in polvere, contenenti una frazione di soya geneticamente modificata IRMM-40R Dried Soya bean powder, Set component code SB-0 SB-0, SB-0,5 SB- SB- SB-5 g g g g g g Certified values (%) GM Soya 0 0, 0,5 5 Set of 6 CRMs of dried soya bean powder with different mass fractions of genetically modified ( roundup ready TM ) soya beans, intended for validation of the polymerase chain reaction (PCR) screening method for the detection of GM food. Each set component of IRMM-40R is saleable also separately. CRM6 CRM63 CRM64 CRM40 CRM385 Defatted peanut Defatted peanut Defetted peanut Peanut Peanut meal (blank) meal (medium level) meal (high level) butter butter 00 g 00 g 00 g In Prep In Prep Certified Value (µg/kg) Aflatoxin B <3 43,3 06

26 84 FRUTTI, ORTAGGI E VEGETALI FRUTTI, ORTAGGI E VEGETALI 85 KEURINGSDIENTS VAN WAREN NRCCRM KVW-3a KVW-3b KVW- KVW-0 Pistache slurry Pistache slurry Nutmeg Salad 00 g 00 g 60 g 60 g Concentrations (µg.kg, unless otherwise stated) Aflatoxin B 3,7 5,5 7,3 Benzoic acid 7,76 mg/kg Sorbic acid 7,67 mg/kg LGC Certified constituent Concentration Potato powder Sulphur dioxide* 357,5 mg/kg 00g LGC 7 * Preservative added to wide range of foodstuffs to prolong shelf life. Whilst the presence of preservative at appropiate levels is beneficial to the consumer, excessive levels can pose a toxic hazard. Their maximum permissible levels are therefore regulated by European legislation (EU Directive 95//EC). NATIONAL FOOD ADMINISTRATION Certified constituent SLV-Fungus Edible fungus (C. tubaeformis) 7 g Concentration (mg/kg) Cadmium 0,437 Cobalt 0,073 Chromium 0,3 Copper 34,4 Iron 0 Lead,43 Manganese 49,9 Nickel 0,38 Zinc 55,0 GBW07605 GBW08504 Tea Gabbage 35 g 30 g Concentrations* (µg/g, unless otherwise stated) Aluminium (0,30) % Antimony 0,056 Arsenic 0,8 0,056 Barium 58 Beryllium 0,034 Bismuth 0,063 Boron 5 Bromine 3,4 Cadmium 0,057 0,09 Caesium 0,9 Calcium 0,43 % 0,79 % Cerium,0 Chromium 0,80 Cobalt 0,8 Copper 7,3 3,00 Dysprosium (0,074) Europium 0,08 Fluorine 30 Gadolinium (0,093) Hafnium (0,033) Holmium (0,09) Iron 64 5,0 Lanthanum 0,60 Lead 4,4 0,8 Lithium (0,36) Lutetium (0,007) Magnesium 0,7 % 0,84 % Manganese 40,0 Mercury (0,03) Molybdenum 0,038,8 % Neodymium (0,44) Nickel 4,6 Nitrogen 33 % Phosphorus 840 0,34 % Potassium,66 %,45 % Praseodymium (0,) Rubidium 74 (3,7) Samarium 0,085 Scandium 0,085 Selenium (0,07) 0,083 Silicon (0,) % Silver (0,08) Sodium 44 0,757 %

27 86 FRUTTI, ORTAGGI E VEGETALI 87 NRCCRM GBW07605 GBW08504 Tea Gabbage 35 g 30 g Concentrations* (µg/g, unless otherwise stated) Strontium 5, 45, Sulphur 0,45 % Terbium (0,0) Thorium 0,06 Titanium 4 Vanadium (0,86) Ytterbium 0,044 Yttrium 0,36 Zinc 6,3 6,7 Standard di fertilizzanti NIST SRM0c SRM93 SRM94 SRM00a SRM694 Phosphate Potassium Ammonium Potassium Phosphate rock (Florida) nitrate dihydrogen dihydrogen rock phosphate phosphate (Western) 90 g 90 g 90 g In Prep 90 g Concentrations* (wt%) Fluorine 3, Nitrogen 3,85,5 Phosphorus 6,9 Potassium 38,66 Uranium 0,044 Al O 3,8 CaO 48,0 43,6 CdO (0,0) Cr 0 3 (0,) Fe O 3 0,79 K 0 0,47 0,5 MgO 0,33 Na O 0,086 P ,34 30, SiO, TiO 0,06 V O 0,05 Standard non inclusi nel catalogo sono disponibili su richiesta. Contattateci!

28 88 FERTILIZZANTI FERTILIZZANTI 89 IRMM, EUROPEAN COMMISSION NRCCRM CRM03 CRM033 CRM3 CRM4 CRM78 CRM79 Phosphate Superphosphate Potassium Potassium Calcium Urea rock chloride sulphate ammonium nitrate 00 g 00 g 00 g 00 g 00 g 00 g Concentrations (g/kg) Al O 3 5,5,0 CaO 57,6 34,8 CO 5,0 Fe O 3,3 4,0 MgO 4,0, P O 5 39,8 93,4 SiO 0,9 9, SO 3 8,4 SO 4 48,0 533 Fluorine 40,4 6,5 Arsenic 9,5 x 0-3 Boron,6 x 0-3 Cadmium 0,8 x ,8 Calcium,03 9,4 Chlorine 478,0 8,5 Chromium 57 x 0-3 Cobalt 0,59 x 0-3 Copper 33,7 x 0-3 Magnesium 0,4 0,74 Manganese 8,8 x 0-3 Mercury 55 x 0-6 Nickel 34,6 x 0-3 Potassium 50,5 48,0 Sodium 5,3,0 Titanium 7 x 0-3 Vanadium 53 x 0-3 Zinc 53 x 0-3 Water soluble 50,3 47,6 Potassium NH 4 -N 30,44 NO 3 -N 30,5 Uric-N 460,9 Total-N 60,9 465,35 Biuret 0,37 The classification of fertilisers is the subject of international standards (ISO) and the specifications for quality are also prescribed in a Community Directive 76//EEC. This Directive also specifies methods of analysis and recommends the use of reference materials for the purpose of verification. GBW0650 GBW0650 GBW06503 Urea Ammonium Potassium sulphate dihydrogen phosphate 35 g 30 g 40 g Concentrations* (wt%, unless otherwise stated) Biuret,39 Boron (,4) µ/g Calcium (,) µ/g (, ) µ/g (67,7) µ/g Iron (,) µ/g (3,5) µ/g (4,7) µ/g Phosphorus 6,85 Potassium 44,79 Magnesium (0,) µ/g (4,0) µ/g Manganese (0,) µ/g (0,) µ/g Nitrogen 46,30,08 Standard non inclusi nel catalogo sono disponibili su richiesta. Contattateci!

29 9 Standard di bevande e soluzioni alcoliche IRMM, EUROPEAN COMMISSION CRM3A and CRM3B Ethanol for NMR-(D/H) isotopic determination 3 x 0 mm tubes (A) or 5 mm tubes (B) Certified Value Ethanol H Ethanol M Ethanol L (D/H) I 09,65 x 0 6 0,69 x ,30 x O 6 (D/H) II 9,76 x ,94 x 0 6,0 x 0 6 R,84,575,708 Quantitative analysis of deuterium in ethanol by NMR spectrometry based on the site specific natural isotope fractionation (SNIF) is of considerable importance for the detection of the wine enrichment. This technique of analysis is prescribed by EC Regulation No. 676/90 on analytical methods for wine quality control. Three sealed NMR tubes containing respectively H-, M- and L- ethanols, to which Tetramethilurea as internal standard and C 6 F 6 as lock substance are added. CRM653 CRM65 CRM65 Low alcohol Wine Low alcohol Beer Low alcohol Beer 0 ml 0 ml 0 ml Certified constituent Certified Value (% ethanol v/v) Ethanol 0,539 0,05 0,505 Low alcohol beverage related to the labelling of alcohol-free or de-alcoholised and low alcohol beverages according to Directive 90/496/EC.

30 9 BEVANDE E SOLUZIONI ALCOLICHE 93 KEURINGSDIENST VAN WAREN KVW-5 KVW-6 KVW-a KVW-b Wine White wine Geneva Geneva 50 ml 50 ml 300 ml 300 ml Certified constituent Concentrations Sorbic acid 0 mg/l Sulphite 05,3 mg/l Alcohol,99 % v/v 34,86 % v/v 34, % v/v LGC LGC 500 Whisky 5x0 ml Concentration (g/00l) Metanol 8, Ethyl acetate 7,0 Propan--ol 67,4 -Methylpropan- ol 65,0 -Methylbutan- ol 9,6 3-Methylbutan- ol 5,4 +3-Methylbutan- ol 70, Acetaldehyde (9) Butan--ol (0,6) Furfural (,3) Standard di oli vegetali NIST SRM563 Coconut oil 0x4 ml (5 of each type) Mass fraction* (mg/kg, unless otherwise stated) SRM563- (natural) SRM563- (fortified) Cholesterol (3,4) 638 Retinyl acetate (<) (8,) Ergocalciferol (<) 0,9 dl-a-tocopheryl acetate (<) 58 Fat (99) % (97) % Capric acid (C0:0) (5,8) % (5,8) % Lauric acid (C:0) (46) % (45) % Myristic acid (C4:0) (8) % (8) % Palmitic acid (C6:0) (9,4) % (9,) % Stearic acid (C8:0) (,8) % (,7) % Oleic acid (C8:) (7) % (6,6) % * Values in brackets are not certified and are given only for reference or information. LGC5000 LGC500 LGC500 LGC5003 LGC5004 LCCSOO5 Brandy Wine Wine Wine Lager shandy Lager 5x50 ml 5x50 ml 5x50 ml 5x50 ml 5x330 ml 5x440 ml Certified Value (ml/l00 ml at 0 C) Alcohol 39,98 5,04 0,5 4,66,0 4,75 LGC5404 LGC5405 LGC5406 LGC5407 LCC5408 Ethanol/water Ethanol/water Ethanol/water Ethanol/water Ethanol/water 5x50 ml 5x50 ml 5x50 ml 5x50 ml 5x50 ml Certified Value (nominal, ml/00 ml at 0 C) Alcohol

31 94 OLI VEGETALI OLI VEGETALI 95 IRMM, EUROPEAN COMMISSION CRM6 Soya-maize oil blend x 5 ml Certified Value Methyl ester of Mass fraction in Total Fatty Acids Methyl Esters (g/00 g) 4:0 n-tetradecanoic acids (0,) 6:0 n-hexadecanoic acids 0,65 6: ω7 (0,) 7:0 (0,) 7: (0,) 8:0 n-octadecanoic acids,87 8: n-octadecenoic acids 4,4 8: ω7 () 8: trans (0,5) 8: n-octadecadienoic acids 56,66 8: trans (0,5) 8:3 n-octadecatrienoic acids 4,68 8:3 trans (0,5) 0:0 (0,3) 0: (0,) :0 (0,) Sterols Mass fraction in Fat (mg/00 g) Cholesterol,5 β-sitosterol (399,8) Campesterol (37,4) Stigmasterol (59,5) 7 -Avenasterol (5,6) 7 -Stigmasterol (5,) IRMM, EUROPEAN COMMISSION CRM537 CRM538 CRM539 Plastic film A Plastic film B Plastic film C 33 x,5 cm 5 x,5 cm 45 x 5 cm Certified Property Certified Value (mg/dm ) Overall migration in olive oil Overall migration by total immersion in olive oil 0 days at 40 C 8,3 Overall migration by single sided cell in olive oil 0 days at 4 C 5,7 Overall migration by pouch in olive oil 0 days at 40 C 6, Overall migration in olive oil: CRM537, CRM538 and CRM539 consist of additive free linear low density polyethylene sheets. They are intended to determine the overall migration applyng the draft ENV 86 standard procedure estabilioshed by the Technical Committee of the European Committee for Standardisation (CEN). KEURINGSDIENST VAN WAREN KVW- Frying oil 0 ml Concentration (g/00g) Di- and Poly-merised Triglycerides 7,4 Values in brackets are not certified The fatty acid (methyl ester) profile was determined by capillary and packed gas chromatography. Although the entire profile is characterised, certified values only given for the major components (> %) whereas indicative values are given for all minor components detected. This CRM may also be used to determine the order of elution of individual fatty acid methyl ester in gas chromatography. CRM458 CRM459 Coconut oil Coconut oil 45 g 45 g Concentrations (µg/kg) POLYCYCLIC AROMATIC HYDROCARBONS* Pyrene 9,4 <0,9 Chrysene 4,9 <0,6 Benzo[k]fluoranthene,87 <0, Benzo[a]pyrene 0,93 <0,3 Benzo[ghi]perylene 0,97 <0, Indeno[,,3-cd]pyrene,00 <0, * The main source of human PAH intaken by food is caused by consuming cereal products, edible oils and fats. The contamination of edible oils mainily results from the drying process of the oil seeds upon open fire and is of growing importance due to increasing demands for native, not refined oils.

32 96 OLI VEGETALI 97 LGC LGC70 Corn oil 5 x 5 ml Concentration (mg/kg) 3-tert-Butyl-4-hydroxyanisole (BHA) 49,4,6-Di-tert-butyl-4-methylphenol (BHT) 49,7 Miscellanea di standard in matrici alimentari NIST Antioxidants added to a wide range of foodstuffs to prolong shelf life. Whilst the presence of antioxidants at appropiate levels is beneficial to the consumer, excessive levels can pose a toxic hazard. Their maximum permissible levels are therefore regulated by European legislation (EU Directive 95//EC). LGC7 LGC73 Olive oil Olive oil 5 ml 5 ml Concentrations (mg/kg) α-tocopherol 7, 73,6 Antioxidant added to a wide range of foodstuffs to prolong shelf life. Whilst the presence of antioxidants at appropiate levels is beneficial to the consumer, excessive levels can pose a toxic hazard. Their maximum permissible levels are therefore regulated by European legislation (EU Directive 95//EC). SRM845 SRM544 Whole egg powder Diet composite 3x8 g 4x5 g Certified Values* (g/kg, unless otherwise stated) Cholesterol 9,0 0,483 Caprylic acid (C8:0) (0,3) Capric acid (C0:0) (0,3) Lauric acid (C:0),3 Myristic acid (C4:0),0 Palmitic acid (C6:0) 5,77 Palmitoleic acid (C6:) (0,4) Stearic acid (8:0),00 Oleic acid (C8:),64 Linoleic acid (C8:) 6,56 Linolenic acid (C8:3) (0,6) Arachidic acid (C0:0) (0,) Eicosenoic acid (C0:) (0,) Arachidonic acid (C0:4) (0,) Behenic acid (C:0) (0,) Protein (5,8) % Moisture (73,) % Total fat (3,68) % Ash (0,97) % Carbohydrate (6,9) % Calories () cal/kg Calcium (0,5) Potassium (,5) Sodium (,7) Standard non inclusi nel catalogo sono disponibili su richiesta. Contattateci!