Natural Oils. June 2012

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1 Natural Oils June 2012

2 Natural Oils The demand for natural and naturally derived ingredients is higher than ever 2

3 Natural Oils Approvals for Natural and/or Organic Cosmetics Trade Name INCI Name EU / non EU Eco status Cosmos Natrue Cegesoft PS 6 Cegesoft HF 52 Olus/ Vegetable Oil Hydrogenated Vegetable Oil * * Cegesoft HF 62 Cegesoft VP Shea Butters Hydrogenated Vegetable Oil Olus (and) Hydrogenated Vegetable Oil (and) Candellila Cera/ Vegetable Oil (and) Hydrogenated Vegetable Oil (and) Euphorbia Cerifera (Candellila) Wax For all types * * Cegesoft SB Butyrospermum Parkii Butter (EU)/Butyrospermum Parkii (Shea) Butter ** Cegesoft SBE Butyrospermum Parkii Butter (EU)/Butyrospermum Parkii (Shea) Butter no no no Cetiol SB 45 Butyrospermum Parkii Butter (EU)/Butyrospermum Parkii (Shea) Butter no no Cegesoft SH Cegesoft PFO Shorea Stenoptera Seed Butter Passiflora Incarnata Seed Oil ( )* ( ) Cegesoft GPO Elaeis Guineensis Oil (EU) Elaeis Guineensis (Palm) Oil (non EU) ( )*/** ( ) Cegesoft PFO, Cegesoft PS 6 and Cegesoft VP have as well the status as Registered raw material BDIH Controlled Natural Cosmetic. * CPAI products allowed for certification of cosmetic products until ** only for COSMOS approval by Ecocert ( ) possible but not applied for 3

4 Common Natural Oils Cegesoft PS 6 INCI: Olus Oil (EU) Vegetable Oil (CTFA) Slow spreading emollient With long lasting skin feel Based on canola oil which contains oleic (omega-9), linoleic acid (omega-6) and tocopherol Advantageous for sensitive skin Similar spreading properties like paraffin oil subliquidum 4

5 Common Natural Oils Cegesoft VP INCI: Olus Oil (and) Hydrogenated Vegetable Oil (and) Candelilla Wax Waxy emollient Based on canola, palm, soy and candellila Basis for stick preparations Consistency and melting behaviour close to petrolatum 5

6 Common Natural Waxes Cegesoft HF 52 Cegesoft HF 62 Waxes obtained by hydrogenation of vegetable oils Consistency factors and basis for stick preparations Different in origin, fatty acid composition and melting behaviour for a variety of application Delivered as pellets C-chain distribution INCI Source Cegesoft HF 52 Cegesoft HF 62 Hydrogenated Vegetable Oil Palm/Special Rape Seed Oil Hydrogenated Vegetable Oil Rape Seed Oil Palmitic Acid [%] 38 5 Stearic Acid [%] Oleic Acid [%] 32 - Eicosic Acid [%] 3 7 Behenic Acid [%] Others [%] 1 2 Slip Melting Point

7 Exotic Oils Golden Palm Oil Cegesoft GPO Shea Butters Cetiol SB 45, Cegesoft SB & Cegesoft SBE Shorea Butter Cegesoft SH Passion Flower Oil Cegesoft PFO 7

8 Shea Butters Origin: Central/West Africa Shea butter is a semi solid wax obtained from the nuts of the fruits of of the wild growing Karite tree Butyrospermum Parkii INCI: Butyrospermum Parkii Butter(EU) Butyrospermum Parkii (Shea) Butter (CTFA) Shea butter is well known for Soft and pleasant long term skin feel Caring & moisturizing effect with a weak gloss High content of triglycerides, rich in oleic and linoleic acids Food grade quality Good crystallization behaviour 8

9 Shea Butters Cetiol SB 45, Cegesoft SB and Cegesoft SBE additionally provide: Excellent odor and color quality Support of UV protection and Soothing properties due to a High content of unsaponifiable matter with active ingredient character in Cetiol SB 45 and Cegesoft SBE Cetiol SB 45 Cegesoft SB Cegesoft SBE Melting point C: min Unsaponifiables %: 9-13 min Add on property: supports consistency most natural grades/organic concentrated active content 9

10 Shorea Butter - Cegesoft SH Origin : Borneo The Illipe tree is a large tree growing in tropical rainforest, the butter is obtained from the fruit kernel. INCI: Shorea Stenoptera Seed Butter Cegesoft SH Leaves a silky, non-lubricating, velvet skin feeling Melting point some degrees below body temperature C Moisturises Improves wet & dry combability of hair from a shampoo Improves hair gloss High oxidative stability due to high content of saturated fatty acids & low content of mono-unsaturated fatty acids Good crystallisation behaviour 10

11 Cegesoft SH vs. Cetiol SB 45 Sensory Assessment 11

12 Cegesoft SH Hair Performance Assessment with a shampoo containing Cegesoft SH Result: Cegesoft SH improves wet & dry combability and hair gloss 12

13 Passionflower Oil Cegesoft PFO Origin: South America, Africa, Madagascar The oil is produced from the seeds which are sun dried prior to pressing INCI: Passiflora Incarnata Seed Oil Cegesoft PFO High content of linoleic fatty acid, approx. 70 % omega-6, an essential fatty acid known to reduce transepidermal water loss of the skin Pleasant & silky skin feel comparable to evening primrose oil Long term skin feel due to low spreading behaviour Similar properties as Evening Primrose oil 13

14 Golden Palm Oil Cegesoft GPO Origin: Southeast Asia Golden Palm oil is extracted from the fruit flesh of the palm tree Elaeis guineensis and not comparable to palm kernel oil which is lauric oil. INCI: Elaeis Guieensis Seed Oil (EU) Elaeis Guieensis (Palm) Oil (CTFA) Cegesoft GPO Slow spreading emollient with long lasting skin feel Can be used as natural colorant for yellow orange colors Contains about 400 ppm carotenes Contains about 1000 ppm tocopherols and tocotrienols Resistant against autoxidation 14

15 Cegesoft GPO Natural coloration of cosmetic formulations, e.g. body oils 0 % 0.1 % 1 % 5 % Pure Cegesoft GPO 15

16 TEWL Difference (g/cm 2 h) Transepidermal Water Loss (TEWL) study with some Cegesoft Types Differences= TEWL after application minus TEWL before application Cegesoft GPO Cegesoft PFO Cegesoft SBE Cegesoft SH blank Before application of the pure oil *This test has been performed on Asian skin Time after application (min) (n=5) 16

17 17 Formulations

18 Naturecare Face Cream with Cegesoft HF 52 & PS 6 Ingredients Eco status INCI Weight % (as is) EMULGADE PL 68/50 Cetearyl Glucoside (and) Cetearyl Alcohol 5.00 LANETTE E Sodium Ceterayl Sulfate 0.25 CUTINA HVG Hydrogenated Vegetable Glycerate 2.00 CETIOL OE Caprylyl Carprylate 5.00 CETIOL MM Myristyl Myristate 3.00 CEGESOFT HF 52 Hydrogenated Vegetable Oil 2.00 CEGESOFT PS 6 Olus 5.00 MYRITOL 331 Cocoglycerides 3.00 LIPOFRUCTYL ARGAN LS 9779 Argania Spinosa Kernel Oil 2.00 COVI-OX T 90 EU C Tocopherol 0.50 Ethanol Ethanol 15.0 Glycerin Glycerin 5.00 Water, denim. Aqua ph-value to be adjusted to Viscosity [mpas]: Brookfield RVT, 23 C, spindle 5, 10rpm ,000 mpas Formulation number: SC-DE/08/131/18 18

19 Naturecare Anti-Age Day Cream with Cegesoft SB, Cegesoft PFO & PS 6 Ingredients Eco Status INCI Weight % (as is) Function EMULGADE PL 68/50 Cetearyl Glucoside (and) Cetearyl Alcohol 3.00 O/W Emulsion Base EUMULGIN SG Sodium Ceterayl Sulfate 0.50 O/W Emulsifier CUTINA GMS-V Glyceryl Stearate 3.00 Consistency Factor CEGESOFT PS 6 Olus 5.00 Emollient CEGESOFT SB Butyrospermum Parkii 1.00 Emollient CEGESOFT GPO Elaeis Guineensis Oil 0.50 Emollient CETIOL LC Coco-Caprylate / Caprate 9.00 Emollient Keltrol T (Kelco) Xanthan Gum 0.25 Agent, thickening COVI-OX T90 EU C Tocopherol 1.00 Active ingredient Ginseng Extract * Grape Extract * *(Burgundy Botanicals Extracts Iberia S.A.) Panax Ginseng Extract (and) Maltodextrin (and) Silica Vitis Vinifera Seed Extract (and) Silica (EU) Vitis Vinifera (Grape) Seed Extract (and) Silica (non EU) Ethanol Ethanol Perfume Keep Smiling Natura Öko (Düllberg Konzentra) 0.05 Active ingredient 0.05 Active ingredient Preservative Parfum 0.15 Fragrance Lara Care 200 Galactoarabinan 0.50 Glycerin Glycerin 7.00 Humectant Water demin. Aqua ph-value (as is) 5.20 Viscosity (Brookfield/RVT/23 C/ spindle 5/ 10 rpm) mpas 19 Formulation number: SC-DE/07/070/41

20 * Body Milk with Cegesoft HF 62 & VP formulated under consideration of Ecocert guidelines Ingredients Eco Status INCI Weight % (as is) CETIOL CC Dicaprylyl Carbonate 5.00 MYRITOL 318 Caprylic/ Capric Triglyceride 5.00 Vegetal Oil Jojoba (Fytosan) Jojoba Wax 5.00 CEGESOFT VP Olus (and) Hydrogenated Vegetable Oil (and) Candelilla Cera CEGESOFT HF 62 Hydrogenated Vegetable Oil 2.00 LANETTE O Cetearyl Alcohol EUMULGIN VL 75 Lauryl Glucoside (and) Polyglyceryl-2 Dipolyhydroxystearate (and) Glycerin 3.50 Glycerin Glycerin 3.00 Dissolvine GL 38 (Akzo) Tetrasodium Glutamate Diacetate 0.05 Water, de-ionized Aqua Keltrol CGSFT (SPCI) Hamamelis HYHA12 (Fytosan) Perfume Fleur d amandier (Expressions Parfumées) Geogard 221 (Lonza) Xanthan Gum Hamamelis Virginiana Distillate* Dehydroacetic Acid (and) Benzyl Alcohol ph-value Viscosity [mpas]: Brookfield RVT,spindle 5, 10rpm Formulation number: FR 00/661/213 ** Ingredients proceeding from Organic Farming ( 14,560 mpas 20 * Only Ecocert has the ability to certify finished products according to Guidelines for Natural and Organic Cosmetics

21 Golden Body Butter with Cegesoft GPO & SH & Cetiol SB 45 Ingredients EMULGADE PL 68/50 EUMULGIN SG CUTINA PES CUTINA GMS V Eco Status INCI Weight % (as is) Cetearyl Glucoside (and) Cetearyl Alcohol Sodium Stearoyl Glutamate Pentaerythrityl Distearate Glyceryl Stearate CETIOL CC CETIOL OE CETIOL SB 45 CEGESOFT GPO CEGESOFT SH Silocon Oil AK (Wacker) Cosmedia SP Glycerin Water Preservative Dicaprylyl Carbonate Dicaprylyl Ether Butyrospermum Parkii Butter (EU) Butyrospermum Parkii (Shea) Butter (non EU) Elaeis Guineensis Oil (EU) Elaeis Guineensis (Palm) Oil (non EU) Shorea Stenoptera Butter (EU) Shorea Stenoptera Butter (non EU) Dimethicone Sodium Polyacrylate Glycerin Aqua q.s. Viscosity [mpas], Brookfield RVT 23 C, spindle TE 5rpm with Helipath approx. 1,200,000 mpas Formulation number: SC-US/162/634/132/5 21

22 Naturecare Body Lotion with Cegesoft PS 6, GPO & Cetiol SB 45 Ingredients Eco status INCI Weight % (as is) EMULGADE PL 68/50 Cetearyl Glucose and Cetearyl Alcohol 3.0 EUMULGIN SG Sodium Stearoyl Glutamate 0.5 CUTINA GMS-V Glyceryl Stearate 3.0 CEGESOFT PS 6 Olus (EU), Vegetable Oil (non EU) 5.0 CEGESOFT GPO CETIOL OE CETIOL SB 45 MYRITOL 331 COVI-OX T90 EU C Keltrol T Elaeis Guineensis Oil Dicaprylyl Ether Sheabutter Cocoglycerides Tocopherol Xanthan Gum Water demin. Water Glycerin Glycerin 7.0 Lara Care 200 Galactoarabinan, Water 0.5 Ginseng Extract* Panax Ginseng Root Extract (and) Maltodextrin (and) Silica 0.05 Grape Seed Extract *(Burgundy Botanical Extracts Iberia S.A.) Vitis Vinifera Seed Extract (and) Silica (EU) Vitis Vinifera (Grape) Seed Extract (and) Silica (Non EU) 0.05 Ethanol 15.0 ph-value (as is) Viscosity (Brookfield RVF, 23 C, spindle 5; 10 rpm) Formulation number: SC-DE/07/070/26 11,200 mpas

23 Moisturizing Shower & Bath Oil with Cegesoft PS 6 Ingredients TEXAPON WW 100 Eco Status INCI Weight % (as is) MIPA-Laureth Sulfate (and) Laureth-4 (and) Cocamide DEA PLANTAPON LC7 NaOH 50% CEGESOFT PS 6 EUTANOL G CETIOL OE Perfume Preservative Laureth-7 Citrate Olus (EU); Vegetable Oil (non EU) Octyldodecanol Dicaprylyl Ether q.s. ph-value (10%) 5.80 Viscosity [mpas], Brookfield RVT 23 C, spindle 4,10 rpm < Formulation number: HB-ES/05/501/01D

24 Natural Soothing Care for Hair & Scalp with Cetiol SB 45 Ingredients Eco Status INCI Weight % (as is) DEHYQUART L80 CETIOL SB 45 LAMESOFT TM Benz COSMEDIA CTH (E) Aloe Extract *(Burgundy Botanical Extracts Iberia S.A.) Preservative Perfume Water, de-ionized Dicocylethyl Hydroxyethylmonium Methosylfate (and)propylene Glycol Butyrospermum Parkii Butter (EU) Butyrospermum Parkii (Shea) Butter (non EU) Glycol Distearate (and) Coco-Glucoside (and) Glyceryl Oleate (and) Glyceryl Stearate Polyquarternium-37 (and) Propylene Glycol Dicaprylate/Dicaprate (and)ppg-1 Trideceth-6 Aloe Barbadensis (EU); Aloe Barbadensis Leaf Extract (US) Parfume Aqua ph-value 3.67 Viscosity [mpas], Brookfield RVT 20 C, spindle 4,10 rpm 15,600 Formulation number: HB-ES/02/204/11B 24

25 Forever Trendy Grease Hair Care Balm with Cegesoft SB & PS 6, HF 62 Ingredients Eko INCI Weight % Status (as is) Funktion CEGESOFT VP Olus Oil (and) Hydrogenated Vegetable Oil Consistency Factor (and) Candellila Cera CETIOL CC Dicaprylyl Carbonate 5.00 Emollient CEGESOFT SB Butyrospermum Parkii Emollient CEGESOFT PS 6 Olus Oil Emollient EUTANOL G Octyldodecanol Emollient CEGESOFT HF 62 Hydrogenated Vegetable Oil 8.00 Consistency Factor Vegetal Oil Jojoba HVJO12 (Fytosan)** Jojoba Oil 5.00 Emollient LIPOFRUCTYL ARGAN LS 9779** Argania Spinosa Oil 5.00 Active COVIOX T90 EU C Tocopherol 0.50 Active Viscosity ( Brk RVT, TE, Speed 4, 25 C) 250, 000 mpa.s ** Ingredients proceeding from Organic Farming ( and ( Formulation number: FR

26 Natural Oils and Waxes for more natural solutions in. 26

27 27 Back-up

28 Naturalness indicator 100 % natural, renewable feedstocks synthetic feedstocks Only physical purification by water/alcohol or energy Chemically processed, catalyst or reaction aids used Renewable & synthetic building blocks combined in a chemical process Chemically processed 70% natural based C < 70% natural based C Natural Natural modified Eco Cognis Hybrids Ecohybrids Hybrids Synthetics * All calculations exclude catalyst, preservatives and reaction aids 28

29 DISCLAIMER This document, or any answers or information provided herein by BASF, does not constitute a legally binding obligation of BASF. While the descriptions, designs, data and information contained herein are presented in good faith and believed to be accurate, they are provided for your guidance only. Because many factors may affect processing or application/use, we recommend that you make tests to determine the suitability of a product for your particular purpose prior to use. It does not relieve our customers of the obligation to perform a full inspection of the products upon delivery or any other obligation. The claims and supporting data provided in this publication have not been evaluated for compliance with any jurisdiction s regulatory requirements and the results reported may not be generally true under other conditions or in other matrices. Users must evaluate what claims and information are appropriate and comply with a jurisdiction s regulatory requirements. NO WARRANTIES OF ANY KIND, EITHER EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA, OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA, OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERM SAND CONDITIONS OF SALE. 29 BASF Personal Care

30 30 BASF Personal Care

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